EP0299020B1 - Dispositif de traitement des peaux par humidification - Google Patents
Dispositif de traitement des peaux par humidification Download PDFInfo
- Publication number
- EP0299020B1 EP0299020B1 EP88900819A EP88900819A EP0299020B1 EP 0299020 B1 EP0299020 B1 EP 0299020B1 EP 88900819 A EP88900819 A EP 88900819A EP 88900819 A EP88900819 A EP 88900819A EP 0299020 B1 EP0299020 B1 EP 0299020B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- hide
- treatment device
- skin
- treatment
- treatment liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000007788 liquid Substances 0.000 claims abstract description 79
- 238000000034 method Methods 0.000 claims abstract description 21
- 230000008569 process Effects 0.000 claims abstract description 18
- 238000004043 dyeing Methods 0.000 claims abstract description 6
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 230000000149 penetrating effect Effects 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 239000000758 substrate Substances 0.000 claims 7
- 230000035515 penetration Effects 0.000 abstract description 6
- 239000012530 fluid Substances 0.000 description 6
- 238000004040 coloring Methods 0.000 description 4
- 238000011081 inoculation Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 235000013372 meat Nutrition 0.000 description 2
- 230000037368 penetrate the skin Effects 0.000 description 2
- 238000005554 pickling Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 206010000496 acne Diseases 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000002255 vaccination Methods 0.000 description 1
- 229960005486 vaccine Drugs 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C15/00—Apparatus for chemical treatment or washing of hides, skins, or leather
Definitions
- the invention relates to a device for treating hides with liquids in the so-called wet processes, for example liming, pickling, tanning, dyeing or the like, consisting of a liquid-permeable base which absorbs the skin relentlessly and a treatment device which can be placed essentially tightly on the top of the skin , by means of which the treatment liquid is penetrated into the skin under high pressure.
- those wet treatment processes are those treatment stages in which the skin is treated with dissolved chemicals with a high fluid requirement.
- Dyeing processes could already be improved somewhat (DE-PS 822 060) in that the skins lie on a belt and are guided past a paint spraying device, which at least reduced the difficulties in manipulating the skin.
- the need for coloring liquid is considerable, since it is sprayed onto the skin at a distance, a large amount of coloring liquid does not come into contact with the skin and, furthermore, a considerable exposure time must be provided in order to penetrate the coloring liquid into the skin to enable. Coloring through is not possible in this way or only with great expenditure of time.
- the treatment liquid In the other aforementioned wet processes, the treatment liquid must penetrate the skin intensively and completely, which is why it must be in constant contact with the treatment liquid over a long period of time. In order to enable targeted working with the lowest possible fluid requirement even in these wet processes, it has been proposed (EP-OS 0 009 081) to introduce the treatment fluid into the skin under high pressure in a kind of inoculation process.
- the invention has for its object to improve the aforementioned and aforementioned device in such a way that a uniform penetration of the treatment fluids into the skin is ensured at reduced working pressure.
- the treatment device has a plurality of liquid supply channels arranged approximately perpendicular to the base, which expand over a large area on the underside of the device facing the skin and are arranged to fill the area, and that between the underside of the device and the Skin arranged a net-like pad and the space between the pad, skin, pad and treatment device is essentially sealed off from the outside.
- the feed channels have a comparatively large-area expansion of, for example, several cm 2 in the region of their mouth, these extensions having such a geometric outline and such an arrangement that they connect closely to one another, that is to say they cover a large area overall.
- the mesh-like support is provided on the skin, which on the one hand levels the skin somewhat in this area, and on the other hand for a punctual penetration of the treatment liquid over a larger one Cross section ensures.
- the space between the base, the skin, the support and the treatment device can be sealed off from the outside. This is usually possible in that the parts are moved together in a correspondingly tight manner without the need for separate edge seals.
- the large-area extensions of the feed channels on the underside of the treatment device can have a polygonal or round outline, at the center of which at least one feed channel opens.
- the extensions can, for example, have an outline in the form of equilateral triangles, squares, polygons or circles.
- a likewise mesh-like intermediate layer can also be arranged between the skin and the base in the device according to the invention, in order to allow the treatment liquids which penetrate the skin to run off. Since such an intermediate layer would, however, be too flexible to absorb the treatment pressure present on the other side, an unyielding underlay must also be provided, which then has a plurality of processes arranged next to one another for the treatment liquid penetrating the skin. The excess treatment liquid penetrating the skin thus penetrates through the fine-meshed intermediate layer to the unyielding base, where it is carried away by the processes.
- the mesh-like support and intermediate layer consists of a fine-mesh plastic or metal mesh, which on the one hand has the necessary flexibility to adapt to unevenness in the skin, and on the other hand has the necessary resistance to the working pressure without the mesh size changing under the influence of the working pressure .
- metal mesh fulfills another task, namely to form a support for the skin, which distributes the treatment liquid supplied from the outside uniformly and allows it to penetrate into the skin at points.
- the underside of the treatment device or the extensions arranged there to fill the area can have an extent corresponding to the width or length of the skin, at least in one direction of extension.
- the treatment liquids are introduced into the skin in strips, which in turn is then moved batchwise through the device.
- the skin between the support and the intermediate layer are designed as conveyor belts.
- the skin can therefore be placed between the two conveyor belts and transported between them into the device, so that the manual tasks required for the entire treatment are limited to the task of the skin at the inlet of the conveyor belts and the removal of the skin at the outlet of the conveyor belts. If necessary, the skin can also be thrown off at the conveyor belt outlet.
- the base is designed as a table and can be raised against the treatment device.
- the skin is introduced between the support and the treatment device by means of the metal nets designed as conveyor belts, then the table is raised against the treatment device with simultaneous pressing of the intermediate layer, skin and support against the treatment device and with a tight seal to the outside, whereupon the treatment liquid is passed over the feed channels can be fed.
- the base is designed as a circumferential link belt, between the links of which the treatment liquid can run off.
- the link belt forms a sufficiently rigid support for the skin, which is also transported here between a fine-meshed intermediate layer and a support.
- the link belt can be trough-shaped in the area of the treatment device and the underside of the treatment device can be curved to fill the trough.
- the skin between the support and the intermediate layer is conveyed into the trough between the treatment device and the link belt and can in turn be treated batchwise, but advantageously also in a continuous flow.
- the treatment device is designed as a rotating cylinder, on the circumference of which the extensions of the feed channels are arranged, the feed channels being controllable into their open position only in the region of the trough.
- the extensions on the underside of the treatment device always remain in the same position relative to the skin, so that the exposure time of the treatment liquid can only be controlled by the transport speed through the trough gap. In this way, skin to skin can be moved through the treatment device.
- the fine-meshed support and intermediate layer outside the treatment device is at least one cleaning device, e.g. a spray device is assigned, by means of which impurities, which stuck between the meshes and originate from the skin, can be removed.
- the spray device can be operated with pressurized water or compressed air. In this way it is ensured that, above all, the fine-meshed support has free mesh cross-sections before each entry into the device, in order to enable the treatment fluids to be distributed correctly.
- the device according to the invention is further characterized by a collecting container which holds the excess treatment liquid penetrating the skin and from which the liquid can be recirculated.
- the device according to the invention makes it possible to work with highly concentrated treatment liquids and these treatment liquids do not or only minimally change their composition during the treatment, the excess of the treatment liquid can be reused.
- a purely mechanical preparation e.g. filtering out the treatment liquid so that it can be fed back to the treatment device. Only the losses caused by penetration into the skin can be compensated for in terms of quantity. Waste water does not occur in large quantities, at least, since only treatment liquid that can no longer be used for chemical and / or physical reasons must be removed. These are extremely small quantities with well-known ingredients that are easy to control in waste disposal.
- the treatment device is assigned a large-volume pressure container for the treatment liquids, which is provided on the one hand with the collecting container and on the other hand with a feed line for fresh treatment liquid.
- the pressure vessel e.g. a wind boiler
- the pressure container is fed on the one hand from the collecting container with the recirculated treatment liquid, and on the other hand with fresh treatment liquid to compensate for the liquid remaining in the skin and any liquid otherwise lost.
- the treatment device can also be fed directly with pumps.
- the device in the embodiment according to FIG. 1 has, as essential components, a base 1 and a treatment device 2 arranged above it, the base 1 being designed as a kind of table 3 in a rigid and unyielding construction.
- the top of the table 3 has several outlets 4 for the treatment liquid.
