GB1415417A - Hydrotreating of petroleum distillates using shaped catalyst prtticles - Google Patents
Hydrotreating of petroleum distillates using shaped catalyst prtticlesInfo
- Publication number
- GB1415417A GB1415417A GB4789973A GB4789973A GB1415417A GB 1415417 A GB1415417 A GB 1415417A GB 4789973 A GB4789973 A GB 4789973A GB 4789973 A GB4789973 A GB 4789973A GB 1415417 A GB1415417 A GB 1415417A
- Authority
- GB
- United Kingdom
- Prior art keywords
- particles
- catalyst
- hydrotreating
- inch
- petroleum distillates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- 239000003209 petroleum derivative Substances 0.000 title abstract 2
- 239000002245 particle Substances 0.000 abstract 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 2
- 239000011148 porous material Substances 0.000 abstract 2
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 abstract 1
- 241000219793 Trifolium Species 0.000 abstract 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 abstract 1
- 229940010552 ammonium molybdate Drugs 0.000 abstract 1
- 235000018660 ammonium molybdate Nutrition 0.000 abstract 1
- 239000011609 ammonium molybdate Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 abstract 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 abstract 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052753 mercury Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 abstract 1
- 229910000480 nickel oxide Inorganic materials 0.000 abstract 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 abstract 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical class [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000011800 void material Substances 0.000 abstract 1
Classifications
-
- B01J35/50—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/076—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B01J35/60—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
-
- B01J35/615—
-
- B01J35/633—
-
- B01J35/635—
-
- B01J35/647—
Abstract
1415417 Shaped hydrotreating catalyst AMERICAN CYANAMID CO 12 Oct 1973 47899/73 Heading B1E [Also in Divisions C4 and C5] A catalyst for use in hydrotreating petroleum distillates comprises porous, but non-hollow; particles having a polylobal cross-sectional shape characterised by a concavity index greater than 1.0, a void fraction of 0.25 to 0.60, a ratio of geometric volume to geometric surface in the range 0.001 to 0.042 inch, a catalytic surface area greater than 100 m<SP>2</SP>/g, a catalytic pore volume of 0.35 to 0.65 cc/g which results from a major portion of pores of diameter 40 to 90 when measured with mercury up to 50000 psi abs. and a contact angle of 140, and when containing more than two lobes at least 15% of the points within the particles are greater than 0.015 inch from the particle surface and a composition cmprising a major portion by weight of alumina, 5 to 25% molybdenum oxide and 1-8% of cobalt and/or nickel oxides. In examples catalyst particles are formed by extruding alumina powder which has been moistened with aqueous ammonium molybdate and cobalt nitrate in "dumbell" or "3 leaf clover" cross sections and presulphiding. The catalyst particles can also have cross sections corresponding to a Figure of eight and tetralobal rods.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4789973A GB1415417A (en) | 1973-10-12 | 1973-10-12 | Hydrotreating of petroleum distillates using shaped catalyst prtticles |
DE19732354330 DE2354330A1 (en) | 1973-10-12 | 1973-10-30 | METHOD FOR TREATMENT OF PETROLEUM DISTILLATES WITH HYDROGEN IN THE PRESENCE OF SHAPED CATALYST PARTICLES |
FR7338687A FR2249160B1 (en) | 1973-10-12 | 1973-10-30 | |
NL7315061A NL7315061A (en) | 1973-10-12 | 1973-11-02 | PROCEDURE FOR PREPARING CATALYSTS. |
MY1978192A MY7800192A (en) | 1973-10-12 | 1978-12-31 | Hydrotreating of petroleum distillates using shaped catalyst particles |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4789973A GB1415417A (en) | 1973-10-12 | 1973-10-12 | Hydrotreating of petroleum distillates using shaped catalyst prtticles |
DE19732354330 DE2354330A1 (en) | 1973-10-12 | 1973-10-30 | METHOD FOR TREATMENT OF PETROLEUM DISTILLATES WITH HYDROGEN IN THE PRESENCE OF SHAPED CATALYST PARTICLES |
FR7338687A FR2249160B1 (en) | 1973-10-12 | 1973-10-30 | |
NL7315061A NL7315061A (en) | 1973-10-12 | 1973-11-02 | PROCEDURE FOR PREPARING CATALYSTS. |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1415417A true GB1415417A (en) | 1975-11-26 |
Family
ID=27431761
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4789973A Expired GB1415417A (en) | 1973-10-12 | 1973-10-12 | Hydrotreating of petroleum distillates using shaped catalyst prtticles |
Country Status (5)
Country | Link |
---|---|
