DE614913C - Verfahren zur Erhoehung der Netzfaehigkeit von Mercerisierlaugen - Google Patents
Verfahren zur Erhoehung der Netzfaehigkeit von MercerisierlaugenInfo
- Publication number
- DE614913C DE614913C DE1930C0005330 DEC0005330D DE614913C DE 614913 C DE614913 C DE 614913C DE 1930C0005330 DE1930C0005330 DE 1930C0005330 DE C0005330 D DEC0005330 D DE C0005330D DE 614913 C DE614913 C DE 614913C
- Authority
- DE
- Germany
- Prior art keywords
- increase
- mixture
- wetting ability
- mercerising
- liquors
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000009736 wetting Methods 0.000 title claims description 10
- 238000000034 method Methods 0.000 title claims description 5
- 238000009992 mercerising Methods 0.000 title description 6
- -1 nitrogenous organic bases monoacylated ethylenediamines Chemical class 0.000 claims description 3
- 238000006467 substitution reaction Methods 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims 1
- 238000012986 modification Methods 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 30
- 239000000203 mixture Substances 0.000 description 14
- 239000004744 fabric Substances 0.000 description 7
- 229920000742 Cotton Polymers 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 150000003739 xylenols Chemical class 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- 150000002989 phenols Chemical class 0.000 description 3
- PETRWTHZSKVLRE-UHFFFAOYSA-N 2-Methoxy-4-methylphenol Chemical compound COC1=CC(C)=CC=C1O PETRWTHZSKVLRE-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 2
- 229940073608 benzyl chloride Drugs 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 2
- 150000002171 ethylene diamines Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005517 mercerization Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- HLVFKOKELQSXIQ-UHFFFAOYSA-N 1-bromo-2-methylpropane Chemical compound CC(C)CBr HLVFKOKELQSXIQ-UHFFFAOYSA-N 0.000 description 1
- WKWHVVVPIFXOJI-UHFFFAOYSA-N 2,3-dimethylphenol;2,4-dimethylphenol;2,5-dimethylphenol;2,6-dimethylphenol;3,4-dimethylphenol Chemical compound CC1=CC=C(O)C(C)=C1.CC1=CC=C(C)C(O)=C1.CC1=CC=C(O)C=C1C.CC1=CC=CC(O)=C1C.CC1=CC=CC(C)=C1O WKWHVVVPIFXOJI-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- CJKRXEBLWJVYJD-UHFFFAOYSA-N N,N'-diethylethylenediamine Chemical compound CCNCCNCC CJKRXEBLWJVYJD-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- KBGBDGQCRFNDLU-UHFFFAOYSA-N benzyl(diethyl)azanium;chloride Chemical compound Cl.CCN(CC)CC1=CC=CC=C1 KBGBDGQCRFNDLU-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- NQGIJDNPUZEBRU-UHFFFAOYSA-N dodecanoyl chloride Chemical compound CCCCCCCCCCCC(Cl)=O NQGIJDNPUZEBRU-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- DDQBWEOPDZBVJW-KTKRTIGZSA-N n'-[(z)-octadec-9-enyl]ethane-1,2-diamine Chemical compound CCCCCCCC\C=C/CCCCCCCCNCCN DDQBWEOPDZBVJW-KTKRTIGZSA-N 0.000 description 1
- IPNZNLYKVIVNSK-YPKPFQOOSA-N n,n'-diethyl-n'-[(z)-octadec-9-enyl]ethane-1,2-diamine Chemical compound CCCCCCCC\C=C/CCCCCCCCN(CC)CCNCC IPNZNLYKVIVNSK-YPKPFQOOSA-N 0.000 description 1
- 229940113162 oleylamide Drugs 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
- D06M13/127—Mono-aldehydes, e.g. formaldehyde; Monoketones
-
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/137—Acetals, e.g. formals, or ketals
-
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
-
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/332—Di- or polyamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/335—Amines having an amino group bound to a carbon atom of a six-membered aromatic ring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/338—Organic hydrazines; Hydrazinium compounds
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
-
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/405—Acylated polyalkylene polyamines
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/17—Natural resins, resinous alcohols, resinous acids, or derivatives thereof
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatment Of Fiber Materials (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
DEUTSCHES REICH
PATENTSCHRIFT
KLASSE 8 k GRUPPE
Sk C S3. so
Patentiert im Deutschen Reiclie vom 28. Mai 1930 ab Das Hauptpatent hat angefangen am 16. Januar 1930.
