IT1249955B - Procedimento di idrogenazione della glicerina - Google Patents
Procedimento di idrogenazione della glicerinaInfo
- Publication number
- IT1249955B IT1249955B ITTO910537A ITTO910537A IT1249955B IT 1249955 B IT1249955 B IT 1249955B IT TO910537 A ITTO910537 A IT TO910537A IT TO910537 A ITTO910537 A IT TO910537A IT 1249955 B IT1249955 B IT 1249955B
- Authority
- IT
- Italy
- Prior art keywords
- hydrogenation procedure
- glycerine hydrogenation
- glycerin
- glycerine
- ethanediol
- Prior art date
Links
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 title abstract 6
- 235000011187 glycerol Nutrition 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 238000005984 hydrogenation reaction Methods 0.000 title 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 1
- 229960004063 propylene glycol Drugs 0.000 abstract 1
- 235000013772 propylene glycol Nutrition 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Il procedimento di idrogenazione catalitica della glicerina è volto essenzialmente alla produzione di composti ossigenati aventi da 1 a 3 atomi di carbonio, principalmente 1,2 propandiolo e 1,2 etandiolo. Esso prevede di porre a contatto e di far reagire la glicerina con idrogeno in presenza di un catalizzatore comprendente rame-zinco in condizioni di temperatura di almeno 220°C.
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITTO910537A IT1249955B (it) | 1991-07-10 | 1991-07-10 | Procedimento di idrogenazione della glicerina |
| AU19466/92A AU649337B2 (en) | 1991-07-10 | 1992-07-07 | A method of hydrogenating glycerol |
| EP19920830359 EP0523015A3 (en) | 1991-07-10 | 1992-07-07 | A method of hydrogenating glycerol |
| CA002073312A CA2073312A1 (en) | 1991-07-10 | 1992-07-07 | Method of hydrogenating glycerol |
| FI923131A FI923131A7 (fi) | 1991-07-10 | 1992-07-07 | Menetelmä glyserolin hydrogenoimiseksi |
| NO92922683A NO922683L (no) | 1991-07-10 | 1992-07-08 | Fremgangsmaate for hydrogenering av glyserol |
| MX9204041A MX9204041A (es) | 1991-07-10 | 1992-07-09 | Un metodo de hidrogenacion de glicerol. |
| US07/911,133 US5214219A (en) | 1991-07-10 | 1992-07-09 | Method of hydrogenating glycerol |
| ZA925178A ZA925178B (en) | 1991-07-10 | 1992-07-10 | A method of hydrogenating glycerol |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITTO910537A IT1249955B (it) | 1991-07-10 | 1991-07-10 | Procedimento di idrogenazione della glicerina |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| ITTO910537A0 ITTO910537A0 (it) | 1991-07-10 |
| ITTO910537A1 ITTO910537A1 (it) | 1993-01-10 |
| IT1249955B true IT1249955B (it) | 1995-03-30 |
Family
ID=11409476
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ITTO910537A IT1249955B (it) | 1991-07-10 | 1991-07-10 | Procedimento di idrogenazione della glicerina |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5214219A (it) |
| EP (1) | EP0523015A3 (it) |
| AU (1) | AU649337B2 (it) |
| CA (1) | CA2073312A1 (it) |
| FI (1) | FI923131A7 (it) |
| IT (1) | IT1249955B (it) |
| MX (1) | MX9204041A (it) |
| NO (1) | NO922683L (it) |
| ZA (1) | ZA925178B (it) |
