GB1438645A - Hydrocarbon conversion process - Google Patents

Hydrocarbon conversion process

Info

Publication number
GB1438645A
GB1438645A GB1052873*[A GB1052873A GB1438645A GB 1438645 A GB1438645 A GB 1438645A GB 1052873 A GB1052873 A GB 1052873A GB 1438645 A GB1438645 A GB 1438645A
Authority
GB
United Kingdom
Prior art keywords
larger
pore volume
oil
demetallization
july
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1052873*[A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to NLAANVRAGE7309387,A priority Critical patent/NL175732C/en
Priority to JP48025632A priority patent/JPS48104147A/ja
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Priority to GB1052873*[A priority patent/GB1438645A/en
Priority to CA172,040A priority patent/CA1005777A/en
Priority to BE1005200A priority patent/BE801575A/en
Priority to IT26138/73A priority patent/IT990890B/en
Priority to NLAANVRAGE7309387,A priority patent/NL175732B/en
Priority to SE7309510A priority patent/SE401929B/en
Priority to FR7324709A priority patent/FR2197060B1/fr
Priority to AU57798/73A priority patent/AU478267B2/en
Priority to FI2157/73A priority patent/FI58650C/en
Priority to NO732757A priority patent/NO138909C/en
Priority to DE2334293A priority patent/DE2334293C2/en
Priority to NLAANVRAGE7316396,A priority patent/NL177609C/en
Priority to NL7410162A priority patent/NL7410162A/en
Priority to BE1006288A priority patent/BE822444R/en
Priority to DE19742456329 priority patent/DE2456329A1/en
Priority to FR7439045A priority patent/FR2253080B2/fr
Priority to GB5156374A priority patent/GB1458755A/en
Publication of GB1438645A publication Critical patent/GB1438645A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)

Abstract

1438645 Hydrodemetallization of residual oils SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ BV 5 July 1973 [7 July 1972 5 March 1973] 31966/72 and 10528/73 Heading C5E In a process for the catalytic conversion of residual hydrocarbon oil the oil is first demetallized and subsequently catalytically converted; the demetallization is carried out by contacting the oil with hydrogen in the presence of a catalyst comprising one or more metals having hydrogenation activity on a carrier and meeting either the requirements A or the requirements B-A (1) 10À0-0À15v#p/d>3À5- 0À02v in which p is the specific average pore diameter in nm., d is the specific average particle diameter in mm., and v is the percentage of the total pore volume that consists of pores with a diameter larger than 100 nm., (2) v is smaller than 50, (3) the nitrogen pore volume is larger than 0À6 ml./g., (4) the surface area is larger than 150 m.<SP>2</SP>/g., and (5) p is larger than 5. B (1) p/d>10À0-0À15 v, (2) v is smaller than 50, (3) the total pore volume is larger than 0À4 ml./g., and (4) the surface area is larger than 100 m.<SP>2</SP>/g. The demetallization can be carried out at 300 -450‹ C. and 75-250 bar using a catalyst comprising (a) Mo, V or W and/or (b) Ni or Co on an alumina, silica or silica-alumina support. The catalytic conversion processes envisaged are catalytic cracking, hydrocracking and hydrodesulphurization.
GB1052873*[A 1972-03-07 1973-03-05 Hydrocarbon conversion process Expired GB1438645A (en)

Priority Applications (19)

Application Number Priority Date Filing Date Title
NLAANVRAGE7309387,A NL175732C (en) 1972-07-07 PROCEDURE FOR THE CATALYTIC DEMETALLIZATION OF RESIDUAL HYDROCARBON OILS AND THE FURTHER CATALYTIC CONVERSION OF THE OIL OBTAINED THEREIN.
JP48025632A JPS48104147A (en) 1972-03-07 1973-03-03
GB1052873*[A GB1438645A (en) 1972-07-07 1973-03-05 Hydrocarbon conversion process
CA172,040A CA1005777A (en) 1972-07-07 1973-05-23 Hydrocarbon conversion process
BE1005200A BE801575A (en) 1972-07-07 1973-06-28 PROCESS FOR CONVERTING HYDROCARBONS
IT26138/73A IT990890B (en) 1972-07-07 1973-07-03 PROCESS FOR THE CONVERSION OF HYDROCARBONS
AU57798/73A AU478267B2 (en) 1972-07-07 1973-07-05 Hydrocarbon conversion process
SE7309510A SE401929B (en) 1972-07-07 1973-07-05 PROCEDURE FOR CATALYTIC CONVERSION OF A CARBOHYDRATE OIL, IN WHICH THE OIL IS FIRST DEMETALIZED AND THEREFORE CATALYTIC TRANSFORMED
FR7324709A FR2197060B1 (en) 1972-07-07 1973-07-05
NLAANVRAGE7309387,A NL175732B (en) 1972-07-07 1973-07-05 METHOD FOR CATALYTICALLY METALIZING RESIDUAL HYDROCARBON OILS AND FURTHER CATALYTIC CONVERTING THE OIL OBTAINED THEREOF.
FI2157/73A FI58650C (en) 1972-07-07 1973-07-05 KATALYTISKT KONSERVERINGSFOERFARANDE FOER RESTOLJA
NO732757A NO138909C (en) 1972-07-07 1973-07-05 PROCEDURE FOR DEMETALLIZATION OF A HYDROCARBON OIL IN THE PRESENCE OF HYDROGEN AND A CATALYST OF VANADIUM AND NICKEL ON SILICONE OXYDE CARRIERS
DE2334293A DE2334293C2 (en) 1972-07-07 1973-07-05 Process for the catalytic demetallization of residual hydrocarbon oils and subsequent catalytic hydrocracking, catalytic hydrogenating desulphurization or catalytic cracking
NLAANVRAGE7316396,A NL177609C (en) 1972-07-07 1973-11-30 IMPROVED PROCESS FOR THE CATALYTIC CONVERSION OF A RESIDUAL HYDROCARBON OIL WITH THE METALIZATION OF THE CATALYTIC CONVERSION OIL FIRST.
NL7410162A NL7410162A (en) 1972-07-07 1974-07-29 Demetallisation of residual oils - with metal-silica catalysts with specified pore characteristics and a low loss on ignition
BE1006288A BE822444R (en) 1972-07-07 1974-11-21 PROCESS FOR CONVERTING HYDROCARBONS
DE19742456329 DE2456329A1 (en) 1972-07-07 1974-11-28 METHOD FOR CATALYTIC CONVERSION OF HYDROCARBON RESIDUAL SOILS
FR7439045A FR2253080B2 (en) 1972-07-07 1974-11-28
GB5156374A GB1458755A (en) 1972-07-07 1974-11-28 Hydrocarbon conversion process

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB3196672 1972-07-07
GB1052873*[A GB1438645A (en) 1972-07-07 1973-03-05 Hydrocarbon conversion process

Publications (1)

Publication Number Publication Date
GB1438645A true GB1438645A (en) 1976-06-09

Family

ID=26247579

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1052873*[A Expired GB1438645A (en) 1972-03-07 1973-03-05 Hydrocarbon conversion process

Country Status (10)

Country Link
BE (1) BE801575A (en)
CA (1) CA1005777A (en)
DE (1) DE2334293C2 (en)
FI (1) FI58650C (en)
FR (1) FR2197060B1 (en)
GB (1) GB1438645A (en)
IT (1) IT990890B (en)
NL (2) NL175732B (en)
NO (1) NO138909C (en)
SE (1) SE401929B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0026508A1 (en) * 1979-09-26 1981-04-08 Shell Internationale Researchmaatschappij B.V. Process and apparatus for the demetallization of a hydrocarbon oil
EP0034853A1 (en) * 1980-02-20 1981-09-02 Shell Internationale Researchmaatschappij B.V. Process for the removal of vanadium-containing acid from an acid-extracted deactivated demetallization catalyst
EP0683218A2 (en) 1994-05-19 1995-11-22 Shell Internationale Researchmaatschappij B.V. Process for the conversion of a residual hydrocarbon oil
WO2010084112A1 (en) 2009-01-20 2010-07-29 Shell Internationale Research Maatschappij B.V. Process for the hydro-demetallization of hydrocarbon feedstocks

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7412337A (en) * 1974-09-18 1976-03-22 Shell Int Research PROCEDURE FOR THE PREPARATION OF NEW CATALYSTS.
NL7412761A (en) * 1974-09-27 1976-03-30 Shell Int Research PROCEDURE TO IMPROVE THE QUALITY OF HYDROCARBON HYDROGEN OILS.
JPS601056B2 (en) * 1980-02-19 1985-01-11 千代田化工建設株式会社 Hydrotreatment of heavy hydrocarbon oils containing asphaltenes
EP0068543B1 (en) * 1981-06-25 1988-09-21 Shell Internationale Researchmaatschappij B.V. Process for the preparation of a hydrocarbon mixture

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL167464C (en) * 1970-07-14 1981-12-16 Shell Int Research PROCESS FOR THE CATALYTICALLY HYDRATING DEFUSIONING OF RESIDUAL HYDROCARBON OILS.

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0026508A1 (en) * 1979-09-26 1981-04-08 Shell Internationale Researchmaatschappij B.V. Process and apparatus for the demetallization of a hydrocarbon oil
EP0034853A1 (en) * 1980-02-20 1981-09-02 Shell Internationale Researchmaatschappij B.V. Process for the removal of vanadium-containing acid from an acid-extracted deactivated demetallization catalyst
EP0034853B1 (en) * 1980-02-20 1984-07-04 Shell Internationale Researchmaatschappij B.V. Process for the removal of vanadium-containing acid from an acid-extracted deactivated demetallization catalyst
EP0683218A2 (en) 1994-05-19 1995-11-22 Shell Internationale Researchmaatschappij B.V. Process for the conversion of a residual hydrocarbon oil
WO2010084112A1 (en) 2009-01-20 2010-07-29 Shell Internationale Research Maatschappij B.V. Process for the hydro-demetallization of hydrocarbon feedstocks

Also Published As

Publication number Publication date
FR2197060A1 (en) 1974-03-22
DE2334293A1 (en) 1974-01-24
DE2334293C2 (en) 1983-05-11
FI58650B (en) 1980-11-28
NO138909B (en) 1978-08-28
NO138909C (en) 1978-12-06
NL175732B (en) 1984-07-16
AU5779873A (en) 1975-02-06
IT990890B (en) 1975-07-10
BE801575A (en) 1973-12-28
CA1005777A (en) 1977-02-22
SE401929B (en) 1978-06-05
FI58650C (en) 1981-03-10
NL7309387A (en) 1974-01-09
NL175732C (en)
FR2197060B1 (en) 1979-04-27

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PE20 Patent expired after termination of 20 years

Effective date: 19930704