Gegenstand des Hauptpatents 593 048 ist ein Verfahren zur Erhöhung der Netzfähigkeit
von Mercerisierlaugen, welches durch die Verwendung von Phenolen und stickstoffhaltigen
organischen Basen gekennzeichnet ist.
Bei weiterer Ausbildung dieses Verfahrens wurde gefunden, daß insbesondere Mischungen
aus Phenolen und monoacylierten Äthylendiaminen bzw. deren Homologen und Substitutionsprodukten
den Mercerisierlaugen eine noch beständigere Netzfähigkeit verleihen. Dies zeigt sich darin, daß die Mercerisierlaugen,
welche diese Verbindungen enthalten, ihre Netzfähigkeit sogar nach langem Lagern in offenen Gefäßen nicht verlieren.
Als acylierte Äthylendiamine kann man z. B. Monooleyläthylendiamin, dessen Substitutionsproidukte,
wieMonooleyldiäthyläthylendiamin, oder dessen Alkylierungsprodukte
in Form der freien Basen oder der Salze in Mischung mit geeigneten Phenolen zur Mercerisierlauge
zusetzen.
Die auf diese Art hergestellten Mercerisierlaugen besitzen ein ausgezeichnetes Netzvermögen
von guter Beständigkeit.
Einer Mercerisierlauge von 320 Be werden 1,17 Gewichtsprozent eines Gemisches aus
90 °/0 technischem Xylenolgemisch und 10 °/0
Diäthylaminoäthyloleylamid von der Formel
CH3 (CHa)7-CH = CH-(CH2), — CONHCH2-CH2-N(C2Hä)2
zugesetzt, wodurch diese die Fähigkeit erlangt, rohe unentschlichtete Baumwollgewebestücke
oder stark gezwirnte Rohgarne so vollkommen zu durchdringen, daß sie innerhalb
weniger Sekunden untersinken und sehr rasch und intensiv einschrumpfen.
Eine Lauge von 32 ° Be, welcher man 1,18 Gewichtsprozent eines Gemisches aus
9 Teilen technischem Teerkreosolgemisch und ι Teil Oleylamidoäthyldiäthyknethylammoniummethylsuifat
von folgender Formel
(C2H5),
C17H33CONH-CH2-CH2-N^
/CH3
0-S-O-CH3
0 0
0 0
(hergestellt durch Vereinigen von ι Mol Diäthylamidoäthyloleylamid
mit ι Mol Dimethylsulfat)' zugesetzt hai, ist klar und
besitzt eine - gute Netz·*, Durchdringungs- und Schrumpfwirkung für Rohbauimwiollwaren.
Setzt man zu einer Mercerisierlauge vo'n 35° Be eine Mischung aus 90 Gewichtsprozent
technischem Xylenolgemisch und 10 Gewichtsprozent Oleylamidoäthyldiäthylbenzylammoniumchlorid
von folgender Formel
(C2H5)2
C17H33CO-NH-CH2-CH2-N
(hergestellt nach dem amerikanischen Patent 1737 458 durch mehrstündiges Erhitzen
von Diäthylamidoäthyloleylamid mit Benzylchlorid), so erlangt sie dadurch die Fähigkeit,
rohe, d. h. vollkommen ungebäuchte und selbst unentschlichtete Gewebe und Garne augenblicklich und vollkommen gleichmäßig
zu durchdringen, so daß dieselben rasch untersinken und intensiv einschrumpfen.
Eine Mercerisierlauge von 300 Be und 150C wird mit 1,8 Gewichtsprozent einer
Lösung von 1 Teil Diäthylamidoäthylnaphthensäureamid (hergestellt aus dem Chlorid
eines bei 5 mm Hg zwischen 120 bis i6o° siedenden Naphthensäuregemisches und
asymmetrischem Diäthyläthylendiamin) in 9 Teilen technisches Xylenolgemisch versetzt.
Die klare Lauge besitzt eine außerordentlich hohe Netz- und Schrumpfwirkung, welche nach otägigem offenem Aufbewahren
fast ganz unverändert bleibt.
Schrumpfdiagramme, aufgenommen mit trockenem Rohperlgarn 3/2 nach der
von L a η d ο 11 (Melliands Textilberichte,
Band IX, Sept. 1928, Seite 762/3) angegebenen
Methode:
dieselbe Lauge, nachdem trisch angesetzte te^6Jt a//in b4Z™S;ni
Lauge offenen Schale aufbewahrt
worden ist
nach 15 | Sek. 22,0 |
O;
/0 |
20,8 | 7o |
- 30 | 27,0 |
0/
/0 |
25,7 | % |
- 45 | - 28,3 |
0/
/0 |
27,0 | °/o |
- 60 | 28,8 |
0/
/0 |
27,6 | % |
- 90 | 29,5 |
0/
/0 |
28,2 | 7o |
Lauge | klar | Lauge | klar |
Die Prozentzahlen geben die nach bestimmten Zeiten erreichte Schrumpfung in Prozenten
der ursprünglichen Garnlänge an. Die außerordentlich rasche Reaktion zwischen dem Alkali und der Cellulose, welche ihren
sichtbaren Ausdruck im Schrumpflingsverlauf findet, zeigt, daß der dem Eindringen der
wässerigen Lauge von der natürlichen Roh- : faser entgegengesetzte Widerstand durch den
Netzmittelzusatz augenblicklich überwunden wird.
Rohgarne, welche mit dieser Lauge mercerisiert werden, zeigen einen hervorragenden
Hochglanz und sind vollkommen gleichmäßig anfärbbar.
Netzversuche mit Rohpopelinegeweben:
Die trockenen Gewebestücke netzen sich bei der frisch angesetzten sowie bei der 6 Tage
bei Zimmertemperatur in einer flachen offenen Schale aufbewahrten Lauge im Moment des
Auflegens auf die Lauge vollkommen gleichmäßig durch und sinken innerhalb 15 Sekunden
darin zu Boden.
Die Wirkung der Lauge ist somit selbst bei längerem offenem Aufbewahren, wie dies
in der Praxis meistens vorkommt, unverändert geblieben. Diese Tatsache bedeutet einen wichtigen Vorteil, denn sie ermöglicht
eine fortlaufend gleichmäßige Rohmercerisation.
Man fügt zu einer 3Sgrädigen Natronlauge
1,15 Gewichtsprozent eines Gemisches aus
9 Teilen technischem Xylenolgemisch und ι Teil Naphthenoylamidoäthyldiäthylbenzylammoniumchlorid
(hergestellt durch mehrstündiges Erhitzen von Benzylchlorid mit dem in Beispiel 4 genannten Diäthylamidoäthylnaphthensäureamid)*
und erhält eine klare Flüssigkeit von ausgezeichneter Netz- und Schrumpfwirkung für Rohibaumwollgewebe
und Garne.
Eine Natronlauge von 32° Be, welcher man i,5S Gewichtsprozent eines Gemisches aus
90 Teilen technischem Teerkresolgemisch und 10 Teilen Naphthenoylamidöäthyldiäthylmethylammoniummethylsulfat
(in analoger Weise wie die in Beispiel 2 genannte Substanz durch Vereinigung von Diathylamidoäthylnaphthensäureamid
mit Dimethylsulfat hergestellt) zugesetzt hat, ist klar und besitzt
eine ausgezeichnete Durchdringungs- und
Schrumpffähigkeit für Rohbaumwollgarne und Gewebe. Sie ändert sich bei mehrtägigem
offenem Aufbewahren sowohl in ihrer Wirkung und Beschaffenheit kaum.
