DE3535322C2 - - Google Patents

Info

Publication number
DE3535322C2
DE3535322C2 DE3535322A DE3535322A DE3535322C2 DE 3535322 C2 DE3535322 C2 DE 3535322C2 DE 3535322 A DE3535322 A DE 3535322A DE 3535322 A DE3535322 A DE 3535322A DE 3535322 C2 DE3535322 C2 DE 3535322C2
Authority
DE
Germany
Prior art keywords
content
clay
catalyst
acid
temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE3535322A
Other languages
German (de)
English (en)
Other versions
DE3535322A1 (de
Inventor
Gonzalo Sepulveda
Marcos Rosa-Brussin
Neveida Carrion
Pedro Roa
Alfredo Morales Ruiz
Jose Guitian
Otto Rodrigues
Carlos Caracas Ve Zerpa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Petróleos de Venezuela SA
Original Assignee
Petróleos de Venezuela SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Petróleos de Venezuela SA filed Critical Petróleos de Venezuela SA
Publication of DE3535322A1 publication Critical patent/DE3535322A1/de
Application granted granted Critical
Publication of DE3535322C2 publication Critical patent/DE3535322C2/de
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
DE19853535322 1984-10-03 1985-10-03 Katalysator sowie verfahren zu seiner herstellung und verfahren zur behandlung schwerer rohoele und rueckstaende mit dem katalysator Granted DE3535322A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/657,150 US4568657A (en) 1984-10-03 1984-10-03 Catalyst formed of natural clay for use in the hydrodemetallization and hydroconversion of heavy crudes and residues and method of preparation of same

Publications (2)

Publication Number Publication Date
DE3535322A1 DE3535322A1 (de) 1986-04-03
DE3535322C2 true DE3535322C2 (enExample) 1993-02-18

Family

ID=24636037

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19853535322 Granted DE3535322A1 (de) 1984-10-03 1985-10-03 Katalysator sowie verfahren zu seiner herstellung und verfahren zur behandlung schwerer rohoele und rueckstaende mit dem katalysator

Country Status (6)

Country Link
US (1) US4568657A (enExample)
JP (1) JPS6281487A (enExample)
CA (1) CA1251197A (enExample)
DE (1) DE3535322A1 (enExample)
FR (1) FR2570962B1 (enExample)
MX (2) MX166777B (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4405876A1 (de) * 1994-02-23 1995-10-05 Sued Chemie Ag Katalysator- bzw. Katalysatorträger-Formkörper

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4670132A (en) * 1982-06-29 1987-06-02 Intevep, S.A. Method of hydrocracking and method of preparing a catalyst therefor
CA1329952C (en) 1987-04-27 1994-05-31 Yoshihiko Imanaka Multi-layer superconducting circuit substrate and process for manufacturing same
US5160032A (en) * 1990-02-22 1992-11-03 Uop Hydrocarbon conversion process using alumina clay compositions
US7517446B2 (en) * 2004-04-28 2009-04-14 Headwaters Heavy Oil, Llc Fixed bed hydroprocessing methods and systems and methods for upgrading an existing fixed bed system
EP2272938B9 (en) * 2004-04-28 2015-12-30 Headwaters Heavy Oil, LLC Hydroprocessing method for upgrading heavy hydrocarbon feedstock using a colloidal catalyst
MXPA06012528A (es) 2004-04-28 2007-08-02 Headwaters Heavy Oil Llc Metodos y sistemas de hidroprocesamiento de lecho ebullente y metodos para mejorar un sistema de lecho ebullente existente.
US10941353B2 (en) * 2004-04-28 2021-03-09 Hydrocarbon Technology & Innovation, Llc Methods and mixing systems for introducing catalyst precursor into heavy oil feedstock
CN101426938B (zh) * 2007-01-31 2010-06-02 中国科学院过程工程研究所 一种钢材防氧化涂料及钢材的防氧化方法
US8034232B2 (en) * 2007-10-31 2011-10-11 Headwaters Technology Innovation, Llc Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker
US8142645B2 (en) * 2008-01-03 2012-03-27 Headwaters Technology Innovation, Llc Process for increasing the mono-aromatic content of polynuclear-aromatic-containing feedstocks
US8563456B2 (en) * 2008-10-03 2013-10-22 Chevron U.S.A. Inc. Hydrodemetallization catalyst and process
CA2817595C (en) 2010-12-20 2021-01-05 Chevron U.S.A. Inc. Hydroprocessing catalysts and methods for making thereof
US9790440B2 (en) 2011-09-23 2017-10-17 Headwaters Technology Innovation Group, Inc. Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker
TWI611836B (zh) 2012-02-17 2018-01-21 Advanced Refining Technologies Llc. 觸媒支撐物及其製備方法
TWI579043B (zh) 2012-02-17 2017-04-21 先進精鍊科技有限公司 球形觸媒支撐物及其製備方法
TWI617354B (zh) 2012-06-20 2018-03-11 先進精鍊科技有限公司 改良之含氧化鈦之殘餘氫化處理觸媒
US9644157B2 (en) 2012-07-30 2017-05-09 Headwaters Heavy Oil, Llc Methods and systems for upgrading heavy oil using catalytic hydrocracking and thermal coking
US11414607B2 (en) 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor with increased production rate of converted products
US11414608B2 (en) 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor used with opportunity feedstocks
US11421164B2 (en) 2016-06-08 2022-08-23 Hydrocarbon Technology & Innovation, Llc Dual catalyst system for ebullated bed upgrading to produce improved quality vacuum residue product
JP7336831B2 (ja) 2017-03-02 2023-09-01 ハイドロカーボン テクノロジー アンド イノベーション、エルエルシー ファウリングが少ない堆積物を伴う改良された沸騰床リアクター
US11732203B2 (en) 2017-03-02 2023-08-22 Hydrocarbon Technology & Innovation, Llc Ebullated bed reactor upgraded to produce sediment that causes less equipment fouling
CA3057131C (en) 2018-10-17 2024-04-23 Hydrocarbon Technology And Innovation, Llc Upgraded ebullated bed reactor with no recycle buildup of asphaltenes in vacuum bottoms
US12497569B2 (en) 2022-05-26 2025-12-16 Hydrocarbon Technology & Innovation, Llc Method and system for mixing catalyst precursor into heavy oil using a high boiling hydrocarbon diluent

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR641623A (fr) * 1926-09-29 1928-08-07 Ig Farbenindustrie Ag Procédé pour extraire l'alumine de l'argile et autres matières premières alumineuses au moyen d'acides
GB396780A (en) * 1931-10-31 1933-07-31 Howard Spence Improvements in the preparation of catalytic materials and of carriers therefor
GB585571A (en) * 1942-08-11 1947-02-12 Standard Oil Dev Co Improvements in or relating to the catalytic treatment of hydrocarbons
US2388735A (en) * 1943-07-03 1945-11-13 Filtrol Corp Method of drying pelleted catalyst
GB949889A (en) * 1961-03-02 1964-02-19 Kali Chemie Ag A method of producing carriers for catalytic contacts
DE1271682B (de) * 1961-12-29 1968-07-04 Gen Aniline & Film Corp Verfahren zur Herstellung eines sauren Tonkatalysators
GB1188317A (en) * 1966-12-10 1970-04-15 Mizusawa Industrial Chem Improvements in the production of Active Clay and Finely Divided Silica
FR2122696A5 (enExample) * 1971-01-20 1972-09-01 Raffinage Cie Francaise
JPS5817653B2 (ja) * 1972-09-28 1983-04-08 ジユ−ト − ヒエミ− ア−ゲ− 吸着剤の製造方法
US3876523A (en) * 1973-08-29 1975-04-08 Mobil Oil Corp Catalyst for residua demetalation and desulfurization
US3989645A (en) * 1974-02-07 1976-11-02 Exxon Research And Engineering Company Process for preparing a heavy crude conversion catalyst
US3977961A (en) * 1974-02-07 1976-08-31 Exxon Research And Engineering Company Heavy crude conversion
US3993601A (en) * 1974-02-07 1976-11-23 Exxon Research And Engineering Company Process for preparing a heavy crude conversion catalyst
JPS527887A (en) * 1975-07-09 1977-01-21 Chiyoda Chem Eng & Constr Co Ltd Process for producing catalysts
JPS5239590A (en) * 1975-09-25 1977-03-26 Toyobo Co Ltd Catalyst for removing nox
JPS548604A (en) * 1977-06-22 1979-01-23 Agency Of Ind Science & Technol Method of removing metals in hydrocarbon oil
DE2908491A1 (de) * 1979-03-05 1980-09-18 Huels Chemische Werke Ag Verfahren zur herstellung eines katalysators fuer die hydratation von olefinen zu alkoholen
CA1145285A (en) * 1979-09-26 1983-04-26 Robert A. Van Nordstrand Hydrocarbons hydroprocessing with halloysite catalyst
JPS6038178B2 (ja) * 1980-12-17 1985-08-30 大阪窯業株式会社 炭化水素の低温水蒸気改質用触媒耐火物の製造法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4405876A1 (de) * 1994-02-23 1995-10-05 Sued Chemie Ag Katalysator- bzw. Katalysatorträger-Formkörper

Also Published As

Publication number Publication date
JPS6281487A (ja) 1987-04-14
DE3535322A1 (de) 1986-04-03
FR2570962A1 (fr) 1986-04-04
MX9206179A (es) 1994-04-29
MX166777B (es) 1993-02-04
JPH0510974B2 (enExample) 1993-02-12
CA1251197A (en) 1989-03-14
US4568657A (en) 1986-02-04
FR2570962B1 (fr) 1988-11-04

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Legal Events

Date Code Title Description
OP8 Request for examination as to paragraph 44 patent law
D2 Grant after examination
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee