US3697296A - Electroless gold plating bath and process - Google Patents
Electroless gold plating bath and process Download PDFInfo
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- US3697296A US3697296A US122538A US3697296DA US3697296A US 3697296 A US3697296 A US 3697296A US 122538 A US122538 A US 122538A US 3697296D A US3697296D A US 3697296DA US 3697296 A US3697296 A US 3697296A
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- United States
- Prior art keywords
- gold
- plating
- alkali metal
- plating bath
- cyanoborohydride
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/42—Coating with noble metals
- C23C18/44—Coating with noble metals using reducing agents
Definitions
- a gold chemical plating bath for depositing gold on a catalytic surface which is an aqueous solution having a pH of 1.5 to 5 and contains as essential ingredients a soluble gold compound and an alkali metal cyanoborohydride as the reducing agent.
- ingredients are a chelating agent and an organic monovalent or divalent sulfur compound.
- Plating is preferably carried out at a temperature of 80 to 90 C.
- This invention relates to gold plating and more particularly to electroless gold plating baths and processes for the deposition of gold from such baths.
- electroless gold processes have been employed.
- electroless gold processes There have been a number of electroless gold processes described in the art and W. Goldie in Metallic Coating of Plastics, vol. I, Middlesex, England, Electrochemical Publications Ltd., 1968, pp. 99-103, describes a number of processes.
- formaldehyde formaldehyde
- sodium hypophosphite has been used as a reducing agent with citrates used as a complexing agent.
- Hydrazine, N,N-diethylglycine, citric acid and tartaric acid have also been used.
- some have considered some of these processes not to be true electroless gold processes (R. F. Bunshah, Techniques of Materials Preparation and Handling, part 3, pp. 1372-74, 1968) but to be immersion or displacement gold processes which are limited in the thickness and electrical resistance of the gold deposit obtained.
- a gold chemical plating bath comprising an aqueous solution having a pH within the range of about 1.5 to 5, said solution containing as essential ingredients a. soluble gold compound and an alkali metal cyanoborohydride.
- a process of chemically plating a catalytic surface with gold comprising contacting said surface with an aqueous solution having a pH within the range of about 1.5 to 5 at a temperature within the range of 25 C. up to the boiling point of the solution, said solution containing as essential ingredients a soluble gold compound and an alkali metal cyanoborohydride.
- Plating is accomplished by initially forming an aqueous plating solution having a pH of 1.5 to 5, preferably 2 to 4, which contains a soluble gold compound and an alkali metal cyanoborohydride.
- Gold can then be chemically deposited in uniform layers from such a solution on articles which have catalytic surfaces.
- concentrations of the components in the solution in addition to temperature of operation and other factors which lead to optimum plating conditions.
- gold can be plated chemically from a simple aqueous solution by reducing gold ions on a catalytic surface where the reduction is brought about by an alkali metal cyanoborohydride.
- catalytic surface refers to the surface of any object which contains in whole or in part a material which promotes on its surface the reduction of gold ions. Such surfaces are readily known to those skilled in the art and include iron, steel, nickel, copper, silver, cobalt, platinum and palladium metals. Surfaces of glass, ceramics and plastics are, in general, noncatalytic but are rendered catalytic by known sensitization techniques or by bonding foils of catalytic metals to the noncatalytic surfaces.
- An alkali metal cyanoborohydride is used in the solution as the gold ion reducing agent.
- Sodium cyanoborohydride is commercially available and, thus, is preferred although potassium cyanoborohydride is also suitable.
- the concentration of the cyanoborohydride in the aqueous solution is important to the rate of plating, but not determinative as to operativeness since the presence of minute amounts permits the plating of gold. High concentrations of cyanoborohydride such as a saturated aqueous solution also permit plating. As a practical matter, it is preferred to use the cyanoborohydride at a concentration of 0.1 to 10 grams per liter. A most preferred concentration is 0.1 to 5 grams per liter, and, generally, 0.25 to 2 grams per liter is adequate.
- Gold ions are introduced into the aqueous solution by adding a desired amount of water-soluble gold salt such as the sulfate, chloride, acetate, formate or alkali metal gold cyanide.
- concentration of the gold ions in solution is not critical and may vary over a wide range. As a practical matter, as little as possible should be used as long as an adequate plating rate is maintained. The rate of plating is slightly increased with increases in the concentration of gold ions. An initial concentration of from 0.02 to 0.5 gram mole per liter of salt is preferred.
- the aqueous solution contain a chelating agent to tie up trace amounts of undesirable materials or impurities and also to buffer the pH.
- chelating agents for electroless plating baths are well known and any one or a combination may be used.
- suitable chelating agents are citric acid, tartaric acid, glycolic acid and their alkali metal salts.
- the borates are also useful chelating agents. The amount added is essentially 1 mole for each mole of gold ion present in solution.
- Another optional ingredient which can be added to the solution to increase its shelf life and stability is an organic monovalent or divalent sulfur compound.
- Suitable divalent compounds are disclosed in US. Pat. 3,234,- 031 issued toEberhard Zirngiebl and Henry Gunter on Feb. 8, 1966. Only small amounts of sulfur compound need be added. For example, 0.001 to grams per liter can be used, but usually there is no improvement to be gained from the higher concentrations. Thus, it is preferred to use a concentration of 0.01 to 1 gram per liter.
- the bath In conducting the actual plating operation to deposit gold on a catalytic surface, it is preferred to operate the bath at a temperature of 80 to 95 C., since the rate of plating increases with temperature. While this range is preferred, plating will occur at lower or higher temperatures; thus, the temperature can range between 25 C. up to the boiling point of the solution, but will usually be above 40 C. v
- EXAMPLE 1 An aqueous plating bath was prepared containing 7 g./l. potassium gold cyanide and 30 g./l. citric acid, and 2 g./l. sodium cyanoborohydride. The pH of the bath was 3.5. It was. found that above pH 5 there was no reduction to gold and below pH 1.5 the bath was unstable. The bath .was used to plate copper and nickel foil (2.54 cm. X 7.62 cm.) at 90 C. The plating rate was constant at0.1 mil/hour over a test period of 6 hours. There was gas evolution from the work piece observed and there was a weight increase of 58 mg. during the test period.
- a ceramic chip sensitized with palladium according to known procedures was also plated and was checked for electrical resistance during the plating operation. The electrical resistance was reduced from 127 ohms per square to 0.4 ohm per square after a coating of 0.1 mil in thickness was applied. Similar baths were prepared with 1,4 and 5 g./l. of sodium cyanoborohydride, respectively, and similar results were obtained.
- EXAMPLE 2 An aqueous plating bath of pH 4 was prepared containing 10 g./l. gold chloride and 30 g./l. tartaric acid, and 2 g./l. sodium cyanoborohydride. A copper foil (2.54 cm. x 7.62 cm.) was plated in the bath at 90 C. with a plating rate of 0.05 mil/hour over a test period of 6 hours. The weight increase was 30 mg. Similar baths were prepared with.1,4 and 5 g./l. of sodium cyanoborohydride, respectively, and similar results were obtained.
- EXAMPLE 3 An aqueous plating bath of pH 3.5 was prepared containing 10 g./l. potassium gold cyanide, 30 g./l. citric acid, 0.01 g./l. thiodiglycolic acid, and 2 g./l. sodium cyanoborohydride. Copper foil (2.54 cm. X 7.62 cm.) was plated as in Example 1 and gold was deposited on the copper with no decomposition of the baths after continuously plating over a period of 24 hours. Similar baths were prepared with 1,4 and 5 g./1. of sodium cyanoborohydride, respectively, and similar results were obtained. Similar results were obtained when 0.01 g./l. of mercapto acetic acid was used in place of the thiodiglycolic acid in the bath containing 2 g./l. sodium cyanoborohydride.
- a gold chemicalv plating bath comprising an aqueous 4 solution having a pH within the range of about 1.5 to 5, said solution containing as essential ingredients a watersoluble salt of gold and an alkali metal cyanoborohydride.
- water-soluble gold salt is an alkali metal gold cyanide or a gold salt of a mineral or aliphatic acid
- the water-soluble gold salt is an alkali metal gold cyanide or a gold salt of a mineral or aliphatic acid.
- alkali metal cyanoborohydride is sodium cyanoborohydride present at a concentration ;of 0.25 to 2 grams per liter.
- a process of chemically plating a catalytic surface with gold comprising contacting said surface with an aqueous solution having a pH within the range of about 1.5 to 5 at a temperaturewithin the range of 25 C. up to the boiling point of the solution, said solution containing as essential ingredients a water-soluble salt of gold and an alkali metal cyanoborohydride.
- alkali metal cyanoborohydride is sodium cyanoborohydride present at a concentration of 0.1 to 5 grams per liter.