Eine Natronlauge von 300 Be, welche i)35 Gewichtsprozent eines Gemisches aus
9 Teilen * technischem Xylenolgemisch und ι Teil Diäthylaminoäthyllauroylamid (hergestellt
aus Laurinsäurechlorid und asymmetrischem Diäthyläthylendiamin) enthält, ist klar und besitzt eine hervorragende Netz-
und Durchdringungswirkung für unvorbehandelte Rohbaumwollwaren.
Einer 34grädigen Natronlauge werden 1,15 Gewichtsprozent einer Lösung von
ι Teil Naphthenoylamidoäthylidiäthylisobütylammoniumbromid
(hergestellt durch mehrstündiges Erhitzen des im Beispiel genannten
Diäthylamidoäthylnaphthensäurearnids mit Isobutylbromid) in 9 Teilen technischem Xylenolgemisch
zugesetzt, wodurch dieselbe eine ausgezeichnete Netz- und Schrumpfwirkung
für Rohbaumwollgarne | und selbst | 11,8 To |
schlichtete Gewebe erhält. | 22,4 7o | |
Schrumpfdiagramm (Rohperlgarn 3/2) | 25.5 °/o | |
nach 15 Sek. | 26,6 7o | |
- 30 - | 27,3 °/o | |
- 45 - | ||
- 60 - | ||
- 90 - |
unent-
Rohe und unentschlichtete Popalinegewebe, welche bekanntlich aus stark gezwirntem Material
hergestellt und sehr dicht gewoben sind, netzen sich in der Lauge im Moment des Auflegens sofort vollkommen gleichmäßig
durch und sinken darin innerhalb 15 Sekunden unter.
Claims (1)
- . Patentanspruch:Abänderung des durch Patent 593 048 geschützten Verfahrens zur Erhöhung der Netzfähigkeit von Mercerisierlaugen, dadurch gekennzeichnet, daß man als stickstoffhaltige organische Basen monoacylierte Äthylendiamine, deren Homologe und Substitutionsprodukte bzw. deren Salze verwendet.
Priority Applications (41)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE368279D BE368279A (de) | 1926-10-29 | ||
NL30262D NL30262C (de) | 1926-10-29 | ||
NL30555D NL30555C (de) | 1926-10-29 | ||
NL30506D NL30506C (de) | 1926-10-29 | ||
FR624174D FR624174A (fr) | 1926-10-29 | 1926-11-06 | Procédé permettant d'améliorer l'action de l'alcali sur la cellulose naturelle et ses produits de transformation |
GB15544/27A GB279784A (en) | 1926-10-29 | 1927-06-10 | Improved process for treating natural and artificial cellulose fibres with alkali |
US218109A US1776052A (en) | 1926-10-29 | 1927-09-07 | Process for treating cellulosic fibers with alkali |
DEC43256D DE669426C (de) | 1926-10-29 | 1929-06-17 | Verfahren zum Mercerisieren |
FR38047D FR38047E (fr) | 1926-10-29 | 1930-03-05 | Procédé permettant d'améliorer l'action de l'alcali sur la cellulose naturelle et ses produits de transformation |
GB7549/30A GB350018A (de) | 1926-10-29 | 1930-03-07 | |
US459122A US1851914A (en) | 1926-10-29 | 1930-06-03 | Manufacture and use of new wetting preparations |
FR38872D FR38872E (fr) | 1926-10-29 | 1930-06-11 | Procédé permettant d'améliorer l'action de l'alcali sur la cellulose naturelle et ses produits de transformation |
GB18408/30A GB359399A (de) | 1926-10-29 | 1930-06-16 | |
NL52154A NL28346C (nl) | 1926-10-29 | 1930-06-16 | Werkwijze voor het verhoogen van het bevochtigend vermogen van merceriseerloogen |
FR38915D FR38915E (fr) | 1926-10-29 | 1930-08-04 | Procédé permettant d'améliorer l'action de l'alcali sur la cellulose naturelle etses produits de transformation |
