GB1458755A - Hydrocarbon conversion process - Google Patents
Hydrocarbon conversion processInfo
- Publication number
- GB1458755A GB1458755A GB5156374A GB5156374A GB1458755A GB 1458755 A GB1458755 A GB 1458755A GB 5156374 A GB5156374 A GB 5156374A GB 5156374 A GB5156374 A GB 5156374A GB 1458755 A GB1458755 A GB 1458755A
- Authority
- GB
- United Kingdom
- Prior art keywords
- larger
- catalyst
- oil
- pore volume
- nov
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000006243 chemical reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 title 1
- 229930195733 hydrocarbon Natural products 0.000 title 1
- 150000002430 hydrocarbons Chemical class 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 6
- 239000003921 oil Substances 0.000 abstract 5
- 239000011148 porous material Substances 0.000 abstract 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- 229910052720 vanadium Inorganic materials 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 239000000969 carrier Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B01J35/60—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B01J35/615—
-
- B01J35/635—
-
- B01J35/647—
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
Abstract
1458755 Hydrodemetallization of residual oils SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ BV 28 Nov 1974 [30 Nov 1973 29 July 1974] 51563/74 Addition to 1438645 Heading C5E A process for the catalytic conversion of a residual oil comprises first demetallizing the oil and then catalytically converting the demetallized oil; the demetallization is carried out by contacting the oil with hydrogen in the presence of a catalyst comprising 0À1-15 parts by weight of one or more metals having hydrogenation activity per 100 parts of a silica carrier which has a loss on ignition of less than 1%, or of less than 0À5% if the catalyst comprises vanadium and meeting the requirements (1) p/d>3À5- 0À02v, in which p is the specific average pore diameter in nm., d is the specific average particle diameter in mm. and v is the percentage of the total pore volume that consists of pores with a diameter larger than 100 nm.; (2) the total pore volume is larger than 0À40 ml./g.; (3) v is smaller than 50; and (4) the specific surface area is larger than 100 m.<SP>2</SP>/g., with the proviso that, if the catalyst has such a p and d that the quotient p/d is at most 10-0À15 v, the catalyst also meets the requirements (a) the nitrogen pore volume is larger than 0À60 ml./g., (b) the specific surface area is larger than 150 m.<SP>2</SP>/g. and (c) p is larger than 5 nm. Examples compare the use of catalysts of Ni, Ni+V, Co+Mo, and Ni+Mo on silica carriers with the use of catalysts of Ni+V or Ni + Mo on alumina.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3196672 | 1972-07-07 | ||
| GB1052873*[A GB1438645A (en) | 1972-07-07 | 1973-03-05 | Hydrocarbon conversion process |
| NLAANVRAGE7316396,A NL177609C (en) | 1972-07-07 | 1973-11-30 | IMPROVED PROCESS FOR THE CATALYTIC CONVERSION OF A RESIDUAL HYDROCARBON OIL WITH THE METALIZATION OF THE CATALYTIC CONVERSION OIL FIRST. |
| NL7410162A NL7410162A (en) | 1972-07-07 | 1974-07-29 | Demetallisation of residual oils - with metal-silica catalysts with specified pore characteristics and a low loss on ignition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1458755A true GB1458755A (en) | 1976-12-15 |
Family
ID=27448050
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5156374A Expired GB1458755A (en) | 1972-07-07 | 1974-11-28 | Hydrocarbon conversion process |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE822444R (en) |
| DE (1) | DE2456329A1 (en) |
| FR (1) | FR2253080B2 (en) |
| GB (1) | GB1458755A (en) |
-
1974
- 1974-11-21 BE BE1006288A patent/BE822444R/en active
- 1974-11-28 FR FR7439045A patent/FR2253080B2/fr not_active Expired
- 1974-11-28 GB GB5156374A patent/GB1458755A/en not_active Expired
- 1974-11-28 DE DE19742456329 patent/DE2456329A1/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| DE2456329C2 (en) | 1987-03-26 |
| BE822444R (en) | 1975-05-21 |
| DE2456329A1 (en) | 1975-06-05 |
| FR2253080B2 (en) | 1979-06-01 |
| FR2253080A2 (en) | 1975-06-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] |