GB1408813A - Hydrodesulphurization of crude oil' - Google Patents
Hydrodesulphurization of crude oil'Info
- Publication number
- GB1408813A GB1408813A GB2839273A GB2839273A GB1408813A GB 1408813 A GB1408813 A GB 1408813A GB 2839273 A GB2839273 A GB 2839273A GB 2839273 A GB2839273 A GB 2839273A GB 1408813 A GB1408813 A GB 1408813A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrodesulphurization
- pore radius
- pore
- crude oil
- pore volume
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000010779 crude oil Substances 0.000 title abstract 2
- 239000011148 porous material Substances 0.000 abstract 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 6
- 239000003054 catalyst Substances 0.000 abstract 3
- 229910052757 nitrogen Inorganic materials 0.000 abstract 3
- 239000007788 liquid Substances 0.000 abstract 2
- 238000005259 measurement Methods 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 238000003795 desorption Methods 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
1408813 Hydrodesulphurization catalysts GULF RESEARCH & DEVELOPMENT CO 14 June 1973 [14 June 1972] 28392/73 Heading C5E A catalyst to be used for the hydrodesulphurization of less than 11,918 litres of a crude or reduced crude oil per kilogram of catalyst consists of at least one Group VI metal (i.e. Cr, Mo and/or W) and at least one Group VIII metal (i.e. Fe, Co and/or Ni) supported on alumina and has a pore volume of at least 0À4 c.c./gram, a first pore radius at which onehalf of the total pore volume is filled with liquid nitrogen in an isothermal nitrogen desorption measurement and a second pore radius at which one-half of the total pore volume is filled with liquid nitrogen in the preceding adsorption portion of the same isotherm measurement; said first pore radius being 40-58 and said second pore radius being at least 15 higher than said first pore radius. The: hydrodesulphurization can be carried out at 343-482 C. and a hydrogen partial pressure of 52À5- 350 kg./cm.<SP>2</SP>.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US00262844A US3814684A (en) | 1972-06-14 | 1972-06-14 | Residue hydrodesulfurization process with catalysts whose pores have a small orifice size |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1408813A true GB1408813A (en) | 1975-10-08 |
Family
ID=22999305
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2839273A Expired GB1408813A (en) | 1972-06-14 | 1973-06-14 | Hydrodesulphurization of crude oil' |
Country Status (9)
Country | Link |
---|---|
US (1) | US3814684A (en) |
CA (1) | CA974473A (en) |
DD (1) | DD106057A5 (en) |
DE (1) | DE2330324A1 (en) |
FR (1) | FR2187883B1 (en) |
GB (1) | GB1408813A (en) |
IT (1) | IT985463B (en) |
NL (1) | NL7308298A (en) |
PL (1) | PL88841B1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4526885A (en) * | 1983-02-09 | 1985-07-02 | Imperial Chemical Industries Plc | Catalyst supports and hydrocarbon conversion processes employing catalysts based on these supports |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1020478A (en) * | 1972-07-14 | 1977-11-08 | Gulf Research And Development Company | Hydrodesulfurization of petroleum distillates |
US4006076A (en) * | 1973-04-27 | 1977-02-01 | Chevron Research Company | Process for the production of low-sulfur-content hydrocarbon mixtures |
US3977962A (en) * | 1974-02-07 | 1976-08-31 | Exxon Research And Engineering Company | Heavy crude conversion |
JPS51122105A (en) * | 1975-04-18 | 1976-10-26 | Toa Nenryo Kogyo Kk | Process for hydrofining of hydrocarbon oil |
US4051021A (en) * | 1976-05-12 | 1977-09-27 | Exxon Research & Engineering Co. | Hydrodesulfurization of hydrocarbon feed utilizing a silica stabilized alumina composite catalyst |
US4209424A (en) * | 1977-12-12 | 1980-06-24 | Societe Chimique de la Grande Paroisse, Azote et Products Chimiques | Catalyst for manufacturing amines from alcohols |
JPS5527036A (en) * | 1978-08-16 | 1980-02-26 | Shokubai Kasei Kogyo Kk | Hydrogenation and desulfurization catalyst for heavy hydrocabron oil |
JPS55119445A (en) * | 1979-03-07 | 1980-09-13 | Shokubai Kasei Kogyo Kk | Desulfurization catalyst of petroleum base heavy hydrocarbon oil |
US4326995A (en) * | 1979-12-07 | 1982-04-27 | The United States Of America As Represented By The United States Department Of Energy | Catalyst for hydrotreating carbonaceous liquids |
FR2490507A1 (en) * | 1980-09-19 | 1982-03-26 | Raffinage Cie Francaise | HYDROCARBON HYDROTREATMENT CATALYSTS AND APPLICATION OF SAID CATALYSTS |
FR2598631B1 (en) * | 1986-05-14 | 1988-11-25 | Total France | HYDROCARBON HYDROTREATMENT CATALYST AND APPLICATION OF SAID CATALYST |
-
1972
- 1972-06-14 US US00262844A patent/US3814684A/en not_active Expired - Lifetime
- 1972-12-27 CA CA159,979A patent/CA974473A/en not_active Expired
-
1973
- 1973-06-13 DD DD171520A patent/DD106057A5/xx unknown
- 1973-06-13 FR FR7321417A patent/FR2187883B1/fr not_active Expired
- 1973-06-13 IT IT50780/73A patent/IT985463B/en active
- 1973-06-14 DE DE2330324A patent/DE2330324A1/en active Pending
- 1973-06-14 GB GB2839273A patent/GB1408813A/en not_active Expired
- 1973-06-14 PL PL1973163349A patent/PL88841B1/pl unknown
- 1973-06-14 NL NL7308298A patent/NL7308298A/xx not_active Application Discontinuation
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4526885A (en) * | 1983-02-09 | 1985-07-02 | Imperial Chemical Industries Plc | Catalyst supports and hydrocarbon conversion processes employing catalysts based on these supports |
Also Published As
Publication number | Publication date |
---|---|
IT985463B (en) | 1974-11-30 |
NL7308298A (en) | 1973-12-18 |
DD106057A5 (en) | 1974-05-20 |
US3814684A (en) | 1974-06-04 |
DE2330324A1 (en) | 1974-01-17 |
FR2187883B1 (en) | 1977-05-06 |
PL88841B1 (en) | 1976-09-30 |
CA974473A (en) | 1975-09-16 |
FR2187883A1 (en) | 1974-01-18 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |