MX171865B - , "UN PROCEDIMIENTO PARA EL HIDROTRATAMIENTO DE UN ACEITE DE HIDROCARBURO PESADO QUE CONTIENE ASFALTENOS a Periódica; y uno o más componentes metálicos caty IB de la Tabla Periódica, dichos componentes met75 A o más: a) un diámetro promedio de poros de en - Google Patents
, "UN PROCEDIMIENTO PARA EL HIDROTRATAMIENTO DE UN ACEITE DE HIDROCARBURO PESADO QUE CONTIENE ASFALTENOS a Periódica; y uno o más componentes metálicos caty IB de la Tabla Periódica, dichos componentes met75 A o más: a) un diámetro promedio de poros de enInfo
- Publication number
- MX171865B MX171865B MX011982A MX1198280A MX171865B MX 171865 B MX171865 B MX 171865B MX 011982 A MX011982 A MX 011982A MX 1198280 A MX1198280 A MX 1198280A MX 171865 B MX171865 B MX 171865B
- Authority
- MX
- Mexico
- Prior art keywords
- catalyst
- diameter
- hydrocarbon oil
- heavy hydrocarbon
- components
- Prior art date
Links
- 239000011148 porous material Substances 0.000 title abstract 5
- 239000004215 Carbon black (E152) Substances 0.000 title abstract 3
- 229930195733 hydrocarbon Natural products 0.000 title abstract 3
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 3
- 230000000737 periodic effect Effects 0.000 title 2
- 239000002184 metal Substances 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 6
- 229910052739 hydrogen Inorganic materials 0.000 abstract 4
- 239000001257 hydrogen Substances 0.000 abstract 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 3
- 239000007788 liquid Substances 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/882—Molybdenum and cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8872—Alkali or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Abstract
La presente invención se refiere a un procedimiento para el hidrotratamiento de un aceite de hidrocarburo pesado que contiene asfaltenos, caracterizado por los pasos de a) hacer reaccionar el aceite de hidrocarburo pesado con hidrógeno a una temperatura de entre 300 y 500 grados C, a una presión de hidrógeno entre 50 y 250 atmósferas y a una velocidad espacial de líquido de entre 0.1 y 10 horas -1, en presencia de un catalizador que comprende un portador poroso compuesto de uno o más óxidos de los elementos de los grupos II, III y IV de la Tablalíticos, seleccionándose del grupo VB, VIB, VIII álicos catalíticos en una cantidad de entre aproximadamente 0.1 y 30 por ciento en terminos de óxido metálico con base en el peso total de dicho catalizador, dicho catalizador teniendo un diámetro de tre aproximadamente 180 y 500 A, b) un volumen total de poros en terminos de cc/g que es por lo menos un valor obtenido dividiendo 0.46 entre la diferencia de 1 menos el cuadrado del cociente de 100 dividido entre el diámetro promedio de poros, el volumen de poros con un diámetro de entre 180 y 500 A siendo por lo menos 0.2 cc/g, el volumen de poros con un diámetro de por lo menos 1500 A siendo no mayor 0.03 cc/g, y c) un área de superficie total de 60 m2/g dicho catalizador teniendo un diámetro promedio de catalizador en terminos de mm, de no más de un valor obtenido como la raíz cuadrada del cociente del diámetro promedio de pros dividido entre 100; b) hacer reaccionar por lo menos una par te del producto del paso (a) con hidrógeno, a una temperatura entre 300 y 500 grados C, una presión de hidrógeno entre 50 hy 250 atmósferas y una velocidad espacial de líquido entre 0.1 y 10 horas -1, en preencia de tal catalizador.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55019596A JPS601056B2 (ja) | 1980-02-19 | 1980-02-19 | アスファルテンを含む重質炭化水素油の水素化処理 |
Publications (1)
Publication Number | Publication Date |
---|---|
MX171865B true MX171865B (es) | 1993-11-22 |
Family
ID=12003611
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX011982A MX171865B (es) | 1980-02-19 | 1980-11-27 | , "UN PROCEDIMIENTO PARA EL HIDROTRATAMIENTO DE UN ACEITE DE HIDROCARBURO PESADO QUE CONTIENE ASFALTENOS a Periódica; y uno o más componentes metálicos caty IB de la Tabla Periódica, dichos componentes met75 A o más: a) un diámetro promedio de poros de en |
MX184934A MX162469A (es) | 1980-02-19 | 1980-11-27 | Una composicion catalizadora para el hidrotratamiento de un aceite de hidrocarburo pesado que contiene asfaltenos y metodo para prepararla |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX184934A MX162469A (es) | 1980-02-19 | 1980-11-27 | Una composicion catalizadora para el hidrotratamiento de un aceite de hidrocarburo pesado que contiene asfaltenos y metodo para prepararla |
Country Status (9)
Country | Link |
---|---|
US (2) | US4422960A (es) |
JP (1) | JPS601056B2 (es) |
CA (1) | CA1153750A (es) |
DE (1) | DE3041676A1 (es) |
FR (1) | FR2475931A1 (es) |
GB (1) | GB2069363B (es) |
IT (1) | IT1134471B (es) |
MX (2) | MX171865B (es) |
NL (1) | NL189446C (es) |
Cited By (1)
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---|---|---|---|---|
CN113477261A (zh) * | 2021-07-28 | 2021-10-08 | 南京工业大学 | 一种镍基水处理催化剂及其制备方法和应用 |
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-
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- 1980-02-19 JP JP55019596A patent/JPS601056B2/ja not_active Expired
- 1980-10-07 GB GB8032271A patent/GB2069363B/en not_active Expired
- 1980-10-28 NL NLAANVRAGE8005913,A patent/NL189446C/xx not_active IP Right Cessation
- 1980-11-05 DE DE19803041676 patent/DE3041676A1/de active Granted
- 1980-11-13 CA CA000364622A patent/CA1153750A/en not_active Expired
- 1980-11-26 IT IT26251/80A patent/IT1134471B/it active
- 1980-11-27 FR FR8025215A patent/FR2475931A1/fr active Pending
- 1980-11-27 MX MX011982A patent/MX171865B/es unknown
- 1980-11-27 MX MX184934A patent/MX162469A/es unknown
- 1980-12-14 US US06/210,059 patent/US4422960A/en not_active Expired - Lifetime
-
1982
- 1982-09-30 US US06/428,796 patent/US4444655A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113477261A (zh) * | 2021-07-28 | 2021-10-08 | 南京工业大学 | 一种镍基水处理催化剂及其制备方法和应用 |
CN113477261B (zh) * | 2021-07-28 | 2022-04-29 | 南京工业大学 | 一种镍基水处理催化剂及其制备方法和应用 |
Also Published As
Publication number | Publication date |
---|---|
DE3041676C2 (es) | 1989-06-22 |
DE3041676A1 (de) | 1981-09-03 |
GB2069363B (en) | 1984-10-31 |
IT8026251A0 (it) | 1980-11-26 |
IT1134471B (it) | 1986-08-13 |
US4422960A (en) | 1983-12-27 |
GB2069363A (en) | 1981-08-26 |
NL189446C (nl) | 1993-04-16 |
US4444655A (en) | 1984-04-24 |
NL8005913A (nl) | 1981-09-16 |
JPS56115638A (en) | 1981-09-10 |
JPS601056B2 (ja) | 1985-01-11 |
FR2475931A1 (fr) | 1981-08-21 |
MX162469A (es) | 1991-05-13 |
CA1153750A (en) | 1983-09-13 |
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