Families Citing this family (78)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4442124A1 (de) * | 1994-11-26 | 1996-05-30 | Basf Ag | Verfahren zur Herstellung von Propandiol-1,2 |
| US7663004B2 (en) | 2002-04-22 | 2010-02-16 | The Curators Of The University Of Missouri | Method of producing lower alcohols from glycerol |
| US8017816B2 (en) * | 2002-04-22 | 2011-09-13 | The Curators Of The University Of Missouri | Method of producing lower alcohols from glycerol |
| US8252961B2 (en) | 2002-04-22 | 2012-08-28 | The Curators Of The University Of Missouri | Method of producing lower alcohols from glycerol |
| US7131446B2 (en) * | 2004-03-25 | 2006-11-07 | Tang Kenneth Y | Light-triggered tattoo process |
| BRPI0507874B1 (pt) * | 2004-03-25 | 2019-03-12 | Galen J. Suppes | Processos para converter glicerol em propileno glicol e também em acetol com seletividade elevada |
| GB0514593D0 (en) | 2005-07-15 | 2005-08-24 | Davy Process Techn Ltd | Process |
| CA2634712C (en) * | 2005-12-21 | 2015-11-24 | Virent Energy Systems, Inc. | Catalysts and methods for reforming oxygenated compounds |
| US7790937B2 (en) | 2006-03-03 | 2010-09-07 | Basf Se | Process for the preparation of 1,2-propanediol |
| CN101443300B (zh) | 2006-05-08 | 2013-05-22 | 维仁特公司 | 用于生成多元醇的方法和系统 |
| US7619119B2 (en) | 2006-06-07 | 2009-11-17 | The Procter & Gamble Company | Processes for converting glycerol to amino alcohols |
| BRPI0712800B1 (pt) * | 2006-06-07 | 2016-12-13 | Procter & Gamble | processos para converter glicerol em aminoalcoóis |
| US7619118B2 (en) | 2006-06-07 | 2009-11-17 | The Procter & Gamble Company | Process for the conversion of glycerol to propylene glycol and amino alcohols |
| GB0614823D0 (en) | 2006-07-26 | 2006-09-06 | Davy Process Techn Ltd | Process |
| DE102007027374A1 (de) | 2007-06-11 | 2008-12-18 | Cognis Oleochemicals Gmbh | Verfahren zur Herstellung von 1,2-Propandiol |
| WO2008020077A1 (de) * | 2006-08-17 | 2008-02-21 | Cognis Oleochemicals Gmbh | Verfahren zur herstellung von 1,2-propandiol |
| EP1889825A1 (de) * | 2006-08-17 | 2008-02-20 | Cognis Oleochemicals GmbH | Verfahren zur Herstellung von 1,2-Propandiol |
| US7928148B2 (en) | 2006-10-23 | 2011-04-19 | Archer Daniels Midland Company | Hydrogenolysis of glycerol and products produced therefrom |
| BRPI0711699B1 (pt) * | 2006-10-27 | 2019-04-16 | Archer Daniels Midland Company | Processo para isolar ou purificar bio-propileno glicol |
| DE102006050751A1 (de) * | 2006-10-27 | 2008-05-08 | Clariant International Limited | Verfahren zur Herstellung von 1,2-Propandiol durch Hydrogenolyse von Glycerin |
| WO2008140617A2 (en) | 2006-12-20 | 2008-11-20 | Virent Energy Systems, Inc. | Reactor system for producing gaseous products |
| GB0625614D0 (en) | 2006-12-27 | 2007-01-31 | Leuven K U Res & Dev | Catalytic process for the production of oxygenated hydrocarbons |
| US20100094066A1 (en) * | 2007-01-17 | 2010-04-15 | The Curators Of The University Of Missouri | Gas phase reaction process for polyhydric compounds |
| DE102007003188B3 (de) | 2007-01-22 | 2008-06-05 | Clariant International Ltd. | Verfahren zur Herstellung von 1,2-Propandiol durch Hydrogenolyse von Glycerin |
