IT1249956B - Procedimento di idrogenazione catalitica della glicerina - Google Patents
Procedimento di idrogenazione catalitica della glicerinaInfo
- Publication number
- IT1249956B IT1249956B ITTO910539A ITTO910539A IT1249956B IT 1249956 B IT1249956 B IT 1249956B IT TO910539 A ITTO910539 A IT TO910539A IT TO910539 A ITTO910539 A IT TO910539A IT 1249956 B IT1249956 B IT 1249956B
- Authority
- IT
- Italy
- Prior art keywords
- catalytic hydrogenation
- hydrogenation process
- glycerine
- glycerin
- sulphides
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
Abstract
Il procedimento di idrogenazione catalitica della glicerina è volto essenzialmente alla produzione di composti ossigenati aventi da 1 a 3 atomi di carbonio, particolarmente 1,2-propandiolo e acido lattico. Esso prevede di porre a contatto e di far reagire la glicerina con idrogeno in presenza di un catalizzatore al rutenio modificato con solfuri e di una base in condizioni di temperatura di almeno 200°C.
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITTO910539A IT1249956B (it) | 1991-07-10 | 1991-07-10 | Procedimento di idrogenazione catalitica della glicerina |
AU19465/92A AU1946592A (en) | 1991-07-10 | 1992-07-07 | A catalytic method of hydrogenating glycerol |
EP19920830357 EP0523014A3 (en) | 1991-07-10 | 1992-07-07 | A catalytic method of hyrogenating glycerol |
FI923130A FI923130A (fi) | 1991-07-10 | 1992-07-07 | Katalytiskt foerfarande foer hydrogenering av glycerol |
CA002073322A CA2073322A1 (en) | 1991-07-10 | 1992-07-07 | Catalytic method of hydrogenating glycerol |
NO92922684A NO922684L (no) | 1991-07-10 | 1992-07-08 | Fremgangsmaate for katalytisk hydrogenering av glyserol |
MX9204042A MX9204042A (es) | 1991-07-10 | 1992-07-09 | Un metodo catalitico para hidrogenar glicerol. |
US07/911,146 US5276181A (en) | 1991-07-10 | 1992-07-09 | Catalytic method of hydrogenating glycerol |
ZA925177A ZA925177B (en) | 1991-07-10 | 1992-07-10 | A catalytic method of hydrogenating glycerol |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITTO910539A IT1249956B (it) | 1991-07-10 | 1991-07-10 | Procedimento di idrogenazione catalitica della glicerina |
Publications (3)
Publication Number | Publication Date |
---|---|
ITTO910539A0 ITTO910539A0 (it) | 1991-07-10 |
ITTO910539A1 ITTO910539A1 (it) | 1993-01-10 |
IT1249956B true IT1249956B (it) | 1995-03-30 |
Family
ID=11409477
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ITTO910539A IT1249956B (it) | 1991-07-10 | 1991-07-10 | Procedimento di idrogenazione catalitica della glicerina |
Country Status (9)
Country | Link |
---|---|
US (1) | US5276181A (it) |
EP (1) | EP0523014A3 (it) |
AU (1) | AU1946592A (it) |
CA (1) | CA2073322A1 (it) |
FI (1) | FI923130A (it) |
IT (1) | IT1249956B (it) |
MX (1) | MX9204042A (it) |
NO (1) | NO922684L (it) |
ZA (1) | ZA925177B (it) |
Families Citing this family (48)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4442124A1 (de) * | 1994-11-26 | 1996-05-30 | Basf Ag | Verfahren zur Herstellung von Propandiol-1,2 |
US6555717B2 (en) | 2000-06-20 | 2003-04-29 | E. I. Du Pont De Nemours And Company | Catalytic dehydroxylation of diols and polyols |
US8252961B2 (en) | 2002-04-22 | 2012-08-28 | The Curators Of The University Of Missouri | Method of producing lower alcohols from glycerol |
US8017816B2 (en) * | 2002-04-22 | 2011-09-13 | The Curators Of The University Of Missouri | Method of producing lower alcohols from glycerol |
US7663004B2 (en) | 2002-04-22 | 2010-02-16 | The Curators Of The University Of Missouri | Method of producing lower alcohols from glycerol |
US7131446B2 (en) * | 2004-03-25 | 2006-11-07 | Tang Kenneth Y | Light-triggered tattoo process |
EP1727875B1 (en) | 2004-03-25 | 2015-11-04 | Galen J. Suppes | Process for producing acetol from glycerol |
WO2007001043A1 (ja) * | 2005-06-29 | 2007-01-04 | Hitachi Zosen Corporation | 乳酸の製造方法および乳酸製造装置 |
GB0514593D0 (en) * | 2005-07-15 | 2005-08-24 | Davy Process Techn Ltd | Process |
CN101466663B (zh) * | 2006-06-07 | 2013-11-06 | 宝洁公司 | 将甘油转变成氨基醇的方法 |
US7619119B2 (en) * | 2006-06-07 | 2009-11-17 | The Procter & Gamble Company | Processes for converting glycerol to amino alcohols |
US7619118B2 (en) | 2006-06-07 | 2009-11-17 | The Procter & Gamble Company | Process for the conversion of glycerol to propylene glycol and amino alcohols |
DE102007027374A1 (de) | 2007-06-11 | 2008-12-18 | Cognis Oleochemicals Gmbh | Verfahren zur Herstellung von 1,2-Propandiol |
GB0619691D0 (en) * | 2006-10-05 | 2006-11-15 | Grimley Smith Associates Ltd | Manufacture of biodiesel fuel |
WO2008051540A2 (en) * | 2006-10-23 | 2008-05-02 | Archer-Daniels-Midland Company | Hydrogenolysis of glycerol and products produced therefrom |
EP2038243A1 (en) | 2006-10-27 | 2009-03-25 | Archer-Daniels-Midland Company | Processes for isolating or purifying propylene glycol, ehtylene glycol and products produced therefrom |
WO2008089301A2 (en) * | 2007-01-17 | 2008-07-24 | Curators Of The University Of Missouri | Gas phase reaction process for polyhydric compounds |
EP2138478B1 (en) | 2007-04-17 | 2019-07-24 | Kao Corporation | Process for producing hydrogenolysis products of polyhydric alcohols |
KR100870370B1 (ko) | 2007-08-29 | 2008-11-25 | 지에스칼텍스 주식회사 | 프로판디올 제조용 촉매, 그 제조 방법 및 이를 이용한프로판디올의 제조 방법 |
US8177980B2 (en) | 2007-11-09 | 2012-05-15 | Archer Daniels Midland Company | Separation of a mixture of polyhydric alcohols |
JP5305669B2 (ja) | 2008-01-21 | 2013-10-02 | 花王株式会社 | 多価アルコールの水素化分解物の製造方法 |
AR072446A1 (es) | 2008-03-02 | 2010-09-01 | Dow Global Technologies Inc | Proceso de hidrogenacion mejorado |
DE102008013474B4 (de) * | 2008-03-10 | 2013-08-08 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Katalytisches Verfahren zur Gewinnung von chemischen Grundstoffen aus nachwachsenden Rohstoffen |
US20090264687A1 (en) * | 2008-04-16 | 2009-10-22 | Battelle Memorial Institute | Chemical Production Processes and Systems |
US20110034603A1 (en) * | 2008-04-25 | 2011-02-10 | Nippon Shokubai Co., Ltd. | Polyacrylic acid (salt)-based water-absorbent resin and method for producing same |
WO2010090324A1 (ja) | 2009-02-06 | 2010-08-12 | 株式会社日本触媒 | ポリアクリル酸(塩)系吸水性樹脂およびその製造方法 |
WO2010150278A2 (en) | 2009-06-15 | 2010-12-29 | Ganapati Dadasaheb Yadav; | Hydrogenolysis of polyhydroxy alcohols using metal incorporated manganese oxide octahedral molecular sieve as a catalyst |
KR101292329B1 (ko) * | 2010-05-18 | 2013-08-01 | 주식회사 엘지화학 | 알킬락테이트의 제조방법 및 이를 이용한 락타미드의 제조방법 |
US9227896B2 (en) | 2010-08-18 | 2016-01-05 | Eastman Chemical Company | Process for the separation and purification of a mixed diol stream |
