ES2174528T3 - Procedimiento para la obtencion de 1,6-hexanodiol. - Google Patents
Procedimiento para la obtencion de 1,6-hexanodiol.Info
- Publication number
- ES2174528T3 ES2174528T3 ES98963560T ES98963560T ES2174528T3 ES 2174528 T3 ES2174528 T3 ES 2174528T3 ES 98963560 T ES98963560 T ES 98963560T ES 98963560 T ES98963560 T ES 98963560T ES 2174528 T3 ES2174528 T3 ES 2174528T3
- Authority
- ES
- Spain
- Prior art keywords
- obtaining
- hydrogenation
- esters
- ester
- catalysts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
- C07C2601/08—Systems containing only non-condensed rings with a five-membered ring the ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Procedimiento para la obtención de 1,6-hexanodiol mediante hidrogenación de ésteres de ácido adípico y/o ésteres de ácido 6-hidroxicaproico en fase gaseosas, a alta temperatura y alta presión, en presencia de catalizadores exentos de cromo, caracterizado porque la hidrogenación se lleva a cabo a) con utilización de catalizadores que comprenden como componentes esenciales cobre, manganeso y aluminio, o en presencia de cobre Raney, b) a temperaturas de 150 hasta 230 C y presiones de 10 hasta 70 bar, c) con una proporción molar de hidrógeno con respecto a éster a hidrogenar de 150 a 1 hasta 300 a 1, y d) con una carga del catalizador de 0,01 hasta 0,3 kg de éster con 6 átomos de carbono por litro de catalizador y hora.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE1997157554 DE19757554A1 (de) | 1997-12-23 | 1997-12-23 | Verfahren zur Herstellung von 1,6-Hexandiol |
Publications (1)
Publication Number | Publication Date |
---|---|
ES2174528T3 true ES2174528T3 (es) | 2002-11-01 |
Family
ID=7853196
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES98963560T Expired - Lifetime ES2174528T3 (es) | 1997-12-23 | 1998-12-10 | Procedimiento para la obtencion de 1,6-hexanodiol. |
Country Status (10)
Country | Link |
---|---|
US (1) | US6407294B1 (es) |
EP (1) | EP1042259B1 (es) |
JP (1) | JP2001527056A (es) |
KR (1) | KR100510000B1 (es) |
CN (1) | CN1097038C (es) |
CA (1) | CA2305590C (es) |
DE (2) | DE19757554A1 (es) |
ES (1) | ES2174528T3 (es) |
MY (1) | MY119693A (es) |
WO (1) | WO1999033773A1 (es) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100457066B1 (ko) * | 2002-04-22 | 2004-11-12 | 애경유화 주식회사 | 수소화 반응촉매 및 그의 제조방법, 및 이 촉매를이용하여 무수말레인산으로부터 감마-부티로락톤을제조하는 방법 |
US6919489B1 (en) * | 2004-03-03 | 2005-07-19 | Eastman Chemical Company | Process for a cyclohexanedimethanol using raney metal catalysts |
DE102004033554A1 (de) * | 2004-07-09 | 2006-02-16 | Basf Ag | Katalysator und Verfahren zur Hydrierung von Carbonylverbindungen |
JP5279513B2 (ja) * | 2006-03-03 | 2013-09-04 | ビーエーエスエフ ソシエタス・ヨーロピア | 1,2−プロパンジオールの製法 |
DE102007032311A1 (de) | 2007-07-11 | 2009-01-15 | Lanxess Deutschland Gmbh | Methylcyclopentylester |
DE102008008389A1 (de) | 2008-02-09 | 2009-08-13 | Lanxess Deutschland Gmbh | Methylcyclopentylester |
US8541057B2 (en) * | 2008-12-18 | 2013-09-24 | Invista North America S.A R.L. | Cyclohexane oxidation process byproduct derivatives and methods for using the same |
CN101531568B (zh) * | 2009-04-13 | 2011-12-07 | 烟台万华聚氨酯股份有限公司 | 一种己二酸二甲酯气相加氢气合成1,6-己二醇的方法 |
EP2404889A1 (de) | 2010-07-06 | 2012-01-11 | LANXESS Deutschland GmbH | Verfahren zur Herstellung von Alpha, Omega-Diolen |
CN102351648B (zh) * | 2011-09-09 | 2013-11-20 | 上海戊正工程技术有限公司 | 一种生产1,6-己二醇并联产ε-己内酯的工艺 |
US8884036B2 (en) | 2011-12-30 | 2014-11-11 | E I Du Pont De Nemours And Company | Production of hydroxymethylfurfural from levoglucosenone |
US8865940B2 (en) | 2011-12-30 | 2014-10-21 | E I Du Pont De Nemours And Company | Process for preparing 1,6-hexanediol |
JP2015508401A (ja) | 2011-12-30 | 2015-03-19 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company | イソソルビドからのテトラヒドロフラン−2,5−ジメタノールの生成 |
