EP0080590A2 - Fonte sphéroidale résistant à l'usure et procédé pour sa fabrication - Google Patents

Fonte sphéroidale résistant à l'usure et procédé pour sa fabrication Download PDF

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Publication number
EP0080590A2
EP0080590A2 EP82109487A EP82109487A EP0080590A2 EP 0080590 A2 EP0080590 A2 EP 0080590A2 EP 82109487 A EP82109487 A EP 82109487A EP 82109487 A EP82109487 A EP 82109487A EP 0080590 A2 EP0080590 A2 EP 0080590A2
Authority
EP
European Patent Office
Prior art keywords
cast iron
iron alloy
wear
max
magnesium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP82109487A
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German (de)
English (en)
Other versions
EP0080590A3 (en
EP0080590B1 (fr
Inventor
Hans Jochem Dr. Neuhäuser
Hans-Jürgen Veutgen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Goetze GmbH
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Goetze GmbH
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Filing date
Publication date
Application filed by Goetze GmbH filed Critical Goetze GmbH
Publication of EP0080590A2 publication Critical patent/EP0080590A2/fr
Publication of EP0080590A3 publication Critical patent/EP0080590A3/de
Application granted granted Critical
Publication of EP0080590B1 publication Critical patent/EP0080590B1/fr
Expired legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/04Cast-iron alloys containing spheroidal graphite
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/06Cast-iron alloys containing chromium
    • C22C37/08Cast-iron alloys containing chromium with nickel

Definitions

  • the invention relates to a wear-resistant cast iron alloy of high strength with spherulitic graphite precipitation for the production of machine parts subject to wear, such as piston rings of internal combustion engines, in particular small piston rings with a small radial and / or axial wall thickness, and their manufacturing process.
  • Cast iron alloys for the production of mechanically highly stressed machine parts are special alloys which, in addition to good running and wear properties, good elastic behavior, should also have higher strength properties.
  • Small piston rings in particular, with small diameters of up to 60 mm for example have a lower absolute strength due to small axial wall thicknesses of usually only 1 - 2 mm, and ring fractures occur more frequently, even if they are made from cast iron alloys that are otherwise customary for piston rings with larger diameters are. Special cast iron alloys with higher strength values must therefore be used for such small piston rings.
  • such cast iron alloys contain up to mostly 1.0% chromium, molybdenum, vanadium and copper.
  • the piston rings are cast in a solidifying manner, ledeburitic, and the desired graphite precipitate and the desired structure are obtained by subsequent annealing, quenching and Receive compensation.
  • the tempered carbon obtained during graphitization annealing is produced in spherulitic form, and the rings' strength is increased considerably as a result.
  • the running and wear properties of piston rings made of these alloys are not sufficient, so that the running surfaces of the rings must also be provided with wear protection layers.
  • such cast iron alloys are additionally alloyed with 4.5 to 5.5 percent by weight copper. Copper is then present at these levels in the form of inclusions, which take on the role of more compact graphite precipitates. From these alloys. Cast piston rings can therefore also be used without wear protection layers. However, these special alloys are only suitable for large piston rings in diesel engines, and the strength properties for small piston rings are not sufficient.
  • a cast iron alloy for piston rings with normal spheroidal graphite precipitation which is achieved by special treatment measures, is known which, as alloying elements, contains 1.5 to 4.5% silicon to 3% manganese, up to 3.5% vanadium and to 2 , 5% molybdenum, also up to 2.5% tungsten, up to 1% titanium, up to 2% copper, up to 1% nickel or cobalt and up to 2.5% niobium and / or tantalum.
  • the present invention is therefore based on the object of providing a cast iron alloy with both good wear resistance and good elasticity and high strength, so that it can be used for highly stressed machine parts.
  • the cast iron alloy should above all be used for the manufacture of shatterproof small piston rings without special wear protection of the running surfaces and flank surfaces.
  • Remainder iron including manufacturing-related impurities.
  • the cast iron alloy can contain up to 1.5% aluminum and / or up to 1.0% tin and / or antimony and optionally up to 0.5% the elements boron, zirconium and / or bismuth, especially to increase wear resistance.
  • the structure now appears as a remuneration structure with high martensite proportions.
  • the graphite is fine-grained and spherulitic, and the spherulite number is between 300,000 and 900,000 per cm 2 .
  • very fine graphite spherulites seem to have formed during solidification, but these are not visible, so he knows the cast iron appears staring.
  • these fine precipitates serve as nuclei for the spherulites that form in extremely high numbers, which is 5 to 10 times higher than that of normal spheroidal graphite cast iron alloys.
  • the phosphor phases are not connected in a grid-like manner, but are distributed in a point-like manner in the matrix.
  • Small piston rings with outer diameters of approximately 60 mm, radial wall thicknesses of 50 mm and axial ring heights of 1.5 mm were cast from the alloy according to the invention, thermally treated and machined to usable piston rings.
  • the rings were subjected to engine test runs without prior wear-resistant tread coating. They showed both good wear resistance and good strength, and no rings had broken due to ring breakage or wear damage after running.
  • a cast iron alloy with high wear resistance and high breaking strength has thus been created by the invention.
  • the balanced composition of the alloying elements ensures good sliding and running properties, even though the graphite is extremely fine-grained.
  • the extremely fine distribution of the spherulites in turn improves the strength and elongation properties of the workpieces.
  • the alloy according to the invention is preferably to be used for the production of small piston rings with a small radial wall thickness, it can also be used for similarly stressed and / or dimensioned machine parts. This can also be sealing strips for rotary piston engines or extremely thin-walled and / or extremely loaded agents - and big piston rings.
  • 35 small piston rings with a blank dimension of 55.6 mm outer diameter, 48.6 mm radial wall thickness and 5.2 mm axial pin g height were cast from the melt under ledeburitic white solidification.
  • the rings were then annealed at 950 ° C for 15 minutes, quenched from 1,020 ° C and annealed at 450 ° C.
  • the micrograph 1 shows 100 times Enlargement of graphite excretion in a very fine spherulitic form with a number of spherulites of around 600,000 per square centimeter.
  • Cross section 2 shows the remuneration structure with predominantly martensitic components.
  • the hardness of the rings is 109 to 115 HRB.
  • the rings were then machined to a finished size of 52 x 48 x 1.5 mm.
  • the mean values are

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Pistons, Piston Rings, And Cylinders (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Manufacture Of Alloys Or Alloy Compounds (AREA)
EP82109487A 1981-12-01 1982-10-14 Fonte sphéroidale résistant à l'usure et procédé pour sa fabrication Expired EP0080590B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3147461 1981-12-01
DE3147461A DE3147461C2 (de) 1981-12-01 1981-12-01 Verschleißfeste Gußeisenlegierung hoher Festigkeit mit sphärolithischer Graphitausscheidung, ihr Herstellungsverfahren und ihre Verwendung

Publications (3)

Publication Number Publication Date
EP0080590A2 true EP0080590A2 (fr) 1983-06-08
EP0080590A3 EP0080590A3 (en) 1984-03-07
EP0080590B1 EP0080590B1 (fr) 1986-05-28

Family

ID=6147583

Family Applications (1)

Application Number Title Priority Date Filing Date
EP82109487A Expired EP0080590B1 (fr) 1981-12-01 1982-10-14 Fonte sphéroidale résistant à l'usure et procédé pour sa fabrication

Country Status (4)

Country Link
US (1) US4435226A (fr)
EP (1) EP0080590B1 (fr)
JP (1) JPS58104154A (fr)
DE (1) DE3147461C2 (fr)

Cited By (10)

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EP0576173A2 (fr) * 1992-06-09 1993-12-29 Honda Giken Kogyo Kabushiki Kaisha Acier moulé pour l'usinage
FR2697766A1 (fr) * 1992-11-06 1994-05-13 Tech Ind Fonderie Centre Procédé pour maîtriser, dans un moule de fonderie contre au moins un refroidisseur métallique, la trempe d'une pièce en fonte lamellaire, telle qu'un arbre à cames, un cylindre de laminoir ou autre.
EP0778355A1 (fr) * 1995-12-07 1997-06-11 Mercedes-Benz Ag Composition optimalisée de moulages en fonte grise lamellaire pour disques de freinage de véhicules utilitaires
EP0821073A1 (fr) * 1996-07-25 1998-01-28 Federal-Mogul Burscheid GmbH Alliage de fonte pour la manufacture de segments de piston pour machines à combustion interne
FR2765592A1 (fr) * 1997-07-05 1999-01-08 Daimler Benz Ag Procede pour fabriquer un alliage de fonte a haute teneur en carbone et contenant du niobium alliee et moyen auxiliaire d'alliage approprie
RU2475565C1 (ru) * 2012-02-22 2013-02-20 Юлия Алексеевна Щепочкина Чугун
RU2508418C1 (ru) * 2013-04-17 2014-02-27 Юлия Алексеевна Щепочкина Чугун
EP2924138A1 (fr) * 2014-03-26 2015-09-30 Georg Fischer Eisenguss GmbH Alliage en fonte
CN109609835A (zh) * 2019-01-14 2019-04-12 苏州勤美达精密机械有限公司 一种高强韧耐磨球墨铸铁及其制备工艺和应用
EP3974553A1 (fr) * 2020-09-23 2022-03-30 Tupy S.A. Alliage de fonte vermiculaire, bloc et tête de moteur à combustion

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US5139583A (en) * 1992-01-21 1992-08-18 Kawasaki Steel Corporation Graphite precipitated hot-rolled steel plate having excellent bending workability and hardenability and method therefor
WO1996038596A1 (fr) * 1993-11-24 1996-12-05 Wing Metal Corporation Fonte graphitique spherique a haute resistance mecanique
DE19525863A1 (de) * 1995-07-15 1997-01-16 Ae Goetze Gmbh Gleitringdichtung für die Laufwerke von Gleiskettenfahrzeugen
DE19525862A1 (de) * 1995-07-15 1997-01-16 Ae Goetze Gmbh Gleitringdichtung für die Laufwerke von Gleiskettenfahrzeugen
DE19537848A1 (de) * 1995-10-11 1997-04-17 Mahle Gmbh Bewehrungsteil, dessen Grundwerkstoff austenitisches Gußeisen ist
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DE19720779C1 (de) * 1997-05-17 1998-10-01 Ae Goetze Gmbh Kolbenring aus Gußeisen
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JP4527304B2 (ja) * 2001-03-13 2010-08-18 アイシン精機株式会社 高強度高靱性球状黒鉛鋳鉄
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DE2001495A1 (de) * 1969-12-30 1972-01-27 Sulzer Ag Verfahren zur Herstellung von Gusseisen mit Kugelgraphit
GB1336919A (en) * 1970-10-30 1973-11-14 Goetzewerke Grey cast iron valve seat ring
DE2428821A1 (de) * 1974-06-14 1975-12-18 Goetzewerke Verschleissfeste gusseisenlegierung mit lamellarer bis knoetchenfoermiger graphitausscheidung
DE2428822A1 (de) * 1974-06-14 1976-01-02 Goetzewerke Sphaerogusseisenlegierung mit erhoehter verschleissbestaendigkeit
DE2456700A1 (de) * 1974-11-30 1976-08-12 Goetzewerke Dichtleiste fuer rotationskolbenmotoren
GB1541947A (en) * 1977-12-22 1979-03-14 Tul Pk Tech I Mash Chill-free foundry iron

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0576173A2 (fr) * 1992-06-09 1993-12-29 Honda Giken Kogyo Kabushiki Kaisha Acier moulé pour l'usinage
EP0576173A3 (en) * 1992-06-09 1994-05-18 Honda Motor Co Ltd Cast steel suitable for machining
FR2697766A1 (fr) * 1992-11-06 1994-05-13 Tech Ind Fonderie Centre Procédé pour maîtriser, dans un moule de fonderie contre au moins un refroidisseur métallique, la trempe d'une pièce en fonte lamellaire, telle qu'un arbre à cames, un cylindre de laminoir ou autre.
EP0778355A1 (fr) * 1995-12-07 1997-06-11 Mercedes-Benz Ag Composition optimalisée de moulages en fonte grise lamellaire pour disques de freinage de véhicules utilitaires
US5894010A (en) * 1995-12-07 1999-04-13 Mercedes-Benz Ag Optimized gray cast iron plate alloy for utility vehicle brake disks
EP0821073A1 (fr) * 1996-07-25 1998-01-28 Federal-Mogul Burscheid GmbH Alliage de fonte pour la manufacture de segments de piston pour machines à combustion interne
FR2765592A1 (fr) * 1997-07-05 1999-01-08 Daimler Benz Ag Procede pour fabriquer un alliage de fonte a haute teneur en carbone et contenant du niobium alliee et moyen auxiliaire d'alliage approprie
RU2475565C1 (ru) * 2012-02-22 2013-02-20 Юлия Алексеевна Щепочкина Чугун
RU2508418C1 (ru) * 2013-04-17 2014-02-27 Юлия Алексеевна Щепочкина Чугун
EP2924138A1 (fr) * 2014-03-26 2015-09-30 Georg Fischer Eisenguss GmbH Alliage en fonte
CN109609835A (zh) * 2019-01-14 2019-04-12 苏州勤美达精密机械有限公司 一种高强韧耐磨球墨铸铁及其制备工艺和应用
EP3974553A1 (fr) * 2020-09-23 2022-03-30 Tupy S.A. Alliage de fonte vermiculaire, bloc et tête de moteur à combustion

Also Published As

Publication number Publication date
JPS58104154A (ja) 1983-06-21
EP0080590A3 (en) 1984-03-07
DE3147461A1 (de) 1983-06-16
EP0080590B1 (fr) 1986-05-28
DE3147461C2 (de) 1983-10-13
US4435226A (en) 1984-03-06

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