EP0311796B1 - Procédé de traitement au mouillé de matières en bandes - Google Patents
Procédé de traitement au mouillé de matières en bandes Download PDFInfo
- Publication number
- EP0311796B1 EP0311796B1 EP88114905A EP88114905A EP0311796B1 EP 0311796 B1 EP0311796 B1 EP 0311796B1 EP 88114905 A EP88114905 A EP 88114905A EP 88114905 A EP88114905 A EP 88114905A EP 0311796 B1 EP0311796 B1 EP 0311796B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- liquor
- web
- moisture content
- salt
- treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000011282 treatment Methods 0.000 title claims description 36
- 238000000034 method Methods 0.000 title claims description 18
- 239000000463 material Substances 0.000 title claims description 15
- 239000000975 dye Substances 0.000 claims description 26
- 150000003839 salts Chemical class 0.000 claims description 20
- 239000000982 direct dye Substances 0.000 claims description 10
- 238000010014 continuous dyeing Methods 0.000 claims description 3
- 239000004753 textile Substances 0.000 claims description 3
- 239000000985 reactive dye Substances 0.000 claims description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims 1
- 239000003513 alkali Substances 0.000 claims 1
- 235000002639 sodium chloride Nutrition 0.000 description 17
- 238000004043 dyeing Methods 0.000 description 16
- 239000004744 fabric Substances 0.000 description 7
- 239000000080 wetting agent Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- PGYZAKRTYUHXRA-UHFFFAOYSA-N 2,10-dinitro-12h-[1,4]benzothiazino[3,2-b]phenothiazin-3-one Chemical compound S1C2=CC(=O)C([N+]([O-])=O)=CC2=NC2=C1C=C1SC3=CC=C([N+](=O)[O-])C=C3NC1=C2 PGYZAKRTYUHXRA-UHFFFAOYSA-N 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
- 238000010924 continuous production Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 238000010025 steaming Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 206010066901 Treatment failure Diseases 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 229910021538 borax Inorganic materials 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- 238000009988 textile finishing Methods 0.000 description 2
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 206010016256 fatigue Diseases 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000000988 sulfur dye Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B21/00—Successive treatments of textile materials by liquids, gases or vapours
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
- D06B3/18—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
Definitions
- the invention relates to a method according to the preamble of claim 1.
- the starting point of the invention has been problems which have been pending for a long time in continuous dyeing with direct dyes (noun dyes) (see Fischer-Bobsien "International Lexicon textile finishing + border areas” 4th edition 1975, columns 419-422).
- the dyeing liquor can be applied in a foulard, so that the web is passed through the larger amount of dyeing liquid in the pool of the foulard. This has resulted in unavoidable end processes, both at the beginning and at the end of the web.
- parts of the fleet are towed out of the web, which cause a corresponding depletion of the fleet, which must be readjusted.
- the invention is based on the object of designing a method in such a way that a uniform treatment failure occurs over the length of the web.
- the method is primarily considered for the treatment of flat fabrics.
- the first treatment liquor which is either the salt liquor or the color liquor, the other liquor following in the subsequent second step, is applied in some way and then squeezed to 60 to 120%.
- the moisture values always relate to the amount of treatment liquor in relation to the dry weight of the web to which the treatment liquor has been applied.
- a value of 120% is the upper limit of what can still be squeezed evenly in a squeezing device with interacting rollers; at higher moisture contents, the squeezing mechanism would have to be driven with line pressures so low that the uniformity of the squeezing would no longer be guaranteed and there would even be a risk of the rollers lifting off from one another in certain areas.
- the second treatment liquor (color liquor or salt liquor, depending on what has been applied beforehand) is now applied to the web loaded with the specified amount of moisture, in a special way.
- the material web should not be led through a larger fleet, in which there is a risk of concentration changes due to the amount of treatment agent carried out by the material web.
- the second treatment fleet when the second treatment fleet is applied, the web should only be in contact with the smallest possible amount of liquor, which is very quickly absorbed and transported away by the web and which is accordingly constantly renewed or supplemented by introducing fresh treatment fleets.
- Fresh liquor is therefore always applied to the web on both sides, through which no longer lengths of the web have yet passed. In this way, changes in concentration in the amount of treatment liquor in contact with the material web and corresponding differences in treatment failure can be minimized.
- the second treatment liquor is not squeezed off after application. By squeezing, no total moisture content can be set evenly, which is significantly above 120%. If squeezed after the application of the second treatment fleet, it would at best be possible to add a few 10% of the second treatment fleet, which in many cases is too little for the interaction of the two treatment fleets and the failure of the treatment. For this reason, the web is stripped off after the second treatment liquor has been applied, so that the same amount of treatment liquid can be added in the order of magnitude as in the first application and total moisture contents can be achieved which are in the range of what the web can hold in terms of moisture at all without the moisture dripping from the web or runs down on it.
- Such loads of liquor which have been pushed to the limits of the drip-free moisture content, are advantageous for many treatments, because this gives great water mobility on the web and the transport of the treatment agents between the two fleets and in particular the drawing up of the treatment agents from the entire fleet onto the fibers in the steaming step that generally follows the order.
- a continuous process for dyeing a textile web in which it is provided with a first treatment liquor, partially dehumidified and then passed through an intermediate application unit with another treatment liquor, is known per se from DE-AS 10 78 527.
- the known design is also out of the question for reasons of the required order quantities.
- the gusset applicator comprises two rollers arranged at the same height, between which the web is passed from top to bottom, passing through the treatment liquor in the gusset between the rollers to a certain low height before it passes through the nip. Since the rollers have to seal the gusset downwards, they have to rest against each other with a certain line force, which inevitably means that the web is squeezed vigorously and higher order quantities are in principle not possible.
- a preferred application example of the method according to the invention is the subject of claim 2.
- Gusset application devices with which the application of the dyeing liquid from a small liquor stock and the subsequent stripping can be realized in a gap are known per se from FR-PS 13 81 081.
- the invention does not lie in the gusset application device as such, but in the combination of an impregnation device with squeezing with an impregnation device with very little liquor content, in which subsequently stripped, ie a relatively large amount of liquor is left evenly on the web.
- An application device with stripping is also apparent from DE-OS 20 36 520.
- the web passes a container filled with treatment liquor, is deflected upward and passes through the gap between two horizontally opposite, rotatable, fixedly supported inflatable tubes, where the excess liquor is wiped off.
- an embodiment of the invention is shown in the form of a device designated 100 as a whole for dyeing a flat fabric made of cotton with direct dyes.
- the material web 1 is first passed through a padder 10 which forms the first application device and which comprises a plunge pool 2 which, with a width of the material web 1 of 1.80 m, comprises 30 to 60 l of a salt liquor 3, through which the material web in the manner shown is passed through a deflection roller 4, in order then to be directed vertically upwards and to be squeezed into the nip 5 between the nip rollers 6 and 7 to a moisture content of 70 to 90% by weight of the dry fabric web 1.
- the material web loaded with this moisture is then deflected vertically downwards on a deflection roller 8 and thus passes into the gusset application device 20 which forms the second application device are essentially flat and slightly inclined to the web, ie approach it in the running direction.
- the walls 11, 12 are connected to one another outside the edges of the material web 1, so that an upright, funnel-like trough 9 is formed, which can be filled with a treatment liquid 13 up to a selectable low fill level.
- oblong recesses 15, 16 extending across the width of the material web are formed, in which inflatable pressure hoses 17, 18 are arranged.
- the fabric web is slid through the gap 19 between the tubes 17, 18.
- the treatment liquor 13, which in the exemplary embodiment is a dyeing liquor with direct dyes, received in the trough 9 is stripped down to a total moisture content determined by the pressure in the tubes 17, 18. This total moisture content is in the range of about 100 to 200%, i.e. the same amount of treatment liquor as that which has already been applied in the foulard 10 is added again in the gusset application device 20.
- the level in the trough 9 is kept very low. With a web width of 1.80 m and the corresponding width of the trough 9 there are, for example, 4 to 8 l of the treatment liquor 13 in the trough 9. This amount would only suffice for a few meters of web 1 and would be used up very quickly. For this reason, the treatment liquor 13 is constantly supplied fresh by a feed device 14 and is kept in the trough 9 at a constant, albeit low, level. A significant change in the concentration of the treatment liquor 13 by treatment agents carried along by the material web 1 cannot therefore occur. Except for very small processes of the order of magnitude from 3 to 5 m, the entire length of the web 1 is colored evenly.
- the material web 1 treated in this way now immediately moves into a damper 30 and then into a washing device 40 provided with several compartments.
- a flat fabric made of cotton with a weight per unit area of 200 g / m 2 was provided in accordance with the prior art in a foulard without the addition of salt with the following dyeing liquor and then steamed in the steamer for 2 minutes: 3.0 ml / l Wetting agent 2.0 ml / l Blocking aids 1.0 g / l Oxidizing agent 0.5 ml / l ventilator 7.7 g / l Direct blue I 2.3 g / l Direct blue II
- the fleet order was 85%, the working speed 30 m / min, the web width 1.8 m. The result was a blue-colored web with end drains of the order of 100 m, which had to be used for other purposes.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Treatment Of Fiber Materials (AREA)
- Coloring (AREA)
- Professional, Industrial, Or Sporting Protective Garments (AREA)
Claims (5)
- procédé en continu de teinture d'une nappe de produits textiles selon lequel on applique sur la nappe un bain de teinture et de sel et on humidifie la nappe en partie à une valeur déterminée, procédé caractérisé en ce que,- le sel est appliqué dans un bain de traitement distinct du bain de teinture,- la nappe de produits après application du premier bain de traitement (bain de teinture ou bain de sel) est exprimée jusqu'à une teneur en humidité de 60 à 120 %,- sur la nappe encore humide, on applique le second bain de traitement de façon que la nappe soit toujours en contact qu'avec une petite réserve de liquide, épuisée en continu et renouvelée au fur et à mesure de son épuisement,- et en ce qu'on humidifie partiellement la nappe de produits directement de manière qu'en glissant à travers la fente avec au moins une délimitation élastique adjacente on arrive à une teneur totale en humidité de 100 à 200 %.
- Procédé selon la revendication 1, caractérisé en ce que,- on applique un bain de sel et un bain de teinture à colorants directs,- on applique tout d'abord un premier bain et on exprime à une teneur en humidité de 70 - 90 %,- puis on applique le second bain,- puis on racle la nappe à une teneur totale en humidité de 130 à 160 %.
- Procédé selon la revendication 1, caractérisé en ce qu'on applique un bain de sel et un bain de teinture à colorants au souffre et,- on applique tout d'abord le premier de ces bains et on exprime jusqu'à une teneur en humidité de 70 - 90 %,- puis on applique le second bain,- puis on racle la nappe pour arriver à une teneur totale en humidité comprise entre 160 et 200 %.
- Procédé selon la revendication 1, caractérisé en ce que,- on applique un bain d'alcali le cas échéant avec du sel et un bain de teinture avec des colorants réactifs,- on applique tout d'abord un premier bain, puis on exprime jusqu'à une teneur en humidité de 70 - 100 %,- puis on applique le second bain,- et on racle la nappe de produits jusqu'à une teneur totale en humidité de 160 à 200 %.
- Procédé selon l'une des revendications 1 à 4, caractérisé en ce que les deux bains de traitement sont appliqués à la même température.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3733997 | 1987-10-08 | ||
DE3733997A DE3733997C3 (de) | 1987-10-08 | 1987-10-08 | Verfahren und Vorrichtung zum kontinuierlichen Färben einer textilen Warenbahn |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP92101276.1 Division-Into | 1992-01-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0311796A1 EP0311796A1 (fr) | 1989-04-19 |
EP0311796B1 true EP0311796B1 (fr) | 1992-12-09 |
Family
ID=6337866
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP88114905A Expired - Lifetime EP0311796B1 (fr) | 1987-10-08 | 1988-09-13 | Procédé de traitement au mouillé de matières en bandes |
EP19920101276 Withdrawn EP0483114A3 (en) | 1987-10-08 | 1988-09-13 | Method and apparatus for continuously bleaching a textile sheet-like material |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19920101276 Withdrawn EP0483114A3 (en) | 1987-10-08 | 1988-09-13 | Method and apparatus for continuously bleaching a textile sheet-like material |
Country Status (8)
Country | Link |
---|---|
US (2) | US4878365A (fr) |
EP (2) | EP0311796B1 (fr) |
JP (1) | JPH01124669A (fr) |
BR (1) | BR8805186A (fr) |
DD (1) | DD282934A5 (fr) |
DE (1) | DE3733997C3 (fr) |
ES (1) | ES2036642T3 (fr) |
RU (1) | RU2050427C1 (fr) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3733997C3 (de) * | 1987-10-08 | 1996-12-19 | Kuesters Eduard Maschf | Verfahren und Vorrichtung zum kontinuierlichen Färben einer textilen Warenbahn |
DE3923318A1 (de) * | 1989-07-14 | 1991-01-17 | Kuesters Eduard Maschf | Verfahren und anlage zur vorbehandlung von bahnfoermigem, einen pol aufweisendem textilgut, insbesondere teppichware, vor dem faerben |
AT398089B (de) * | 1989-09-12 | 1994-09-26 | Johannes Zimmer | Verfahren zum färben mit reaktivfarbstoffen von textilen flächengebilden |
DE4005980A1 (de) * | 1990-02-26 | 1991-08-29 | Kuesters Eduard Maschf | Kontinue-verfahren zur behandlung von textilen warenbahnen und entsprechende einrichtung |
FR2661927B1 (fr) * | 1990-05-11 | 1994-02-18 | Sandoz Sa | Procede pour le mercerisage et la teinture au mouille de materiau cellulosique humide. |
DE19531663C2 (de) * | 1995-08-29 | 1997-08-14 | Kuesters Zittauer Maschf Gmbh | Vorrichtung zum Mercerisieren einer textilen Warenbahn |
DE19940608C1 (de) * | 1999-08-27 | 2001-05-10 | Kuesters Eduard Maschf | Verfahren zum Herstellen eines Musters eines Behandlungsausfalls an einer textilen Warenprobe |
US7398660B2 (en) * | 2005-09-14 | 2008-07-15 | Zzakey Technologies Ltd | Dyeing apparatus and method therefor |
DE102009013979A1 (de) | 2009-03-19 | 2010-09-23 | Dürr Systems GmbH | Elektrodenanordnung für einen elektrostatischen Zerstäuber |
CN102321959B (zh) * | 2011-09-01 | 2013-03-13 | 绍兴县永通丝绸印染有限公司 | 一种面料上浆机 |
CN113564845B (zh) * | 2021-07-12 | 2023-05-23 | 晋江市宏兴服饰织造有限公司 | 一种保暖弹性的泳装面料生产设备及其制备工艺 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1071035B (fr) * | 1959-12-17 | |||
US521816A (en) * | 1894-06-26 | reffitt | ||
DE107527C (fr) * | 1898-01-17 | |||
US1979818A (en) * | 1931-06-09 | 1934-11-06 | Samcoe Holding Corp | Method of dyeing |
US2460206A (en) * | 1945-12-07 | 1949-01-25 | Du Pont | Method of continuous dyeing |
