DE69820060T2 - Filmbildendes Terpolymer aus Propylen sowie Verfahren zur Herstellung solcher Terpolymere - Google Patents
Filmbildendes Terpolymer aus Propylen sowie Verfahren zur Herstellung solcher Terpolymere Download PDFInfo
- Publication number
- DE69820060T2 DE69820060T2 DE69820060T DE69820060T DE69820060T2 DE 69820060 T2 DE69820060 T2 DE 69820060T2 DE 69820060 T DE69820060 T DE 69820060T DE 69820060 T DE69820060 T DE 69820060T DE 69820060 T2 DE69820060 T2 DE 69820060T2
- Authority
- DE
- Germany
- Prior art keywords
- terpolymer
- gas phase
- propylene
- weight
- reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
- 229920001897 terpolymer Polymers 0.000 title claims description 54
- 238000000034 method Methods 0.000 title claims description 42
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims description 35
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 title claims description 33
- 239000007789 gas Substances 0.000 claims description 43
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 36
- 229920000642 polymer Polymers 0.000 claims description 36
- 239000005977 Ethylene Substances 0.000 claims description 34
- 238000002844 melting Methods 0.000 claims description 31
- 230000008018 melting Effects 0.000 claims description 31
- 239000004711 α-olefin Substances 0.000 claims description 27
- 238000006116 polymerization reaction Methods 0.000 claims description 25
- 239000010802 sludge Substances 0.000 claims description 24
- 239000000047 product Substances 0.000 claims description 20
- 239000003054 catalyst Substances 0.000 claims description 19
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 15
- 239000000178 monomer Substances 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 239000011541 reaction mixture Substances 0.000 claims description 8
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims description 6
- 239000000155 melt Substances 0.000 claims description 5
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims description 5
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 claims description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 4
- 150000001336 alkenes Chemical class 0.000 claims description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims 2
- 239000012467 final product Substances 0.000 claims 2
- 238000007789 sealing Methods 0.000 description 26
- 239000000463 material Substances 0.000 description 17
- 238000011010 flushing procedure Methods 0.000 description 14
- 238000009826 distribution Methods 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 11
- 229920001577 copolymer Polymers 0.000 description 10
- -1 polypropylene Polymers 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000004743 Polypropylene Substances 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 239000007795 chemical reaction product Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 3
- 238000000113 differential scanning calorimetry Methods 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 241000282326 Felis catus Species 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000012968 metallocene catalyst Substances 0.000 description 2
- 229920005606 polypropylene copolymer Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000034303 cell budding Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000012792 core layer Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000013627 low molecular weight specie Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000011020 pilot scale process Methods 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000009700 powder processing Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 150000003624 transition metals Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/2435—Loop-type reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
