MX166777B - Catalizador formado de arcilla natural para usarse en la hidrodesmetalizacion e hidroconversion de crudos pesados y residuos y metodo para su preparacion - Google Patents

Catalizador formado de arcilla natural para usarse en la hidrodesmetalizacion e hidroconversion de crudos pesados y residuos y metodo para su preparacion

Info

Publication number
MX166777B
MX166777B MX000150A MX15085A MX166777B MX 166777 B MX166777 B MX 166777B MX 000150 A MX000150 A MX 000150A MX 15085 A MX15085 A MX 15085A MX 166777 B MX166777 B MX 166777B
Authority
MX
Mexico
Prior art keywords
clay
hydrodesmetalization
hydroconversion
way
natural clay
Prior art date
Application number
MX000150A
Other languages
English (en)
Inventor
Ruiz Alfredo Morales
Jose Guitian
Otto Rodriguez
Carlos Serpa
Marcos Rosa-Brussin
Nereida Carrion
Pedro Roa
Original Assignee
Intervep S A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Intervep S A filed Critical Intervep S A
Publication of MX166777B publication Critical patent/MX166777B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

La presente invención se refiere a un método para producir un catalizador a partir de arcilla natural para usarse en la hidrodesmetalización e hidroconversion de crudos pesados que comprende las etapas de: proporcionar una arcilla natural: triturar y moler la arcilla natural hasta un tamaño de partícula comprendido entre 20 y 400 mallas; tratar arcilla molida y clasificada por tamaño en un baño de ácido a una temperatura comprendida entre 70 y 140 grados C durante entre 20 y 180 minutos, de tal forma como para modificar las propiedades de composición química y textura de la arcilla; lavar la arcilla tratada con agua; parcialmente secar la arcilla lavada de tal manera como para reducir el contenido de agua de la misma hasta entre 20 y 40 por ciento por peso, con lo que se obtiene la plasticidad necesaria para la extrusión de la arcilla; mezclar la arcilla parcialmente hidratada con entre 5 y 40 por ciento por peso de una sustancia formadora de poro; extruir la arcilla con la sustancia formadora de poro de tal manera como para formar un extruído; y secar el extruído a una temperatura de entre 300 y 800 grados C durante entre 1 y 8 horas.
MX000150A 1984-10-03 1985-10-03 Catalizador formado de arcilla natural para usarse en la hidrodesmetalizacion e hidroconversion de crudos pesados y residuos y metodo para su preparacion MX166777B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/657,150 US4568657A (en) 1984-10-03 1984-10-03 Catalyst formed of natural clay for use in the hydrodemetallization and hydroconversion of heavy crudes and residues and method of preparation of same

Publications (1)

Publication Number Publication Date
MX166777B true MX166777B (es) 1993-02-04

Family

ID=24636037

Family Applications (2)

Application Number Title Priority Date Filing Date
MX000150A MX166777B (es) 1984-10-03 1985-10-03 Catalizador formado de arcilla natural para usarse en la hidrodesmetalizacion e hidroconversion de crudos pesados y residuos y metodo para su preparacion
MX9206179A MX9206179A (es) 1984-10-03 1992-10-27 Procedimiento para la hidrodesmetalizacion e hidroconversion de crudos pesados.

Family Applications After (1)

Application Number Title Priority Date Filing Date
MX9206179A MX9206179A (es) 1984-10-03 1992-10-27 Procedimiento para la hidrodesmetalizacion e hidroconversion de crudos pesados.

Country Status (6)

