GB1232393A - - Google Patents

Info

Publication number
GB1232393A
GB1232393A GB3177167A GB1232393DA GB1232393A GB 1232393 A GB1232393 A GB 1232393A GB 3177167 A GB3177167 A GB 3177167A GB 1232393D A GB1232393D A GB 1232393DA GB 1232393 A GB1232393 A GB 1232393A
Authority
GB
United Kingdom
Prior art keywords
sulphur
nickel
fraction
hydrogen
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3177167A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of GB1232393A publication Critical patent/GB1232393A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1,232,393. Catalytic hydrodesulphurization. BRITISH PETROLEUM CO. Ltd. 2 July, 1968 [11 July, 1967], No. 31771/67. Heading C5E. A process for the desulphurization of an aromatic-containing hydrocarbon fraction containing up to 50 p.p.m. by weight sulphur in which not more than 10 mole per cent hydrogenation of the aromatic hydrocarbons occurs comprises passing the fraction in the liquid phase and in the presence of hydrogen upwardly or downwardly through a bed of supported nickel catalyst at an elevated temperature and pressure such that sulphur combines with the nickel but substantially no hydrogen sulphide is produced, the amount of hydrogen present being not more than the maximum amount that would dissolve in the liquid fraction at the process temperature and pressure. The preferred catalyst for the process comprises nickel on sepiolite. High-sulphur-containing feedstocks may be subjected to a preliminary desulphurization over a conventional catalyst such as cobalt oxide and molybdenum oxide on alumina.
GB3177167A 1967-07-11 1967-07-11 Expired GB1232393A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3177167 1967-07-11

Publications (1)

Publication Number Publication Date
GB1232393A true GB1232393A (en) 1971-05-19

Family

ID=10328163

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3177167A Expired GB1232393A (en) 1967-07-11 1967-07-11

Country Status (9)

Country Link
US (1) US3714030A (en)
JP (1) JPS4927170B1 (en)
AT (1) AT286476B (en)
BE (1) BE717937A (en)
FR (1) FR1573584A (en)
GB (1) GB1232393A (en)
NL (1) NL6809780A (en)
NO (1) NO122197B (en)
SE (1) SE350981B (en)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3884797A (en) * 1971-09-27 1975-05-20 Union Oil Co Hydrofining-reforming process
US4152250A (en) * 1975-12-09 1979-05-01 Chiyoda Chemical Engineering & Construction Demetallation of hydrocarbons with catalysts supported on sepiolite
GB2031011B (en) * 1978-10-05 1983-01-06 Chiyoda Chem Eng Construct Co Processing heavy hydrocarbon oils
JPS59120640A (en) * 1982-12-27 1984-07-12 Takeda Chem Ind Ltd Sampi complex
WO1996017039A1 (en) * 1994-12-01 1996-06-06 Mobil Oil Corporation Integrated process for the production of reformate having reduced benzene content
JP3553258B2 (en) * 1995-02-14 2004-08-11 新日本石油株式会社 Method for hydrogenating aromatic hydrocarbons in hydrocarbon oil and catalyst used therefor
US6495029B1 (en) 1997-08-22 2002-12-17 Exxon Research And Engineering Company Countercurrent desulfurization process for refractory organosulfur heterocycles
CA2243267C (en) 1997-09-26 2003-12-30 Exxon Research And Engineering Company Countercurrent reactor with interstage stripping of nh3 and h2s in gas/liquid contacting zones
US6497810B1 (en) 1998-12-07 2002-12-24 Larry L. Laccino Countercurrent hydroprocessing with feedstream quench to control temperature
US6579443B1 (en) 1998-12-07 2003-06-17 Exxonmobil Research And Engineering Company Countercurrent hydroprocessing with treatment of feedstream to remove particulates and foulant precursors
US6623621B1 (en) 1998-12-07 2003-09-23 Exxonmobil Research And Engineering Company Control of flooding in a countercurrent flow reactor by use of temperature of liquid product stream
US6569314B1 (en) 1998-12-07 2003-05-27 Exxonmobil Research And Engineering Company Countercurrent hydroprocessing with trickle bed processing of vapor product stream
US6835301B1 (en) 1998-12-08 2004-12-28 Exxon Research And Engineering Company Production of low sulfur/low aromatics distillates
US7374667B2 (en) * 2001-03-12 2008-05-20 Bp Corporation North America, Inc. Process for the production of gasoline with a low sulfur content comprising a stage for transformation of sulfur-containing compounds, an acid-catalyst treatment and a desulfurization
US6884531B2 (en) * 2001-05-21 2005-04-26 Saudi Arabian Oil Company Liquid hydrocarbon based fuels for fuel cell on-board reformers
US7081555B2 (en) * 2002-08-07 2006-07-25 Shell Oil Company Process for hydrogenation of aromatics in hydrocarbon feedstocks containing thiopheneic compounds
ATE359119T1 (en) * 2002-09-23 2007-05-15 Shell Int Research CATALYST PARTICLES AND THEIR USE IN DESULFURIZATION
JP2009534411A (en) * 2006-04-21 2009-09-24 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー Method for hydrogenating aromatic compounds in hydrocarbon feedstocks containing thiophene compounds
KR101111006B1 (en) * 2008-08-14 2012-02-15 에스케이에너지 주식회사 Method and apparatus for recovering hydrogen from petroleum desulfurization
CN102639678A (en) * 2009-10-05 2012-08-15 埃克森美孚研究工程公司 Stacking of low activity or regenerated catalyst above higher activity catalyst

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE571792A (en) *
US3274275A (en) * 1963-11-26 1966-09-20 Phillips Petroleum Co Method for production of cyclohexane
US3318965A (en) * 1964-09-04 1967-05-09 Phillips Petroleum Co Hydrogenation of benzene to cyclohexane
US3254134A (en) * 1965-04-05 1966-05-31 Texaco Inc Plural stage hydrogenation of aromatics
GB1098698A (en) * 1965-10-04 1968-01-10 British Petroleum Co Improvements relating to the desulphurisation of petroleum fractions

Also Published As

Publication number Publication date
NO122197B (en) 1971-06-01
AT286476B (en) 1970-12-10
US3714030A (en) 1973-01-30
NL6809780A (en) 1969-01-14
BE717937A (en) 1969-01-13
JPS4927170B1 (en) 1974-07-16
SE350981B (en) 1972-11-13
FR1573584A (en) 1969-07-04

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee