GB1446175A - Shaped catalyst particles and hydrotreating processes employing the same - Google Patents

Shaped catalyst particles and hydrotreating processes employing the same

Info

Publication number
GB1446175A
GB1446175A GB4492973A GB4492973A GB1446175A GB 1446175 A GB1446175 A GB 1446175A GB 4492973 A GB4492973 A GB 4492973A GB 4492973 A GB4492973 A GB 4492973A GB 1446175 A GB1446175 A GB 1446175A
Authority
GB
United Kingdom
Prior art keywords
alumina
range
same
catalyst particles
shaped catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4492973A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wyeth Holdings LLC
Original Assignee
American Cyanamid Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by American Cyanamid Co filed Critical American Cyanamid Co
Priority to GB4492973A priority Critical patent/GB1446175A/en
Publication of GB1446175A publication Critical patent/GB1446175A/en
Priority to MY1980283A priority patent/MY8000283A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/54—Bars or plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/55—Cylinders or rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/67—Pore distribution monomodal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)

Abstract

1446175 Hydrotreating catalyst AMERICAN CYANAMID CO 25 Sept 1973 44929/73 Heading B1E [Also in Division C5] A hydrotreating catalyst comprises a major portion of alumina, 10 to 20% wt molybdenum oxide and 1 to 8% wt of an oxide of cobalt and/or nickel and is in the form of particles of concave cross-sectional shape characterised by a concavity index greater than 1.0, a void fraction in the range 0.25 to 0.60, a ratio of geometric volume to geometric surface of 0.001 to 0.042 inch, a catalytic surface area of greater than 150 m<SP>2</SP>/g and a catalytic pore volume in the range of 0.35 to 0.85 cc/g, wherein a major portion of the pores are of diameter in the range of 40-90Š units. The composition may additionally contain up to 35% wt silica, based on the total weight of silica and alumina or up to 45% wt of zeolite based on the total weight of a zeolite and alumina. The catalyst may be sulphided before use.
GB4492973A 1973-09-25 1973-09-25 Shaped catalyst particles and hydrotreating processes employing the same Expired GB1446175A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB4492973A GB1446175A (en) 1973-09-25 1973-09-25 Shaped catalyst particles and hydrotreating processes employing the same
MY1980283A MY8000283A (en) 1973-09-25 1980-12-31 Shaped catalyst particles and hydrotreating processes employing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB4492973A GB1446175A (en) 1973-09-25 1973-09-25 Shaped catalyst particles and hydrotreating processes employing the same

Publications (1)

Publication Number Publication Date
GB1446175A true GB1446175A (en) 1976-08-18

Family

ID=10435271

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4492973A Expired GB1446175A (en) 1973-09-25 1973-09-25 Shaped catalyst particles and hydrotreating processes employing the same

Country Status (2)

Country Link
GB (1) GB1446175A (en)
MY (1) MY8000283A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0050912A1 (en) * 1980-10-24 1982-05-05 Standard Oil Company Catalyst and process for the hydrotreating of nitrogen-containing feeds
EP0052894A1 (en) * 1980-11-26 1982-06-02 Catalysts and Chemical Europe" Reforming catalysts and use thereof
EP0096322A2 (en) * 1982-06-08 1983-12-21 BASF Aktiengesellschaft Catalyst for the conversion of carbon monoxide and steam into sulfur-containing gases, process for the preparation of the catalyst and its use
EP0527635A2 (en) * 1991-08-12 1993-02-17 Exxon Research And Engineering Company Process for the catalytic hydrotreatment of petroleum feeds for the selective removal of sulfur and nitrogen
WO2003013725A1 (en) * 2001-08-01 2003-02-20 Shell Internationale Research Maatschappij, B.V. Shaped trilobal particles
US7563745B2 (en) 2002-06-07 2009-07-21 Shell Oil Company Shaped catalyst particles for hydrocarbon synthesis
US7811963B2 (en) 2002-11-04 2010-10-12 Shell Oil Company Elongated shaped particles use as a catalyst or support thereof
US7811966B2 (en) 2007-01-18 2010-10-12 Shell Oil Company Catalyst, catalyst precursor, and catalyst carrier
US7998899B2 (en) 2007-11-27 2011-08-16 Shell Oil Company Catalyst with support structure
US8168564B2 (en) 2007-11-27 2012-05-01 Coen Willem Johannes Pieterse Catalyst support

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0050912A1 (en) * 1980-10-24 1982-05-05 Standard Oil Company Catalyst and process for the hydrotreating of nitrogen-containing feeds
EP0052894A1 (en) * 1980-11-26 1982-06-02 Catalysts and Chemical Europe" Reforming catalysts and use thereof
EP0096322A2 (en) * 1982-06-08 1983-12-21 BASF Aktiengesellschaft Catalyst for the conversion of carbon monoxide and steam into sulfur-containing gases, process for the preparation of the catalyst and its use
EP0096322A3 (en) * 1982-06-08 1984-10-10 Basf Aktiengesellschaft Catalyst for the conversion of carbon monoxide and steam into sulfur-containing gases, process for the preparation of the catalyst and its use
EP0527635A2 (en) * 1991-08-12 1993-02-17 Exxon Research And Engineering Company Process for the catalytic hydrotreatment of petroleum feeds for the selective removal of sulfur and nitrogen
EP0527635A3 (en) * 1991-08-12 1993-04-07 Exxon Research And Engineering Company Process for the catalytic hydrotreatment of petroleum feeds for the selective removal of sulfur and nitrogen
WO2003013725A1 (en) * 2001-08-01 2003-02-20 Shell Internationale Research Maatschappij, B.V. Shaped trilobal particles
US7198845B2 (en) 2001-08-01 2007-04-03 Shell Oil Company Shaped trilobal particles
CN100496739C (en) * 2001-08-01 2009-06-10 国际壳牌研究有限公司 Shaped trilobal particles
US7563745B2 (en) 2002-06-07 2009-07-21 Shell Oil Company Shaped catalyst particles for hydrocarbon synthesis
US7811963B2 (en) 2002-11-04 2010-10-12 Shell Oil Company Elongated shaped particles use as a catalyst or support thereof
US7811966B2 (en) 2007-01-18 2010-10-12 Shell Oil Company Catalyst, catalyst precursor, and catalyst carrier
US7998899B2 (en) 2007-11-27 2011-08-16 Shell Oil Company Catalyst with support structure
US8168564B2 (en) 2007-11-27 2012-05-01 Coen Willem Johannes Pieterse Catalyst support

Also Published As

Publication number Publication date
MY8000283A (en) 1980-12-31

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Legal Events

Date Code Title Description
414F Notice of opposition given (sect. 14/1949)
414B Case decided by the comptroller ** grants allowed (sect. 14/1949)
PS Patent sealed [section 19, patents act 1949]
PE20 Patent expired after termination of 20 years

Effective date: 19930924