DE (1) | DE2354330A1 (en) |
FR (1) | FR2249160B1 (en) |
GB (1) | GB1415417A (en) |
MY (1) | MY7800192A (en) |
NL (1) | NL7315061A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0013980A1 (en) * | 1979-01-27 | 1980-08-06 | BASF Aktiengesellschaft | Use of cobalt-molybdene and/or nickel-molybdeneoxide catalysts for the hydrorefining of petroleum hydrocarbons |
US6863436B2 (en) | 2001-12-19 | 2005-03-08 | Eta Sa Fabriques D'ebauches | Watch including a casing ring for a movement mounted in a case assembled via the bezel or via the back cover |
EP1800750A2 (en) * | 2005-12-22 | 2007-06-27 | Institut Français du Pétrole | Method of selective hydrogenation using a catalyst with controlled porosity |
EP1800748A2 (en) * | 2005-12-22 | 2007-06-27 | Institut Français du Pétrole | Method of selective hydrogenation using a sulphided catalyst |
EP1800749A2 (en) * | 2005-12-22 | 2007-06-27 | Institut Francais Du Petrole | Method of selective hydrogenation using a catalyst with a specific support |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3242101A (en) * | 1962-07-24 | 1966-03-22 | Sinclair Research Inc | Nickel-molybdenum-alumina hydrocarbon conversion catalyst |
US3509044A (en) * | 1967-06-26 | 1970-04-28 | Exxon Research Engineering Co | Hydrodesulfurization of petroleum residuum |
US3630888A (en) * | 1970-03-02 | 1971-12-28 | Hydrocarbon Research Inc | Hydrocracking and desulfurization with a catalyst having |
US3674680A (en) * | 1970-03-09 | 1972-07-04 | Standard Oil Co | Process and catalyst for hydroprocessing a resid hydrocarbon |
US3732155A (en) * | 1971-03-31 | 1973-05-08 | Exxon Research Engineering Co | Two-stage hydrodesulfurization process with hydrogen addition in the first stage |
-
1973
- 1973-10-12 GB GB4789973A patent/GB1415417A/en not_active Expired
- 1973-10-30 DE DE19732354330 patent/DE2354330A1/en active Granted
- 1973-10-30 FR FR7338687A patent/FR2249160B1/fr not_active Expired
- 1973-11-02 NL NL7315061A patent/NL7315061A/en not_active Application Discontinuation
-
1978
- 1978-12-31 MY MY1978192A patent/MY7800192A/en unknown
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0013980A1 (en) * | 1979-01-27 | 1980-08-06 | BASF Aktiengesellschaft | Use of cobalt-molybdene and/or nickel-molybdeneoxide catalysts for the hydrorefining of petroleum hydrocarbons |
US6863436B2 (en) | 2001-12-19 | 2005-03-08 | Eta Sa Fabriques D'ebauches | Watch including a casing ring for a movement mounted in a case assembled via the bezel or via the back cover |
EP1800750A2 (en) * | 2005-12-22 | 2007-06-27 | Institut Français du Pétrole | Method of selective hydrogenation using a catalyst with controlled porosity |
EP1800748A2 (en) * | 2005-12-22 | 2007-06-27 | Institut Français du Pétrole | Method of selective hydrogenation using a sulphided catalyst |
EP1800749A2 (en) * | 2005-12-22 | 2007-06-27 | Institut Francais Du Petrole | Method of selective hydrogenation using a catalyst with a specific support |
FR2895414A1 (en) * | 2005-12-22 | 2007-06-29 | Inst Francais Du Petrole | SELECTIVE HYDROGENATION PROCESS IMPLEMENTING A CATALYST WITH CONTROLLED POROSITY |
FR2895416A1 (en) * | 2005-12-22 | 2007-06-29 | Inst Francais Du Petrole | SELECTIVE HYDROGENATION PROCESS USING A SULPHIDE CATALYST |
FR2895415A1 (en) * | 2005-12-22 | 2007-06-29 | Inst Francais Du Petrole | SELECTIVE HYDROGENATION PROCESS IMPLEMENTING A CATALYST WITH A SPECIFIC SUPPORT |
US7645376B2 (en) | 2005-12-22 | 2010-01-12 | Institute Francais Du Petrole | Selective hydrogenation process employing a sulphurized catalyst |
US7718053B2 (en) | 2005-12-22 | 2010-05-18 | Institut Francais Du Petrole | Selective hydrogenation process employing a catalyst having a controlled porosity |
US7736492B2 (en) | 2005-12-22 | 2010-06-15 | Institut Francais Du Petrole | Selective hydrogenation process employing a catalyst with a specific support |
EP1800750A3 (en) * | 2005-12-22 | 2011-04-20 | Institut Français du Pétrole | Method of selective hydrogenation using a catalyst with controlled porosity |
EP1800748A3 (en) * | 2005-12-22 | 2011-04-20 | Institut Français du Pétrole | Method of selective hydrogenation using a sulphided catalyst |
EP1800749A3 (en) * | 2005-12-22 | 2011-04-20 | Institut Français du Pétrole | Method of selective hydrogenation using a catalyst with a specific support |
Also Published As
Publication number | Publication date |
---|---|
NL7315061A (en) | 1975-05-07 |
DE2354330C2 (en) | 1987-11-19 |
MY7800192A (en) | 1978-12-31 |
FR2249160A1 (en) | 1975-05-23 |
FR2249160B1 (en) | 1979-07-20 |
DE2354330A1 (en) | 1975-05-07 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PE20 | Patent expired after termination of 20 years |
Effective date: 19931011 |