Country Link
US (1) US4568657A (es)
JP (1) JPS6281487A (es)
CA (1) CA1251197A (es)
DE (1) DE3535322A1 (es)
FR (1) FR2570962B1 (es)
MX (2) MX166777B (es)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4670132A (en) * 1982-06-29 1987-06-02 Intevep, S.A. Method of hydrocracking and method of preparing a catalyst therefor
CA1329952C (en) 1987-04-27 1994-05-31 Yoshihiko Imanaka Multi-layer superconducting circuit substrate and process for manufacturing same
US5160032A (en) * 1990-02-22 1992-11-03 Uop Hydrocarbon conversion process using alumina clay compositions
DE4405876A1 (de) * 1994-02-23 1995-10-05 Sued Chemie Ag Katalysator- bzw. Katalysatorträger-Formkörper
US10941353B2 (en) * 2004-04-28 2021-03-09 Hydrocarbon Technology & Innovation, Llc Methods and mixing systems for introducing catalyst precursor into heavy oil feedstock
WO2005104749A2 (en) * 2004-04-28 2005-11-10 Headwaters Heavy Oil, Llc Hydroprocessing method and system for upgrading heavy oil using a colloidal or molecular catalyst
ES2585891T3 (es) 2004-04-28 2016-10-10 Headwaters Heavy Oil, Llc Métodos y sistemas de hidroprocesamiento en lecho en ebullición
US7517446B2 (en) * 2004-04-28 2009-04-14 Headwaters Heavy Oil, Llc Fixed bed hydroprocessing methods and systems and methods for upgrading an existing fixed bed system
CN101426938B (zh) * 2007-01-31 2010-06-02 中国科学院过程工程研究所 一种钢材防氧化涂料及钢材的防氧化方法
US8034232B2 (en) * 2007-10-31 2011-10-11 Headwaters Technology Innovation, Llc Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker
US8142645B2 (en) * 2008-01-03 2012-03-27 Headwaters Technology Innovation, Llc Process for increasing the mono-aromatic content of polynuclear-aromatic-containing feedstocks
US8563456B2 (en) * 2008-10-03 2013-10-22 Chevron U.S.A. Inc. Hydrodemetallization catalyst and process
CN103228355A (zh) 2010-12-20 2013-07-31 雪佛龙美国公司 加氢加工催化剂及其制备方法
US9790440B2 (en) 2011-09-23 2017-10-17 Headwaters Technology Innovation Group, Inc. Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker
TWI579043B (zh) * 2012-02-17 2017-04-21 先進精鍊科技有限公司 球形觸媒支撐物及其製備方法
TWI611836B (zh) 2012-02-17 2018-01-21 Advanced Refining Technologies Llc. 觸媒支撐物及其製備方法
TWI632235B (zh) 2012-06-20 2018-08-11 美商先進精鍊科技有限公司 用於殘渣油徑原料之加氫脫硫反應的觸媒及其製備方法
US9644157B2 (en) 2012-07-30 2017-05-09 Headwaters Heavy Oil, Llc Methods and systems for upgrading heavy oil using catalytic hydrocracking and thermal coking
US11414608B2 (en) 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor used with opportunity feedstocks
US11414607B2 (en) 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor with increased production rate of converted products
US11421164B2 (en) 2016-06-08 2022-08-23 Hydrocarbon Technology & Innovation, Llc Dual catalyst system for ebullated bed upgrading to produce improved quality vacuum residue product
US11118119B2 (en) 2017-03-02 2021-09-14 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor with less fouling sediment
US11732203B2 (en) 2017-03-02 2023-08-22 Hydrocarbon Technology & Innovation, Llc Ebullated bed reactor upgraded to produce sediment that causes less equipment fouling
CA3057131C (en) 2018-10-17 2024-04-23 Hydrocarbon Technology And Innovation, Llc Upgraded ebullated bed reactor with no recycle buildup of asphaltenes in vacuum bottoms

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR641623A (fr) * 1926-09-29 1928-08-07 Ig Farbenindustrie Ag Procédé pour extraire l'alumine de l'argile et autres matières premières alumineuses au moyen d'acides
GB396780A (en) * 1931-10-31 1933-07-31 Howard Spence Improvements in the preparation of catalytic materials and of carriers therefor
GB585571A (en) * 1942-08-11 1947-02-12 Standard Oil Dev Co Improvements in or relating to the catalytic treatment of hydrocarbons
US2388735A (en) * 1943-07-03 1945-11-13 Filtrol Corp Method of drying pelleted catalyst
GB949889A (en) * 1961-03-02 1964-02-19 Kali Chemie Ag A method of producing carriers for catalytic contacts
GB1188317A (en) * 1966-12-10 1970-04-15 Mizusawa Industrial Chem Improvements in the production of Active Clay and Finely Divided Silica
FR2122696A5 (es) * 1971-01-20 1972-09-01 Raffinage Cie Francaise
JPS5817653B2 (ja) * 1972-09-28 1983-04-08 ジユ−ト − ヒエミ− ア−ゲ− 吸着剤の製造方法
US3876523A (en) * 1973-08-29 1975-04-08 Mobil Oil Corp Catalyst for residua demetalation and desulfurization
US3993601A (en) * 1974-02-07 1976-11-23 Exxon Research And Engineering Company Process for preparing a heavy crude conversion catalyst
US3977961A (en) * 1974-02-07 1976-08-31 Exxon Research And Engineering Company Heavy crude conversion
US3989645A (en) * 1974-02-07 1976-11-02 Exxon Research And Engineering Company Process for preparing a heavy crude conversion catalyst
JPS527887A (en) * 1975-07-09 1977-01-21 Chiyoda Chem Eng & Constr Co Ltd Process for producing catalysts
JPS5239590A (en) * 1975-09-25 1977-03-26 Toyobo Co Ltd Catalyst for removing nox
JPS548604A (en) * 1977-06-22 1979-01-23 Agency Of Ind Science & Technol Method of removing metals in hydrocarbon oil
DE2908491A1 (de) * 1979-03-05 1980-09-18 Huels Chemische Werke Ag Verfahren zur herstellung eines katalysators fuer die hydratation von olefinen zu alkoholen
CA1145285A (en) * 1979-09-26 1983-04-26 Robert A. Van Nordstrand Hydrocarbons hydroprocessing with halloysite catalyst
JPS6038178B2 (ja) * 1980-12-17 1985-08-30 大阪窯業株式会社 炭化水素の低温水蒸気改質用触媒耐火物の製造法

Also Published As

Publication number Publication date
DE3535322A1 (de) 1986-04-03
CA1251197A (en) 1989-03-14
JPS6281487A (ja) 1987-04-14
JPH0510974B2 (es) 1993-02-12
FR2570962B1 (fr) 1988-11-04
US4568657A (en) 1986-02-04
DE3535322C2 (es) 1993-02-18
MX9206179A (es) 1994-04-29
FR2570962A1 (fr) 1986-04-04

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