DK2134468T3 - PROCESS FOR THE SYNTHESIS OF METAL cubic nanoparticles in the presence of reducing agents TWO - Google Patents
PROCESS FOR THE SYNTHESIS OF METAL cubic nanoparticles in the presence of reducing agents TWO Download PDFInfo
- Publication number
- DK2134468T3 DK2134468T3 DK08787767.6T DK08787767T DK2134468T3 DK 2134468 T3 DK2134468 T3 DK 2134468T3 DK 08787767 T DK08787767 T DK 08787767T DK 2134468 T3 DK2134468 T3 DK 2134468T3
- Authority
- DK
- Denmark
- Prior art keywords
- metal
- nanoparticles
- aqueous solution
- mol
- concentration
- Prior art date
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- 238000000034 method Methods 0.000 title claims description 99
- 239000002105 nanoparticle Substances 0.000 title claims description 90
- 230000008569 process Effects 0.000 title claims description 73
- 239000003638 chemical reducing agent Substances 0.000 title claims description 32
- 230000015572 biosynthetic process Effects 0.000 title description 18
- 238000003786 synthesis reaction Methods 0.000 title description 14
- 229910052751 metal Inorganic materials 0.000 claims description 121
- 239000002184 metal Substances 0.000 claims description 119
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 104
- 239000000243 solution Substances 0.000 claims description 93
- 239000007864 aqueous solution Substances 0.000 claims description 83
- 239000002082 metal nanoparticle Substances 0.000 claims description 58
- 229910052763 palladium Inorganic materials 0.000 claims description 51
- 239000003381 stabilizer Substances 0.000 claims description 50
- 150000001875 compounds Chemical class 0.000 claims description 48
- 235000010378 sodium ascorbate Nutrition 0.000 claims description 34
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 claims description 34
- 229960005055 sodium ascorbate Drugs 0.000 claims description 34
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical group [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 claims description 34
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- 230000000737 periodic effect Effects 0.000 claims description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 239000008139 complexing agent Substances 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
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- 238000002156 mixing Methods 0.000 claims description 8
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- 239000010941 cobalt Substances 0.000 claims description 5
- 229910017052 cobalt Inorganic materials 0.000 claims description 5
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- -1 quaternary ammonium halogen salt Chemical class 0.000 claims description 5
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- 150000004678 hydrides Chemical class 0.000 claims 1
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- 229910002093 potassium tetrachloropalladate(II) Inorganic materials 0.000 description 65
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical group [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 63
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- YJVFFLUZDVXJQI-UHFFFAOYSA-L palladium(ii) acetate Chemical compound [Pd+2].CC([O-])=O.CC([O-])=O YJVFFLUZDVXJQI-UHFFFAOYSA-L 0.000 description 2
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- NWAHZABTSDUXMJ-UHFFFAOYSA-N platinum(2+);dinitrate Chemical compound [Pt+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O NWAHZABTSDUXMJ-UHFFFAOYSA-N 0.000 description 2
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- FDWREHZXQUYJFJ-UHFFFAOYSA-M gold monochloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 description 1
- OTCKNHQTLOBDDD-UHFFFAOYSA-K gold(3+);triacetate Chemical compound [Au+3].CC([O-])=O.CC([O-])=O.CC([O-])=O OTCKNHQTLOBDDD-UHFFFAOYSA-K 0.000 description 1
- ZVUZTTDXWACDHD-UHFFFAOYSA-N gold(3+);trinitrate Chemical compound [Au+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O ZVUZTTDXWACDHD-UHFFFAOYSA-N 0.000 description 1