- the chemical plating bath of claim 16 wherein the chelating agent is citric acid, tartaric acid, and glycolic acid.
Abstract
A GOLD CHEMICAL PLATING BATH IS PROVIDED FOR DEPOSITING GOLD ON A CATALYTIC SURFACE WHICH IS AN AQUEOUS SOLUTION HAVING A PH OF 1.5 TO 5 AND CONTAINS AS ESSENTIAL INGREDIENTS A SOLUBLE GOLD COMPOUND AND AN ALKALI METAL CYANOBOROHYDRIDE AS THE REDUCING AGENT. OPTIONAL, BUT PREFERRED, INGREDIENTS ARE A CHELATING AGENT AND AN ORGANIC MONOVALENT OR DIVALENT SULFUR COMPOUND. PLATING IS PREFERABLY CARRIED OUT AT A TEMPERATURE OF 80 TO 90*C.
Description
3,697,296 Patented Oct. 10, 1972 3,697,296 ELECTROLESS GOLD PLATING BATH AND PROCESS Harold Edward Bellis, Hockessin, Del., assignor to E. I. du Pont de Nemours and Company, Wilmington, Del. No Drawing. Filed Mar. 9, 1971, Ser. No. 122,538
Int. Cl. C23c 3/02 US. Cl. 106-1 17 Claims ABSTRACT OF THE DISCLOSURE A gold chemical plating bath is provided for depositing gold on a catalytic surface which is an aqueous solution having a pH of 1.5 to 5 and contains as essential ingredients a soluble gold compound and an alkali metal cyanoborohydride as the reducing agent. Optional, but preferred, ingredients are a chelating agent and an organic monovalent or divalent sulfur compound. Plating is preferably carried out at a temperature of 80 to 90 C.
BACKGROUND OF THE INVENTION Field of the invention This invention relates to gold plating and more particularly to electroless gold plating baths and processes for the deposition of gold from such baths.
Prior art A variety of applications for gold coatings exist in the electronics industry, where gold is specified because of its corrosion resistance and oxidation resistance. A substantial proportion of the gold deposited in these applications is applied by electrodeposition; however, this method of application is often difiicult or impossible where the areas to be plated are discrete and isolated.
Where electroplated gold is difficult or impossible, electroless gold processes have been employed. There have been a number of electroless gold processes described in the art and W. Goldie in Metallic Coating of Plastics, vol. I, Middlesex, England, Electrochemical Publications Ltd., 1968, pp. 99-103, describes a number of processes. For instance, the original approach to electroless gold was to use formaldehyde as the reducing agent. With gold cyanide plating solutions, sodium hypophosphite has been used as a reducing agent with citrates used as a complexing agent. Hydrazine, N,N-diethylglycine, citric acid and tartaric acid have also been used. However, some have considered some of these processes not to be true electroless gold processes (R. F. Bunshah, Techniques of Materials Preparation and Handling, part 3, pp. 1372-74, 1968) but to be immersion or displacement gold processes which are limited in the thickness and electrical resistance of the gold deposit obtained.
Recently in the art there has appeared another electroless gold process using an alkali metal borohydride or dimethylamine borane as the reducing agent in a bath prepared using potassium gold cyanide, potassium cyanide and potassium hydroxide, see Y. Okinaka, Plating, pp. 914920 (1970). In British Pat. No. 1,058,915, gold is deposited by reducing a soluble gold salt with sodium borohydride or an amine borane. Cyanides can be added to enhance bath life. The major disadvantage of these processes, as well as those mentioned previously is that the plating rate is too slow to make them commercially attractive. Usually, the plating rate will be under 5 microns per hour.
SUMMARY OF THE INVENTION According to the present invention there is provided a gold chemical plating bath comprising an aqueous solution having a pH within the range of about 1.5 to 5, said solution containing as essential ingredients a. soluble gold compound and an alkali metal cyanoborohydride. There is also provided a process of chemically plating a catalytic surface with gold comprising contacting said surface with an aqueous solution having a pH within the range of about 1.5 to 5 at a temperature within the range of 25 C. up to the boiling point of the solution, said solution containing as essential ingredients a soluble gold compound and an alkali metal cyanoborohydride.
DETAILED DESCRIPTION OF THE INVENTION Plating is accomplished by initially forming an aqueous plating solution having a pH of 1.5 to 5, preferably 2 to 4, which contains a soluble gold compound and an alkali metal cyanoborohydride. Gold can then be chemically deposited in uniform layers from such a solution on articles which have catalytic surfaces. There are preferred concentrations of the components in the solution in addition to temperature of operation and other factors which lead to optimum plating conditions. However, it is to be understood that gold can be plated chemically from a simple aqueous solution by reducing gold ions on a catalytic surface where the reduction is brought about by an alkali metal cyanoborohydride.
The term catalytic surface refers to the surface of any object which contains in whole or in part a material which promotes on its surface the reduction of gold ions. Such surfaces are readily known to those skilled in the art and include iron, steel, nickel, copper, silver, cobalt, platinum and palladium metals. Surfaces of glass, ceramics and plastics are, in general, noncatalytic but are rendered catalytic by known sensitization techniques or by bonding foils of catalytic metals to the noncatalytic surfaces.
An alkali metal cyanoborohydride is used in the solution as the gold ion reducing agent. Sodium cyanoborohydride is commercially available and, thus, is preferred although potassium cyanoborohydride is also suitable. The concentration of the cyanoborohydride in the aqueous solution is important to the rate of plating, but not determinative as to operativeness since the presence of minute amounts permits the plating of gold. High concentrations of cyanoborohydride such as a saturated aqueous solution also permit plating. As a practical matter, it is preferred to use the cyanoborohydride at a concentration of 0.1 to 10 grams per liter. A most preferred concentration is 0.1 to 5 grams per liter, and, generally, 0.25 to 2 grams per liter is adequate.
Gold ions are introduced into the aqueous solution by adding a desired amount of water-soluble gold salt such as the sulfate, chloride, acetate, formate or alkali metal gold cyanide. The concentration of the gold ions in solution is not critical and may vary over a wide range. As a practical matter, as little as possible should be used as long as an adequate plating rate is maintained. The rate of plating is slightly increased with increases in the concentration of gold ions. An initial concentration of from 0.02 to 0.5 gram mole per liter of salt is preferred.
While not an essential ingredient, it is preferred that the aqueous solution contain a chelating agent to tie up trace amounts of undesirable materials or impurities and also to buffer the pH. Chelating agents for electroless plating baths are well known and any one or a combination may be used. Among suitable chelating agents are citric acid, tartaric acid, glycolic acid and their alkali metal salts. The borates are also useful chelating agents. The amount added is essentially 1 mole for each mole of gold ion present in solution.
Another optional ingredient which can be added to the solution to increase its shelf life and stability is an organic monovalent or divalent sulfur compound. Suitable divalent compounds are disclosed in US. Pat. 3,234,- 031 issued toEberhard Zirngiebl and Henry Gunter on Feb. 8, 1966. Only small amounts of sulfur compound need be added. For example, 0.001 to grams per liter can be used, but usually there is no improvement to be gained from the higher concentrations. Thus, it is preferred to use a concentration of 0.01 to 1 gram per liter.
In conducting the actual plating operation to deposit gold on a catalytic surface, it is preferred to operate the bath at a temperature of 80 to 95 C., since the rate of plating increases with temperature. While this range is preferred, plating will occur at lower or higher temperatures; thus, the temperature can range between 25 C. up to the boiling point of the solution, but will usually be above 40 C. v
The invention can be further understood by referring to the following examples in which parts and percentages are by weight unless otherwise indicated.
EXAMPLE 1 An aqueous plating bath was prepared containing 7 g./l. potassium gold cyanide and 30 g./l. citric acid, and 2 g./l. sodium cyanoborohydride. The pH of the bath was 3.5. It was. found that above pH 5 there was no reduction to gold and below pH 1.5 the bath was unstable. The bath .was used to plate copper and nickel foil (2.54 cm. X 7.62 cm.) at 90 C. The plating rate was constant at0.1 mil/hour over a test period of 6 hours. There was gas evolution from the work piece observed and there was a weight increase of 58 mg. during the test period. A ceramic chip sensitized with palladium according to known procedures was also plated and was checked for electrical resistance during the plating operation. The electrical resistance was reduced from 127 ohms per square to 0.4 ohm per square after a coating of 0.1 mil in thickness was applied. Similar baths were prepared with 1,4 and 5 g./l. of sodium cyanoborohydride, respectively, and similar results were obtained.
