KR890014432A - 카복실산의 제조방법 - Google Patents

카복실산의 제조방법 Download PDF

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Publication number
KR890014432A
KR890014432A KR1019890003773A KR890003773A KR890014432A KR 890014432 A KR890014432 A KR 890014432A KR 1019890003773 A KR1019890003773 A KR 1019890003773A KR 890003773 A KR890003773 A KR 890003773A KR 890014432 A KR890014432 A KR 890014432A
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KR
South Korea
Prior art keywords
carboxylic acid
carbon atoms
rhodium
carbon
catalyst
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KR1019890003773A
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English (en)
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KR0132673B1 (ko
Inventor
핌블렛 길리안
Original Assignee
케이쓰 워윅 덴비치
비피 케미칼스 리미티드
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Publication of KR890014432A publication Critical patent/KR890014432A/ko
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Publication of KR0132673B1 publication Critical patent/KR0132673B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

내용 없음.

Description

카복실산의 제조방법
내용없음

Claims (7)

  1. 탄소지지체상에 지지된 로듐 및 니켈을 함유하는 촉매 및 할로겐 또는 할로겐 화합물의 존재하에 고온 및 고압에서, 알코올을 일산화탄소 및 수소의 기체 혼합물과 접촉시킴을 특징으로 하여, n개의 탄소원자를 갖는 알코올로부터 (n+1)개의 탄소원자를 갖는 카복실산을 제조하는 방법.
  2. 제1항에 있어서, 촉매에서 로듐에 대한 니켈의 중량비가 0.05:1 내지 10:1의 범위인 방법.
  3. 제1항 또는 2항중 어느 한 항에 있어서, 촉매가 0.05 내지 10중량%의 니켈을 함유하는 방법.
  4. 제1 내지 3항중 어느 한 항에 있어서, 촉매가 0.1 내지 7%의 로듐을 함유하는 방법.
  5. 제1항에 있어서, n개의 탄소원자를 갖는 알코올이 메탄올이고, (N+1)개의 탄소원자를 갖는 카복실산이 아세트산인 방법.
  6. 제1항에 있어서, 기체 혼합물중의 수소에 대한 일산화탄소의 몰비가 5:1 내지 1:4의 범위내인 방법.
  7. 제1항에 있어서, 150 내지 300℃의 온도 및 1 내지 50 atm의 압력하에서 수행하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890003773A 1988-03-26 1989-03-25 카복실산의 제조방법 KR0132673B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB888807284A GB8807284D0 (en) 1988-03-26 1988-03-26 Chemical process
GB8807284.8 1988-03-26

Publications (2)

Publication Number Publication Date
KR890014432A true KR890014432A (ko) 1989-10-23
KR0132673B1 KR0132673B1 (ko) 1998-04-13

Family

ID=10634197

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019890003773A KR0132673B1 (ko) 1988-03-26 1989-03-25 카복실산의 제조방법

Country Status (13)

Country Link
US (1) US5258549A (ko)
EP (1) EP0335625B1 (ko)
JP (1) JP2868528B2 (ko)
KR (1) KR0132673B1 (ko)
CN (1) CN1024001C (ko)
AT (1) ATE90931T1 (ko)
AU (1) AU612804B2 (ko)
DE (1) DE68907247T2 (ko)
GB (1) GB8807284D0 (ko)
MY (1) MY110253A (ko)
NO (1) NO169889C (ko)
NZ (1) NZ228449A (ko)
SU (1) SU1715203A3 (ko)

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US5488143A (en) * 1992-06-30 1996-01-30 Korea Institute Of Science And Technology Processes for the carbonylation of methanol to form acetic acid, methyl acetate and acetic anhydride
KR960007736B1 (ko) * 1993-07-27 1996-06-11 한국과학기술연구원 원료 가스 중에 함유된 철 카르보닐 화합물의 제거 방법
GB9223170D0 (en) * 1992-11-05 1992-12-16 British Petroleum Co Plc Process for preparing carboxylic acids
US5510525A (en) * 1993-07-22 1996-04-23 Gas Research Institute Direct catalytic oxidative carbonylation of lower alkanes to acids
US5916840A (en) * 1994-07-01 1999-06-29 Monsanto Company Process for preparing carboxylic acid salts and catalysts useful in such process
US5900505A (en) * 1997-02-04 1999-05-04 Eastman Chemical Company Heterogeneous vapor phase carbonylation process
WO1999050218A1 (en) * 1998-03-31 1999-10-07 Haldor Topsøe A/S Process for production of acetic acid
US6159896A (en) * 1999-02-16 2000-12-12 Eastman Chemical Company Iridium catalyst for carbonylation of lower aliphatic alcohols
US6137000A (en) * 1999-02-16 2000-10-24 Eastman Chemical Company Method for carbonylation of lower aliphatic alcohols using a supported iridium and lanthanide series catalyst
US6160163A (en) * 1999-02-16 2000-12-12 Eastman Chemical Company Method for the vapor-phase carbonylation of lower aliphatic alcohols using a supported platinum catalyst and halide promoter
CN1086604C (zh) * 1999-04-06 2002-06-26 华南理工大学 用于甲(乙)醇直接气相羰基化的含钼组分催化剂制备方法
US6160155A (en) * 1999-04-29 2000-12-12 General Electric Company Method and catalyst system for producing aromatic carbonates
US6353132B1 (en) 1999-08-25 2002-03-05 Eastman Chemical Company Vapor phase carbonylation process using group 5 metal promoted iridium catalyst
US6355837B1 (en) 1999-08-25 2002-03-12 Eastman Chemical Company Vapor phase carbonylation process using group 4 metal promoted iridium catalyst
US6355595B1 (en) 1999-08-25 2002-03-12 Eastman Chemical Company Group 5 metal promoted iridium carbonylation catalyst
US6441222B1 (en) 2000-05-22 2002-08-27 Eastman Chemical Company Vapor phase carbonylation process using iridium-gold co-catalysts
US6506933B1 (en) 2000-05-22 2003-01-14 Eastman Chemical Company Vapor phase carbonylation process using gold catalysts
US6509293B1 (en) 2000-05-22 2003-01-21 Eastman Chemical Company Gold based heterogeneous carbonylation catalysts
US6177380B1 (en) 2000-05-22 2001-01-23 Eastman Chemical Company Iridium-gold carbonylation co-catalysts
DE10061572A1 (de) 2000-12-11 2002-06-27 Bosch Gmbh Robert Brennstoffeinspritzventil
US6613938B2 (en) 2001-06-19 2003-09-02 Eastman Chemical Company Method for carbonylation of lower aliphatic alcohols using tin promoted platinum catalyst
US6903045B2 (en) 2001-06-19 2005-06-07 Eastman Chemical Company Tin promoted platinum catalyst for carbonylation of lower alkyl alcohols
US6537944B1 (en) 2001-06-20 2003-03-25 Eastman Chemical Company Tungsten promoted catalyst for carbonylation of lower alkyl alcohols
US6617471B2 (en) 2001-06-20 2003-09-09 Eastman Chemical Company Method for carbonylation of lower aliphatic alcohols using tin promoted iridium catalyst
US6548444B2 (en) 2001-06-20 2003-04-15 Eastman Chemical Company Tin promoted iridium catalyst for carbonylation of lower alkyl alcohols
US6646154B2 (en) 2001-06-20 2003-11-11 Eastman Chemical Company Method for carbonylation of lower alkyl alcohols using tungsten promoted group VIII catalyst
CN1315771C (zh) * 2002-05-06 2007-05-16 伊斯曼化学公司 连续羰基化工艺
CA2496839A1 (en) 2004-07-19 2006-01-19 Woodland Chemical Systems Inc. Process for producing ethanol from synthesis gas rich in carbon monoxide
BRPI0710578B1 (pt) 2006-04-05 2016-11-29 Woodland Biofuels Inc método de produção de etanol a partir de gás de síntese
US7737298B2 (en) * 2006-06-09 2010-06-15 Eastman Chemical Company Production of acetic acid and mixtures of acetic acid and acetic anhydride
US7582792B2 (en) * 2006-06-15 2009-09-01 Eastman Chemical Company Carbonylation process
US7253304B1 (en) 2006-06-20 2007-08-07 Eastman Chemical Company Carbonylation process
US7629491B2 (en) * 2006-06-26 2009-12-08 Eastman Chemical Company Hydrocarboxylation process
US20090247783A1 (en) * 2008-04-01 2009-10-01 Eastman Chemical Company Carbonylation process
WO2010033227A1 (en) * 2008-09-19 2010-03-25 Nektar Therapeutics Polymer conjugates of thymosin alpha 1 peptides
US9012683B2 (en) 2010-11-12 2015-04-21 Eastman Chemical Company Coproduction of acetic acid and acetic anhydride
US9421522B2 (en) 2011-12-28 2016-08-23 Eastman Chemical Company Iridium catalysts for carbonylation

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US2650245A (en) * 1949-04-08 1953-08-25 British Celanese Synthesis of acetic acid from co and methanol
US2650246A (en) * 1949-11-04 1953-08-25 British Celanese Production of acetic acid from methanol
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US3717670A (en) * 1968-08-02 1973-02-20 Monsanto Co Production of carboxylic acids and esters
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GB8807284D0 (en) * 1988-03-26 1988-04-27 Bp Chem Int Ltd Chemical process

Also Published As

Publication number Publication date
CN1036947A (zh) 1989-11-08
DE68907247T2 (de) 1993-10-21
US5258549A (en) 1993-11-02
NZ228449A (en) 1992-01-29
ATE90931T1 (de) 1993-07-15
NO169889C (no) 1992-08-19
DE68907247D1 (de) 1993-07-29
JPH01299248A (ja) 1989-12-04
KR0132673B1 (ko) 1998-04-13
NO891230L (no) 1989-09-27
EP0335625B1 (en) 1993-06-23
MY110253A (en) 1998-03-31
NO169889B (no) 1992-05-11
EP0335625A2 (en) 1989-10-04
EP0335625A3 (en) 1990-02-07
SU1715203A3 (ru) 1992-02-23
AU612804B2 (en) 1991-07-18
CN1024001C (zh) 1994-03-16
AU3164189A (en) 1989-09-28
JP2868528B2 (ja) 1999-03-10
NO891230D0 (no) 1989-03-21
GB8807284D0 (en) 1988-04-27

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