DK2601251T3 - Modified phyllosilicate - Google Patents
Modified phyllosilicate Download PDFInfo
- Publication number
- DK2601251T3 DK2601251T3 DK11738754.8T DK11738754T DK2601251T3 DK 2601251 T3 DK2601251 T3 DK 2601251T3 DK 11738754 T DK11738754 T DK 11738754T DK 2601251 T3 DK2601251 T3 DK 2601251T3
- Authority
- DK
- Denmark
- Prior art keywords
- phyllosilicate
- acetylcholine
- choline
- modified
- cation exchange
- Prior art date
Links
- 229910052615 phyllosilicate Inorganic materials 0.000 title claims description 101
- OIPILFWXSMYKGL-UHFFFAOYSA-N acetylcholine Chemical compound CC(=O)OCC[N+](C)(C)C OIPILFWXSMYKGL-UHFFFAOYSA-N 0.000 claims description 39
- -1 hexadecyltrimethylammonium ions Chemical class 0.000 claims description 36
- 239000000203 mixture Substances 0.000 claims description 35
- 229960004373 acetylcholine Drugs 0.000 claims description 34
- RLGQACBPNDBWTB-UHFFFAOYSA-N cetyltrimethylammonium ion Chemical class CCCCCCCCCCCCCCCC[N+](C)(C)C RLGQACBPNDBWTB-UHFFFAOYSA-N 0.000 claims description 30
- 229960001231 choline Drugs 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 29
- OEYIOHPDSNJKLS-UHFFFAOYSA-N choline Chemical compound C[N+](C)(C)CCO OEYIOHPDSNJKLS-UHFFFAOYSA-N 0.000 claims description 26
- 230000008569 process Effects 0.000 claims description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 24
- 239000003607 modifier Substances 0.000 claims description 15
- 238000005341 cation exchange Methods 0.000 claims description 14
- 229920000642 polymer Polymers 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 239000004381 Choline salt Substances 0.000 claims description 7
- 235000019417 choline salt Nutrition 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 150000003248 quinolines Chemical class 0.000 claims description 7
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- JUGOREOARAHOCO-UHFFFAOYSA-M acetylcholine chloride Chemical compound [Cl-].CC(=O)OCC[N+](C)(C)C JUGOREOARAHOCO-UHFFFAOYSA-M 0.000 claims description 3
- 229960004266 acetylcholine chloride Drugs 0.000 claims description 3
- 238000000746 purification Methods 0.000 claims description 3
- 239000001763 2-hydroxyethyl(trimethyl)azanium Substances 0.000 claims description 2
- 235000019743 Choline chloride Nutrition 0.000 claims description 2
- SGMZJAMFUVOLNK-UHFFFAOYSA-M choline chloride Chemical compound [Cl-].C[N+](C)(C)CCO SGMZJAMFUVOLNK-UHFFFAOYSA-M 0.000 claims description 2
- 229960003178 choline chloride Drugs 0.000 claims description 2
- 239000012744 reinforcing agent Substances 0.000 claims description 2
- 238000002955 isolation Methods 0.000 claims 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 29
- 239000002114 nanocomposite Substances 0.000 description 28
- 229910052901 montmorillonite Inorganic materials 0.000 description 24
- 239000003795 chemical substances by application Substances 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 12
- 238000002360 preparation method Methods 0.000 description 11
- 150000001768 cations Chemical class 0.000 description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 230000009467 reduction Effects 0.000 description 6
- 235000013305 food Nutrition 0.000 description 5
- 230000035699 permeability Effects 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 230000004888 barrier function Effects 0.000 description 4
- 230000005540 biological transmission Effects 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000012512 characterization method Methods 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 230000002787 reinforcement Effects 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- ZMJIUWPWADQNLC-UHFFFAOYSA-N 1-(3-chlorophenyl)-2-(ethylamino)propan-1-one Chemical compound CCNC(C)C(=O)C1=CC=CC(Cl)=C1 ZMJIUWPWADQNLC-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- PDSVZUAJOIQXRK-UHFFFAOYSA-N trimethyl(octadecyl)azanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)C PDSVZUAJOIQXRK-UHFFFAOYSA-N 0.000 description 2
- AZUYLZMQTIKGSC-UHFFFAOYSA-N 1-[6-[4-(5-chloro-6-methyl-1H-indazol-4-yl)-5-methyl-3-(1-methylindazol-5-yl)pyrazol-1-yl]-2-azaspiro[3.3]heptan-2-yl]prop-2-en-1-one Chemical compound ClC=1C(=C2C=NNC2=CC=1C)C=1C(=NN(C=1C)C1CC2(CN(C2)C(C=C)=O)C1)C=1C=C2C=NN(C2=CC=1)C AZUYLZMQTIKGSC-UHFFFAOYSA-N 0.000 description 1
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical group C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 229920000229 biodegradable polyester Polymers 0.000 description 1
- 239000004622 biodegradable polyester Substances 0.000 description 1
- 229920002988 biodegradable polymer Polymers 0.000 description 1
- 239000004621 biodegradable polymer Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- PBAYDYUZOSNJGU-UHFFFAOYSA-N chelidonic acid Natural products OC(=O)C1=CC(=O)C=C(C(O)=O)O1 PBAYDYUZOSNJGU-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000003869 coulometry Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- OGQYPPBGSLZBEG-UHFFFAOYSA-N dimethyl(dioctadecyl)azanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC OGQYPPBGSLZBEG-UHFFFAOYSA-N 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910052909 inorganic silicate Inorganic materials 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical group C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910000269 smectite group Inorganic materials 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 1
- 238000009210 therapy by ultrasound Methods 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- SZEMGTQCPRNXEG-UHFFFAOYSA-M trimethyl(octadecyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C SZEMGTQCPRNXEG-UHFFFAOYSA-M 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/19—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1334—Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.]
- Y10T428/1345—Single layer [continuous layer]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1397—Single layer [continuous layer]
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Wrappers (AREA)
- Biological Depolymerization Polymers (AREA)
- Packging For Living Organisms, Food Or Medicinal Products That Are Sensitive To Environmental Conditiond (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Laminated Bodies (AREA)
- Saccharide Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP10382216 | 2010-08-04 | ||
| PCT/EP2011/063406 WO2012017026A1 (en) | 2010-08-04 | 2011-08-03 | Modified phyllosilicate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2601251T3 true DK2601251T3 (en) | 2015-03-30 |
Family
ID=43244826
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK11738754.8T DK2601251T3 (en) | 2010-08-04 | 2011-08-03 | Modified phyllosilicate |
Country Status (15)
| Country | Link |
|---|---|
| US (2) | US9169389B2 (enExample) |
| EP (2) | EP2601252B1 (enExample) |
| JP (2) | JP5927189B2 (enExample) |
| CN (2) | CN103097445B (enExample) |
| BR (2) | BR112013002710B1 (enExample) |
| CY (1) | CY1116139T1 (enExample) |
| DK (1) | DK2601251T3 (enExample) |
| ES (2) | ES2557590T3 (enExample) |
| HR (1) | HRP20150322T1 (enExample) |
| PL (2) | PL2601252T3 (enExample) |
| PT (1) | PT2601251E (enExample) |
| RS (1) | RS53908B1 (enExample) |
| SI (1) | SI2601251T1 (enExample) |
| SM (1) | SMT201500078B (enExample) |
| WO (2) | WO2012017025A1 (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2601252B1 (en) * | 2010-08-04 | 2015-10-14 | Instituto Tecnológico Del Embalaje, Transporte Y Logistica Itene | Polymer nanocomposite comprising polylactic acid reinforced with the modified phyllosilicate |
| JP5889671B2 (ja) * | 2012-02-24 | 2016-03-22 | 旭化成ケミカルズ株式会社 | エチレン酢酸ビニル共重合体樹脂組成物 |
| PL2787040T3 (pl) | 2013-04-04 | 2016-09-30 | Kompozycja do wytwarzania nanostrukturyzowanego biodegradowalnego materiału polimerowego, otrzymany materiał i jego zastosowania | |
| KR102382909B1 (ko) * | 2014-07-11 | 2022-04-04 | 엘리멘티스 스페셜티즈, 인크. | 하나 이상의 분지형 알킬 치환기를 갖는 4급 암모늄 이온을 갖는 유기점토 조성물 |
| US9562145B2 (en) | 2014-07-11 | 2017-02-07 | Elementis Specialties, Inc. | Organoclay compositions having quaternary ammonium ion having one or more branched alkyl substituents |
| JP6398406B2 (ja) * | 2014-07-15 | 2018-10-03 | 富士ゼロックス株式会社 | ポリ乳酸樹脂変性用の改質剤、樹脂組成物及び樹脂成形体 |
| KR102550842B1 (ko) * | 2014-12-09 | 2023-07-05 | 스마트폴리머 게엠베하 | 활성 성분의 표적화된 방출을 갖는 기능성 셀룰로오스 성형품의 제조 방법 |
| CN105199347B (zh) * | 2015-10-09 | 2017-10-13 | 湖北工业大学 | Pla/mmt降解增强母料共混改性pla/pbat复合材料及其制备方法 |
| WO2018050770A1 (en) | 2016-09-15 | 2018-03-22 | Instituto Tecnológico Del Embalaje, Transporte Y Logística (Itene) | Polymer nanocomposite comprising poly(ethylene terephthalate) reinforced with an intercalated phyllosilicate |
| CN107099116A (zh) * | 2017-05-18 | 2017-08-29 | 湖南省达琪新材料有限公司 | 聚酰胺多胺插层层状硅酸盐复合材料的制备方法 |
| CN108821301B (zh) * | 2018-06-08 | 2022-06-21 | 安徽艾米伦特建材科技有限公司 | 保温材料用改性蒙脱土及其制备方法 |
| US11912926B2 (en) | 2018-09-04 | 2024-02-27 | Saudi Arabian Oil Company | Synthetic functionalized additives, methods of synthesizing, and methods of use |
| CN112639048A (zh) | 2018-09-04 | 2021-04-09 | 沙特阿拉伯石油公司 | 合成官能化添加剂、合成的方法和使用的方法 |
| US11242478B2 (en) * | 2018-09-13 | 2022-02-08 | Saudi Arabian Oil Company | Charged composite materials, methods of synthesizing, and methods of use |
| CN109796646A (zh) * | 2018-12-12 | 2019-05-24 | 青岛大学 | 一种碳纳米管改性层状硅酸盐协同增强充油型多元溶液共凝橡胶及其制备方法 |
| WO2020219447A1 (en) | 2019-04-23 | 2020-10-29 | Elementis Specialties, Inc. | Slurry compositions containing mixed branched alkyl organoclay compositions |
| CN117050486A (zh) * | 2022-05-07 | 2023-11-14 | 深圳市裕同包装科技股份有限公司 | 用于制造阻隔层的组合物、阻隔层及其制造方法和包装材料 |
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| JPS6379773A (ja) * | 1986-09-19 | 1988-04-09 | 松下電工株式会社 | 無機層状多孔体の製法 |
| JPS6385067A (ja) * | 1986-09-25 | 1988-04-15 | 松下電工株式会社 | 無機層状多孔体の製法 |
| CN1214711A (zh) * | 1996-02-23 | 1999-04-21 | 陶氏化学公司 | 聚合物复合材料及其制备方法 |
| BR9707876A (pt) * | 1996-12-31 | 1999-07-27 | Dow Chemical Co | Composto de polímero metodos para formar um composto de fibra reforçada e método para aumentar a distância entre as camadas de um silicata inorgânico em camadas |
| JPH11131047A (ja) * | 1997-10-29 | 1999-05-18 | Co-Op Chem Co Ltd | 有機−粘土複合体と有機溶剤よりなる組成物 |
| FR2771308B1 (fr) | 1997-11-25 | 1999-12-31 | Inst Francais Du Petrole | Procede d'isomerisation des normales paraffines c5-c10 utilisant un phyllosilicate 2:1 dioctaedrique ponte a grande distance reticulaire |
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| JP2008075068A (ja) * | 2006-08-25 | 2008-04-03 | Canon Inc | 樹脂組成物 |
| JP5146868B2 (ja) * | 2006-09-06 | 2013-02-20 | 独立行政法人物質・材料研究機構 | ポリ乳酸複合材料 |
| US20090018264A1 (en) * | 2007-07-12 | 2009-01-15 | Canon Kabushiki Kaisha | Resin composition |
| JP2009242775A (ja) * | 2008-03-13 | 2009-10-22 | Toray Ind Inc | 難燃性ポリエステル樹脂組成物およびそれからなる繊維構造物 |
| US8633261B2 (en) * | 2008-04-15 | 2014-01-21 | The University Of Queensland | Polymer composites having particles with mixed organic modifications |
| EP2601252B1 (en) * | 2010-08-04 | 2015-10-14 | Instituto Tecnológico Del Embalaje, Transporte Y Logistica Itene | Polymer nanocomposite comprising polylactic acid reinforced with the modified phyllosilicate |
-
2011
- 2011-08-03 EP EP11739067.4A patent/EP2601252B1/en active Active
- 2011-08-03 PL PL11739067T patent/PL2601252T3/pl unknown
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- 2011-08-03 EP EP11738754.8A patent/EP2601251B1/en active Active
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2015
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