EXAMPLE 2 An aqueous plating bath of pH 4 was prepared containing 10 g./l. gold chloride and 30 g./l. tartaric acid, and 2 g./l. sodium cyanoborohydride. A copper foil (2.54 cm. x 7.62 cm.) was plated in the bath at 90 C. with a plating rate of 0.05 mil/hour over a test period of 6 hours. The weight increase was 30 mg. Similar baths were prepared with.1,4 and 5 g./l. of sodium cyanoborohydride, respectively, and similar results were obtained.
EXAMPLE 3 An aqueous plating bath of pH 3.5 was prepared containing 10 g./l. potassium gold cyanide, 30 g./l. citric acid, 0.01 g./l. thiodiglycolic acid, and 2 g./l. sodium cyanoborohydride. Copper foil (2.54 cm. X 7.62 cm.) was plated as in Example 1 and gold was deposited on the copper with no decomposition of the baths after continuously plating over a period of 24 hours. Similar baths were prepared with 1,4 and 5 g./1. of sodium cyanoborohydride, respectively, and similar results were obtained. Similar results were obtained when 0.01 g./l. of mercapto acetic acid was used in place of the thiodiglycolic acid in the bath containing 2 g./l. sodium cyanoborohydride.
Whatis claimed is:
1. A gold chemicalv plating bath comprising an aqueous 4 solution having a pH within the range of about 1.5 to 5, said solution containing as essential ingredients a watersoluble salt of gold and an alkali metal cyanoborohydride.
2. The chemical plating bath of claim 1 wherein the water-soluble gold salt is present at a concentration of 0.02 to 0.5 mole per liter.
3. The chemical plating bath of claim 2 wherein the water-soluble gold salt is an alkali metal gold cyanide or a gold salt of a mineral or aliphatic acid,
4. The chemical plating bath of claim 3 wherein the alkali metal cyanoborohydride is sodium cyanoborohydride.
5. The chemical plating bath of claim 1 wherein the alkali metal cyanoborohydride is present at a concentration of 0.1 to 10 grams per liter.
6. The chemical plating bath of claim 2 wherein the alkali metal cyanoborohydride is present at a concentration of 0.1 to 5 grams per liter.
7. The chemical plating bath of claim 6 wherein the water-soluble gold salt is an alkali metal gold cyanide or a gold salt of a mineral or aliphatic acid.
8. The chemical plating bath of claim 7 wherein the alkali metal cyanoborohydride is sodium cyanoborohydride present at a concentration ;of 0.25 to 2 grams per liter.
9. A process of chemically plating a catalytic surface with gold comprising contacting said surface with an aqueous solution having a pH within the range of about 1.5 to 5 at a temperaturewithin the range of 25 C. up to the boiling point of the solution, said solution containing as essential ingredients a water-soluble salt of gold and an alkali metal cyanoborohydride.
10. The process of claim 9 wherein the temperature is within the range of to C.
11. The process of claim 1 wherein the water-soluble gold salt is present at a concentration of 0.02 '0 0.5 mole per liter and the alkali metal cyanoborohydride is present at a concentration of 0.1 to 10 grams per liter.
12. The process of claim 11 wherein the catalytic surface is the surface of a metal object.
13. The process of claim 12 wherein the alkali metal cyanoborohydride is sodium cyanoborohydride present at a concentration of 0.1 to 5 grams per liter.
14. The process of claim 12 wherein the surface of a metal object is of iron, steel, nickel, copper, silver cobalt, platinum and palladium.
15. The process of claim 11 wherein the solution additionally contains a chelating agent.
16. The chemical plating bath of claim 6 wherein the solution additionaly contains chelating agent and from 0.001 to 5 grams per liter of at least one organic monovalent or divalent sulfur compound as a bath stabilizer.
17. The chemical plating bath of claim 16 wherein the chelating agent is citric acid, tartaric acid, and glycolic acid.
References Cited UNITED STATES PATENTS 2,976,181 3/1961 Brookshire 117-130 E 3,589,916 6/1971 McCormackv 1061 LORENZO B. HAYES, Primary Examiner US. Cl. X.R.
117-47 A, E, 130 B,
P0-1O50 HNEITEIU EETATES @FFKQE a m X T fififd'ifilfifil l E51 QQRREQEULQN Patent No. 3,697,296 Dated October 10, 1972 Inventor(s) Harold Edward Bellis It is certified that error appears in the above-identified patent and that said Letters Patent are hereby corrected as shown below:
5" a Column 4, line 36, "claim 1" should be claim 10 Column 4, line 37, "0.020 0.05" should be 0.02 to 0.05
Column l, line 51, "additionaly vshould be additionally Signed and sealed this 29th day of May 1973.
(SEAL) Attest I EDWARD M. FLETCHER, JR. ROBERT GOTTSCHALK Attestlng Officer Commissioner of Patents
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12253871A | 1971-03-09 | 1971-03-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3697296A true US3697296A (en) | 1972-10-10 |
Family
ID=22403281
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US122538A Expired - Lifetime US3697296A (en) | 1971-03-09 | 1971-03-09 | Electroless gold plating bath and process |
Country Status (5)
Country | Link |
---|---|
US (1) | US3697296A (en) |
CA (1) | CA969703A (en) |
DE (1) | DE2211439A1 (en) |
FR (1) | FR2128781B1 (en) |
GB (1) | GB1321963A (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3857724A (en) * | 1971-08-20 | 1974-12-31 | Ibm | Primer for electroless plating |
JPS5093234A (en) * | 1973-12-24 | 1975-07-25 | ||
US3917885A (en) * | 1974-04-26 | 1975-11-04 | Engelhard Min & Chem | Electroless gold plating process |
US4091128A (en) * | 1976-10-08 | 1978-05-23 | Ppg Industries, Inc. | Electroless gold plating bath |
US4337091A (en) * | 1981-03-23 | 1982-06-29 | Hooker Chemicals & Plastics Corp. | Electroless gold plating |
US4374876A (en) * | 1981-06-02 | 1983-02-22 | Occidental Chemical Corporation | Process for the immersion deposition of gold |
US4804559A (en) * | 1985-10-14 | 1989-02-14 | Hitachi, Ltd. | Electroless gold plating solution |
US4830668A (en) * | 1986-11-24 | 1989-05-16 | W. C. Heraeus Gmbh | Acidic bath for electroless deposition of gold films |
EP0369545A1 (en) * | 1988-11-15 | 1990-05-23 | H.B.T. Holland Biotechnology B.V. | Process for the preparation of elemental sols |
US5470381A (en) * | 1992-11-25 | 1995-11-28 | Kanto Kagaku Kabushiki Kaisha | Electroless gold plating solution |
-
1971
- 1971-03-09 US US122538A patent/US3697296A/en not_active Expired - Lifetime
-
1972
- 1972-02-24 CA CA135,518A patent/CA969703A/en not_active Expired
- 1972-03-09 GB GB1110872A patent/GB1321963A/en not_active Expired
- 1972-03-09 DE DE19722211439 patent/DE2211439A1/en active Pending
- 1972-03-09 FR FR7208258A patent/FR2128781B1/fr not_active Expired
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3857724A (en) * | 1971-08-20 | 1974-12-31 | Ibm | Primer for electroless plating |
JPS5093234A (en) * | 1973-12-24 | 1975-07-25 | ||
US3917885A (en) * | 1974-04-26 | 1975-11-04 | Engelhard Min & Chem | Electroless gold plating process |
US4091128A (en) * | 1976-10-08 | 1978-05-23 | Ppg Industries, Inc. | Electroless gold plating bath |
US4337091A (en) * | 1981-03-23 | 1982-06-29 | Hooker Chemicals & Plastics Corp. | Electroless gold plating |
US4374876A (en) * | 1981-06-02 | 1983-02-22 | Occidental Chemical Corporation | Process for the immersion deposition of gold |
US4804559A (en) * | 1985-10-14 | 1989-02-14 | Hitachi, Ltd. | Electroless gold plating solution |
US4880464A (en) * | 1985-10-14 | 1989-11-14 | Hitachi, Ltd. | Electroless gold plating solution |
US4830668A (en) * | 1986-11-24 | 1989-05-16 | W. C. Heraeus Gmbh | Acidic bath for electroless deposition of gold films |
EP0369545A1 (en) * | 1988-11-15 | 1990-05-23 | H.B.T. Holland Biotechnology B.V. | Process for the preparation of elemental sols |
US5470381A (en) * | 1992-11-25 | 1995-11-28 | Kanto Kagaku Kabushiki Kaisha | Electroless gold plating solution |
Also Published As
Publication number | Publication date |
---|---|
FR2128781A1 (en) | 1972-10-20 |
CA969703A (en) | 1975-06-24 |
GB1321963A (en) | 1973-07-04 |
FR2128781B1 (en) | 1975-10-24 |
DE2211439A1 (en) | 1972-09-21 |
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