DE69802403T2 - Oxidationsbeständige starre aromatische polyimidzusammensetzungen und verfahren zu ihrer herstellung - Google Patents
Oxidationsbeständige starre aromatische polyimidzusammensetzungen und verfahren zu ihrer herstellungInfo
- Publication number
- DE69802403T2 DE69802403T2 DE69802403T DE69802403T DE69802403T2 DE 69802403 T2 DE69802403 T2 DE 69802403T2 DE 69802403 T DE69802403 T DE 69802403T DE 69802403 T DE69802403 T DE 69802403T DE 69802403 T2 DE69802403 T2 DE 69802403T2
- Authority
- DE
- Germany
- Prior art keywords
- polyimide
- mole percent
- phenylenediamine
- composition
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920001721 polyimide Polymers 0.000 title claims description 98
- 239000004642 Polyimide Substances 0.000 title claims description 76
- 239000000203 mixture Substances 0.000 title claims description 59
- 238000000034 method Methods 0.000 title claims description 35
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 70
- 229920005575 poly(amic acid) Polymers 0.000 claims description 51
- 229920000642 polymer Polymers 0.000 claims description 46
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 35
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 claims description 32
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims description 32
- 229940018564 m-phenylenediamine Drugs 0.000 claims description 30
- 125000003118 aryl group Chemical group 0.000 claims description 29
- 150000004985 diamines Chemical class 0.000 claims description 28
- 239000009719 polyimide resin Substances 0.000 claims description 22
- 239000002904 solvent Substances 0.000 claims description 19
- GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 claims description 16
- 239000000945 filler Substances 0.000 claims description 16
- 239000002002 slurry Substances 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 15
- WKDNYTOXBCRNPV-UHFFFAOYSA-N bpda Chemical group C1=C2C(=O)OC(=O)C2=CC(C=2C=C3C(=O)OC(C3=CC=2)=O)=C1 WKDNYTOXBCRNPV-UHFFFAOYSA-N 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 229910002804 graphite Inorganic materials 0.000 claims description 8
- 239000010439 graphite Substances 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052622 kaolinite Inorganic materials 0.000 claims description 4
- 239000004927 clay Substances 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052982 molybdenum disulfide Inorganic materials 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- -1 polytetrafluoroethylene Polymers 0.000 claims description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 238000013019 agitation Methods 0.000 claims 1
- 150000000000 tetracarboxylic acids Chemical class 0.000 claims 1
- 230000003647 oxidation Effects 0.000 description 25
- 238000007254 oxidation reaction Methods 0.000 description 25
- 238000009864 tensile test Methods 0.000 description 20
- 230000004580 weight loss Effects 0.000 description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 12
- 238000012360 testing method Methods 0.000 description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 8
- 230000005484 gravity Effects 0.000 description 8
- 229910021383 artificial graphite Inorganic materials 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 description 6
- 239000000523 sample Substances 0.000 description 6
- 238000000465 moulding Methods 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- 238000005530 etching Methods 0.000 description 4
- 239000012065 filter cake Substances 0.000 description 4
- 238000010926 purge Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- HLBLWEWZXPIGSM-UHFFFAOYSA-N 4-Aminophenyl ether Chemical compound C1=CC(N)=CC=C1OC1=CC=C(N)C=C1 HLBLWEWZXPIGSM-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 229920003223 poly(pyromellitimide-1,4-diphenyl ether) Polymers 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 125000006158 tetracarboxylic acid group Chemical group 0.000 description 2
- ITQTTZVARXURQS-UHFFFAOYSA-N 3-methylpyridine Chemical compound CC1=CC=CN=C1 ITQTTZVARXURQS-UHFFFAOYSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000007514 bases Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000012255 powdered metal Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/1003—Preparatory processes
- C08G73/1007—Preparatory processes from tetracarboxylic acids or derivatives and diamines
- C08G73/1028—Preparatory processes from tetracarboxylic acids or derivatives and diamines characterised by the process itself, e.g. steps, continuous
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/1067—Wholly aromatic polyimides, i.e. having both tetracarboxylic and diamino moieties aromatically bound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C08L79/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/886,233 US5886129A (en) | 1997-07-01 | 1997-07-01 | Oxidatively stable rigid aromatic polyimide compositions and process for their preparation |
| PCT/US1998/013607 WO1999001497A1 (en) | 1997-07-01 | 1998-06-30 | Oxidatively stable rigid aromatic polyimide compositions and process for their preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69802403D1 DE69802403D1 (de) | 2001-12-13 |
| DE69802403T2 true DE69802403T2 (de) | 2002-06-27 |
Family
ID=25388670
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69802403T Expired - Lifetime DE69802403T2 (de) | 1997-07-01 | 1998-06-30 | Oxidationsbeständige starre aromatische polyimidzusammensetzungen und verfahren zu ihrer herstellung |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5886129A (enExample) |
| EP (1) | EP0993482B1 (enExample) |
| JP (2) | JP4295362B2 (enExample) |
| CN (1) | CN1145657C (enExample) |
| CA (1) | CA2293447C (enExample) |
| DE (1) | DE69802403T2 (enExample) |
| WO (1) | WO1999001497A1 (enExample) |
Families Citing this family (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101184798A (zh) * | 2005-05-27 | 2008-05-21 | 纳幕尔杜邦公司 | 具有低热膨胀系数的树脂组合物和由其制备的制品 |
| US20070160856A1 (en) * | 2005-12-05 | 2007-07-12 | Krizan Timothy D | Polyimide aircraft engine parts |
| US20070152195A1 (en) * | 2005-12-30 | 2007-07-05 | Saint-Gobain Performance Plastics Corporation | Electrostatic dissipative composite material |
| US20070154717A1 (en) * | 2005-12-30 | 2007-07-05 | Saint-Gobain Performance Plastics Corporation | Thermally stable composite material |
| US20070155949A1 (en) * | 2005-12-30 | 2007-07-05 | Saint-Gobain Performance Plastics Corporation | Thermally stable composite material |
| US20070154716A1 (en) * | 2005-12-30 | 2007-07-05 | Saint-Gobain Performance Plastics Corporation | Composite material |
| US7776433B2 (en) * | 2006-11-30 | 2010-08-17 | General Electric Company | Thermal oxidative barrier coatings for organic matrix composite substrates and coated articles |