WO2013101980A1 (en) | 2011-12-30 | 2013-07-04 | E. I. Du Pont De Nemours And Company | Process for preparing 1, 6-hexanediol |
CN104024197A (zh) | 2011-12-30 | 2014-09-03 | 纳幕尔杜邦公司 | 己二醇的制备方法 |
US8889912B2 (en) | 2011-12-30 | 2014-11-18 | E I Du Pont De Nemours And Company | Process for preparing 1,6-hexanediol |
US9018423B2 (en) | 2012-04-27 | 2015-04-28 | E I Du Pont De Nemours And Company | Production of alpha, omega-diols |
US8859826B2 (en) | 2012-04-27 | 2014-10-14 | E I Du Pont De Nemours And Company | Production of alpha, omega-diols |
US8846985B2 (en) | 2012-04-27 | 2014-09-30 | E I Du Pont De Nemours And Company | Production of alpha, omega-diols |
EP2759598A1 (de) | 2013-01-24 | 2014-07-30 | Evonik Industries AG | Verfahren zur Herstellung von alpha, omega-Alkandiol |
WO2016025214A1 (en) * | 2014-08-15 | 2016-02-18 | Exxonmobil Chemical Patents Inc. | Process and system for making cyclohexanone |
CN107774279B (zh) * | 2016-08-30 | 2020-09-04 | 中国石油化工股份有限公司 | 加氢催化剂 |
CN108014801A (zh) * | 2016-11-04 | 2018-05-11 | 中国石油化工股份有限公司 | 生产醇的催化剂及方法 |
CN108014803A (zh) * | 2016-11-04 | 2018-05-11 | 中国石油化工股份有限公司 | 制醇的催化剂及方法 |
CN108014804A (zh) * | 2016-11-04 | 2018-05-11 | 中国石油化工股份有限公司 | 制备醇的催化剂及其使用方法 |
CN108014815A (zh) * | 2016-11-04 | 2018-05-11 | 中国石油化工股份有限公司 | 制备醇的催化剂及方法 |
CN108607562A (zh) * | 2018-05-03 | 2018-10-02 | 中溶科技股份有限公司 | 用于己二酸二烷基酯制己二醇的催化剂及制备方法和应用 |
CN113683483B (zh) * | 2021-06-07 | 2022-05-13 | 浙江博聚新材料有限公司 | 一种高纯1,6-己二醇的生产方法及装置 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE414199C (de) * | 1922-12-21 | 1925-05-27 | Eduard Schrack | Regelbarer elektrischer Kondensator mit einer starren und einer biegsamen Belegung |
US3933930A (en) * | 1975-03-06 | 1976-01-20 | Celanese Corporation | Hexanediol from cyclohexane |
DE4141199A1 (de) * | 1991-12-13 | 1993-06-17 | Sued Chemie Ag | Chromfreier katalysator fuer die hydrierung von organischen verbindungen, die die carbonylfunktionen enthalten |
GB9324782D0 (en) * | 1993-12-02 | 1994-01-19 | Davy Mckee London | Process |
GB9324753D0 (en) | 1993-12-02 | 1994-01-19 | Davy Mckee London | Process |
DE19607954A1 (de) | 1996-03-01 | 1997-09-04 | Basf Ag | Verfahren zur Herstellung von 1,6-Hexandiol und Caprolacton |
MY118128A (en) | 1996-03-01 | 2004-09-30 | Basf Ag | The preparation of 1, 6-hexanediol and caprolactone |
CN1092174C (zh) | 1996-03-01 | 2002-10-09 | 巴斯福股份公司 | 纯度超过99%的1,6-己二醇的制备方法 |
-
1997
- 1997-12-23 DE DE1997157554 patent/DE19757554A1/de not_active Withdrawn
-
1998
- 1998-12-01 MY MYPI98005428A patent/MY119693A/en unknown
- 1998-12-10 CA CA002305590A patent/CA2305590C/en not_active Expired - Fee Related
- 1998-12-10 EP EP98963560A patent/EP1042259B1/de not_active Expired - Lifetime
- 1998-12-10 WO PCT/EP1998/008072 patent/WO1999033773A1/de active IP Right Grant
- 1998-12-10 DE DE59803387T patent/DE59803387D1/de not_active Expired - Lifetime
- 1998-12-10 CN CN98809712A patent/CN1097038C/zh not_active Expired - Fee Related
- 1998-12-10 KR KR10-2000-7006980A patent/KR100510000B1/ko not_active IP Right Cessation
- 1998-12-10 JP JP2000526460A patent/JP2001527056A/ja active Pending
- 1998-12-10 US US09/529,789 patent/US6407294B1/en not_active Expired - Lifetime
- 1998-12-10 ES ES98963560T patent/ES2174528T3/es not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
WO1999033773A1 (de) | 1999-07-08 |
CA2305590A1 (en) | 1999-07-08 |
CA2305590C (en) | 2007-06-12 |
DE59803387D1 (de) | 2002-04-18 |
JP2001527056A (ja) | 2001-12-25 |
US6407294B1 (en) | 2002-06-18 |
CN1097038C (zh) | 2002-12-25 |
EP1042259A1 (de) | 2000-10-11 |
KR20010033479A (ko) | 2001-04-25 |
KR100510000B1 (ko) | 2005-08-26 |
EP1042259B1 (de) | 2002-03-13 |
MY119693A (en) | 2005-06-30 |
DE19757554A1 (de) | 1999-06-24 |
CN1272835A (zh) | 2000-11-08 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG2A | Definitive protection |
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