ATE528070T1 - Sauerstoffentfernung - Google Patents
SauerstoffentfernungInfo
- Publication number
- ATE528070T1 ATE528070T1 AT07705384T AT07705384T ATE528070T1 AT E528070 T1 ATE528070 T1 AT E528070T1 AT 07705384 T AT07705384 T AT 07705384T AT 07705384 T AT07705384 T AT 07705384T AT E528070 T1 ATE528070 T1 AT E528070T1
- Authority
- AT
- Austria
- Prior art keywords
- hydrocarbon
- gas mixture
- free oxygen
- oxygen removal
- hydrogen
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
- B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
- B01J8/0457—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being placed in separate reactors
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00203—Coils
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00504—Controlling the temperature by means of a burner
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00004—Scale aspects
- B01J2219/00006—Large-scale industrial plants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/00038—Processes in parallel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/0004—Processes in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
- C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1258—Pre-treatment of the feed
- C01B2203/1264—Catalytic pre-treatment of the feed
- C01B2203/127—Catalytic desulfurisation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1276—Mixing of different feed components
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Gyroscopes (AREA)
- Industrial Gases (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB0605232.8A GB0605232D0 (en) | 2006-03-16 | 2006-03-16 | Oxygen removal |
PCT/GB2007/050100 WO2007105012A1 (en) | 2006-03-16 | 2007-03-05 | Oxygen removal |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE528070T1 true ATE528070T1 (de) | 2011-10-15 |
Family
ID=36292814
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT07705384T ATE528070T1 (de) | 2006-03-16 | 2007-03-05 | Sauerstoffentfernung |
Country Status (12)
Country | Link |
---|---|
US (1) | US9017642B2 (de) |
EP (1) | EP1993719B9 (de) |
JP (1) | JP5721310B2 (de) |
CN (1) | CN101394922B (de) |
AT (1) | ATE528070T1 (de) |
AU (1) | AU2007226323B2 (de) |
BR (1) | BRPI0708866A2 (de) |
CA (1) | CA2641183C (de) |
ES (1) | ES2373987T3 (de) |
GB (1) | GB0605232D0 (de) |
NO (1) | NO20083689L (de) |
WO (1) | WO2007105012A1 (de) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5274802B2 (ja) * | 2006-09-15 | 2013-08-28 | 株式会社日本触媒 | 酸素除去方法 |
JP5033829B2 (ja) * | 2008-08-27 | 2012-09-26 | 株式会社神鋼環境ソリューション | 消化ガスの脱酸素方法及び装置 |
EP2336083A1 (de) * | 2009-12-17 | 2011-06-22 | Topsøe Fuel Cell A/S | Gasgenerator und Verfahren zur Umwandlung eines Brennstoffs in ein sauerstoffarmen Gases und/oder wasserstoffangereicherten Gases |
GB201000097D0 (en) * | 2010-01-05 | 2010-12-29 | Johnson Matthey Plc | Apparatus and process for treating natural gas |
JP5545719B2 (ja) * | 2010-01-28 | 2014-07-09 | 住友精化株式会社 | メタンを主成分とするガスの処理方法および処理装置 |
CA2709722A1 (en) | 2010-07-15 | 2012-01-15 | Alakh Prasad | Integrated biogas cleaning a system to remove water, siloxanes, sulfur, oxygen, chlorides, and volatile organic compounds |
JP5389753B2 (ja) * | 2010-07-27 | 2014-01-15 | 株式会社日立製作所 | 石炭ガス化ガスのco2分離回収装置 |
JP2012142173A (ja) * | 2010-12-28 | 2012-07-26 | Jx Nippon Oil & Energy Corp | 燃料電池用脱硫システム、燃料電池用水素製造システム及び燃料電池システム、並びに、炭化水素系燃料の脱硫方法及び水素の製造方法 |
CN102161924A (zh) * | 2011-01-25 | 2011-08-24 | 任国平 | 一种煤层气用生物质炭低温脱氧法 |
JP2012211213A (ja) * | 2011-03-30 | 2012-11-01 | Tokyo Gas Co Ltd | バイオガスの精製方法 |
JP2012207145A (ja) * | 2011-03-30 | 2012-10-25 | Sumitomo Seika Chem Co Ltd | メタンを主成分とするガスの処理方法 |
CN103160352B (zh) * | 2013-03-11 | 2014-09-03 | 大连天元气体技术有限公司 | 一种含氧煤层气的脱氧方法 |
US9238601B2 (en) * | 2013-10-15 | 2016-01-19 | Uop Llc | Method for providing oxygen free regeneration gas for natural gas dryers |
DE102014223759A1 (de) * | 2014-11-20 | 2016-05-25 | Wacker Chemie Ag | Entfernung von Sauerstoff aus Kohlenwasserstoff-haltigen Gasgemischen |
US11993514B2 (en) * | 2019-12-06 | 2024-05-28 | Palo Alto Research Center Incorporated | Liquid metal condensate catalyzed hydrocarbon pyrolysis |
WO2023209423A1 (en) * | 2022-04-28 | 2023-11-02 | Kara Technologies Inc. | Method of deoxygenation of a hydrocarbon in the presence of methane-containing gas environment and catalyst structure |
Family Cites Families (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2384065A (en) | 1941-07-18 | 1945-09-04 | Air Reduction | Purification of gases |
GB844971A (en) | 1957-11-26 | 1960-08-17 | Johnson Matthey Co Ltd | Improvements in and relating to the purification of gases or gaseous mixtures |
NL270250A (de) * | 1960-10-19 | |||
US4181503A (en) * | 1978-10-30 | 1980-01-01 | United Technologies Corporation | Process for alternately steam reforming sulfur containing hydrocarbons that vary in oxygen content |
NO152209C (no) | 1982-09-13 | 1985-08-28 | Norsk Hydro As | Fremgangsmaate ved pumping og avgassing av vann |
GB2149391B (en) | 1983-11-10 | 1987-10-07 | Westinghouse Electric Corp | Method for removing dissolved oxygen from aqueous media |
US4579723A (en) | 1985-03-28 | 1986-04-01 | The Boc Group, Inc. | Methods for purifying inert gas streams |
NO158283C (no) | 1986-02-13 | 1988-08-17 | Norsk Hydro As | Fremgangsmaate og anordning for behandling av blandinger vaeske/gass. |
GB8610196D0 (en) | 1986-04-25 | 1986-05-29 | Ici Plc | Sulphur compounds removal |
US4755498A (en) * | 1986-04-30 | 1988-07-05 | International Fuel Cells Corporation | Steam reforming catalyst |
GB8623482D0 (en) | 1986-09-30 | 1986-11-05 | Johnson Matthey Plc | Catalytic generation of hydrogen |
GB8805447D0 (en) * | 1988-03-08 | 1988-04-07 | British Petroleum Co Plc | Chemical process |
EP0391839B1 (de) | 1989-04-05 | 1992-06-03 | GebràDer Sulzer Aktiengesellschaft | Verfahren zum Anfahren eines Prozesses zum Deoxidieren von Wasser, insbesondere von Meerwasser |
GB9022060D0 (en) | 1990-10-10 | 1990-11-21 | Ici Plc | Mercury removal |
US5204075A (en) * | 1991-05-30 | 1993-04-20 | The Boc Group, Inc. | Process for the purification of the inert gases |
US5446232A (en) | 1994-02-14 | 1995-08-29 | Occidental Chemical Corporation | Removing oxygen from hydrocarbon gases |
