GB1408813A - Hydrodesulphurization of crude oil' - Google Patents

Hydrodesulphurization of crude oil'

Info

Publication number
GB1408813A
GB1408813A GB2839273A GB2839273A GB1408813A GB 1408813 A GB1408813 A GB 1408813A GB 2839273 A GB2839273 A GB 2839273A GB 2839273 A GB2839273 A GB 2839273A GB 1408813 A GB1408813 A GB 1408813A
Authority
GB
United Kingdom
Prior art keywords
hydrodesulphurization
pore radius
pore
crude oil
pore volume
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2839273A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gulf Research and Development Co
Original Assignee
Gulf Research and Development Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gulf Research and Development Co filed Critical Gulf Research and Development Co
Publication of GB1408813A publication Critical patent/GB1408813A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

1408813 Hydrodesulphurization catalysts GULF RESEARCH & DEVELOPMENT CO 14 June 1973 [14 June 1972] 28392/73 Heading C5E A catalyst to be used for the hydrodesulphurization of less than 11,918 litres of a crude or reduced crude oil per kilogram of catalyst consists of at least one Group VI metal (i.e. Cr, Mo and/or W) and at least one Group VIII metal (i.e. Fe, Co and/or Ni) supported on alumina and has a pore volume of at least 0À4 c.c./gram, a first pore radius at which onehalf of the total pore volume is filled with liquid nitrogen in an isothermal nitrogen desorption measurement and a second pore radius at which one-half of the total pore volume is filled with liquid nitrogen in the preceding adsorption portion of the same isotherm measurement; said first pore radius being 40-58 Š and said second pore radius being at least 15 Š higher than said first pore radius. The: hydrodesulphurization can be carried out at 343-482‹ C. and a hydrogen partial pressure of 52À5- 350 kg./cm.<SP>2</SP>.
GB2839273A 1972-06-14 1973-06-14 Hydrodesulphurization of crude oil' Expired GB1408813A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US00262844A US3814684A (en) 1972-06-14 1972-06-14 Residue hydrodesulfurization process with catalysts whose pores have a small orifice size

Publications (1)

Publication Number Publication Date
GB1408813A true GB1408813A (en) 1975-10-08

Family

ID=22999305

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2839273A Expired GB1408813A (en) 1972-06-14 1973-06-14 Hydrodesulphurization of crude oil'

Country Status (9)

Country Link
US (1) US3814684A (en)
CA (1) CA974473A (en)
DD (1) DD106057A5 (en)
DE (1) DE2330324A1 (en)
FR (1) FR2187883B1 (en)
GB (1) GB1408813A (en)
IT (1) IT985463B (en)
NL (1) NL7308298A (en)
PL (1) PL88841B1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4526885A (en) * 1983-02-09 1985-07-02 Imperial Chemical Industries Plc Catalyst supports and hydrocarbon conversion processes employing catalysts based on these supports

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1020478A (en) * 1972-07-14 1977-11-08 Gulf Research And Development Company Hydrodesulfurization of petroleum distillates
US4006076A (en) * 1973-04-27 1977-02-01 Chevron Research Company Process for the production of low-sulfur-content hydrocarbon mixtures
US3977962A (en) * 1974-02-07 1976-08-31 Exxon Research And Engineering Company Heavy crude conversion
JPS51122105A (en) * 1975-04-18 1976-10-26 Toa Nenryo Kogyo Kk Process for hydrofining of hydrocarbon oil
US4051021A (en) * 1976-05-12 1977-09-27 Exxon Research & Engineering Co. Hydrodesulfurization of hydrocarbon feed utilizing a silica stabilized alumina composite catalyst
US4209424A (en) * 1977-12-12 1980-06-24 Societe Chimique de la Grande Paroisse, Azote et Products Chimiques Catalyst for manufacturing amines from alcohols
JPS5527036A (en) * 1978-08-16 1980-02-26 Shokubai Kasei Kogyo Kk Hydrogenation and desulfurization catalyst for heavy hydrocabron oil
JPS55119445A (en) * 1979-03-07 1980-09-13 Shokubai Kasei Kogyo Kk Desulfurization catalyst of petroleum base heavy hydrocarbon oil
US4326995A (en) * 1979-12-07 1982-04-27 The United States Of America As Represented By The United States Department Of Energy Catalyst for hydrotreating carbonaceous liquids
FR2490507A1 (en) * 1980-09-19 1982-03-26 Raffinage Cie Francaise HYDROCARBON HYDROTREATMENT CATALYSTS AND APPLICATION OF SAID CATALYSTS
FR2598631B1 (en) * 1986-05-14 1988-11-25 Total France HYDROCARBON HYDROTREATMENT CATALYST AND APPLICATION OF SAID CATALYST

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4526885A (en) * 1983-02-09 1985-07-02 Imperial Chemical Industries Plc Catalyst supports and hydrocarbon conversion processes employing catalysts based on these supports

Also Published As

Publication number Publication date
IT985463B (en) 1974-11-30
NL7308298A (en) 1973-12-18
DD106057A5 (en) 1974-05-20
US3814684A (en) 1974-06-04
DE2330324A1 (en) 1974-01-17
FR2187883B1 (en) 1977-05-06
PL88841B1 (en) 1976-09-30
CA974473A (en) 1975-09-16
FR2187883A1 (en) 1974-01-18

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee