MX9206179A - Procedimiento para la hidrodesmetalizacion e hidroconversion de crudos pesados. - Google Patents

Procedimiento para la hidrodesmetalizacion e hidroconversion de crudos pesados.

Info

Publication number
MX9206179A
MX9206179A MX9206179A MX9206179A MX9206179A MX 9206179 A MX9206179 A MX 9206179A MX 9206179 A MX9206179 A MX 9206179A MX 9206179 A MX9206179 A MX 9206179A MX 9206179 A MX9206179 A MX 9206179A
Authority
MX
Mexico
Prior art keywords
catalyst
hydroconversion
procedure
heavy
hydrodesmetalization
Prior art date
Application number
MX9206179A
Other languages
English (en)
Inventor
Pedro Roa
Alfredo Morales Ruiz
Jose Guitian
Otto Rodriguez
Carlos Zerpa
Gonzalo Sepulveda
Marcos Rosa-Brussin
Nereida Carrion
Original Assignee
Intevep Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Intevep Sa filed Critical Intevep Sa
Publication of MX9206179A publication Critical patent/MX9206179A/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16Clays or other mineral silicates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Un catalizador estable natural activo para usarse en la hidrodesmetalización (HDM) y la hidroconversión (HC) de crudos y residuos pesados y en particular, un método para la preparación del catalizador a partir de arcilla natural y un procedimiento para el tratamiento de crudos y residuos pesados con el catalizador. El catalizador está exento de metales hidrogenantes de los grupos VIB y VII de la tabla periódica y comprende primordialmente hierro, sílice y aluminio, derivados de la composición de la arcilla natural. El catalizador tiene un área de superficie de entre 20 y 100 m2/g, un volumen de poro total de entre 0.20 y 0.90 cc/g, en el que entre el 50 y el 100 del volumen del poro total contiene poros con un diámetro mayor de 400 A. El catalizador tiene una relación I(Fe)/I(Si + Al) de entre 0.2 y 0.9 de acuerdo como se determina por medio de XPS.
MX9206179A 1984-10-03 1992-10-27 Procedimiento para la hidrodesmetalizacion e hidroconversion de crudos pesados. MX9206179A (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/657,150 US4568657A (en) 1984-10-03 1984-10-03 Catalyst formed of natural clay for use in the hydrodemetallization and hydroconversion of heavy crudes and residues and method of preparation of same

Publications (1)

Publication Number Publication Date
MX9206179A true MX9206179A (es) 1994-04-29

Family

ID=24636037

Family Applications (2)

Application Number Title Priority Date Filing Date
MX000150A MX166777B (es) 1984-10-03 1985-10-03 Catalizador formado de arcilla natural para usarse en la hidrodesmetalizacion e hidroconversion de crudos pesados y residuos y metodo para su preparacion
MX9206179A MX9206179A (es) 1984-10-03 1992-10-27 Procedimiento para la hidrodesmetalizacion e hidroconversion de crudos pesados.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
MX000150A MX166777B (es) 1984-10-03 1985-10-03 Catalizador formado de arcilla natural para usarse en la hidrodesmetalizacion e hidroconversion de crudos pesados y residuos y metodo para su preparacion

Country Status (6)