- the treatment device 2 consists of a pressure-resistant housing 5 with a central feed channel 6 and a plurality of feed channels 7 connected to it, which run approximately perpendicular to the surface of the table 3 and are arranged in parallel rows next to one another and one behind the other. They are connected to the central feed line 6 via a distribution line 8. This is provided with a valve 9 to shut off the entire treatment device 2. Furthermore, each individual feed channel 7 has a schematically indicated shut-off valve 10.
- the feed channels 7 open out into expansions 11 which are large in relation to the channel cross section and which are openly arranged on the underside 12 of the treatment device 2.
- valves 10 in the feed channels 7 can be designed differently, for example mechanically operated piston valves 13, as shown in the middle version, or electromagnetic valves, as indicated on the right.
- each feed channel 7 can also have only one orifice 13 ', in which case only the central shut-off valve 9 in the central feed line 6 provides for switching on and off.
- the piston valve 13 has a plunger 13 ′′ on an extension, which serves to cover part of the support 27 described later, if there is, for example, no skin underneath, on the one hand to prevent the pressure from decreasing too quickly at this point and on the other keep fluid consumption as low as possible.
- the processes 4 on the top of the table-like base 3 can be directed to a central one. Drain channel 14 may be connected.
- an endless upper belt 15 and also an endless lower belt 16 run between the table-like base 1 and the treatment device 2, between which the skin is applied at 17.
- Upper belt and lower belt are guided over several deflection rollers and at least one drive roller each.
- At least the upper band 15 consists of a fine-meshed metal mesh and serves as a support for the skin in the area of the treatment device 2.
- the lower band 16 can also be a fine-mesh metal net, but possibly also another permeable band.
- the skin given up at 17 is retracted between the upper band 15 and lower band 16 between the table-like base 1 and the treatment device 2 and brought into position by stopping the bands.
- the design is such that the upper belt 15 is located directly below the underside 12 of the treatment device 2 and, as it were, the extensions 11 of the feed channels 7 are limited at the bottom.
- the gap between the base 1 and the treatment device 2 is closed and sealed to the outside, in that in this embodiment the base 1 can be displaced in the direction of the arrow 18, for example by means of a pressure cylinder, and against the lower belt 16 serving as an intermediate layer in the area of the treatment device skin lying thereon and the upper band 15 forming the support act in such a way that they are pressed tightly against the treatment device 2.
- the treatment liquid is then fed in via the central feed channel 6 or the valves 10 are opened. After sufficient exposure time, during which the excess and skin-penetrating treatment liquid is drained off via the outlets 4 and the channel 14 (FIG. 2), the table-like support 1 is lowered, the belts 15, 16 are transported at least one skin length further and at the same time the next one Skin inserted into the device.
- the upper and lower belts 15, 16 pass through a pinch gap formed by two rollers 19, 20, in which the excess treatment liquid which causes the skin to swell is squeezed out. Finally, the upper belt 15 and the lower belt 16 each pass a spray device 21, by means of which any impurities are removed from the meshes of the belts.
- the trough can be equipped with chemical-physical sensors 23, for example p "knives, in order to determine the chemical-physical data of the excess treatment liquid and the degree of its reusability.
- the trough-shaped collecting container 22 can be equipped with a device 24 for maintaining a certain temperature of the The excess treatment liquid can be recirculated via an outlet 25.
- the extensions 11 are arranged on the underside 12 of the treatment device 2 (FIG. 1) to fill the entire area.
- the extensions 11 have an outline in the form of equilateral triangles, in the center of which the feed channels 7 open out.
- Figure 3 b) shows extensions 11 with a square outline and again centrally opening feed channels 7, while
- Figure 3 c) shows extensions 11 with a circular outline and feed channels 7 ending in their center.
- the extensions 11 in the embodiment according to FIG. 3 d) are designed as polygons, specifically in the form of regular hexagons. Instead of only one feed channel 7, a plurality of channels can of course open at each extension 11, with a symmetrical arrangement with respect to the outline of the extension being favorable.
- the device is shown in another embodiment.
- the pad 1 consists of a link belt 30 which is guided over deflection rollers so that its upper run 31 can be deformed into a trough shape.
- the individual links of the link belt 30 have drain gaps between them through which the excess treatment liquid can drain.
- the treatment device 2 is arranged above the link belt 30 in the form of a circular cylinder 32, which is provided over its entire circumference with extensions 11 of feed channels, not shown.
- the treatment liquid can be fed into the cylinder 32 via a central feed line and can be supplied to the extensions 11 via corresponding radial feed channels.
- the feed channels each have a shut-off valve which can be opened and closed by means of an actuating element 33. can.
- a control cam 34 is provided, which is located only on the track section of the rotatable cylinder 32, which coincides with the link belt 30.
- the treatment of the skin takes place in this path section, in which the upper run 31 of the link belt 30 is deflected in a trough-shaped manner.
- a support formed by an upper belt 33 is provided, as is also a lower belt 34.
- the skin is applied between the upper band 33 and lower band 34 at 35 and transported into the gap between the treatment device 2 and the link belt 30.
- FIG. 5 shows part of the supply device for the treatment device in the form of a flow diagram. It has a wind boiler 36 as a storage container for the treatment liquid, which is equipped with a pressure transmitter 37 and a safety valve 38. The level of the treatment liquid is controlled between a maximum level 39 and a minimum level 40 within the wind chamber 36.
- the wind boiler 36 is connected to the treatment device 2 via a supply line 41 and is also connected to the collecting container 22 via a feed line 42 and to a reservoir 44 which contains fresh treatment liquid via a further feed line 43.
- Pumps 45 and 46 are inserted into the feed lines 42 and 43. Losses of treatment liquid are compensated for via the feed line 43, as are any concentration fluctuations, while the recirculable treatment liquid is conveyed out of the collecting container 22 via the feed line 42.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment Of Fiber Materials (AREA)
Abstract
Claims (16)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT88900819T ATE59413T1 (de) | 1987-01-28 | 1988-01-08 | Vorrichtung zum behandeln von haeuten in nassprozessen. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19873702478 DE3702478A1 (de) | 1987-01-28 | 1987-01-28 | Vorrichtung zum behandeln von haeuten in nassprozessen |
DE3702478 | 1987-01-28 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0299020A1 EP0299020A1 (fr) | 1989-01-18 |
EP0299020B1 true EP0299020B1 (fr) | 1990-12-27 |
Family
ID=6319697
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP88900819A Expired - Lifetime EP0299020B1 (fr) | 1987-01-28 | 1988-01-08 | Dispositif de traitement des peaux par humidification |
Country Status (11)
Country | Link |
---|---|
US (1) | US5000017A (fr) |
EP (1) | EP0299020B1 (fr) |
JP (1) | JPH01502913A (fr) |
KR (1) | KR890700684A (fr) |
AR (1) | AR242265A1 (fr) |
BR (1) | BR8805024A (fr) |
CS (1) | CS266348B2 (fr) |
DE (2) | DE3702478A1 (fr) |
IN (1) | IN168502B (fr) |
WO (1) | WO1988005828A1 (fr) |
YU (1) | YU12588A (fr) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3930767A1 (de) * | 1989-09-14 | 1991-03-28 | Johs Krause Gmbh Maschinenfabr | Vorrichtung zum behandeln von haeuten in nassprozessen |
DE4316008A1 (de) * | 1993-05-13 | 1994-11-17 | Domaga Fa | Verfahren und Vorrichtung zum Auftragen von Flüssigkeiten auf die Lederoberfläche oder ähnliche flache Materialien |
AUPO598197A0 (en) * | 1997-04-03 | 1997-05-01 | Future Tan Pty Ltd | Treatment of hides |
AUPO871397A0 (en) * | 1997-08-22 | 1997-09-18 | Future Tan Pty Ltd | Improved treatment of hides |
DE19961745A1 (de) * | 1999-12-21 | 2001-06-28 | Harald Suese | Druck-Wechsel-Gerbgefäß |
US20050193780A1 (en) * | 2004-03-02 | 2005-09-08 | Giancarlo Cassarino | Apparatus and felt for embossing leather and artificial leather type textiles using high tension |
US6854301B1 (en) | 2004-04-13 | 2005-02-15 | Albany International Corp. | Extended nip press for the leather industry |
KR100861346B1 (ko) | 2008-03-27 | 2008-10-01 | 백철운 | 피혁원단의 습식 가공장치 및 그 가공방법 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE328884C (fr) * | ||||
GB114631A (en) * | 1917-04-06 | 1919-03-06 | Felice Gilardini | Improvements in Apparatus for the Rapid Tanning of Hides and Skins. |
US1363771A (en) * | 1918-04-06 | 1920-12-28 | Gilardini Felice | Process and apparatus for the instantaneous tannage of hides and skins |
GB160422A (en) * | 1919-12-05 | 1921-03-07 | Felice Gilardini | Improvements in apparatus for the rapid tanning of hides and skins |
DE822060C (de) * | 1950-04-20 | 1951-11-22 | Charvo Soc | Verfahren und Vorrichtung zum selbsttaetigen Spritzen von Unterlagen, wie beispielsweise Haeuten, mit Fluessigkeiten, wie Farbloesungen, und deren Trocknung |
US2702229A (en) * | 1951-06-27 | 1955-02-15 | Secotan Inc | Process and apparatus for fluid treatment of pervious sheet materials |
FR1295999A (fr) * | 1961-05-03 | 1962-06-15 | Giralt Baixeras S A | Machine pour le traitement de matière en feuille |
FR1488976A (fr) * | 1965-07-01 | 1967-07-21 | Ct Tech Du Cuir | Appareil pour le traitement de feuilles perméables tels que les peaux animales ou autres |
DE2249369C3 (de) * | 1972-10-09 | 1979-01-18 | Josef Dipl.-Ing. 6000 Frankfurt Busek | Presse zum Entwässern von Flächengebilden, wie Lederhäuten |
SU737463A1 (ru) * | 1977-03-23 | 1980-05-30 | Центральный научно-исследовательский институт кожевенно-обувной промышленности | Установка дл проходной жидкостной обработки кож |
DE2831617A1 (de) * | 1978-07-19 | 1980-01-31 | Arenco Bmd Maschfab | Verfahren zur herstellung gegerbter haeute und felle |
DE3151518A1 (de) * | 1981-12-24 | 1983-07-07 | ERMO Erwin Morlock Automations GmbH, 7516 Karlsbad | Einrichtung zum herstellen von leder |
DE3346923C1 (de) * | 1983-12-24 | 1985-05-02 | Lederfabrik Louis Schweizer GmbH & Co, 7157 Murrhardt | Vorrichtung zum Behandeln von flächigen Gebilden, wie Leder, Häute, Textilien und dgl. |
ATA212285A (de) * | 1985-07-17 | 1988-09-15 | Schmidt Alexander Gmbh | Vorrichtung zum faerben von leder |
-
1987
- 1987-01-28 DE DE19873702478 patent/DE3702478A1/de not_active Withdrawn
-
1988
- 1988-01-08 DE DE8888900819T patent/DE3861436D1/de not_active Expired - Lifetime
- 1988-01-08 JP JP63501023A patent/JPH01502913A/ja active Pending
- 1988-01-08 WO PCT/EP1988/000009 patent/WO1988005828A1/fr active IP Right Grant
- 1988-01-08 EP EP88900819A patent/EP0299020B1/fr not_active Expired - Lifetime
- 1988-01-08 BR BR8805024A patent/BR8805024A/pt not_active Application Discontinuation
- 1988-01-13 IN IN26/CAL/88A patent/IN168502B/en unknown
- 1988-01-22 AR AR88309907A patent/AR242265A1/es active
- 1988-01-25 YU YU00125/88A patent/YU12588A/xx unknown
- 1988-01-27 CS CS88508A patent/CS266348B2/cs unknown
- 1988-09-24 KR KR1019880701162A patent/KR890700684A/ko not_active Application Discontinuation
-
1990
- 1990-07-13 US US07/558,151 patent/US5000017A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE3861436D1 (de) | 1991-02-07 |
JPH01502913A (ja) | 1989-10-05 |
IN168502B (fr) | 1991-04-13 |
AR242265A1 (es) | 1993-03-31 |
EP0299020A1 (fr) | 1989-01-18 |
CS266348B2 (en) | 1989-12-13 |
BR8805024A (pt) | 1989-10-31 |
KR890700684A (ko) | 1989-04-26 |
DE3702478A1 (de) | 1988-08-11 |
US5000017A (en) | 1991-03-19 |
YU12588A (en) | 1989-06-30 |
WO1988005828A1 (fr) | 1988-08-11 |
CS50888A2 (en) | 1989-02-10 |
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CH217021A (de) | Verfahren und Vorrichtung zum Entrinden von Baumstämmen. |
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