DE630991T1 - Stromloses goldbeschichtungsbad. - Google Patents
Stromloses goldbeschichtungsbad.Info
- Publication number
- DE630991T1 DE630991T1 DE0630991T DE92924008T DE630991T1 DE 630991 T1 DE630991 T1 DE 630991T1 DE 0630991 T DE0630991 T DE 0630991T DE 92924008 T DE92924008 T DE 92924008T DE 630991 T1 DE630991 T1 DE 630991T1
- Authority
- DE
- Germany
- Prior art keywords
- salt
- coating bath
- gold coating
- mercaptobenzothiazole
- thiosulfate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title claims 4
- 239000010931 gold Substances 0.000 title claims 4
- 229910052737 gold Inorganic materials 0.000 title claims 4
- 239000011248 coating agent Substances 0.000 title 1
- 238000000576 coating method Methods 0.000 title 1
- 230000005611 electricity Effects 0.000 title 1
- 150000003839 salts Chemical class 0.000 claims 4
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 238000007747 plating Methods 0.000 claims 2
- 239000000243 solution Substances 0.000 claims 2
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 claims 2
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 claims 1
- FLFWJIBUZQARMD-UHFFFAOYSA-N 2-mercapto-1,3-benzoxazole Chemical compound C1=CC=C2OC(S)=NC2=C1 FLFWJIBUZQARMD-UHFFFAOYSA-N 0.000 claims 1
- HOASVNMVYBSLSU-UHFFFAOYSA-N 6-ethoxy-3h-1,3-benzothiazole-2-thione Chemical compound CCOC1=CC=C2N=C(S)SC2=C1 HOASVNMVYBSLSU-UHFFFAOYSA-N 0.000 claims 1
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 claims 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- -1 alkylamine compounds Chemical class 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- 229960005070 ascorbic acid Drugs 0.000 claims 1
- 235000010323 ascorbic acid Nutrition 0.000 claims 1
- 239000011668 ascorbic acid Substances 0.000 claims 1
- ZBKIUFWVEIBQRT-UHFFFAOYSA-N gold(1+) Chemical compound [Au+] ZBKIUFWVEIBQRT-UHFFFAOYSA-N 0.000 claims 1
- 150000003840 hydrochlorides Chemical class 0.000 claims 1
- 239000006174 pH buffer Substances 0.000 claims 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/42—Coating with noble metals
- C23C18/44—Coating with noble metals using reducing agents
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemically Coating (AREA)
Claims (2)
1. Lösung zum stromlosen Vergolden, umfassend eine wäßrige
Lösung, die als Bestandteile a) Tetrachlorogold(III)-Säure oder ein Salz davon oder ein Sulfit- oder
Thiosulfat-Gold(I)-Komplexsalz als Goldquelle, b) ein
Alkalimetall- oder Ammoniumsulfit oder -thiosulfat, c)
Ascorbinsäure oder ein Salz davon und d) einen pH-Puffer enthält, dadurch gekennzeichnet, daß ferner e) eine Verbindung,
gewählt aus 2-Mercaptobenzothiazol, 6-Ethoxy-2-Mercaptobenzothiazol,
2-Mercaptobenzimida&zgr;ol, 2-Mercaptobenzoxazol
und Salzen davon, vorhanden ist.
2. Lösung zum stromlosen Vergolden nach Anspruch 1, dadurch gekennzeichnet, daß als zusätzlicher Bestandteil f) eine
Verbindung, gewählt aus Alkylaminverbindungen und Sulfaten und Hydrochloriden davon, vorhanden ist.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/JP1992/001538 WO1994012686A1 (en) | 1992-11-25 | 1992-11-25 | Electroless gold plating bath |
Publications (1)
Publication Number | Publication Date |
---|---|
DE630991T1 true DE630991T1 (de) | 1995-07-13 |
Family
ID=14042674
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69224914T Expired - Fee Related DE69224914T2 (de) | 1992-11-25 | 1992-11-25 | Stromloses goldbeschichtungsbad |
DE0630991T Pending DE630991T1 (de) | 1992-11-25 | 1992-11-25 | Stromloses goldbeschichtungsbad. |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69224914T Expired - Fee Related DE69224914T2 (de) | 1992-11-25 | 1992-11-25 | Stromloses goldbeschichtungsbad |
Country Status (4)
Country | Link |
---|---|
US (1) | US5470381A (de) |
EP (1) | EP0630991B1 (de) |
DE (2) | DE69224914T2 (de) |
WO (1) | WO1994012686A1 (de) |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2927142B2 (ja) * | 1993-03-26 | 1999-07-28 | 上村工業株式会社 | 無電解金めっき浴及び無電解金めっき方法 |
WO1999018255A1 (en) | 1997-10-03 | 1999-04-15 | Massachusetts Institute Of Technology | Selective substrate metallization |
DE19745601C2 (de) * | 1997-10-08 | 2001-07-12 | Fraunhofer Ges Forschung | Lösung und Verfahren zum stromlosen Abscheiden von Goldschichten sowie Verwendung der Lösung |
DE19745602C1 (de) | 1997-10-08 | 1999-07-15 | Atotech Deutschland Gmbh | Verfahren und Lösung zur Herstellung von Goldschichten |
US5935306A (en) * | 1998-02-10 | 1999-08-10 | Technic Inc. | Electroless gold plating bath |
JP3920462B2 (ja) * | 1998-07-13 | 2007-05-30 | 株式会社大和化成研究所 | 貴金属を化学的還元析出によって得るための水溶液 |
US6383269B1 (en) | 1999-01-27 | 2002-05-07 | Shipley Company, L.L.C. | Electroless gold plating solution and process |
JP3466521B2 (ja) * | 1999-10-04 | 2003-11-10 | 新光電気工業株式会社 | 置換型無電解金めっき液及び無電解金めっき方法 |
EP1090825A3 (de) | 1999-10-07 | 2002-04-10 | Österreichische Bundesbahnen | Zweiachsiger Eisenbahngüterwagen |
DE10018025A1 (de) | 2000-04-04 | 2001-10-18 | Atotech Deutschland Gmbh | Verfahren zum Erzeugen von lötfähigen Oberflächen und funktionellen Oberflächen auf Schaltungsträgern |
JP3482402B2 (ja) * | 2001-06-29 | 2003-12-22 | 日本エレクトロプレイテイング・エンジニヤース株式会社 | 置換金メッキ液 |
JP4375702B2 (ja) * | 2001-10-25 | 2009-12-02 | ローム・アンド・ハース・エレクトロニック・マテリアルズ,エル.エル.シー. | めっき組成物 |
US6911230B2 (en) * | 2001-12-14 | 2005-06-28 | Shipley Company, L.L.C. | Plating method |
JP3892730B2 (ja) * | 2002-01-30 | 2007-03-14 | 関東化学株式会社 | 無電解金めっき液 |
SG116489A1 (en) * | 2003-04-21 | 2005-11-28 | Shipley Co Llc | Plating composition. |
KR100953612B1 (ko) * | 2003-06-02 | 2010-04-20 | 삼성에스디아이 주식회사 | 생체물질 고정용 기판 및 이의 제조방법 |
EP1645658A4 (de) * | 2003-06-05 | 2011-08-03 | Nippon Mining Co | Lösung zur stromlosen vergoldung |
JP4603320B2 (ja) * | 2003-10-22 | 2010-12-22 | 関東化学株式会社 | 無電解金めっき液 |
US7300501B2 (en) * | 2004-04-05 | 2007-11-27 | Nikko Materials Co., Ltd. | Electroless gold plating liquid |
JP4711435B2 (ja) * | 2004-07-09 | 2011-06-29 | Jx日鉱日石金属株式会社 | 無電解金めっき液 |
JP4740137B2 (ja) * | 2004-07-15 | 2011-08-03 | 積水化学工業株式会社 | 導電性微粒子の製造方法 |
JP2006111960A (ja) * | 2004-09-17 | 2006-04-27 | Shinko Electric Ind Co Ltd | 非シアン無電解金めっき液及び無電解金めっき方法 |
EP1813696B1 (de) * | 2004-11-15 | 2018-12-26 | JX Nippon Mining & Metals Corporation | Lösung zur stromlosen vergoldung |
US20070175358A1 (en) * | 2006-02-01 | 2007-08-02 | Kilnam Hwang | Electroless gold plating solution |
US20070175359A1 (en) * | 2006-02-01 | 2007-08-02 | Kilnam Hwang | Electroless gold plating solution and method |
GB0903642D0 (en) * | 2009-02-27 | 2009-09-30 | Bae Systems Plc | Electroless metal deposition for micron scale structures |
DE102009041264A1 (de) | 2009-09-11 | 2011-03-24 | IPHT Jena Institut für Photonische Technologien e.V. | Verfahren zur Herstellung von optisch aktiven Nanostrukturen |
JP4831710B1 (ja) * | 2010-07-20 | 2011-12-07 | 日本エレクトロプレイテイング・エンジニヤース株式会社 | 無電解金めっき液及び無電解金めっき方法 |
JP5610500B1 (ja) * | 2014-05-21 | 2014-10-22 | 小島化学薬品株式会社 | 有機金錯体 |
KR101444687B1 (ko) * | 2014-08-06 | 2014-09-26 | (주)엠케이켐앤텍 | 무전해 금도금액 |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3700469A (en) * | 1971-03-08 | 1972-10-24 | Bell Telephone Labor Inc | Electroless gold plating baths |
US3697296A (en) * | 1971-03-09 | 1972-10-10 | Du Pont | Electroless gold plating bath and process |
US3977884A (en) * | 1975-01-02 | 1976-08-31 | Shipley Company, Inc. | Metal plating solution |
JPS5217333A (en) * | 1975-08-01 | 1977-02-09 | Hitachi Ltd | Plating solution |
GB1547028A (en) * | 1976-11-19 | 1979-06-06 | Mine Safety Appliances Co | Electroless gold plating baths |
US4246195A (en) * | 1978-10-06 | 1981-01-20 | Halcon Research And Development Corporation | Purification of carbonylation products |
JPS56108869A (en) * | 1980-01-31 | 1981-08-28 | Asahi Glass Co Ltd | Nickel coat forming method |
JPS5819468A (ja) * | 1981-07-28 | 1983-02-04 | Asahi Glass Co Ltd | ニツケル被膜の形成方法 |
GB2114159B (en) * | 1982-01-25 | 1986-02-12 | Mine Safety Appliances Co | Method and bath for the electroless plating of gold |
JPS61253376A (ja) * | 1985-05-01 | 1986-11-11 | Shinko Electric Ind Co Ltd | 銅又は銅合金材の電解金めっき用前処理液 |
CN1003524B (zh) * | 1985-10-14 | 1989-03-08 | 株式会社日立制作所 | 无电浸镀金溶液 |
JPS6299477A (ja) * | 1985-10-25 | 1987-05-08 | C Uyemura & Co Ltd | 無電解金めつき液 |
DE3614090C1 (en) * | 1986-04-25 | 1987-04-30 | Heraeus Gmbh W C | Bath for the currentless deposition of gold layers |
DE3640028C1 (de) * | 1986-11-24 | 1987-10-01 | Heraeus Gmbh W C | Saures Bad fuer das stromlose Abscheiden von Goldschichten |
JP2655329B2 (ja) * | 1988-01-28 | 1997-09-17 | 関東化学 株式会社 | 無電解金めつき液 |
JPH0270084A (ja) * | 1988-09-06 | 1990-03-08 | C Uyemura & Co Ltd | 金めっき浴及び金めっき方法 |
US5130168A (en) * | 1988-11-22 | 1992-07-14 | Technic, Inc. | Electroless gold plating bath and method of using same |
US5258062A (en) * | 1989-06-01 | 1993-11-02 | Shinko Electric Industries Co., Ltd. | Electroless gold plating solutions |
US4985076A (en) * | 1989-11-03 | 1991-01-15 | General Electric Company | Autocatalytic electroless gold plating composition |
JPH04350172A (ja) * | 1991-05-28 | 1992-12-04 | Kanto Chem Co Inc | 無電解金めっき液 |
US5232492A (en) * | 1992-01-23 | 1993-08-03 | Applied Electroless Concepts Inc. | Electroless gold plating composition |
EP0618307B1 (de) * | 1993-03-26 | 1997-11-12 | C. Uyemura & Co, Ltd | Chemisches Vergoldungsbad |
JPH06299477A (ja) * | 1993-04-15 | 1994-10-25 | Mitsubishi Baarinton Kk | カーペツトの製造方法 |
US5338343A (en) * | 1993-07-23 | 1994-08-16 | Technic Incorporated | Catalytic electroless gold plating baths |
-
1992
- 1992-11-25 DE DE69224914T patent/DE69224914T2/de not_active Expired - Fee Related
- 1992-11-25 WO PCT/JP1992/001538 patent/WO1994012686A1/ja active IP Right Grant
- 1992-11-25 DE DE0630991T patent/DE630991T1/de active Pending
- 1992-11-25 US US08/256,369 patent/US5470381A/en not_active Expired - Lifetime
- 1992-11-25 EP EP92924008A patent/EP0630991B1/de not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE69224914D1 (de) | 1998-04-30 |
EP0630991A4 (de) | 1995-01-18 |
DE69224914T2 (de) | 1998-10-22 |
EP0630991A1 (de) | 1994-12-28 |
EP0630991B1 (de) | 1998-03-25 |
WO1994012686A1 (en) | 1994-06-09 |
US5470381A (en) | 1995-11-28 |
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