GB1410924A - Hydrocarbon conversion process - Google Patents

Hydrocarbon conversion process

Info

Publication number
GB1410924A
GB1410924A GB5954771A GB5954771A GB1410924A GB 1410924 A GB1410924 A GB 1410924A GB 5954771 A GB5954771 A GB 5954771A GB 5954771 A GB5954771 A GB 5954771A GB 1410924 A GB1410924 A GB 1410924A
Authority
GB
United Kingdom
Prior art keywords
hydrodesulphurization
bar
catalyst
catalytic
dec
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5954771A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Priority to GB5954771A priority Critical patent/GB1410924A/en
Priority to CA155,291A priority patent/CA981615A/en
Priority to NL7216877A priority patent/NL7216877A/xx
Priority to FR7245433A priority patent/FR2164741B1/fr
Priority to DE2262410A priority patent/DE2262410A1/en
Priority to JP12733672A priority patent/JPS5628956B2/ja
Publication of GB1410924A publication Critical patent/GB1410924A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/14—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/643—Pore diameter less than 2 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/67—Pore distribution monomodal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

1410924 Catalytic hydrodesulphurization of residual oils SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ BV 20 Dec 1972 [22 Dec 1971 (2)] 59547/71 and 59548/71 Heading C5E The catalytic hydrodesulphurization with catalyst replenishment of residual oils is carried out using a catalyst having a pore volume above 0À30 ml./g. and which is in the form either of particles less than 10% of the pore volume of which is present in pores of diameter above 100 nm., said particles having a specific average pore diameter (p, measured in nm.) and specific average particle diameter (d, measured in mm.) that: (a) if the oil has a total vanadium plus nickel content of at most 120 p.p.m. wt. then 0À025 Î P H2 # p/(d)<SP>0À6</SP> # 0À1ÎP H2 -5À0, the hydrogen partial pressure P H2 being at least 70 bar; or (b) if the oil has a total vanadium plus nickel content above 120 p.p.m. then 4À5 > p/(d)<SP>0À6</SP> > 14À0 and the hydrogen partial pressure P H2 being at least 50 bar. The hydrodesulphurization can be carried out at 300-475‹ C. and 50-200 bar using a catalyst containing Ni and/or Co together with Mo and/or W on a support such as alumina or silica-alumina. The hydrodesulphurization can be preceded by a demetallization by catalytic hydrogenation.
GB5954771A 1971-12-22 1971-12-22 Hydrocarbon conversion process Expired GB1410924A (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
GB5954771A GB1410924A (en) 1971-12-22 1971-12-22 Hydrocarbon conversion process
CA155,291A CA981615A (en) 1971-12-22 1972-10-31 Hydrocarbon conversion process
NL7216877A NL7216877A (en) 1971-12-22 1972-12-13
FR7245433A FR2164741B1 (en) 1971-12-22 1972-12-20
DE2262410A DE2262410A1 (en) 1971-12-22 1972-12-20 METHOD FOR CATALYTIC HYDRATING DESULFURIZATION WITH CATALYST FILLING
JP12733672A JPS5628956B2 (en) 1971-12-22 1972-12-20

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB5954771A GB1410924A (en) 1971-12-22 1971-12-22 Hydrocarbon conversion process
GB5954871 1971-12-22

Publications (1)

Publication Number Publication Date
GB1410924A true GB1410924A (en) 1975-10-22

Family

ID=26267794

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5954771A Expired GB1410924A (en) 1971-12-22 1971-12-22 Hydrocarbon conversion process

Country Status (6)

Country Link
JP (1) JPS5628956B2 (en)
CA (1) CA981615A (en)
DE (1) DE2262410A1 (en)
FR (1) FR2164741B1 (en)
GB (1) GB1410924A (en)
NL (1) NL7216877A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1217756A (en) * 1983-08-10 1987-02-10 Hri, Inc. Demetallization catalyst and process for metals- containing hydrocarbon feedstocks
JPS6078746U (en) * 1983-11-04 1985-06-01 日本クラウンコルク株式会社 Cap device for liquid containers

Also Published As

Publication number Publication date
FR2164741B1 (en) 1975-11-07
NL7216877A (en) 1973-06-26
CA981615A (en) 1976-01-13
JPS4870705A (en) 1973-09-25
JPS5628956B2 (en) 1981-07-04
FR2164741A1 (en) 1973-08-03
DE2262410A1 (en) 1973-06-28

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee