FR2243020A1 - Catalysts for conversion of heavy oils - esp. hydro-cracking, with controlled pore size, giving increased activity and selectivity - Google Patents
Catalysts for conversion of heavy oils - esp. hydro-cracking, with controlled pore size, giving increased activity and selectivityInfo
- Publication number
- FR2243020A1 FR2243020A1 FR7332668A FR7332668A FR2243020A1 FR 2243020 A1 FR2243020 A1 FR 2243020A1 FR 7332668 A FR7332668 A FR 7332668A FR 7332668 A FR7332668 A FR 7332668A FR 2243020 A1 FR2243020 A1 FR 2243020A1
- Authority
- FR
- France
- Prior art keywords
- catalysts
- selectivity
- pore size
- controlled pore
- heavy oils
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011148 porous material Substances 0.000 title abstract 6
- 239000003054 catalyst Substances 0.000 title abstract 4
- 238000004517 catalytic hydrocracking Methods 0.000 title abstract 2
- 239000000295 fuel oil Substances 0.000 title abstract 2
- 238000006243 chemical reaction Methods 0.000 title 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
-
- B01J35/60—
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
-
- B01J35/615—
-
- B01J35/633—
-
- B01J35/635—
-
- B01J35/647—
Abstract
Catalysts with an alumina carrier and 0-30 wt % silica, and active hydrogenating components, have controlled pore size such that the volume (V) of pores with 0-300 angstroms radius is >0.30 ml/g. the vol. of pores with 0-30 angstroms radius is 25% of (V), the vol. of pores with 75-300 angstroms radius is 40% of (V), and the vol. of pores with 75-75000 angstroms radius is 0.25 ml/g. Catalysts are for hydrocracking of condensed ring cpdS. in heavy oils and removal of sulphur and nitrogen cpds. Activity, selectivity and mechanical strength of the catalysts is improved.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7332668A FR2243020A1 (en) | 1973-09-11 | 1973-09-11 | Catalysts for conversion of heavy oils - esp. hydro-cracking, with controlled pore size, giving increased activity and selectivity |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7332668A FR2243020A1 (en) | 1973-09-11 | 1973-09-11 | Catalysts for conversion of heavy oils - esp. hydro-cracking, with controlled pore size, giving increased activity and selectivity |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2243020A1 true FR2243020A1 (en) | 1975-04-04 |
| FR2243020B1 FR2243020B1 (en) | 1976-06-18 |
Family
ID=9124872
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7332668A Granted FR2243020A1 (en) | 1973-09-11 | 1973-09-11 | Catalysts for conversion of heavy oils - esp. hydro-cracking, with controlled pore size, giving increased activity and selectivity |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2243020A1 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0024199A1 (en) * | 1979-08-15 | 1981-02-25 | Exxon Research And Engineering Company | Catalyst having low volume of large pores and hydrocarbon hydroconversion process using same |
| WO1998015498A1 (en) * | 1996-10-05 | 1998-04-16 | RWE-DEA Aktiengesellschaft für Mineraloel und Chemie | Method for producing dispersible aluminium silicates |
| WO1998015497A1 (en) * | 1996-10-05 | 1998-04-16 | RWE-DEA Aktiengesellschaft für Mineraloel und Chemie | Method for producing dispersible aluminium silicates |
| US7125532B2 (en) | 1996-10-05 | 2006-10-24 | Sasol Germany Gmbh | Process for the manufacture of dispersible alumino-silicates |
-
1973
- 1973-09-11 FR FR7332668A patent/FR2243020A1/en active Granted
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0024199A1 (en) * | 1979-08-15 | 1981-02-25 | Exxon Research And Engineering Company | Catalyst having low volume of large pores and hydrocarbon hydroconversion process using same |
| WO1998015498A1 (en) * | 1996-10-05 | 1998-04-16 | RWE-DEA Aktiengesellschaft für Mineraloel und Chemie | Method for producing dispersible aluminium silicates |
| WO1998015497A1 (en) * | 1996-10-05 | 1998-04-16 | RWE-DEA Aktiengesellschaft für Mineraloel und Chemie | Method for producing dispersible aluminium silicates |
| US6245310B1 (en) | 1996-10-05 | 2001-06-12 | Rwe-Dea Aktiengesellschaft Fuer Mineraloel Und Chemie | Process for the manufacture of dispersible alumino-silicates |
| US7125532B2 (en) | 1996-10-05 | 2006-10-24 | Sasol Germany Gmbh | Process for the manufacture of dispersible alumino-silicates |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2243020B1 (en) | 1976-06-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |