GB1523343A - Process for the upgrading of heavy hydrocarbon oils - Google Patents
Process for the upgrading of heavy hydrocarbon oilsInfo
- Publication number
- GB1523343A GB1523343A GB39291/75A GB3929175A GB1523343A GB 1523343 A GB1523343 A GB 1523343A GB 39291/75 A GB39291/75 A GB 39291/75A GB 3929175 A GB3929175 A GB 3929175A GB 1523343 A GB1523343 A GB 1523343A
- Authority
- GB
- United Kingdom
- Prior art keywords
- larger
- pore volume
- nickel nitrate
- sept
- diameter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004215 Carbon black (E152) Substances 0.000 title abstract 2
- 229930195733 hydrocarbon Natural products 0.000 title abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000003921 oil Substances 0.000 title abstract 2
- 239000011148 porous material Substances 0.000 abstract 5
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract 3
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 abstract 2
- 229940010552 ammonium molybdate Drugs 0.000 abstract 2
- 235000018660 ammonium molybdate Nutrition 0.000 abstract 2
- 239000011609 ammonium molybdate Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 238000005984 hydrogenation reaction Methods 0.000 abstract 2
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 abstract 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 abstract 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 239000010779 crude oil Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
- 239000000295 fuel oil Substances 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 229920005610 lignin Polymers 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 235000019837 monoammonium phosphate Nutrition 0.000 abstract 1
- 239000006012 monoammonium phosphate Substances 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- OGUCKKLSDGRKSH-UHFFFAOYSA-N oxalic acid oxovanadium Chemical compound [V].[O].C(C(=O)O)(=O)O OGUCKKLSDGRKSH-UHFFFAOYSA-N 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000004071 soot Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- B01J35/60—
-
- B01J35/615—
-
- B01J35/635—
-
- B01J35/638—
-
- B01J35/647—
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
Abstract
1523343 Hydrogenation of heavy oils SHELL INTERNATIONAL RESEARCH MAATSCHAPPIJ BV 25 Sept 1975 [27 Sept 1974] 39291/75 Heading C5E Heavy hydrocarbon oil having a C 5 -asphaltene content above 5% by weight and a V k210 above 30 cSt is treated, to reduce its C 5 -asphaltene content by at least 30% and its V k210 by at least 50%, by contacting at at least 400 C., a hydrogen partial pressure of at least 100 bar and a space velocity of at most 2 1.1<SP>-1</SP>.h<SP>-1</SP> with a catalyst comprising one or more metals having hydrogenation activity on a carrier and which meets the requirements (1) P/d>3À5-0À02 v (p is the specific average pore diameter in nm, d is the specific average particle diameter in mm and v is the percentage of the total pore volume that consists of pores with a diameter larger than 100 nm); (2) the total pore volume is larger than 0.40 ml./g.; (3) v is smaller than 50; (4) the specific surface area is larger than 100 m.<SP>2</SP>/g.; and (5) if p/d#10-0.15 v then (a) the nitrogen pore volume is larger than 0.60 ml./g., (b) the specific surface area is larger than 150 m.<SP>2</SP>/g., and (c)p is larger than 5 nm. The process can be used to treat crude, topped crude oil, or long or short residues at 400-500 C., and a hydrogen partial pressure of 100-300 bars in fixed or moving beds or in the fluid phase. The catalysts used in examples are prepared by granulating soot, alumina, silica, or spray-dried alumina plus 2% glass powder on a rotating disc with aqueous citric acid or lignin sulphonate and impregnating the granular carrier with (a) nickel nitrate, ammonium molybdate and monoammonium phosphate, (b) nickel nitrate and vanadyl oxalate, or (c) cobalt or nickel nitrate, ammonium molybdate and hydrogen peroxide.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL7412761A NL7412761A (en) | 1974-09-27 | 1974-09-27 | PROCEDURE TO IMPROVE THE QUALITY OF HYDROCARBON HYDROGEN OILS. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1523343A true GB1523343A (en) | 1978-08-31 |
Family
ID=19822180
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB39291/75A Expired GB1523343A (en) | 1974-09-27 | 1975-09-25 | Process for the upgrading of heavy hydrocarbon oils |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS5160206A (en) |
| CA (1) | CA1067845A (en) |
| DE (1) | DE2542878A1 (en) |
| FR (1) | FR2286186A1 (en) |
| GB (1) | GB1523343A (en) |
| MX (1) | MX3110E (en) |
| NL (1) | NL7412761A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114939596A (en) * | 2022-04-20 | 2022-08-26 | 中国石油化工股份有限公司 | Method for determining relationship between crude oil content of crude oil contaminated soil and particle size of soil aggregate and grading pretreatment method for crude oil contaminated soil |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58219293A (en) * | 1982-06-15 | 1983-12-20 | Chiyoda Chem Eng & Constr Co Ltd | Hydrocracking of heavy oil |
| JPS59112840A (en) * | 1982-12-16 | 1984-06-29 | Osaka Gas Co Ltd | Catalyst composition for preparing fuel gas |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3810830A (en) * | 1969-10-08 | 1974-05-14 | Shell Oil Co | Hydocracking and hydrodesulfurization processes utilizing a salt-containing neutralized silica-alumina support calcined at different temperature ranges |
| NL175732C (en) * | 1972-07-07 | Shell Int Research | PROCEDURE FOR THE CATALYTIC DEMETALLIZATION OF RESIDUAL HYDROCARBON OILS AND THE FURTHER CATALYTIC CONVERSION OF THE OIL OBTAINED THEREIN. |
-
1974
- 1974-09-27 NL NL7412761A patent/NL7412761A/en not_active Application Discontinuation
-
1975
- 1975-07-29 CA CA232,457A patent/CA1067845A/en not_active Expired
- 1975-09-25 JP JP50114955A patent/JPS5160206A/en active Pending
- 1975-09-25 FR FR7529383A patent/FR2286186A1/en active Granted
- 1975-09-25 MX MX100155U patent/MX3110E/en unknown
- 1975-09-25 DE DE19752542878 patent/DE2542878A1/en not_active Ceased
- 1975-09-25 GB GB39291/75A patent/GB1523343A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114939596A (en) * | 2022-04-20 | 2022-08-26 | 中国石油化工股份有限公司 | Method for determining relationship between crude oil content of crude oil contaminated soil and particle size of soil aggregate and grading pretreatment method for crude oil contaminated soil |
Also Published As
| Publication number | Publication date |
|---|---|
| NL7412761A (en) | 1976-03-30 |
| JPS5160206A (en) | 1976-05-26 |
| FR2286186B1 (en) | 1979-07-13 |
| CA1067845A (en) | 1979-12-11 |
| DE2542878A1 (en) | 1976-04-08 |
| MX3110E (en) | 1980-01-17 |
| FR2286186A1 (en) | 1976-04-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 19920925 |