| US7977517B2 (en) | 2007-03-08 | 2011-07-12 | Virent Energy Systems, Inc. | Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons |
| CN103159589B (zh) | 2007-04-17 | 2016-08-10 | 花王株式会社 | 多元醇的氢解产物的制造方法 |
| EP2162416B8 (en) | 2007-05-18 | 2018-12-19 | BioFuel-Solution i Malmö AB | Gas phase process for monoalcohol production from glycerol |
| CN101085719B (zh) * | 2007-06-29 | 2011-09-21 | 上海华谊丙烯酸有限公司 | 一种甘油加氢制备1,2-丙二醇的方法 |
| US8058484B2 (en) | 2007-08-24 | 2011-11-15 | Syntroleum Corporation | Flexible glycerol conversion process |
| KR100870369B1 (ko) | 2007-08-29 | 2008-11-25 | 지에스칼텍스 주식회사 | 프로판디올 제조용 촉매의 제조 방법 및 이를 이용한프로판디올의 제조 방법 |
| BRPI0815783A2 (pt) | 2007-08-31 | 2015-02-24 | Basf Se | Processo para a preparação de 1,2-propanodiol. |
| US8252962B2 (en) | 2007-08-31 | 2012-08-28 | Basf Se | Method for producing 1,2-propandiol by hydrogenating glycerine in a two-step reactor cascade |
| US8273924B2 (en) | 2007-08-31 | 2012-09-25 | Basf Se | Method for producing 1,2-propandiol by low-pressure hydrogenation of glycerine |
| JP5190065B2 (ja) * | 2007-10-31 | 2013-04-24 | 三井化学株式会社 | プロピレングリコールの製造方法 |
| US8177980B2 (en) * | 2007-11-09 | 2012-05-15 | Archer Daniels Midland Company | Separation of a mixture of polyhydric alcohols |
| US20090136771A1 (en) * | 2007-11-28 | 2009-05-28 | Evans Ronald J | Composition for preparing a surface for coating and methods of making and using same |
| KR101707830B1 (ko) | 2007-12-19 | 2017-02-17 | 더 큐레이터스 오브 더 유니버시티 오브 미주리 | 글리세롤로부터 저급 알코올을 생성하는 방법 |
| JP5305669B2 (ja) | 2008-01-21 | 2013-10-02 | 花王株式会社 | 多価アルコールの水素化分解物の製造方法 |
| AR072446A1 (es) | 2008-03-02 | 2010-09-01 | Dow Global Technologies Inc | Proceso de hidrogenacion mejorado |
| DE102008013474B4 (de) * | 2008-03-10 | 2013-08-08 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Katalytisches Verfahren zur Gewinnung von chemischen Grundstoffen aus nachwachsenden Rohstoffen |
| JP5350059B2 (ja) * | 2008-04-22 | 2013-11-27 | 三井化学株式会社 | プロピレングリコールの製造方法 |
| WO2009133066A1 (de) * | 2008-04-28 | 2009-11-05 | Basf Se | Verfahren zur hydrogenolyse von polyolen |
| WO2009133787A1 (ja) | 2008-04-30 | 2009-11-05 | 三井化学株式会社 | プロピレングリコールの製造方法 |
| DE102008026583A1 (de) | 2008-06-03 | 2009-12-24 | Bayer Technology Services Gmbh | Verfahren zur Herstellung von Kraftstoffadditiven aus Glycerin |
| WO2009149047A1 (en) | 2008-06-05 | 2009-12-10 | Huntsman Petrochemical Corporation | Process for the production and purification of propylene glycol |
| DE102008027601A1 (de) | 2008-06-10 | 2009-12-17 | Clariant International Limited | Verfahren zur Herstellung von 1,2-Propandiol durch Hydrogenolyse von Glycerin |
| CA2729659C (en) * | 2008-07-16 | 2015-11-24 | Michio Ikura | Conversion of glycerol to naphtha-range oxygenates |
| US8137527B1 (en) | 2008-07-28 | 2012-03-20 | Primafuel, Inc. | Carbon dioxide isolation and generation |
| WO2010016462A1 (ja) * | 2008-08-04 | 2010-02-11 | チッソ株式会社 | グリセリンからのグリコール及び1-プロパノールの製造方法 |
| US8350108B2 (en) * | 2008-08-27 | 2013-01-08 | Virent, Inc. | Synthesis of liquid fuels from biomass |