US2784583A (en) * | 1953-07-24 | 1957-03-12 | Dungler Julien | Foulards or padders |
DE1054048B (de) * | 1956-11-02 | 1959-04-02 | Benteler Werke Ag | Dreiwalzenfoulard |
DE1078527B (de) * | 1957-03-11 | 1960-03-31 | Haas Friedrich Maschf | Vierwalzenfoulard |
FR1212022A (fr) * | 1957-07-15 | 1960-03-21 | Muller Fichter & Cie X | Foulard de teinture |
NL295000A (fr) * | 1962-07-05 | |||
FR1381081A (fr) * | 1964-01-30 | 1964-12-04 | Kleinewefers Soehne J | Dispositif pour faire passer à travers une enceinte une matière quelconque, notamment une matière textile, en bande large ou en écheveau avec des traversées étanches à la pression |
DE2036520A1 (en) * | 1970-07-23 | 1972-02-03 | Vepa Ag, Basel (Schweiz) | Dye padding process - squeezing of excess liquor by passing between inflatable tubes |
DE2116485A1 (en) * | 1971-04-05 | 1972-10-12 | Vepa Ag, Riehen (Schweiz) | Washing endless material - in a continuous washing appliance suitable for strands and widths of textile material |
US4193762A (en) * | 1978-05-01 | 1980-03-18 | United Merchants And Manufacturers, Inc. | Textile treatment process |
US4202774A (en) * | 1978-05-24 | 1980-05-13 | Dorr-Oliver Incorporated | Flow distributor for fluid bed biological reactor |
JPS5567059A (en) * | 1978-11-13 | 1980-05-20 | Santo Tekkosho Kk | Continuous liquid impregnating apparatus for cloth |
DE3037156A1 (de) * | 1980-10-01 | 1982-05-06 | Hoechst Ag, 6000 Frankfurt | Verfahren zur kontinuierlichen, gleichmaessigen auftragen von faerbeflotten auf nasse, textile warenbahnen |
CH668446A5 (de) * | 1985-05-10 | 1988-12-30 | Benninger Ag Maschf | Vorrichtung zum behandeln einer laufenden textilbahn in einem fluessigkeitsbad. |
EP0286767B1 (fr) * | 1987-04-16 | 1991-07-31 | Triatex International | Procédé et installation pour l'application en continu des liquides sur une matière en bande absorbante compressible |
DE3733997C3 (de) * | 1987-10-08 | 1996-12-19 | Kuesters Eduard Maschf | Verfahren und Vorrichtung zum kontinuierlichen Färben einer textilen Warenbahn |
-
1987
- 1987-10-08 DE DE3733997A patent/DE3733997C3/de not_active Expired - Fee Related
-
1988
- 1988-09-13 EP EP88114905A patent/EP0311796B1/fr not_active Expired - Lifetime
- 1988-09-13 ES ES198888114905T patent/ES2036642T3/es not_active Expired - Lifetime
- 1988-09-13 EP EP19920101276 patent/EP0483114A3/de not_active Withdrawn
- 1988-10-03 RU SU884356584A patent/RU2050427C1/ru active
- 1988-10-06 DD DD88320540A patent/DD282934A5/de not_active IP Right Cessation
- 1988-10-07 BR BR8805186A patent/BR8805186A/pt not_active IP Right Cessation
- 1988-10-07 JP JP63253648A patent/JPH01124669A/ja active Pending
- 1988-10-11 US US07/255,611 patent/US4878365A/en not_active Expired - Fee Related
-
1989
- 1989-10-16 US US07/422,253 patent/US4997453A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
ES2036642T3 (es) | 1993-06-01 |
EP0483114A2 (fr) | 1992-04-29 |
EP0483114A3 (en) | 1992-07-22 |
JPH01124669A (ja) | 1989-05-17 |
DE3733997C2 (fr) | 1990-10-04 |
DD282934A5 (de) | 1990-09-26 |
DE3733997C3 (de) | 1996-12-19 |
BR8805186A (pt) | 1989-05-23 |
US4878365A (en) | 1989-11-07 |
RU2050427C1 (ru) | 1995-12-20 |
DE3733997A1 (de) | 1989-04-27 |
EP0311796A1 (fr) | 1989-04-19 |
US4997453A (en) | 1991-03-05 |
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