NL7512700A - Hydrodesulphurisn of heavy hydrocarbons - with a cobalt-molybdenum-alumina catalyst of specified pore and particle size - Google Patents

Hydrodesulphurisn of heavy hydrocarbons - with a cobalt-molybdenum-alumina catalyst of specified pore and particle size

Info

Publication number
NL7512700A
NL7512700A NL7512700A NL7512700A NL7512700A NL 7512700 A NL7512700 A NL 7512700A NL 7512700 A NL7512700 A NL 7512700A NL 7512700 A NL7512700 A NL 7512700A NL 7512700 A NL7512700 A NL 7512700A
Authority
NL
Netherlands
Prior art keywords
hydrodesulphurisn
molybdenum
cobalt
particle size
heavy hydrocarbons
Prior art date
Application number
NL7512700A
Other languages
Dutch (nl)
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Priority to NL7512700A priority Critical patent/NL7512700A/en
Publication of NL7512700A publication Critical patent/NL7512700A/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

The hydrodeulphurisation (HDS) of hydrocarbon oils of which >70 vol. % boils above 360 degrees C and which have a C5-asphaltene content of 1.0 wt. % and a total V and Ni content of 15 ppm is carried out using a catalyst contg. 6-11 pts. wt. of Co + Mo per 100 pts. wt. of Al2O3 support and having a specific av. pore dia. (p, in nm) and a specific av. particle dia. (d, in mn) such that p/(d) 0-9 = 3-20. The product can be cracked or hydrocracked to produce gasoline or kerosene, or can be used as a blending stock for the prodn. of low-S fuel oils. The activity of the catalyst is at a max. when the particle and pore size requirements are fulfilled.
NL7512700A 1975-10-30 1975-10-30 Hydrodesulphurisn of heavy hydrocarbons - with a cobalt-molybdenum-alumina catalyst of specified pore and particle size NL7512700A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
NL7512700A NL7512700A (en) 1975-10-30 1975-10-30 Hydrodesulphurisn of heavy hydrocarbons - with a cobalt-molybdenum-alumina catalyst of specified pore and particle size

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7512700A NL7512700A (en) 1975-10-30 1975-10-30 Hydrodesulphurisn of heavy hydrocarbons - with a cobalt-molybdenum-alumina catalyst of specified pore and particle size

Publications (1)

Publication Number Publication Date
NL7512700A true NL7512700A (en) 1976-01-30

Family

ID=19824761

Family Applications (1)

Application Number Title Priority Date Filing Date
NL7512700A NL7512700A (en) 1975-10-30 1975-10-30 Hydrodesulphurisn of heavy hydrocarbons - with a cobalt-molybdenum-alumina catalyst of specified pore and particle size

Country Status (1)

Country Link
NL (1) NL7512700A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL8005913A (en) * 1980-02-19 1981-09-16 Chiyoda Chem Eng Construct Co PROCESS FOR HYDROGENIZING HEAVY HYDROCARBON OILS, WHICH CONTAIN ASPHALTENS AND CATALYSTS FOR THIS PROCESS.

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL8005913A (en) * 1980-02-19 1981-09-16 Chiyoda Chem Eng Construct Co PROCESS FOR HYDROGENIZING HEAVY HYDROCARBON OILS, WHICH CONTAIN ASPHALTENS AND CATALYSTS FOR THIS PROCESS.

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Legal Events

Date Code Title Description
BV The patent application has lapsed