US8829248B2 (en) | 2010-08-18 | 2014-09-09 | Eastman Chemical Company | Method for recovery and recycle of ruthenium homogeneous catalysts |
US8466328B2 (en) | 2010-08-18 | 2013-06-18 | Eastman Chemical Company | Method for recovery and recycle of ruthenium homogeneous catalysts |
US8709376B2 (en) | 2010-09-23 | 2014-04-29 | Eastman Chemical Company | Process for recovering and recycling an acid catalyst |
US8785686B2 (en) | 2010-09-23 | 2014-07-22 | Eastman Chemical Company | Process for recovering and recycling an acid catalyst |
CA2828880C (en) | 2011-03-14 | 2018-11-20 | Kevin ADLAF | Improved methods for producing bioderived propylene glycol |
EP2720792A1 (en) * | 2011-06-14 | 2014-04-23 | Shell Internationale Research Maatschappij B.V. | Aqueous catalyst sulfiding process |
EP2565175B1 (en) | 2011-08-31 | 2021-04-21 | Aristotle University of Thessaloniki | Catalytic process for the production of 1,2-propanediol from crude glycerol stream |
AT511965B1 (de) * | 2011-10-11 | 2013-04-15 | Amitava Dipl Ing Dr Kundu | Verfahren zur herstellung von milchsäure |
CN103041806B (zh) * | 2011-10-17 | 2015-04-15 | 中国石油化工股份有限公司 | Ru/C催化剂的制备方法和甘油氢解的方法 |
WO2013148505A1 (en) | 2012-03-27 | 2013-10-03 | Eastman Chemical Company | Process for the separation and purification of a mixed diol stream |
US8829234B2 (en) | 2012-03-27 | 2014-09-09 | Eastman Chemical Company | Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and heterogeneous catalyst |
US8765999B2 (en) | 2012-03-27 | 2014-07-01 | Eastman Chemical Company | Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and a homogeneous catalyst |
US8703999B2 (en) | 2012-03-27 | 2014-04-22 | Eastman Chemical Company | Hydrocarboxylation of methylene dipropionate in the presence of propionic acid and a heterogeneous catalyst |
US8927766B2 (en) | 2012-03-27 | 2015-01-06 | Eastman Chemical Company | Hydrocarboxylation of methylene dipropionate in the presence of a propionic acid and a homogeneous catalyst |
US9040748B2 (en) | 2012-06-08 | 2015-05-26 | Eastman Chemical Company | Hydrocarboxylation of aqueous formaldehyde using a dehydrating recycle stream to decrease water concentration |
WO2014089827A1 (en) * | 2012-12-14 | 2014-06-19 | Empire Technology Development Llc | Synthesis of short chain carboxylic acids from carbohydrate biomass |
WO2014134733A1 (en) | 2013-03-07 | 2014-09-12 | University Of Saskatchewan | Process for hydrogenolysis of glycerol |
JP2014189498A (ja) * | 2013-03-26 | 2014-10-06 | Hitachi Zosen Corp | 乳酸の製造方法 |
CA2945927C (en) | 2014-04-22 | 2022-07-26 | Archer Daniels Midland Company | Improved process of making bioderived propylene glycol |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BR8204165A (pt) * | 1981-07-22 | 1983-07-12 | Du Pont | Processo para hidrogenolise de pentitois e misturas de pentitois com outros glicois hexitois e misturas de hexitois com outros poliois e poliois para etileno glicol |
US4404411A (en) * | 1982-02-01 | 1983-09-13 | E. I. Du Pont De Nemours And Company | Hydrogenolysis of polyols to ethylene glycol in nonaqueous solvents |
US4430253A (en) * | 1982-02-11 | 1984-02-07 | Ethyl Corporation | Sulfide-modified ruthenium catalyst |
US4476331A (en) * | 1982-02-11 | 1984-10-09 | Ethyl Corporation | Two stage hydrogenolysis of carbohydrate to glycols using sulfide modified ruthenium catalyst in second stage |