| CN101422739B (zh) * | 2008-11-03 | 2011-12-14 | 大连大学 | 催化氢解甘油制备二元醇的负载型催化剂及其制备方法 |
| PL2358653T3 (pl) * | 2008-11-05 | 2016-01-29 | Biofuel Solution I Malmoe Ab | Sposób wytwarzania niższych węglowodorów z glicerolu |
| AU2010218248A1 (en) | 2009-02-25 | 2011-09-01 | W. R. Grace & Co.-Conn. | Process for making 1, 2-propane diol from hydrogenation of glycerol |
| US8987528B2 (en) | 2009-04-16 | 2015-03-24 | Mossi & Ghisolfi International S.A.R.L. | Method of hydrogenolysis of sugar alcohols |
| WO2010150278A2 (en) | 2009-06-15 | 2010-12-29 | Ganapati Dadasaheb Yadav; | Hydrogenolysis of polyhydroxy alcohols using metal incorporated manganese oxide octahedral molecular sieve as a catalyst |
| CA2766113A1 (en) * | 2009-06-30 | 2011-01-06 | Paul George Blommel | Processes and reactor systems for converting sugars and sugar alcohols |
| WO2011009936A2 (en) | 2009-07-24 | 2011-01-27 | Basf Se | Process for the preparation of 1,2-propanediol from glycerol |
| DE102010015006A1 (de) | 2010-04-14 | 2011-11-24 | Tu Darmstadt | Katalysator zur Hydrierung von wässrigen mehrwertigen Alkohollösungen |
| US8829248B2 (en) | 2010-08-18 | 2014-09-09 | Eastman Chemical Company | Method for recovery and recycle of ruthenium homogeneous catalysts |
| US9227896B2 (en) | 2010-08-18 | 2016-01-05 | Eastman Chemical Company | Process for the separation and purification of a mixed diol stream |
| US8466328B2 (en) | 2010-08-18 | 2013-06-18 | Eastman Chemical Company | Method for recovery and recycle of ruthenium homogeneous catalysts |
| US8785686B2 (en) | 2010-09-23 | 2014-07-22 | Eastman Chemical Company | Process for recovering and recycling an acid catalyst |
| US8709376B2 (en) | 2010-09-23 | 2014-04-29 | Eastman Chemical Company | Process for recovering and recycling an acid catalyst |
| CN102225883B (zh) * | 2011-03-10 | 2013-08-21 | 江苏大学 | Cu/TiO2催化剂、制备方法及催化甘油氢解的方法 |
| EP3153219B1 (en) | 2011-03-14 | 2019-06-19 | Archer Daniels Midland Company | Improved methods for producing bioderived propylene glycol |
| EP2565175B1 (en) | 2011-08-31 | 2021-04-21 | Aristotle University of Thessaloniki | Catalytic process for the production of 1,2-propanediol from crude glycerol stream |
| CN102584532A (zh) * | 2011-12-06 | 2012-07-18 | 复旦大学 | 一种提高丙三醇重整-加氢制备1,2-丙二醇的选择性的方法 |
| US8829234B2 (en) | 2012-03-27 | 2014-09-09 | Eastman Chemical Company | Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and heterogeneous catalyst |
| US8703999B2 (en) | 2012-03-27 | 2014-04-22 | Eastman Chemical Company | Hydrocarboxylation of methylene dipropionate in the presence of propionic acid and a heterogeneous catalyst |
| WO2013148505A1 (en) | 2012-03-27 | 2013-10-03 | Eastman Chemical Company | Process for the separation and purification of a mixed diol stream |
| US8765999B2 (en) | 2012-03-27 | 2014-07-01 | Eastman Chemical Company | Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and a homogeneous catalyst |
| US8927766B2 (en) | 2012-03-27 | 2015-01-06 | Eastman Chemical Company | Hydrocarboxylation of methylene dipropionate in the presence of a propionic acid and a homogeneous catalyst |
| US9040748B2 (en) | 2012-06-08 | 2015-05-26 | Eastman Chemical Company | Hydrocarboxylation of aqueous formaldehyde using a dehydrating recycle stream to decrease water concentration |
| US9464015B2 (en) | 2013-03-07 | 2016-10-11 | University Of Saskatchewan | Process for hydrogenolysis of glycerol |
| AR095195A1 (es) * | 2013-03-15 | 2015-09-30 | W R Grace & Co -Conn | Proceso para la producción selectiva de propanoles por hidrogenación de glicerol |
| US9938215B2 (en) | 2014-04-22 | 2018-04-10 | Archer Daniels Midland Company | Process of making bioderived propylene glycol |
| CN105771999B (zh) * | 2016-03-25 | 2019-02-26 | 北京石油化工学院 | 一种甘油加氢催化剂及其制备方法与应用 |
| CN108636404B (zh) * | 2018-04-16 | 2021-05-04 | 江苏七洲绿色化工股份有限公司 | 一种甘油水溶液加氢制备1,3-丙二醇的规整催化剂及1,3-丙二醇的制备方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE541362C (de) * | 1927-10-25 | 1932-01-11 | I G Farbenindustrie Akt Ges | Verfahren zur Hydrierung von Polyoxyverbindungen |
| GB430576A (en) * | 1932-12-23 | 1935-06-21 | Du Pont | Improvements in or relating to the manufacture of glycerol and glycols |
| FR860273A (fr) * | 1938-09-23 | 1941-01-10 | Bombrini Parodi Delfino | Procédé pour la production de glycérine par la réduction d'hydrates de carbone |
| BR8204165A (pt) * | 1981-07-22 | 1983-07-12 | Du Pont | Processo para hidrogenolise de pentitois e misturas de pentitois com outros glicois hexitois e misturas de hexitois com outros poliois e poliois para etileno glicol |
| US4404411A (en) * | 1982-02-01 | 1983-09-13 | E. I. Du Pont De Nemours And Company | Hydrogenolysis of polyols to ethylene glycol in nonaqueous solvents |
| GB8702654D0 (en) * | 1987-02-06 | 1987-03-11 | Davy Mckee Ltd | Process |
| US5120885A (en) * | 1990-09-21 | 1992-06-09 | Kao Corporation | Process for producing alcohol |
-
1991
- 1991-07-10 IT ITTO910537A patent/IT1249955B/it active IP Right Grant
-
1992
- 1992-07-07 AU AU19466/92A patent/AU649337B2/en not_active Ceased
- 1992-07-07 FI FI923131A patent/FI923131A7/fi not_active Application Discontinuation
- 1992-07-07 EP EP19920830359 patent/EP0523015A3/en not_active Ceased
- 1992-07-07 CA CA002073312A patent/CA2073312A1/en not_active Abandoned
- 1992-07-08 NO NO92922683A patent/NO922683L/no unknown
- 1992-07-09 US US07/911,133 patent/US5214219A/en not_active Expired - Fee Related
- 1992-07-09 MX MX9204041A patent/MX9204041A/es unknown
- 1992-07-10 ZA ZA925178A patent/ZA925178B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU649337B2 (en) | 1994-05-19 |
| MX9204041A (es) | 1993-07-01 |
| ITTO910537A0 (it) | 1991-07-10 |
| ITTO910537A1 (it) | 1993-01-10 |
| FI923131L (fi) | 1993-01-11 |
| FI923131A7 (fi) | 1993-01-11 |
| CA2073312A1 (en) | 1993-01-11 |
| EP0523015A2 (en) | 1993-01-13 |
| US5214219A (en) | 1993-05-25 |
| AU1946692A (en) | 1993-02-25 |
| ZA925178B (en) | 1993-04-28 |
| NO922683L (no) | 1993-01-11 |
| NO922683D0 (no) | 1992-07-08 |
| EP0523015A3 (en) | 1993-05-26 |
| FI923131A0 (fi) | 1992-07-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 0001 | Granted | ||
| TA | Fee payment date (situation as of event date), data collected since 19931001 |
Effective date: 19950731 |