- 125000001072 heteroaryl group Chemical group 0.000 description 1
- 238000007210 heterogeneous catalysis Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000001261 hydroxy acids Chemical class 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- KZCOBXFFBQJQHH-UHFFFAOYSA-N octane-1-thiol Chemical compound CCCCCCCCS KZCOBXFFBQJQHH-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000013110 organic ligand Substances 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- AEPKDRAICDFPEY-UHFFFAOYSA-L palladium(2+);dinitrite Chemical compound [Pd+2].[O-]N=O.[O-]N=O AEPKDRAICDFPEY-UHFFFAOYSA-L 0.000 description 1
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
- JKDRQYIYVJVOPF-FDGPNNRMSA-L palladium(ii) acetylacetonate Chemical compound [Pd+2].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O JKDRQYIYVJVOPF-FDGPNNRMSA-L 0.000 description 1
- INIOZDBICVTGEO-UHFFFAOYSA-L palladium(ii) bromide Chemical compound Br[Pd]Br INIOZDBICVTGEO-UHFFFAOYSA-L 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical group OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 229930192851 perforin Natural products 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N phosphine group Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 1
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
- CJWLZBLADIYQOV-UHFFFAOYSA-L platinum(2+);dinitrite Chemical compound [Pt+2].[O-]N=O.[O-]N=O CJWLZBLADIYQOV-UHFFFAOYSA-L 0.000 description 1
- PQTLYDQECILMMB-UHFFFAOYSA-L platinum(2+);sulfate Chemical compound [Pt+2].[O-]S([O-])(=O)=O PQTLYDQECILMMB-UHFFFAOYSA-L 0.000 description 1
- SNPHNDVOPWUNON-UHFFFAOYSA-J platinum(4+);tetrabromide Chemical compound [Br-].[Br-].[Br-].[Br-].[Pt+4] SNPHNDVOPWUNON-UHFFFAOYSA-J 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- CQLFBEKRDQMJLZ-UHFFFAOYSA-M silver acetate Chemical compound [Ag+].CC([O-])=O CQLFBEKRDQMJLZ-UHFFFAOYSA-M 0.000 description 1
- 229940071536 silver acetate Drugs 0.000 description 1
- SDLBJIZEEMKQKY-UHFFFAOYSA-M silver chlorate Chemical compound [Ag+].[O-]Cl(=O)=O SDLBJIZEEMKQKY-UHFFFAOYSA-M 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- KKKDGYXNGYJJRX-UHFFFAOYSA-M silver nitrite Chemical compound [Ag+].[O-]N=O KKKDGYXNGYJJRX-UHFFFAOYSA-M 0.000 description 1
- YPNVIBVEFVRZPJ-UHFFFAOYSA-L silver sulfate Chemical compound [Ag+].[Ag+].[O-]S([O-])(=O)=O YPNVIBVEFVRZPJ-UHFFFAOYSA-L 0.000 description 1
- 229910000367 silver sulfate Inorganic materials 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 150000003573 thiols Chemical group 0.000 description 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
- 229910003452 thorium oxide Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- ZMBHCYHQLYEYDV-UHFFFAOYSA-N trioctylphosphine oxide Chemical compound CCCCCCCCP(=O)(CCCCCCCC)CCCCCCCC ZMBHCYHQLYEYDV-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
- B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
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- B22F1/05—Metallic powder characterised by the size or surface area of the particles
- B22F1/054—Nanosized particles
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- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/05—Metallic powder characterised by the size or surface area of the particles
- B22F1/054—Nanosized particles
- B22F1/0553—Complex form nanoparticles, e.g. prism, pyramid, octahedron
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- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/05—Metallic powder characterised by the size or surface area of the particles
- B22F1/054—Nanosized particles
- B22F1/056—Submicron particles having a size above 100 nm up to 300 nm
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
- B22F9/24—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from liquid metal compounds, e.g. solutions
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
- B22F9/24—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from liquid metal compounds, e.g. solutions
- B22F9/26—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from liquid metal compounds, e.g. solutions using gaseous reductors
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
- C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
- C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
- C10G45/36—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
- C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
- C10G45/40—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing platinum group metals or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2999/00—Aspects linked to processes or compositions used in powder metallurgy
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Nanotechnology (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0702409A FR2914200B1 (fr) | 2007-03-30 | 2007-03-30 | Procede de synthese de nanoparticules metalliques cubiques en presence de deux reducteurs |
| PCT/FR2008/000294 WO2008132314A2 (fr) | 2007-03-30 | 2008-03-05 | Procede de synthese de nanoparticules metalliques cubiques en presence de deux reducteurs |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2134468T3 true DK2134468T3 (en) | 2016-02-15 |
Family
ID=38625842
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK08787767.6T DK2134468T3 (en) | 2007-03-30 | 2008-03-05 | PROCESS FOR THE SYNTHESIS OF METAL cubic nanoparticles in the presence of reducing agents TWO |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8652232B2 (zh) |
| EP (1) | EP2134468B1 (zh) |
| CN (1) | CN101646491B (zh) |
| DK (1) | DK2134468T3 (zh) |
| FR (1) | FR2914200B1 (zh) |
| SA (1) | SA08290175B1 (zh) |
| TW (1) | TWI374119B (zh) |
| WO (1) | WO2008132314A2 (zh) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110023658A1 (en) * | 2009-08-03 | 2011-02-03 | Seashell Technology, Llc | Methods For The Production Of Silver Nanocubes |
| CN102179525B (zh) * | 2011-04-15 | 2013-05-08 | 北京航空航天大学 | 一种室温条件制备镍铂双层纳米碗的可控合成方法 |
| FR2974740B1 (fr) * | 2011-05-02 | 2014-01-10 | Commissariat Energie Atomique | Composition pour la synthese de nanoparticules bimetalliques dans un liquide ionique et procede associe |
| US9732401B2 (en) * | 2011-11-16 | 2017-08-15 | M. Technique Co., Ltd. | Solid metal alloy |
| WO2013073068A1 (ja) * | 2011-11-16 | 2013-05-23 | エム・テクニック株式会社 | 銀銅合金粒子の製造方法 |
| RU2479562C1 (ru) * | 2012-03-20 | 2013-04-20 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Волгоградский государственный технический университет" (ВогГТУ) | Способ получения линейных алканов |
| EP2870997B1 (en) * | 2012-07-09 | 2019-12-04 | Toyota Jidosha Kabushiki Kaisha | Catalyst for emission gas purification and production method thereof |
| US9928945B2 (en) | 2012-10-24 | 2018-03-27 | Nippon Soda Co., Ltd. | Production method for particles of element having standard electrode potential greater than 0V |
| CN103121100B (zh) * | 2013-02-07 | 2015-10-28 | 东华大学 | 一种转移油酸包覆的纳米银颗粒至水相的方法 |
| CN103433044B (zh) * | 2013-08-27 | 2015-05-13 | 安徽大学 | 一种钴-镍双金属氢氧化物纳米复合物的制备方法 |
| IN2013MU02841A (zh) * | 2013-09-02 | 2015-07-03 | Tata Chemicals Ltd | |
| WO2015125650A1 (ja) * | 2014-02-21 | 2015-08-27 | 国立大学法人高知大学 | ニッケル粉の製造方法 |
| JP6442298B2 (ja) * | 2014-03-26 | 2018-12-19 | 国立大学法人高知大学 | ニッケル粉の製造方法 |
| US20160001370A1 (en) | 2014-07-03 | 2016-01-07 | Carestream Health, Inc. | Reducing agents for silver morphology control |
| CN104128616B (zh) * | 2014-08-12 | 2016-03-23 | 苏州思美特表面材料科技有限公司 | 一种金属粉末的制备方法 |
| EP3250320A4 (en) * | 2015-01-29 | 2018-08-08 | BASF Corporation | Platinum group metal (pgm) catalysts for automotive emissions treatment |
| CN105170997A (zh) * | 2015-10-13 | 2015-12-23 | 东南大学 | 双还原剂纳米金量子点的室温快速合成方法 |
| CN108430676B (zh) * | 2015-12-15 | 2021-11-02 | 意大利科技研究基金会 | 在不使用形状导向剂的情况下在含水环境中合成金属纳米颗粒的方法 |
| CN106001607A (zh) * | 2016-07-06 | 2016-10-12 | 济宁利特纳米技术有限责任公司 | 一种在疏水相中制备银纳米立方体的方法 |
| CN106311225A (zh) * | 2016-08-10 | 2017-01-11 | 华南理工大学 | 一种木质素碳纳米微球负载钯催化剂及其制备方法和应用 |
| CN109420495A (zh) * | 2017-08-30 | 2019-03-05 | 中国科学院大连化学物理研究所 | 负载型钯纳米立方体催化剂及制备和过氧化氢合成中应用 |
| CN107685156A (zh) * | 2017-10-11 | 2018-02-13 | 中国科学院合肥物质科学研究院 | 银纳米立方体的制备方法 |
| CN108031858A (zh) * | 2017-11-28 | 2018-05-15 | 苏州大学 | 一种表面形貌可控的钯纳米立方八面体的制备方法 |
| CN108723385B (zh) * | 2018-06-07 | 2021-07-09 | 大连民族大学 | 一种单晶银纳米球水相制备方法 |
| CN109355677B (zh) * | 2018-11-15 | 2020-05-19 | 江苏科技大学 | 表面掺杂磷元素的钯立方纳米晶及其制备方法和应用 |
| WO2020150354A1 (en) * | 2019-01-17 | 2020-07-23 | Shell Oil Company | A bimetallic nanoparticle-based catalyst, its use in selective hydrogenation, and a method of making the catalyst |
| EP3946726A1 (en) * | 2019-03-29 | 2022-02-09 | ExxonMobil Chemical Patents Inc. | Compositions comprising nanoparticles and processes for making nanoparticles |
| US11331725B2 (en) * | 2019-07-19 | 2022-05-17 | Honda Motor Co., Ltd. | Synthetic method for preparing small palladium nanocubes |
| CN110842212A (zh) * | 2019-11-07 | 2020-02-28 | 南京师范大学 | 一种超细Pd四面体纳米材料及其制备方法和应用 |
| IT201900020697A1 (it) | 2019-11-11 | 2021-05-11 | Fondazione St Italiano Tecnologia | Processo per la produzione di nanocristalli di Pt ultra-piccoli con elevata percentuale di domini superficiali {111} |
| CN113118432B (zh) * | 2019-12-30 | 2022-05-24 | Tcl科技集团股份有限公司 | 贵金属纳米粒子及其制备方法和应用 |
| CN111992734B (zh) * | 2020-08-21 | 2022-02-22 | 山东建邦胶体材料有限公司 | 一种粒径可控的纳米银的制备方法 |
| CN112692274A (zh) * | 2020-12-21 | 2021-04-23 | 有研亿金新材料有限公司 | 一种高分散性超细铂粉的制备方法及应用 |
| CN115779897B (zh) * | 2022-11-28 | 2024-05-24 | 青岛科技大学 | 一种利用电催化降解水中有机污染物的双金属纳米材料的制备及应用 |
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| US5147841A (en) * | 1990-11-23 | 1992-09-15 | The United States Of America As Represented By The United States Department Of Energy | Method for the preparation of metal colloids in inverse micelles and product preferred by the method |
| US6090858A (en) * | 1998-03-18 | 2000-07-18 | Georgia Tech Reseach Corporation | Shape control method for nanoparticles for making better and new catalysts |
| US7585349B2 (en) * | 2002-12-09 | 2009-09-08 | The University Of Washington | Methods of nanostructure formation and shape selection |
| CN1232377C (zh) * | 2003-06-05 | 2005-12-21 | 中国科学院理化技术研究所 | 立方体银纳米晶颗粒的制备方法 |
| FR2874515B1 (fr) | 2004-08-26 | 2007-09-07 | Inst Francais Du Petrole | Catalyseur comportant des nanoparticules metalliques anisotropes supportees, methode de synthese et applications |
| US8129199B2 (en) * | 2004-12-13 | 2012-03-06 | University of South Caroliina | Surface enhanced Raman spectroscopy using shaped gold nanoparticles |
| US7547347B2 (en) * | 2005-05-13 | 2009-06-16 | University Of Rochester | Synthesis of nano-materials in ionic liquids |
| US20070068343A1 (en) * | 2005-06-30 | 2007-03-29 | Lukehart Charles M | Synthesis of shape-specific transition metal nanoparticles |
| FR2893262A1 (fr) | 2005-11-14 | 2007-05-18 | Inst Francais Du Petrole | Procede de synthese en presence de reducteur d'un catalyseur a base de nanoparticules metalliques anisotropes. |
| KR100797484B1 (ko) * | 2006-08-29 | 2008-01-23 | 삼성전기주식회사 | 큐빅 형태의 구리 나노입자의 제조방법 |
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- 2008-03-05 EP EP08787767.6A patent/EP2134468B1/fr active Active
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- 2008-03-05 CN CN200880010232.8A patent/CN101646491B/zh active Active
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| US8652232B2 (en) | 2014-02-18 |
| US20100280296A1 (en) | 2010-11-04 |
| WO2008132314A3 (fr) | 2008-12-31 |
| CN101646491B (zh) | 2014-07-02 |
| SA08290175B1 (ar) | 2013-09-01 |
| FR2914200A1 (fr) | 2008-10-03 |
| TW200902449A (en) | 2009-01-16 |
| FR2914200B1 (fr) | 2009-11-27 |
| EP2134468A2 (fr) | 2009-12-23 |
| EP2134468B1 (fr) | 2015-11-04 |
| CN101646491A (zh) | 2010-02-10 |
| TWI374119B (en) | 2012-10-11 |
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