MX9206179A - Procedimiento para la hidrodesmetalizacion e hidroconversion de crudos pesados. - Google Patents
Procedimiento para la hidrodesmetalizacion e hidroconversion de crudos pesados.Info
- Publication number
- MX9206179A MX9206179A MX9206179A MX9206179A MX9206179A MX 9206179 A MX9206179 A MX 9206179A MX 9206179 A MX9206179 A MX 9206179A MX 9206179 A MX9206179 A MX 9206179A MX 9206179 A MX9206179 A MX 9206179A
- Authority
- MX
- Mexico
- Prior art keywords
- catalyst
- hydroconversion
- procedure
- heavy
- hydrodesmetalization
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/16—Clays or other mineral silicates
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Un catalizador estable natural activo para usarse en la hidrodesmetalización (HDM) y la hidroconversión (HC) de crudos y residuos pesados y en particular, un método para la preparación del catalizador a partir de arcilla natural y un procedimiento para el tratamiento de crudos y residuos pesados con el catalizador. El catalizador está exento de metales hidrogenantes de los grupos VIB y VII de la tabla periódica y comprende primordialmente hierro, sílice y aluminio, derivados de la composición de la arcilla natural. El catalizador tiene un área de superficie de entre 20 y 100 m2/g, un volumen de poro total de entre 0.20 y 0.90 cc/g, en el que entre el 50 y el 100 del volumen del poro total contiene poros con un diámetro mayor de 400 A. El catalizador tiene una relación I(Fe)/I(Si + Al) de entre 0.2 y 0.9 de acuerdo como se determina por medio de XPS.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/657,150 US4568657A (en) | 1984-10-03 | 1984-10-03 | Catalyst formed of natural clay for use in the hydrodemetallization and hydroconversion of heavy crudes and residues and method of preparation of same |
Publications (1)
Publication Number | Publication Date |
---|---|
MX9206179A true MX9206179A (es) | 1994-04-29 |
Family
ID=24636037
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX000150A MX166777B (es) | 1984-10-03 | 1985-10-03 | Catalizador formado de arcilla natural para usarse en la hidrodesmetalizacion e hidroconversion de crudos pesados y residuos y metodo para su preparacion |
MX9206179A MX9206179A (es) | 1984-10-03 | 1992-10-27 | Procedimiento para la hidrodesmetalizacion e hidroconversion de crudos pesados. |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX000150A MX166777B (es) | 1984-10-03 | 1985-10-03 | Catalizador formado de arcilla natural para usarse en la hidrodesmetalizacion e hidroconversion de crudos pesados y residuos y metodo para su preparacion |
Country Status (6)
Country | Link |
---|---|
US (1) | US4568657A (es) |
JP (1) | JPS6281487A (es) |
CA (1) | CA1251197A (es) |
DE (1) | DE3535322A1 (es) |
FR (1) | FR2570962B1 (es) |
MX (2) | MX166777B (es) |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4670132A (en) * | 1982-06-29 | 1987-06-02 | Intevep, S.A. | Method of hydrocracking and method of preparing a catalyst therefor |
CA1329952C (en) | 1987-04-27 | 1994-05-31 | Yoshihiko Imanaka | Multi-layer superconducting circuit substrate and process for manufacturing same |
US5160032A (en) * | 1990-02-22 | 1992-11-03 | Uop | Hydrocarbon conversion process using alumina clay compositions |
DE4405876A1 (de) * | 1994-02-23 | 1995-10-05 | Sued Chemie Ag | Katalysator- bzw. Katalysatorträger-Formkörper |
US10941353B2 (en) * | 2004-04-28 | 2021-03-09 | Hydrocarbon Technology & Innovation, Llc | Methods and mixing systems for introducing catalyst precursor into heavy oil feedstock |
KR101493631B1 (ko) | 2004-04-28 | 2015-02-13 | 헤드워터스 헤비 오일, 엘엘씨 | 에뷸레이트 베드 하이드로프로세싱 방법 및 시스템 및 기존의 에뷸레이트 베드 시스템을 개량하는 방법 |
US7517446B2 (en) * | 2004-04-28 | 2009-04-14 | Headwaters Heavy Oil, Llc | Fixed bed hydroprocessing methods and systems and methods for upgrading an existing fixed bed system |
EP1753844B1 (en) * | 2004-04-28 | 2016-06-08 | Headwaters Heavy Oil, LLC | Hydroprocessing method and system for upgrading heavy oil |
WO2008095329A1 (fr) * | 2007-01-31 | 2008-08-14 | Institute Of Process Engineering, Chinese Academy Of Sciences | Revêtement anti-oxydation pour l'acier et méthode de protection de l'acier |
US8034232B2 (en) | 2007-10-31 | 2011-10-11 | Headwaters Technology Innovation, Llc | Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker |
US8142645B2 (en) * | 2008-01-03 | 2012-03-27 | Headwaters Technology Innovation, Llc | Process for increasing the mono-aromatic content of polynuclear-aromatic-containing feedstocks |
US8563456B2 (en) * | 2008-10-03 | 2013-10-22 | Chevron U.S.A. Inc. | Hydrodemetallization catalyst and process |
WO2012088025A2 (en) | 2010-12-20 | 2012-06-28 | Chevron U.S.A. Inc. | Hydroprocessing catalysts and methods for making thereof |
US9790440B2 (en) | 2011-09-23 | 2017-10-17 | Headwaters Technology Innovation Group, Inc. | Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker |
TWI611836B (zh) | 2012-02-17 | 2018-01-21 | Advanced Refining Technologies Llc. | 觸媒支撐物及其製備方法 |
TWI579043B (zh) * | 2012-02-17 | 2017-04-21 | 先進精鍊科技有限公司 | 球形觸媒支撐物及其製備方法 |
TWI617354B (zh) | 2012-06-20 | 2018-03-11 | 先進精鍊科技有限公司 | 改良之含氧化鈦之殘餘氫化處理觸媒 |
US9644157B2 (en) | 2012-07-30 | 2017-05-09 | Headwaters Heavy Oil, Llc | Methods and systems for upgrading heavy oil using catalytic hydrocracking and thermal coking |
US11414607B2 (en) | 2015-09-22 | 2022-08-16 | Hydrocarbon Technology & Innovation, Llc | Upgraded ebullated bed reactor with increased production rate of converted products |
US11414608B2 (en) | 2015-09-22 | 2022-08-16 | Hydrocarbon Technology & Innovation, Llc | Upgraded ebullated bed reactor used with opportunity feedstocks |
US11421164B2 (en) | 2016-06-08 | 2022-08-23 | Hydrocarbon Technology & Innovation, Llc | Dual catalyst system for ebullated bed upgrading to produce improved quality vacuum residue product |
US11732203B2 (en) | 2017-03-02 | 2023-08-22 | Hydrocarbon Technology & Innovation, Llc | Ebullated bed reactor upgraded to produce sediment that causes less equipment fouling |
KR102505534B1 (ko) | 2017-03-02 | 2023-03-02 | 하이드로카본 테크놀로지 앤 이노베이션, 엘엘씨 | 오염 침전물이 적은 업그레이드된 에뷸레이티드 베드 반응기 |
CA3057131C (en) | 2018-10-17 | 2024-04-23 | Hydrocarbon Technology And Innovation, Llc | Upgraded ebullated bed reactor with no recycle buildup of asphaltenes in vacuum bottoms |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR641623A (fr) * | 1926-09-29 | 1928-08-07 | Ig Farbenindustrie Ag | Procédé pour extraire l'alumine de l'argile et autres matières premières alumineuses au moyen d'acides |
GB396780A (en) * | 1931-10-31 | 1933-07-31 | Howard Spence | Improvements in the preparation of catalytic materials and of carriers therefor |
GB585571A (en) * | 1942-08-11 | 1947-02-12 | Standard Oil Dev Co | Improvements in or relating to the catalytic treatment of hydrocarbons |
US2388735A (en) * | 1943-07-03 | 1945-11-13 | Filtrol Corp | Method of drying pelleted catalyst |
GB949889A (en) * | 1961-03-02 | 1964-02-19 | Kali Chemie Ag | A method of producing carriers for catalytic contacts |
GB1188317A (en) * | 1966-12-10 | 1970-04-15 | Mizusawa Industrial Chem | Improvements in the production of Active Clay and Finely Divided Silica |
FR2122696A5 (es) * | 1971-01-20 | 1972-09-01 | Raffinage Cie Francaise | |
JPS5817653B2 (ja) * | 1972-09-28 | 1983-04-08 | ジユ−ト − ヒエミ− ア−ゲ− | 吸着剤の製造方法 |
US3876523A (en) * | 1973-08-29 | 1975-04-08 | Mobil Oil Corp | Catalyst for residua demetalation and desulfurization |
US3993601A (en) * | 1974-02-07 | 1976-11-23 | Exxon Research And Engineering Company | Process for preparing a heavy crude conversion catalyst |
US3989645A (en) * | 1974-02-07 | 1976-11-02 | Exxon Research And Engineering Company | Process for preparing a heavy crude conversion catalyst |
US3977961A (en) * | 1974-02-07 | 1976-08-31 | Exxon Research And Engineering Company | Heavy crude conversion |
JPS527887A (en) * | 1975-07-09 | 1977-01-21 | Chiyoda Chem Eng & Constr Co Ltd | Process for producing catalysts |
JPS5239590A (en) * | 1975-09-25 | 1977-03-26 | Toyobo Co Ltd | Catalyst for removing nox |
JPS548604A (en) * | 1977-06-22 | 1979-01-23 | Agency Of Ind Science & Technol | Method of removing metals in hydrocarbon oil |
DE2908491A1 (de) * | 1979-03-05 | 1980-09-18 | Huels Chemische Werke Ag | Verfahren zur herstellung eines katalysators fuer die hydratation von olefinen zu alkoholen |
CA1145285A (en) * | 1979-09-26 | 1983-04-26 | Robert A. Van Nordstrand | Hydrocarbons hydroprocessing with halloysite catalyst |
JPS6038178B2 (ja) * | 1980-12-17 | 1985-08-30 | 大阪窯業株式会社 | 炭化水素の低温水蒸気改質用触媒耐火物の製造法 |
-
1984
- 1984-10-03 US US06/657,150 patent/US4568657A/en not_active Expired - Fee Related
-
1985
- 1985-09-30 CA CA000491827A patent/CA1251197A/en not_active Expired
- 1985-10-03 DE DE19853535322 patent/DE3535322A1/de active Granted
- 1985-10-03 JP JP60221130A patent/JPS6281487A/ja active Granted
- 1985-10-03 FR FR8514660A patent/FR2570962B1/fr not_active Expired
- 1985-10-03 MX MX000150A patent/MX166777B/es unknown
-
1992
- 1992-10-27 MX MX9206179A patent/MX9206179A/es unknown
Also Published As
Publication number | Publication date |
---|---|
US4568657A (en) | 1986-02-04 |
JPS6281487A (ja) | 1987-04-14 |
MX166777B (es) | 1993-02-04 |
CA1251197A (en) | 1989-03-14 |
DE3535322C2 (es) | 1993-02-18 |
FR2570962B1 (fr) | 1988-11-04 |
FR2570962A1 (fr) | 1986-04-04 |
DE3535322A1 (de) | 1986-04-03 |
JPH0510974B2 (es) | 1993-02-12 |
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