| US7476339B2 (en) * | 2006-08-18 | 2009-01-13 | Saint-Gobain Ceramics & Plastics, Inc. | Highly filled thermoplastic composites |
| CN102219901B (zh) * | 2006-10-20 | 2013-02-27 | 长兴化学工业股份有限公司 | 酰胺酸酯低聚物、含所述低聚物的聚酰亚胺树脂的前驱物组合物及其应用 |
| CN101165079B (zh) * | 2006-10-20 | 2011-05-25 | 长兴化学工业股份有限公司 | 酰胺酸酯低聚物、含所述低聚物的聚酰亚胺树脂的前驱物组合物及其应用 |
| US7901763B2 (en) * | 2006-12-22 | 2011-03-08 | E.I. Du Pont De Nemours And Company | Porous infusible polymer parts |
| US8309645B2 (en) * | 2007-10-04 | 2012-11-13 | Saint-Gobain Performance Plastics Corporation | Thermally stable composite material formed of polyimide |
| US20090093608A1 (en) * | 2007-10-04 | 2009-04-09 | Saint-Gobain Performance Plastics Corporation | Polyimide material with improved thermal and mechanical properties |
| WO2009086479A1 (en) * | 2007-12-28 | 2009-07-09 | Saint-Gobain Performance Plastics Corporation | Etch resistant polymer composition |
| US7858687B2 (en) * | 2008-07-30 | 2010-12-28 | E.I. Du Pont De Nemours And Company | Polyimide resins for high temperature wear applications |
| US8324304B2 (en) * | 2008-07-30 | 2012-12-04 | E I Du Pont De Nemours And Company | Polyimide resins for high temperature wear applications |
| WO2010025363A1 (en) * | 2008-08-29 | 2010-03-04 | E. I. Du Pont De Nemours And Company | Composite parts for airplane engines |
| KR101663845B1 (ko) * | 2008-08-29 | 2016-10-07 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 항공기 엔진용 복합재 부품 |
| US20120053272A1 (en) | 2009-02-27 | 2012-03-01 | Robert Ray Burch | Polyimide resins for high temperature wear applications |
| WO2010107802A1 (en) * | 2009-03-17 | 2010-09-23 | E. I. Du Pont De Nemours And Company | Co-polymer based polyimide articles and their uses in an aircraft |
| KR20110131285A (ko) * | 2009-03-17 | 2011-12-06 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 공중합체 기반 폴리이미드로부터 제조된 물품 및 고온 유리 취급 응용에서의 그의 용도 |
| US20110098409A1 (en) * | 2009-10-27 | 2011-04-28 | E.I. Du Pont De Nemours And Company | Compositions and articles for high-temperature wear use |
| EP2493961A4 (en) * | 2009-10-27 | 2013-03-13 | Du Pont | POLYIMIDE RESINS FOR HIGH TEMPERATURE WEAR APPLICATIONS |
| CN102666728B (zh) * | 2009-10-27 | 2015-03-25 | 纳幕尔杜邦公司 | 用于高温磨耗应用的聚酰亚胺树脂 |
| KR101004429B1 (ko) | 2009-12-30 | 2010-12-28 | 주식회사 대림코퍼레이션 | 내열성과 고온영역의 인장특성이 향상된 전방향족 폴리이미드 수지의 제조방법 |
| WO2012050972A2 (en) | 2010-09-29 | 2012-04-19 | E. I. Du Pont De Nemours And Company | Polyimide resins for high temperature applications |
| US20130085195A1 (en) * | 2011-09-30 | 2013-04-04 | E.I. Du Pont De Nemours And Company | Co-polymer based polyimide articles and their uses in high temperature applications |
| KR101967946B1 (ko) * | 2011-12-19 | 2019-08-13 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 폴리이미드 수지 조성물 |
| TWI492970B (zh) | 2013-01-28 | 2015-07-21 | Taimide Technology Inc | 粉狀呈色消光劑、含有該消光劑之聚醯亞胺膜、及其製造方法 |
| US9863732B2 (en) | 2013-08-28 | 2018-01-09 | Proof Research, Inc. | Lightweight composite mortar tube |
| EP2886583B1 (de) | 2013-12-17 | 2018-10-17 | Evonik Fibres GmbH | Polyimidpulver mit hoher thermooxidativer Beständigkeit |
| JP2017533120A (ja) * | 2014-10-01 | 2017-11-09 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ | 飲料缶印刷ユニットのパーツである非熱可塑性ポリイミドを含むスピンドルカバー |
| US10302127B2 (en) | 2015-04-28 | 2019-05-28 | E. I. Du Pont De Nemours And Company | Needle bearing |
| WO2017197077A1 (en) | 2016-05-12 | 2017-11-16 | E I Du Pont De Nemours And Company | Polyimide compositions and a polyimide test socket housing |
| WO2018080797A1 (en) | 2016-10-25 | 2018-05-03 | E. I. Du Pont De Nemours And Company | Retainer ring |
| JP6871059B2 (ja) * | 2017-05-22 | 2021-05-12 | 大豊工業株式会社 | 摺動部材用樹脂材料及び摺動部材 |
| WO2022046617A1 (en) | 2020-08-24 | 2022-03-03 | Ddp Specialty Electronic Materials Us 9, Llc | Antifriction coating composition |
| KR102484478B1 (ko) | 2020-10-08 | 2023-01-03 | 연세대학교 원주산학협력단 | 기계적 물성이 향상된 판상형 폴리이미드 분말의 제조방법 |
| WO2024259184A1 (en) * | 2023-06-16 | 2024-12-19 | Dupont Specialty Products Usa, Llc | Polyimides: compositions, methods of making, and parts made therefrom |
| WO2025193509A1 (en) | 2024-03-12 | 2025-09-18 | Dupont Specialty Products Usa, Llc | Part comprising a polyimide composition |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3179614A (en) * | 1961-03-13 | 1965-04-20 | Du Pont | Polyamide-acids, compositions thereof, and process for their preparation |
| BE627626A (enExample) * | 1962-01-26 | 1900-01-01 | ||
| NL293724A (enExample) * | 1962-06-06 | |||
| JPS60206639A (ja) * | 1984-03-31 | 1985-10-18 | 日東電工株式会社 | ポリイミド−金属箔複合フイルムの製造方法 |
| US4622384A (en) * | 1985-04-26 | 1986-11-11 | E. I. Du Pont De Nemours And Company | Polyimide molding resins and molded articles |
| US4755555A (en) * | 1985-04-26 | 1988-07-05 | E. I. Du Pont De Nemours And Company | Polyimide molding resins and molded articles |
| JPH0745580B2 (ja) * | 1986-05-16 | 1995-05-17 | 宇部興産株式会社 | 芳香族ポリイミドフィルム |
| JPS646118A (en) * | 1987-06-19 | 1989-01-10 | Toray Industries | Copolyimide fiber |
| US5075036A (en) * | 1989-08-16 | 1991-12-24 | E. I. Du Pont De Nemours And Company | Conductive polyimide containing carbon black and graphite and preparation thereof |
| US5432001A (en) * | 1990-01-30 | 1995-07-11 | Trw Inc. | Concentrated prepolymer composition useful for forming polyimide articles |
| US5162492A (en) * | 1990-10-11 | 1992-11-10 | E. I. Du Pont De Nemours And Company | Hydrolytically and oxidatively stable polyimides |
| US5308569A (en) * | 1990-11-27 | 1994-05-03 | Ube Industries, Ltd. | Process for the preparation of aromatic polyimide film |
| US5243024A (en) * | 1990-12-21 | 1993-09-07 | Amoco Corporation | High moduli polyimides |
-
1997
- 1997-07-01 US US08/886,233 patent/US5886129A/en not_active Expired - Lifetime
-
1998
- 1998-06-30 JP JP50730799A patent/JP4295362B2/ja not_active Expired - Lifetime
- 1998-06-30 DE DE69802403T patent/DE69802403T2/de not_active Expired - Lifetime
- 1998-06-30 CN CNB988066297A patent/CN1145657C/zh not_active Expired - Lifetime
- 1998-06-30 WO PCT/US1998/013607 patent/WO1999001497A1/en not_active Ceased
- 1998-06-30 CA CA002293447A patent/CA2293447C/en not_active Expired - Fee Related
- 1998-06-30 EP EP98935507A patent/EP0993482B1/en not_active Expired - Lifetime
-
2008
- 2008-09-01 JP JP2008224064A patent/JP5281340B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0993482B1 (en) | 2001-11-07 |
| CN1261382A (zh) | 2000-07-26 |
| JP5281340B2 (ja) | 2013-09-04 |
| JP2002508022A (ja) | 2002-03-12 |
| WO1999001497A1 (en) | 1999-01-14 |
| DE69802403D1 (de) | 2001-12-13 |
| JP4295362B2 (ja) | 2009-07-15 |
| CA2293447A1 (en) | 1999-01-14 |
| US5886129A (en) | 1999-03-23 |
| CA2293447C (en) | 2008-12-23 |
| CN1145657C (zh) | 2004-04-14 |
| EP0993482A1 (en) | 2000-04-19 |
| JP2009001825A (ja) | 2009-01-08 |
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