GB23562/30A GB360472A (en) | 1926-10-29 | 1930-08-06 | Process for the treatment of natural and artificial cellulosic fibres with alkali |
US473773A US1851393A (en) | 1926-10-29 | 1930-08-07 | Preparation of wetting agents for use in mercerizing lyes |
FR39219D FR39219E (fr) | 1926-10-29 | 1930-08-12 | Procédé permettant d'améliorer l'action de l'alcali sur la cellulose naturelle etses produits de transformation |
US475373A US1851394A (en) | 1926-10-29 | 1930-08-14 | Preparation of wetting agents |
DE1930C0009130 DE679766C (de) | 1926-10-29 | 1930-08-21 | Verfahren zum Mercerisieren |
GB25356/30A GB361865A (en) | 1926-10-29 | 1930-08-25 | Process for the treatment of natural and artificial cellulosic fibres with alkali |
US506507A US2008459A (en) | 1926-10-29 | 1931-01-03 | Process for increasing the wettingout power of alkaline lyes |
US506506A US2008458A (en) | 1926-10-29 | 1931-01-03 | Process for increasing the wettingout power of alkaline lyes |
GB831/31A GB364844A (en) | 1926-10-29 | 1931-01-09 | Process for the treatment of natural and artificial cellulose fibres with alkali |
NL55095A NL28668C (nl) | 1926-10-29 | 1931-01-09 | Werkwijze voor het vergrooten van het bevochtigend vermogen van alkaliseeringsvloeistoffen |
FR39681D FR39681E (fr) | 1926-10-29 | 1931-01-12 | Procédé permettant d'améliorer l'action de l'alcali sur la cellulose naturelle etses produits de transformation |
GB1521/31A GB365323A (en) | 1926-10-29 | 1931-01-16 | Process for the treatment of natural and artificial cellulosic fibres with alkali |
FR40131D FR40131E (fr) | 1926-10-29 | 1931-04-20 | Procédé permettant d'améliorer l'action de l'alcali sur la cellulose naturelle etses produits de transformation |
GB12102/31A GB374214A (en) | 1926-10-29 | 1931-04-23 | Process for the treatment of natural and artificial cellulosic fibres with alkali |
US537225A US1976886A (en) | 1926-10-29 | 1931-05-13 | Preparation of wetting agents for use in alkalizing lyes |
NL56978A NL30340C (nl) | 1926-10-29 | 1931-05-21 | Werkwijze voor hetvergrooten van het bevochtigend vermogen van alkaliseeringsvloeistoffen |
FR40318D FR40318E (fr) | 1926-10-29 | 1931-05-21 | Procédé permettant d'améliorer l'action de l'alcali sur la cellulose naturelle etses produits de transformation |
GB15194/31A GB368606A (en) | 1926-10-29 | 1931-05-22 | Process for the treatment of natural and artificial cellulosic fibres with alkali |
US552547A US1998550A (en) | 1926-10-29 | 1931-07-22 | Preparation of wetting agents for use in mercerizing lyes |
FR40615D FR40615E (fr) | 1926-10-29 | 1931-07-24 | Procédé permettant d'améliorer l'action de l'alcali sur la cellulose naturelle et ses produits de transformation |
GB21692/31A GB378194A (en) | 1926-10-29 | 1931-07-29 | Improved process for treating natural and artificial cellulosic fibres with alkali |
GB22803/31A GB382345A (en) | 1926-10-29 | 1931-08-12 | Improved process for treating natural and artificial cellulosic fibres with alkali |
GB25545/31A GB382373A (en) | 1926-10-29 | 1931-09-11 | Improved process for treating natural and artificial cellulosic fibres with alkali |