- B01J8/26—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/34—Polymerisation in gaseous state
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00121—Controlling the temperature by direct heating or cooling
- B01J2219/00128—Controlling the temperature by direct heating or cooling by evaporation of reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00162—Controlling or regulating processes controlling the pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00164—Controlling or regulating processes controlling the flow
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00184—Controlling or regulating processes controlling the weight of reactants in the reactor vessel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/916—Interpolymer from at least three ethylenically unsaturated monoolefinic hydrocarbon monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI972714A FI104824B (fi) | 1997-06-24 | 1997-06-24 | Menetelmä propeenin terpolymeerien aikaansaamiseksi |
| FI972714 | 1997-06-24 | ||
| PCT/FI1998/000556 WO1998058971A1 (en) | 1997-06-24 | 1998-06-24 | Propylene terpolymers and a process for the production thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69820060D1 DE69820060D1 (de) | 2004-01-08 |
| DE69820060T2 true DE69820060T2 (de) | 2004-07-22 |
Family
ID=8549114
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69820060T Revoked DE69820060T2 (de) | 1997-06-24 | 1998-06-24 | Filmbildendes Terpolymer aus Propylen sowie Verfahren zur Herstellung solcher Terpolymere |
Country Status (16)
| Country | Link |
|---|---|
| US (2) | US6365682B1 (enExample) |
| EP (1) | EP0991679B1 (enExample) |
| JP (1) | JP2002504956A (enExample) |
| KR (1) | KR100551509B1 (enExample) |
| CN (1) | CN1107084C (enExample) |
| AR (1) | AR013126A1 (enExample) |
| AT (1) | ATE255134T1 (enExample) |
| AU (1) | AU726669B2 (enExample) |
| BR (1) | BR9810625A (enExample) |
| DE (1) | DE69820060T2 (enExample) |
| ES (1) | ES2209155T3 (enExample) |
| FI (1) | FI104824B (enExample) |
| MY (1) | MY120993A (enExample) |
| TW (1) | TW562812B (enExample) |
| WO (1) | WO1998058971A1 (enExample) |
| ZA (1) | ZA985489B (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102008006699B4 (de) | 2007-02-01 | 2024-07-04 | Sumitomo Chemical Co. Ltd. | Verfahren zur Herstellung eines Copolymermaterials auf Propylenbasis |
Families Citing this family (67)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6921794B2 (en) * | 1997-08-12 | 2005-07-26 | Exxonmobil Chemical Patents Inc. | Blends made from propylene ethylene polymers |
| US6635715B1 (en) * | 1997-08-12 | 2003-10-21 | Sudhin Datta | Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers |
| US7232871B2 (en) * | 1997-08-12 | 2007-06-19 | Exxonmobil Chemical Patents Inc. | Propylene ethylene polymers and production process |
| AU4962399A (en) * | 1998-07-01 | 2000-01-24 | Exxon Chemical Patents Inc. | Elastic blends comprising crystalline polymer and crystallizable polymers of propylene |
| AU2002220722A1 (en) * | 2000-11-28 | 2002-06-11 | Borealis Gmbh | Use of propylene terpolymers for the production of films |
| EP1209187A1 (en) * | 2000-11-28 | 2002-05-29 | Borealis GmbH | Use of propylene terpolymers for the production of films |
| JP5156167B2 (ja) | 2001-04-12 | 2013-03-06 | エクソンモービル・ケミカル・パテンツ・インク | プロピレン−エチレンポリマー及び製造法 |
| ATE370184T1 (de) | 2001-06-27 | 2007-09-15 | Borealis Tech Oy | Verfahren zur herstellung einer polymerfolie die ein statistisches propylencopolymer enthält |
| ATE278723T1 (de) * | 2001-06-27 | 2004-10-15 | Borealis Tech Oy | Propylen-copolymer mit zufälliger comonomerverteilung und verfahren zu seiner herstellung |
| ATE396472T1 (de) | 2002-06-26 | 2008-06-15 | Avery Dennison Corp | Längsorientierte polymere filme |
| ATE435245T1 (de) * | 2005-05-12 | 2009-07-15 | Basell Poliolefine Srl | Propylen-ethylen-copolymere und herstellungsverfahren dafür |
| ES2398725T3 (es) | 2006-06-14 | 2013-03-21 | Avery Dennison Corporation | Material para etiquetas orientado en la dirección longitudinal que se puede conformar y cortar con troquel y etiquetas y proceso para su preparación |
| BRPI0713492A2 (pt) | 2006-06-20 | 2012-01-24 | Avery Dennison Corp | filme polimérico de multi-camadas para rotulagem de adesivos de derretimento a quente e etiqueta e rótulo dos mesmos |
| DE602006004987D1 (de) | 2006-07-10 | 2009-03-12 | Borealis Tech Oy | Elektrischer Isolierfilm |
| EP1886806B1 (en) | 2006-07-10 | 2010-11-10 | Borealis Technology Oy | Biaxially oriented polypropylene film |
| EP1892264A1 (en) | 2006-08-25 | 2008-02-27 | Borealis Technology Oy | Extrusion coated substrate |
| EP1900764B1 (en) | 2006-08-25 | 2009-04-01 | Borealis Technology Oy | Polypropylene foam |
| EP1903579B1 (en) | 2006-09-25 | 2010-03-24 | Borealis Technology Oy | Coaxial cable |
| DE602006007028D1 (de) * | 2006-12-18 | 2009-07-09 | Borealis Tech Oy | Terpolymer mit hohem Schmelzpunkt |
| ATE424424T1 (de) | 2006-12-28 | 2009-03-15 | Borealis Tech Oy | Verfahren zur herstellung von verzweigtem polypropylen |
| RU2458734C2 (ru) * | 2007-08-03 | 2012-08-20 | Базелль Полиолефин Италия С.Р.Л. | Способ получения пропиленовых терполимеров |
| US7868104B2 (en) * | 2007-10-26 | 2011-01-11 | Exxonmobil Chemical Patents Inc. | Crystallizable propylene copolymers |
| DE602007009851D1 (de) * | 2007-11-30 | 2010-11-25 | Borealis Tech Oy | Random-Propylencopolymer mit hohem Comonomergehalt |
| CN102834424B (zh) * | 2010-04-14 | 2014-08-13 | 巴塞尔聚烯烃意大利有限责任公司 | 用于薄膜的丙烯基三元共聚物 |
| WO2012031952A1 (en) | 2010-09-06 | 2012-03-15 | Basell Poliolefine Italia S.R.L. | Polypropylene-based terpolymers for films |
| US9006368B2 (en) | 2010-09-06 | 2015-04-14 | Basell Poliolefine Italia S.R.L. | Propylene-based terpolymers for film |
| EP2699718B1 (en) | 2011-04-21 | 2015-03-04 | Basell Poliolefine Italia S.r.l. | Propylene-based terpolymers for fibers |
| CN103781614B (zh) | 2011-09-01 | 2016-08-31 | 巴塞尔聚烯烃意大利有限责任公司 | 用于薄膜的基于丙烯的三元共聚物 |
| EP2666793A1 (en) | 2012-05-21 | 2013-11-27 | Basell Poliolefine Italia S.r.l. | Propylene based terpolymer |
| US9676532B2 (en) | 2012-08-15 | 2017-06-13 | Avery Dennison Corporation | Packaging reclosure label for high alcohol content products |
| EP2749580B1 (en) * | 2012-12-28 | 2016-09-14 | Borealis AG | Process for producing copolymers of propylene |
| EP2813438A1 (en) | 2013-06-11 | 2014-12-17 | Basell Poliolefine Italia S.r.l. | Propylene based terpolymers |
| CN105452364B (zh) | 2013-08-14 | 2018-05-11 | 博里利斯股份公司 | 低温下具有改进的耐冲击性的丙烯组合物 |
| US9777142B2 (en) | 2013-08-21 | 2017-10-03 | Borealis Ag | High flow polyolefin composition with high stiffness and toughness |
| CA2919171A1 (en) | 2013-08-21 | 2015-02-26 | Borealis Ag | High flow polyolefin composition with high stiffness and toughness |
| PT2853563T (pt) | 2013-09-27 | 2016-07-14 | Borealis Ag | Filmes adequados para processamento de bopp a partir de polímeros com xs elevada e tm elevado |
| ES2568615T3 (es) | 2013-10-11 | 2016-05-03 | Borealis Ag | Película para etiquetas orientada en la dirección de la máquina |
| CN104558335B (zh) * | 2013-10-11 | 2017-06-09 | 中国石油化工股份有限公司 | 一种基于丙烯的三元共聚物的制备方法 |
| ES2661108T3 (es) | 2013-10-24 | 2018-03-27 | Borealis Ag | Homopolímero de polipropileno de bajo punto de fusión con alto contenido de regioerrores y alto peso molecular |
| WO2015075088A1 (en) | 2013-11-22 | 2015-05-28 | Borealis Ag | Low emission propylene homopolymer with high melt flow |
| BR112016011829B1 (pt) | 2013-12-04 | 2022-01-18 | Borealis Ag | Composição de polipropileno, fibra e trama soprada em fusão, artigo e uso da composição de polipropileno |
| JP6192029B2 (ja) | 2013-12-09 | 2017-09-06 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 多層金属蒸着フィルム |
| WO2015091839A1 (en) | 2013-12-18 | 2015-06-25 | Borealis Ag | Bopp film with improved stiffness/toughness balance |
| CN105829438A (zh) * | 2013-12-31 | 2016-08-03 | 博里利斯股份公司 | 制备丙烯三聚物的方法 |
| WO2015107020A1 (en) | 2014-01-17 | 2015-07-23 | Borealis Ag | Process for preparing propylene/1-butene copolymers |
| US10100185B2 (en) | 2014-02-06 | 2018-10-16 | Borealis Ag | Soft copolymers with high impact strength |
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| EP2907841A1 (en) | 2014-02-14 | 2015-08-19 | Borealis AG | Polypropylene composite |
| ES2659731T3 (es) | 2014-05-20 | 2018-03-19 | Borealis Ag | Composición de polipropileno para aplicaciones en interiores de automóviles |
| CA2951030C (en) | 2014-06-02 | 2023-03-28 | Christopher J. Blackwell | Films with enhanced scuff resistance, clarity, and conformability |
| EP3197786B1 (en) | 2014-09-24 | 2019-05-29 | Basell Poliolefine Italia S.r.l. | Containers comprising propylene-based terpolymers |
| EP3271408B1 (en) | 2015-03-19 | 2019-12-04 | Basell Poliolefine Italia S.r.l. | Propylene based terpolymer |
| KR101867254B1 (ko) | 2015-06-12 | 2018-06-12 | 보레알리스 아게 | 프로필렌 중합체 조성물의 제조 방법 |
| US10851191B2 (en) | 2015-06-30 | 2020-12-01 | Borealis Ag | Process for preparing propylene polymer compositions |
| WO2017001479A1 (en) | 2015-06-30 | 2017-01-05 | Borealis Ag | Process for preparing propylene polymer compositions |
| EP3187512A1 (en) | 2015-12-31 | 2017-07-05 | Borealis AG | Process for preparing propylene copolymer compositions |
| EP3257877B1 (en) | 2016-06-16 | 2023-10-04 | Borealis AG | Nucleated propylene-ethylene-butylene terpolymers and moulded articles made thereof |
| EP3453727A1 (en) * | 2017-09-08 | 2019-03-13 | Borealis AG | Process for preparing polypropylene composition |
| CN109721856A (zh) * | 2017-10-27 | 2019-05-07 | 中国石油化工股份有限公司 | 镀铝三元共聚聚丙烯流延膜树脂组合物 |
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| US11407867B2 (en) | 2017-11-09 | 2022-08-09 | Basell Poliolefine Italia S.R.L. | Heat-shrinkable label |
| CA3011038A1 (en) * | 2018-07-11 | 2020-01-11 | Nova Chemicals Corporation | Polyethylene composition and film having a good permeability, stiffness and sealability |
| CA3011031A1 (en) * | 2018-07-11 | 2020-01-11 | Nova Chemicals Corporation | Polyethylene composition and film having outstanding properties |
| CA3011050A1 (en) * | 2018-07-11 | 2020-01-11 | Nova Chemicals Corporation | Polyethylene composition and film having high stiffness, outstanding sealability and high permeability |
| CN111995703A (zh) * | 2020-08-18 | 2020-11-27 | 上海葛蓝化工科技有限公司 | 一种液相环管与卧式气相组成的多反应器烯烃聚合系统和聚合方法 |
| CN117916087A (zh) * | 2021-07-02 | 2024-04-19 | 格雷斯公司 | 丙烯三元共聚物和由其制造的热封膜 |
| CN116656036B (zh) * | 2023-06-29 | 2025-04-04 | 浙江大学宁波“五位一体”校区教育发展中心 | 一种高韧性聚烯烃薄膜及其制备方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2075993B (en) * | 1980-04-21 | 1983-11-30 | Sumitomo Chemical Co | Catalytic process for producing propylene block copolymers |
| IT1209255B (it) | 1980-08-13 | 1989-07-16 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine. |
| WO1986005794A1 (en) * | 1985-04-01 | 1986-10-09 | Uss Engineers And Consultants, Inc. | Terpolymer production |
| US4740551A (en) * | 1986-06-18 | 1988-04-26 | Shell Oil Company | Multistage copolymerization process |
| CA1308857C (en) * | 1988-03-30 | 1992-10-13 | Brian J. Pellon | Propylene copolymerization process |