US4496780A (en) * | 1983-06-22 | 1985-01-29 | Uop Inc. | Hydrocracking of polyols |
-
1991
- 1991-07-10 IT ITTO910539A patent/IT1249956B/it active IP Right Grant
-
1992
- 1992-07-07 EP EP19920830357 patent/EP0523014A3/en not_active Ceased
- 1992-07-07 FI FI923130A patent/FI923130A/fi not_active Application Discontinuation
- 1992-07-07 CA CA002073322A patent/CA2073322A1/en not_active Abandoned
- 1992-07-07 AU AU19465/92A patent/AU1946592A/en not_active Abandoned
- 1992-07-08 NO NO92922684A patent/NO922684L/no unknown
- 1992-07-09 MX MX9204042A patent/MX9204042A/es unknown
- 1992-07-09 US US07/911,146 patent/US5276181A/en not_active Expired - Fee Related
- 1992-07-10 ZA ZA925177A patent/ZA925177B/xx unknown
Also Published As
Publication number | Publication date |
---|---|
NO922684L (no) | 1993-01-11 |
ITTO910539A0 (it) | 1991-07-10 |
ITTO910539A1 (it) | 1993-01-10 |
CA2073322A1 (en) | 1993-01-11 |
US5276181A (en) | 1994-01-04 |
AU1946592A (en) | 1993-02-25 |
NO922684D0 (no) | 1992-07-08 |
MX9204042A (es) | 1993-02-26 |
EP0523014A3 (en) | 1993-06-16 |
FI923130A0 (fi) | 1992-07-07 |
ZA925177B (en) | 1993-04-28 |
EP0523014A2 (en) | 1993-01-13 |
FI923130A (fi) | 1993-01-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
IT1249956B (it) | Procedimento di idrogenazione catalitica della glicerina | |
IT1249955B (it) | Procedimento di idrogenazione della glicerina | |
AU5601386A (en) | Alcohols production by hydrogenation of carboxylic acids | |
MY111225A (en) | Process for producing highly purified acetic acid | |
BR9913475A (pt) | Processo para a produção de 1,3-propanodiol | |
KR890014432A (ko) | 카복실산의 제조방법 | |
DE3575086D1 (de) | Katalysator zur synthese von methanol und hoehere alkohole enthaltenden alkoholgemischen. | |
DE68908260D1 (de) | Herstellung von alkoholen und ethern durch katalytische hydrogenierung von estern. | |
KR890012928A (ko) | 포름알데히드 및 그의 유도체의 제조방법 | |
ATE224188T1 (de) | Nicht-beta oxidierbare fettsäureanaloge,deren verwendung als therapeutisch wirksame medikamente sowie deren herstellung | |
ATE88453T1 (de) | Katalytisches einstufenverfahren zur direkten umwandlung von polysacchariden in mehrwertige alkohole. | |
KR900011713A (ko) | α-하이드록시 카르복시산 아미드의 제조방법 | |
KR840005422A (ko) | 글리옥실산 및 글리옥실산 유도체의 제조방법 | |
MY106783A (en) | Process for producing alcohol | |
US4405819A (en) | Process for the production of alcohols from carboxylic acids | |
KR880002792A (ko) | 알데히드 및/또는 케톤의 수소화 방법 | |
GR3022346T3 (en) | Process for producing sclareolide. | |
US4257968A (en) | Oxidation of phenol to p-benzoquinone in acetonitrile/methanol cosolvent | |
FR2411888A1 (fr) | Procede de production, a l'aide d'un micro-organisme, d'acides gras a longues chaines carbonees lineaires | |
DE69921830D1 (de) | Hydrierung von hopfensäuren | |
KR880011066A (ko) | (페닐에테닐) 페닐프로피온산과 그 에스테르 및 (벤조일페닐) 프로피온산 또는 그 에스테르의 제조방법 | |
KR970006259A (ko) | 4-t-부틸사이클헥산올의 제조방법 | |
KR920002512A (ko) | 정제 테레프탈산의 제조방법 | |
ES2053727T3 (es) | Procedimiento mejorado de hidrogenacion para la preparacion de 4-aminofenol. | |
CN112778118B (zh) | 一种乙醇酸甲酯制备乙醛酸的方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
0001 | Granted | ||
TA | Fee payment date (situation as of event date), data collected since 19931001 |
Effective date: 19950731 |