Country Link
US (1) US4568657A (es)
JP (1) JPS6281487A (es)
CA (1) CA1251197A (es)
DE (1) DE3535322A1 (es)
FR (1) FR2570962B1 (es)
MX (2) MX166777B (es)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
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US4670132A (en) * 1982-06-29 1987-06-02 Intevep, S.A. Method of hydrocracking and method of preparing a catalyst therefor
CA1329952C (en) 1987-04-27 1994-05-31 Yoshihiko Imanaka Multi-layer superconducting circuit substrate and process for manufacturing same
US5160032A (en) * 1990-02-22 1992-11-03 Uop Hydrocarbon conversion process using alumina clay compositions
DE4405876A1 (de) * 1994-02-23 1995-10-05 Sued Chemie Ag Katalysator- bzw. Katalysatorträger-Formkörper
US10941353B2 (en) * 2004-04-28 2021-03-09 Hydrocarbon Technology & Innovation, Llc Methods and mixing systems for introducing catalyst precursor into heavy oil feedstock
KR101493631B1 (ko) 2004-04-28 2015-02-13 헤드워터스 헤비 오일, 엘엘씨 에뷸레이트 베드 하이드로프로세싱 방법 및 시스템 및 기존의 에뷸레이트 베드 시스템을 개량하는 방법
US7517446B2 (en) * 2004-04-28 2009-04-14 Headwaters Heavy Oil, Llc Fixed bed hydroprocessing methods and systems and methods for upgrading an existing fixed bed system
EP1753844B1 (en) * 2004-04-28 2016-06-08 Headwaters Heavy Oil, LLC Hydroprocessing method and system for upgrading heavy oil
WO2008095329A1 (fr) * 2007-01-31 2008-08-14 Institute Of Process Engineering, Chinese Academy Of Sciences Revêtement anti-oxydation pour l'acier et méthode de protection de l'acier
US8034232B2 (en) 2007-10-31 2011-10-11 Headwaters Technology Innovation, Llc Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker
US8142645B2 (en) * 2008-01-03 2012-03-27 Headwaters Technology Innovation, Llc Process for increasing the mono-aromatic content of polynuclear-aromatic-containing feedstocks
US8563456B2 (en) * 2008-10-03 2013-10-22 Chevron U.S.A. Inc. Hydrodemetallization catalyst and process
WO2012088025A2 (en) 2010-12-20 2012-06-28 Chevron U.S.A. Inc. Hydroprocessing catalysts and methods for making thereof
US9790440B2 (en) 2011-09-23 2017-10-17 Headwaters Technology Innovation Group, Inc. Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker
TWI611836B (zh) 2012-02-17 2018-01-21 Advanced Refining Technologies Llc. 觸媒支撐物及其製備方法
TWI579043B (zh) * 2012-02-17 2017-04-21 先進精鍊科技有限公司 球形觸媒支撐物及其製備方法
TWI617354B (zh) 2012-06-20 2018-03-11 先進精鍊科技有限公司 改良之含氧化鈦之殘餘氫化處理觸媒
US9644157B2 (en) 2012-07-30 2017-05-09 Headwaters Heavy Oil, Llc Methods and systems for upgrading heavy oil using catalytic hydrocracking and thermal coking
US11414607B2 (en) 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor with increased production rate of converted products
US11414608B2 (en) 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor used with opportunity feedstocks
US11421164B2 (en) 2016-06-08 2022-08-23 Hydrocarbon Technology & Innovation, Llc Dual catalyst system for ebullated bed upgrading to produce improved quality vacuum residue product
US11732203B2 (en) 2017-03-02 2023-08-22 Hydrocarbon Technology & Innovation, Llc Ebullated bed reactor upgraded to produce sediment that causes less equipment fouling
KR102505534B1 (ko) 2017-03-02 2023-03-02 하이드로카본 테크놀로지 앤 이노베이션, 엘엘씨 오염 침전물이 적은 업그레이드된 에뷸레이티드 베드 반응기
CA3057131C (en) 2018-10-17 2024-04-23 Hydrocarbon Technology And Innovation, Llc Upgraded ebullated bed reactor with no recycle buildup of asphaltenes in vacuum bottoms

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FR641623A (fr) * 1926-09-29 1928-08-07 Ig Farbenindustrie Ag Procédé pour extraire l'alumine de l'argile et autres matières premières alumineuses au moyen d'acides
GB396780A (en) * 1931-10-31 1933-07-31 Howard Spence Improvements in the preparation of catalytic materials and of carriers therefor
GB585571A (en) * 1942-08-11 1947-02-12 Standard Oil Dev Co Improvements in or relating to the catalytic treatment of hydrocarbons
US2388735A (en) * 1943-07-03 1945-11-13 Filtrol Corp Method of drying pelleted catalyst
GB949889A (en) * 1961-03-02 1964-02-19 Kali Chemie Ag A method of producing carriers for catalytic contacts
GB1188317A (en) * 1966-12-10 1970-04-15 Mizusawa Industrial Chem Improvements in the production of Active Clay and Finely Divided Silica
FR2122696A5 (es) * 1971-01-20 1972-09-01 Raffinage Cie Francaise
JPS5817653B2 (ja) * 1972-09-28 1983-04-08 ジユ−ト − ヒエミ− ア−ゲ− 吸着剤の製造方法
US3876523A (en) * 1973-08-29 1975-04-08 Mobil Oil Corp Catalyst for residua demetalation and desulfurization
US3993601A (en) * 1974-02-07 1976-11-23 Exxon Research And Engineering Company Process for preparing a heavy crude conversion catalyst
US3989645A (en) * 1974-02-07 1976-11-02 Exxon Research And Engineering Company Process for preparing a heavy crude conversion catalyst
US3977961A (en) * 1974-02-07 1976-08-31 Exxon Research And Engineering Company Heavy crude conversion
JPS527887A (en) * 1975-07-09 1977-01-21 Chiyoda Chem Eng & Constr Co Ltd Process for producing catalysts
JPS5239590A (en) * 1975-09-25 1977-03-26 Toyobo Co Ltd Catalyst for removing nox
JPS548604A (en) * 1977-06-22 1979-01-23 Agency Of Ind Science & Technol Method of removing metals in hydrocarbon oil
DE2908491A1 (de) * 1979-03-05 1980-09-18 Huels Chemische Werke Ag Verfahren zur herstellung eines katalysators fuer die hydratation von olefinen zu alkoholen
CA1145285A (en) * 1979-09-26 1983-04-26 Robert A. Van Nordstrand Hydrocarbons hydroprocessing with halloysite catalyst
JPS6038178B2 (ja) * 1980-12-17 1985-08-30 大阪窯業株式会社 炭化水素の低温水蒸気改質用触媒耐火物の製造法

Also Published As

Publication number Publication date
US4568657A (en) 1986-02-04
JPS6281487A (ja) 1987-04-14
MX166777B (es) 1993-02-04
CA1251197A (en) 1989-03-14
DE3535322C2 (es) 1993-02-18
FR2570962B1 (fr) 1988-11-04
FR2570962A1 (fr) 1986-04-04
DE3535322A1 (de) 1986-04-03
JPH0510974B2 (es) 1993-02-12

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