| EP0955322A3 (en) * | 1988-12-26 | 1999-12-08 | Mitsui Chemicals, Inc. | Olefin copolymers and processes for preparing same |
| FI88047C (fi) | 1991-05-09 | 1993-03-25 | Neste Oy | Pao tvenne elektrondonorer baserad katalysator foer polymerisation av olefiner |
| US5587229A (en) | 1992-01-23 | 1996-12-24 | Montell North America Inc. | Resilient, high shrinkage propylene polymer yarn and articles made therefrom |
| US5346756A (en) | 1992-10-30 | 1994-09-13 | Himont Incorporated | Nonwoven textile material from blends of propylene polymer material and olefin polymer compositions |
| US5508318A (en) | 1993-07-15 | 1996-04-16 | Montell North America Inc. | Compositions of irradiated and non-irradiated olefin polymer materials with reduced gloss |
| IT1269194B (it) * | 1994-01-21 | 1997-03-21 | Spherilene Srl | Composizioni polimeriche ad elevata processabilita' basate su lldpe |
| IT1269914B (it) * | 1994-03-24 | 1997-04-16 | Himonty Inc | Composizioni verniciabili di copolimeri cristallini del propilene aventi bassa temperatura di saldabilita' |
| BE1009963A3 (fr) * | 1995-12-22 | 1997-11-04 | Solvay | Compositions a base de copolymeres statistiques du propylene, procede pour leur fabrication, et feuilles multicouches thermoscellables les contenant. |
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1997
- 1997-06-24 FI FI972714A patent/FI104824B/fi not_active IP Right Cessation
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1998
- 1998-06-24 EP EP98929463A patent/EP0991679B1/en not_active Revoked
- 1998-06-24 CN CN98808290A patent/CN1107084C/zh not_active Expired - Lifetime
- 1998-06-24 KR KR1019997012298A patent/KR100551509B1/ko not_active Expired - Lifetime
- 1998-06-24 ZA ZA985489A patent/ZA985489B/xx unknown
- 1998-06-24 WO PCT/FI1998/000556 patent/WO1998058971A1/en not_active Ceased
- 1998-06-24 ES ES98929463T patent/ES2209155T3/es not_active Expired - Lifetime
- 1998-06-24 DE DE69820060T patent/DE69820060T2/de not_active Revoked
- 1998-06-24 MY MYPI98002885A patent/MY120993A/en unknown
- 1998-06-24 AU AU79213/98A patent/AU726669B2/en not_active Expired
- 1998-06-24 BR BR9810625-2A patent/BR9810625A/pt not_active IP Right Cessation
- 1998-06-24 AR ARP980103030A patent/AR013126A1/es active IP Right Grant
- 1998-06-24 AT AT98929463T patent/ATE255134T1/de not_active IP Right Cessation
- 1998-06-24 US US09/446,503 patent/US6365682B1/en not_active Expired - Lifetime
- 1998-06-24 JP JP50385699A patent/JP2002504956A/ja active Pending
- 1998-08-13 TW TW087113335A patent/TW562812B/zh active
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102008006699B4 (de) | 2007-02-01 | 2024-07-04 | Sumitomo Chemical Co. Ltd. | Verfahren zur Herstellung eines Copolymermaterials auf Propylenbasis |
Also Published As
| Publication number | Publication date |
|---|---|
| BR9810625A (pt) | 2000-07-25 |
| DE69820060D1 (de) | 2004-01-08 |
| EP0991679A1 (en) | 2000-04-12 |
| FI104824B (fi) | 2000-04-14 |
| JP2002504956A (ja) | 2002-02-12 |
| US20020082376A1 (en) | 2002-06-27 |
| CN1107084C (zh) | 2003-04-30 |
| TW562812B (en) | 2003-11-21 |
| AU726669B2 (en) | 2000-11-16 |
| KR100551509B1 (ko) | 2006-02-13 |
| AU7921398A (en) | 1999-01-04 |
| US6365682B1 (en) | 2002-04-02 |
| EP0991679B1 (en) | 2003-11-26 |
| ES2209155T3 (es) | 2004-06-16 |
| ATE255134T1 (de) | 2003-12-15 |
| WO1998058971A1 (en) | 1998-12-30 |
| AR013126A1 (es) | 2000-12-13 |
| CN1267310A (zh) | 2000-09-20 |
| ZA985489B (en) | 1999-01-20 |
| US6552149B2 (en) | 2003-04-22 |
| KR20010020516A (ko) | 2001-03-15 |
| MY120993A (en) | 2005-12-30 |
| FI972714A7 (fi) | 1998-12-25 |
| FI972714A0 (fi) | 1997-06-24 |
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