EA200700445A1 - Способ гидрирования глицерина - Google Patents

Способ гидрирования глицерина

Info

Publication number
EA200700445A1
EA200700445A1 EA200700445A EA200700445A EA200700445A1 EA 200700445 A1 EA200700445 A1 EA 200700445A1 EA 200700445 A EA200700445 A EA 200700445A EA 200700445 A EA200700445 A EA 200700445A EA 200700445 A1 EA200700445 A1 EA 200700445A1
Authority
EA
Eurasian Patent Office
Prior art keywords
glycerin
hydrogenation
hydrogen
contact
hydrogenated
Prior art date
Application number
EA200700445A
Other languages
English (en)
Other versions
EA010314B1 (ru
Inventor
Майкл Уильям Маршалл Так
Саймон Николас Тилли
Original Assignee
Дэйви Проусесс Текнолоджи Лтд.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Дэйви Проусесс Текнолоджи Лтд. filed Critical Дэйви Проусесс Текнолоджи Лтд.
Publication of EA200700445A1 publication Critical patent/EA200700445A1/ru
Publication of EA010314B1 publication Critical patent/EA010314B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/10—Monohydroxylic acyclic alcohols containing three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Способ гидрирования глицерина, в котором сырье, содержащее глицерин, приводят в контакт с потоком водородсодержащего газа и гидрируют в паровой фазе в присутствии катализатора при температуре примерно 160-260°С, давлении примерно 10-30 бар, соотношении водорода к глицерину от 400:1 до примерно 600:1 и времени контакта примерно 0,01-2,5 с.
EA200700445A 2005-07-15 2006-06-30 Способ гидрирования глицерина EA010314B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB0514593.3A GB0514593D0 (en) 2005-07-15 2005-07-15 Process
PCT/GB2006/050181 WO2007010299A1 (en) 2005-07-15 2006-06-30 Process

Publications (2)

Publication Number Publication Date
EA200700445A1 true EA200700445A1 (ru) 2007-06-29
EA010314B1 EA010314B1 (ru) 2008-08-29

Family

ID=34897311

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200700445A EA010314B1 (ru) 2005-07-15 2006-06-30 Способ гидрирования глицерина

Country Status (19)

Country Link
US (1) US7355083B2 (ru)
EP (1) EP1836147B1 (ru)
JP (1) JP5149796B2 (ru)
KR (1) KR101325084B1 (ru)
CN (1) CN101006036B (ru)
AR (1) AR058013A1 (ru)
AU (1) AU2006252177B2 (ru)
BR (1) BRPI0606159B1 (ru)
CA (1) CA2569622C (ru)
DK (1) DK1836147T3 (ru)
EA (1) EA010314B1 (ru)
ES (1) ES2298101T3 (ru)
GB (1) GB0514593D0 (ru)
MY (1) MY142306A (ru)
NZ (1) NZ551994A (ru)
PL (1) PL1836147T3 (ru)
TW (1) TWI394740B (ru)
WO (1) WO2007010299A1 (ru)
ZA (1) ZA200700897B (ru)

Families Citing this family (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2634712C (en) * 2005-12-21 2015-11-24 Virent Energy Systems, Inc. Catalysts and methods for reforming oxygenated compounds
KR101460807B1 (ko) * 2006-05-08 2014-11-11 바이렌트, 아이엔씨. 폴리올을 제조하는 방법 및 시스템
US7619119B2 (en) 2006-06-07 2009-11-17 The Procter & Gamble Company Processes for converting glycerol to amino alcohols
US7619118B2 (en) 2006-06-07 2009-11-17 The Procter & Gamble Company Process for the conversion of glycerol to propylene glycol and amino alcohols
GB0614823D0 (en) * 2006-07-26 2006-09-06 Davy Process Techn Ltd Process
DE102006050751A1 (de) 2006-10-27 2008-05-08 Clariant International Limited Verfahren zur Herstellung von 1,2-Propandiol durch Hydrogenolyse von Glycerin
MX2009006509A (es) * 2006-12-20 2009-10-28 Virent Energy Systems Inc Sistema reactor para la produccion de productos gaseosos.
DE102007003188B3 (de) 2007-01-22 2008-06-05 Clariant International Ltd. Verfahren zur Herstellung von 1,2-Propandiol durch Hydrogenolyse von Glycerin
MY154790A (en) * 2007-03-08 2015-07-31 Virent Inc Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons
BRPI0701993A2 (pt) * 2007-03-30 2008-11-18 Petroleo Brasileiro Sa mÉtodo para reciclagem e aproveitamento da glicerina obtida da produÇço do biodiesel
CN103159589B (zh) * 2007-04-17 2016-08-10 花王株式会社 多元醇的氢解产物的制造方法
JP5302543B2 (ja) * 2008-01-21 2013-10-02 花王株式会社 多価アルコールの水素化分解物の製造方法
ES2706327T3 (es) * 2007-05-18 2019-03-28 Biofuel Solution I Malmoe Ab Procedimiento en fase gaseosa para la producción de monoalcohol a partir de glicerol
KR100870369B1 (ko) 2007-08-29 2008-11-25 지에스칼텍스 주식회사 프로판디올 제조용 촉매의 제조 방법 및 이를 이용한프로판디올의 제조 방법
CN101918344A (zh) * 2007-08-31 2010-12-15 巴斯夫欧洲公司 通过在两步反应器级联中将甘油氢化制备1,2-丙二醇的方法
PL2200960T3 (pl) * 2007-08-31 2016-04-29 Basf Se Sposób wytwarzania 1,2-propanodiolu przez niskociśnieniowe uwodornianie glicerolu
EP2200959A2 (de) * 2007-08-31 2010-06-30 Basf Se Verfahren zur herstellung von 1,2-propandiol durch hydrierung von glycerin in wenigstens drei hintereinandergeschalteten reaktoren
WO2009057584A1 (ja) 2007-10-31 2009-05-07 Mitsui Chemicals, Inc. プロピレングリコールの製造方法
GB0724232D0 (en) * 2007-12-12 2008-01-23 Davy Process Techn Ltd Process
CN101456791B (zh) 2007-12-13 2012-07-04 中国科学院兰州化学物理研究所 利用生物基甘油生产1,2-丙二醇的方法
JP5305669B2 (ja) * 2008-01-21 2013-10-02 花王株式会社 多価アルコールの水素化分解物の製造方法
JP5612806B2 (ja) * 2008-01-30 2014-10-22 花王株式会社 多価アルコールの水素化分解物の製造方法
AR072446A1 (es) * 2008-03-02 2010-09-01 Dow Global Technologies Inc Proceso de hidrogenacion mejorado
US20090246430A1 (en) 2008-03-28 2009-10-01 The Coca-Cola Company Bio-based polyethylene terephthalate polymer and method of making same
US8378152B2 (en) * 2008-04-30 2013-02-19 Mitsui Chemicals, Inc. Method of producing propylene glycol
DE102008027601A1 (de) 2008-06-10 2009-12-17 Clariant International Limited Verfahren zur Herstellung von 1,2-Propandiol durch Hydrogenolyse von Glycerin
BRPI0803898A2 (pt) * 2008-07-30 2010-11-09 Univ Rio De Janeiro processo catalìtico para a transformação de glicerina em insumos para o setor petroquìmico
JP5555867B2 (ja) * 2008-08-04 2014-07-23 国立大学法人 千葉大学 グリセリンからのグリコール及び１−プロパノールの製造方法
EP2331486A2 (en) * 2008-08-27 2011-06-15 Virent Energy Systems Inc. Synthesis of liquid fuels from biomass
US8071820B2 (en) * 2008-12-23 2011-12-06 Uop Llc Method for converting glycerol to propanol
KR101050058B1 (ko) * 2008-12-31 2011-07-19 서울대학교산학협력단 프로판디올 제조용 촉매의 제조 방법 및 그를 이용한 프로판디올의 제조 방법
US20100189791A1 (en) 2009-01-23 2010-07-29 Teva Pharmaceutical Industries, Ltd. Delayed release rasagiline malate formulation
CN102333591A (zh) 2009-02-25 2012-01-25 格雷斯公司 从丙三醇的氢化制备1，2-丙烷二醇的方法
PL2403894T3 (pl) 2009-03-03 2016-12-30 Opakowanie pochodzenia biologicznego z politereftalanu etylenu i sposób jego produkcji
WO2010150278A2 (en) 2009-06-15 2010-12-29 Ganapati Dadasaheb Yadav; Hydrogenolysis of polyhydroxy alcohols using metal incorporated manganese oxide octahedral molecular sieve as a catalyst
KR20120098584A (ko) * 2009-06-30 2012-09-05 바이렌트, 아이엔씨. 당분 및 당알코올을 변환하기 위한 공정 및 반응기 시스템
WO2011009936A2 (en) 2009-07-24 2011-01-27 Basf Se Process for the preparation of 1,2-propanediol from glycerol
BRPI1000430A2 (pt) 2010-02-24 2011-10-25 Petroleo Brasileiro Sa produção de propilenoglicol a partir de glicerina
DE102010015006A1 (de) 2010-04-14 2011-11-24 Tu Darmstadt Katalysator zur Hydrierung von wässrigen mehrwertigen Alkohollösungen
BR112013023149A2 (pt) * 2011-03-10 2019-09-24 Gtc Technology Us Llc processo para converter glicerina em propilenoglicol
CN102924233B (zh) * 2012-10-20 2015-04-15 青岛科技大学 一种甘油氢解制备丙二醇的方法
AR095195A1 (es) 2013-03-15 2015-09-30 W R Grace & Co -Conn Proceso para la producción selectiva de propanoles por hidrogenación de glicerol
CN107673952A (zh) * 2017-09-26 2018-02-09 龙岩卓越生物基材料有限公司 利用生物甘油制备1,2‑丙二醇及正丙醇的方法

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE524101C (de) * 1926-01-13 1931-05-11 I G Farbenindustrie Akt Ges Verfahren zur UEberfuehrung von hoeherwertigen Alkoholen in niedrigerwertige
BR8204165A (pt) 1981-07-22 1983-07-12 Du Pont Processo para hidrogenolise de pentitois e misturas de pentitois com outros glicois hexitois e misturas de hexitois com outros poliois e poliois para etileno glicol
US4642394A (en) 1985-07-16 1987-02-10 Celanese Corporation Production of propanediols
GB8917862D0 (en) * 1989-08-04 1989-09-20 Davy Mckee London Process
EP0510238A1 (en) 1991-04-26 1992-10-28 NOVAMONT S.p.A. Process for producing lower poliols and mixtures thereof
IT1249955B (it) 1991-07-10 1995-03-30 Menon S R L Procedimento di idrogenazione della glicerina
IT1249956B (it) 1991-07-10 1995-03-30 Menon S R L Procedimento di idrogenazione catalitica della glicerina
IT1256802B (it) 1992-01-31 1995-12-15 Novamont Spa Catalizzatore di idrogenazione, procedimento per la sua preparazione ed impiego, particolarmente per l'drogenazione e/o idrogenolisi di carboidrati e polioli.
DE4238492C2 (de) * 1992-11-14 1995-06-14 Degussa Verfahren zur Herstellung von 1,2- und 1,3-Propandiol
DE4302464A1 (de) 1993-01-29 1994-08-04 Henkel Kgaa Herstellung von 1,2-Propandiol aus Glycerin
DE4442124A1 (de) 1994-11-26 1996-05-30 Basf Ag Verfahren zur Herstellung von Propandiol-1,2
EP0833808B1 (en) 1995-06-20 2000-05-03 Kao Corporation Method for producing alcohol
TW476746B (en) 1997-07-23 2002-02-21 Shell Int Research Hydrogenolysis of glycerol
US6291725B1 (en) 2000-03-03 2001-09-18 Board Of Trustees Operating Michigan State University Catalysts and process for hydrogenolysis of sugar alcohols to polyols
DE60101743T2 (de) 2000-06-20 2004-12-09 E.I. Du Pont De Nemours And Co., Wilmington Katalytische dehydroxylation von diolen und polyolen
US6841085B2 (en) 2001-10-23 2005-01-11 Battelle Memorial Institute Hydrogenolysis of 6-carbon sugars and other organic compounds
JP2003261550A (ja) 2002-03-06 2003-09-19 Sumitomo Chem Co Ltd プロピレンオキサイド及びプロピルアルコールの製造方法
EP2298721B1 (en) 2004-03-25 2014-06-04 Galen J. Suppes Process for producing an antifreeze composition containing lower alcohols and glycerol via alcoholysis of a glyceride

Also Published As

Publication number Publication date
AR058013A1 (es) 2008-01-23
MY142306A (en) 2010-11-15
WO2007010299A1 (en) 2007-01-25
TW200708500A (en) 2007-03-01
US7355083B2 (en) 2008-04-08
KR20080025357A (ko) 2008-03-20
AU2006252177A2 (en) 2008-08-07
AU2006252177B2 (en) 2011-06-23
BRPI0606159A2 (pt) 2009-06-13
EP1836147A1 (en) 2007-09-26
CN101006036A (zh) 2007-07-25
PL1836147T3 (pl) 2013-06-28
CA2569622C (en) 2013-08-27
ES2298101T3 (es) 2013-04-17
ES2298101T1 (es) 2008-05-16
TWI394740B (zh) 2013-05-01
ZA200700897B (en) 2008-07-30
BRPI0606159B1 (pt) 2015-08-11
KR101325084B1 (ko) 2013-11-06
EA010314B1 (ru) 2008-08-29
CA2569622A1 (en) 2007-01-15
DK1836147T3 (da) 2013-04-22
CN101006036B (zh) 2011-09-07
JP2009501203A (ja) 2009-01-15
US20070149830A1 (en) 2007-06-28
NZ551994A (en) 2010-05-28
AU2006252177A1 (en) 2007-02-01
EP1836147B1 (en) 2013-02-20
JP5149796B2 (ja) 2013-02-20
GB0514593D0 (en) 2005-08-24

Similar Documents

Publication Publication Date Title
EA200700445A1 (ru) Способ гидрирования глицерина
AR074367A1 (es) Procedimiento y dispositivo para la generacion de un gas de sintesis bruto
NZ598774A (en) Direct and selective production of ethanol from acetic acid utilizing a platinum/tin catalyst
EA200901458A1 (ru) Каталитическая гидрогенизация диоксида углерода в смесь синтез-газа
EA200800170A1 (ru) Способ конверсии синтез-газа в оксигенаты, содержащие спирты с+
EA201100292A1 (ru) Способ сжижения углеродсодержащего материала с получением жидкого углеводорода
AR063457A1 (es) Procedimiento para producir spinetoram por reduccion selectiva de espinosina factor et- j y et-l
MX2012003651A (es) Catalizador de carburo de tungsteno soportado sobre carbon mesoporoso, preparacion y aplicacion del mismo.
ATE528070T1 (de) Sauerstoffentfernung
MY145762A (en) Method to start a process for producing hydrocarbons from synthesis gas
EA200702485A1 (ru) Удаление диоксида углерода из газового потока
FI3132009T3 (fi) Menetelmä
MX336316B (es) Metodo para producir hidrogeno destinado a su almacenamiento y transporte.
EA200701037A1 (ru) Способ каталитического дегидрирования пропана в пропилен
MY152298A (en) Processfor producing hydrocarbon oil
MY155540A (en) Process for regenerating a catalyst
MY158629A (en) An improved process for hydrogenating alkyl ester(s) in the presence of carbon monoxide
FR2944716B1 (fr) Catalyseur et procede d'oxydation electrochimique du methane
MY171117A (en) A catalyst for treating exhaust gas of natural gas vehicles
DE50213319D1 (ru)
AR081347A1 (es) Procedimiento para la preparacion de gas de sintesis
WO2009011160A1 (ja) 炭化水素油の製造方法
EP1844855A4 (en) CATALYST FOR A CATALYTIC PROCESS FOR THE PREPARATION OF HYDROGEN FROM BIOETHANOL AND / OR ETHANOL, CATALYST PREPARATION METHOD AND USE THEREOF IN THE CATALYTIC PROCESS
MY150274A (en) Process for the production of 1,2-propanediol
WO2010077860A3 (en) Methods for improving syngas-to-ethanol catalyst selectivity

Legal Events

Date Code Title Description
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KZ KG MD TJ TM

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): RU