DEC51598D DE716182C (de) | 1926-10-29 | 1936-05-02 | Verfahren zum Mercerisieren |
FR821342D FR821342A (fr) | 1926-10-29 | 1937-04-30 | Agents de mouillage et procédé d'amélioration du pouvoir de mouillage des lessives de mercerisage |
GB12493/37A GB480837A (en) | 1926-10-29 | 1937-05-01 | Process for the treatment of natural and artificial cellulose fibres with alkali |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEC38909D DE591923C (de) | 1926-10-29 | 1926-10-29 | Verfahren zur Erhoehung der Netzfaehigkeit von Mercerisierlaugen |
Publications (1)
Publication Number | Publication Date |
---|---|
DE614913C true DE614913C (de) | 1935-06-25 |
Family
ID=7023507
Family Applications (5)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DEC38909D Expired - Lifetime DE591923C (de) | 1926-10-29 | 1926-10-29 | Verfahren zur Erhoehung der Netzfaehigkeit von Mercerisierlaugen |
DE1930C0000330 Expired - Lifetime DE593048C (de) | 1926-10-29 | 1930-01-15 | Verfahren zur Erhoehung der Netzfaehigkeit von Mercerisierlaugen |
DE1930C0000630 Expired - Lifetime DE661428C (de) | 1926-10-29 | 1930-01-16 | Mercerisieren |
DE1930C0005330 Expired DE614913C (de) | 1926-10-29 | 1930-05-27 | Verfahren zur Erhoehung der Netzfaehigkeit von Mercerisierlaugen |
DE1930C0007930 Expired DE674894C (de) | 1926-10-29 | 1930-07-31 | Verfahren zum Verbessern der Mercerisierlaugen |
Family Applications Before (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DEC38909D Expired - Lifetime DE591923C (de) | 1926-10-29 | 1926-10-29 | Verfahren zur Erhoehung der Netzfaehigkeit von Mercerisierlaugen |
DE1930C0000330 Expired - Lifetime DE593048C (de) | 1926-10-29 | 1930-01-15 | Verfahren zur Erhoehung der Netzfaehigkeit von Mercerisierlaugen |
DE1930C0000630 Expired - Lifetime DE661428C (de) | 1926-10-29 | 1930-01-16 | Mercerisieren |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE1930C0007930 Expired DE674894C (de) | 1926-10-29 | 1930-07-31 | Verfahren zum Verbessern der Mercerisierlaugen |
Country Status (2)
Country | Link |
---|---|
BE (5) | BE372565A (de) |
DE (5) | DE591923C (de) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE864855C (de) * | 1936-06-14 | 1953-01-29 | Basf Ag | Verfahren zum Mercerisieren |
-
0
- BE BE371067D patent/BE371067A/xx unknown
- BE BE380065D patent/BE380065A/xx unknown
- BE BE372774D patent/BE372774A/xx unknown
- BE BE376477D patent/BE376477A/xx unknown
- BE BE372565D patent/BE372565A/xx unknown
-
1926
- 1926-10-29 DE DEC38909D patent/DE591923C/de not_active Expired - Lifetime
-
1930
- 1930-01-15 DE DE1930C0000330 patent/DE593048C/de not_active Expired - Lifetime
- 1930-01-16 DE DE1930C0000630 patent/DE661428C/de not_active Expired - Lifetime
- 1930-05-27 DE DE1930C0005330 patent/DE614913C/de not_active Expired
- 1930-07-31 DE DE1930C0007930 patent/DE674894C/de not_active Expired
Also Published As
Publication number | Publication date |
---|---|
BE380065A (de) | |
DE661428C (de) | |
BE372565A (de) | |
BE371067A (de) | |
BE376477A (de) | |
DE593048C (de) | |
DE674894C (de) | 1939-04-24 |
BE372774A (de) | |
DE591923C (de) |
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