FR2731693B1 (fr) | 1995-03-16 | 1997-05-23 | Air Liquide | Procede et installation de generation d'azote pour le traitement thermique |
US20020007595A1 (en) | 1997-06-24 | 2002-01-24 | Uli Maier-Roeltgen | Method for reforming hydrocarbons autothermally |
GB9806199D0 (en) | 1998-03-24 | 1998-05-20 | Johnson Matthey Plc | Catalytic generation of hydrogen |
CN1167497C (zh) * | 1998-12-15 | 2004-09-22 | 高级技术材料公司 | 现场处理废气流的装置和方法 |
EP1181241B1 (de) | 1999-05-03 | 2005-08-24 | Nuvera Fuel Cells | Autothermen dampfreformierungsystem mit integrierten shift betten , reaktor für präferentielle oxidation ,hilfsreaktor und systemsteuerungen |
US6280864B1 (en) * | 1999-06-18 | 2001-08-28 | Uop Llc | Control system for providing hydrogen for use with fuel cells |
AU2001249645A1 (en) * | 2000-03-31 | 2001-10-15 | The Regents Of The University Of Michigan | Transition metal carbides, nitrides and borides and their oxygen containing analogs useful as water gas shift catalysts |
GB0223300D0 (en) * | 2002-10-08 | 2002-11-13 | Bp Chem Int Ltd | Process |
NO20030647D0 (no) | 2003-02-10 | 2003-02-10 | Minox Technology As | Fremgangsmåte og anlegg for rensing av produsert vann |
WO2004074405A2 (en) * | 2003-02-18 | 2004-09-02 | Hydrogensource Llc | Hydrogen generator for hydrogen desulfurization of hydrocarbon feeds |
US20040159584A1 (en) | 2003-02-18 | 2004-08-19 | Ke Liu | Mini-CPO providing hydrogen for hydrogen desulfurization of hydrocarbon feeds |
-
2006
- 2006-03-16 GB GBGB0605232.8A patent/GB0605232D0/en not_active Ceased
-
2007
- 2007-03-05 WO PCT/GB2007/050100 patent/WO2007105012A1/en active Application Filing
- 2007-03-05 CA CA2641183A patent/CA2641183C/en not_active Expired - Fee Related
- 2007-03-05 AU AU2007226323A patent/AU2007226323B2/en not_active Ceased
- 2007-03-05 CN CN200780007687.XA patent/CN101394922B/zh not_active Expired - Fee Related
- 2007-03-05 EP EP07705384.1A patent/EP1993719B9/de not_active Not-in-force
- 2007-03-05 US US12/293,175 patent/US9017642B2/en not_active Expired - Fee Related
- 2007-03-05 ES ES07705384T patent/ES2373987T3/es active Active
- 2007-03-05 BR BRPI0708866-3A patent/BRPI0708866A2/pt active Search and Examination
- 2007-03-05 JP JP2008558910A patent/JP5721310B2/ja not_active Expired - Fee Related
- 2007-03-05 AT AT07705384T patent/ATE528070T1/de not_active IP Right Cessation
-
2008
- 2008-08-27 NO NO20083689A patent/NO20083689L/no not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
EP1993719B9 (de) | 2014-04-16 |
AU2007226323A1 (en) | 2007-09-20 |
CN101394922B (zh) | 2012-06-27 |
JP5721310B2 (ja) | 2015-05-20 |
CN101394922A (zh) | 2009-03-25 |
JP2009530435A (ja) | 2009-08-27 |
EP1993719A1 (de) | 2008-11-26 |
EP1993719B1 (de) | 2011-10-12 |
US9017642B2 (en) | 2015-04-28 |
AU2007226323B2 (en) | 2011-03-17 |
US20090242462A1 (en) | 2009-10-01 |
NO20083689L (no) | 2008-10-08 |
ES2373987T3 (es) | 2012-02-10 |
BRPI0708866A2 (pt) | 2011-06-14 |
CA2641183C (en) | 2013-04-30 |
GB0605232D0 (en) | 2006-04-26 |
WO2007105012A1 (en) | 2007-09-20 |
CA2641183A1 (en) | 2007-09-20 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |