GB1197474A - Polymeric Wax Crystal Modifiers for High Wax Content Petroleum Oils - Google Patents

Polymeric Wax Crystal Modifiers for High Wax Content Petroleum Oils

Info

Publication number
GB1197474A
GB1197474A GB40549/67A GB4054967A GB1197474A GB 1197474 A GB1197474 A GB 1197474A GB 40549/67 A GB40549/67 A GB 40549/67A GB 4054967 A GB4054967 A GB 4054967A GB 1197474 A GB1197474 A GB 1197474A
Authority
GB
United Kingdom
Prior art keywords
polymeric
wax
petroleum oils
crystal modifiers
content petroleum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB40549/67A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB1197474A publication Critical patent/GB1197474A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/192Macromolecular compounds
    • C10L1/195Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G73/00Recovery or refining of mineral waxes, e.g. montan wax
    • C10G73/02Recovery of petroleum waxes from hydrocarbon oils; Dewaxing of hydrocarbon oils
    • C10G73/04Recovery of petroleum waxes from hydrocarbon oils; Dewaxing of hydrocarbon oils with the use of filter aids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G73/00Recovery or refining of mineral waxes, e.g. montan wax
    • C10G73/02Recovery of petroleum waxes from hydrocarbon oils; Dewaxing of hydrocarbon oils
    • C10G73/06Recovery of petroleum waxes from hydrocarbon oils; Dewaxing of hydrocarbon oils with the use of solvents
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1625Hydrocarbons macromolecular compounds
    • C10L1/1633Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds
    • C10L1/1641Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds from compounds containing aliphatic monomers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1625Hydrocarbons macromolecular compounds
    • C10L1/1633Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds
    • C10L1/165Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds from compounds containing aromatic monomers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1625Hydrocarbons macromolecular compounds
    • C10L1/1633Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds
    • C10L1/1666Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds from compounds containing non-conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/192Macromolecular compounds
    • C10L1/195Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/196Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof
    • C10L1/1963Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof mono-carboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/192Macromolecular compounds
    • C10L1/195Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/196Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof
    • C10L1/1966Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof poly-carboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/192Macromolecular compounds
    • C10L1/195Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/197Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid
    • C10L1/1973Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid mono-carboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/234Macromolecular compounds
    • C10L1/236Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof
    • C10L1/2364Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof homo- or copolymers derived from unsaturated compounds containing amide and/or imide groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Lubricants (AREA)

Abstract

1,197,474. Polymeric oil additives. ESSO RESEARCH & ENG. CO. 5 Sept., 1967 [14 Oct., 1966], No. 40549/67. Heading C3P. [Also in Division C5] The examples describe the preparation of the following oil additive polymer and copolymer (1) behenyl fumarate/vinyl acetate copolymer using t-butyl perbenzoate as catalyst and nheptane as solvent and (2) poly-n-C 24 methacrylate using azobisisobutyronitrile as catalyst and n-heptane as solvent.
GB40549/67A 1966-10-14 1967-09-05 Polymeric Wax Crystal Modifiers for High Wax Content Petroleum Oils Expired GB1197474A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US58665466A 1966-10-14 1966-10-14

Publications (1)

Publication Number Publication Date
GB1197474A true GB1197474A (en) 1970-07-08

Family

ID=24346613

Family Applications (1)

Application Number Title Priority Date Filing Date
GB40549/67A Expired GB1197474A (en) 1966-10-14 1967-09-05 Polymeric Wax Crystal Modifiers for High Wax Content Petroleum Oils

Country Status (7)

Country Link
US (1) US3729296A (en)
BE (1) BE745920Q (en)
CA (2) CA977549A (en)
DE (2) DE1645738A1 (en)
FR (1) FR1553794A (en)
GB (1) GB1197474A (en)
NL (1) NL154550B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3765849A (en) * 1971-07-07 1973-10-16 Exxon Research Engineering Co Flow improvers for hydrocarbon oils and method of preparing same
US7067599B2 (en) 1998-12-02 2006-06-27 Infineum International Ltd. Fuel oil additives and compositions

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3926579A (en) * 1968-09-16 1975-12-16 Exxon Research Engineering Co Petroleum crude oils containing polymers comprised of c' 18'+14 c' 40 'alpha-olefins have reduced tendency to deposit wax
US3854893A (en) * 1972-06-14 1974-12-17 Exxon Research Engineering Co Long side chain polymeric flow improvers for waxy hydrocarbon oils
US4514314A (en) * 1981-06-02 1985-04-30 Exxon Research And Engineering Co. Oil soluble ester pour point depressant additive for lubricants
US4460453A (en) * 1982-09-29 1984-07-17 Exxon Research And Engineering Co. Solvent dewaxing waxy bright stock using a combination polydialkyl fumarate-vinyl acetate copolymer and polyalkyl (meth-) acrylate polymer dewaxing aid
US4439308A (en) * 1982-09-29 1984-03-27 Exxon Research And Engineering Co. Solvent dewaxing waxy bright stock using a combination polydialkylfumarate-vinyl acetate copolymer and wax-naphthalene condensate dewaxing aid
JPH08912B2 (en) 1982-09-29 1996-01-10 エクソン・リサーチ・アンド・エンジニアリング・カンパニー Solvent dewaxing of row bright stock containing blends using polydialkyl fumarate-vinyl acetate copolymer and wax-naphthalene condensate dewaxing aids
US4461698A (en) * 1982-09-29 1984-07-24 Exxon Research And Engineering Co. Solvent dewaxing waxy hydrocarbon distillate oils using a combination wax-naphthalene condensate and poly-dialkylfumarate/vinyl acetate copolymer dewaxing aid
US4406771A (en) * 1982-09-29 1983-09-27 Exxon Research And Engineering Co. Solvent dewaxing waxy hydrocarbon oil distillates using a combination poly di-alkyl fumarate-vinyl acetate copolymer having pendent carbon side chain length of predominantly C22 and polyalkyl(meth-)acrylate polymer dewaxing aid
US4451353A (en) * 1982-09-29 1984-05-29 Exxon Research And Engineering Co. Solvent dewaxing waxy hydrocarbon distillates using a combination poly acrylate polymer and polymethacrylate polymer dewaxing aid
US4670130A (en) * 1984-03-14 1987-06-02 Exxon Research & Engineering Co. The use of dialkyl fumarate-vinyl acetate copolymers as dewaxing aids
US4956492A (en) * 1984-03-14 1990-09-11 Exxon Research And Engineering Co. Dialkyl fumarate - vinyl acetate copolymers useful as dewaxing aids
US4594142A (en) * 1985-04-25 1986-06-10 Exxon Research And Engineering Co. Dewaxing waxy hydrocarbon oils using di-alkyl fumarate-vinyl laurate copolymer dewaxing aids
US4564438A (en) * 1985-05-31 1986-01-14 Nalco Chemical Company Styrene-dialkyl maleate copolymers as dewaxing agents
GB8521393D0 (en) * 1985-08-28 1985-10-02 Exxon Chemical Patents Inc Middle distillate compositions
GB8521392D0 (en) * 1985-08-28 1985-10-02 Exxon Chemical Patents Inc Middle distillate composition
US4728414A (en) * 1986-11-21 1988-03-01 Exxon Research And Engineering Company Solvent dewaxing using combination poly (n-C24) alkylmethacrylate-poly (C8 -C20 alkyl (meth-) acrylate dewaxing aid
DE3818438A1 (en) * 1988-05-31 1989-12-07 Roehm Gmbh MINERAL OIL WITH IMPROVED FLOW BEHAVIOR
US6616716B2 (en) * 1997-12-15 2003-09-09 Maersk Olie & Gas A/S Method of improving the flow properties of a crude oil or natural gas liquid
US6136760A (en) * 1999-09-21 2000-10-24 Exxon Research And Engineering Company Reducing low temperature scanning brookfield gel index value in engine oils (LAW798)
US7417009B2 (en) * 2004-03-26 2008-08-26 Nalco Company Paraffin inhibitors
US8143202B2 (en) * 2006-11-07 2012-03-27 Ciba Corp. Methacrylate copolymer pour point depressants
DE102011003855A1 (en) * 2011-02-09 2012-08-09 Evonik Rohmax Additives Gmbh Process for dewaxing mineral oil compositions

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2600448A (en) * 1949-07-15 1952-06-17 Rohm & Haas Copolymers from allyl esters and acrylic esters
US2600446A (en) * 1949-07-15 1952-06-17 Rohm & Haas Copolymers of methacrylates and allyl esters
US2600383A (en) * 1949-07-15 1952-06-17 Rohm & Haas Copolymers from allyl esters and methacrylic esters
US2628198A (en) * 1951-03-31 1953-02-10 Standard Oil Dev Co Alkyl maleate-vinyl acetate copolymers
US2721877A (en) * 1951-08-22 1955-10-25 Exxon Research Engineering Co Lubricating oil additives and a process for their preparation
US2825717A (en) * 1954-05-06 1958-03-04 Exxon Research Engineering Co Dialkyl fumarate-vinyl acetate copolymers
US2993032A (en) * 1956-02-03 1961-07-18 California Research Corp Detergent copolymers
US3046226A (en) * 1958-02-19 1962-07-24 Minnesota Mining & Mfg Lubricating oil compositions
US3087893A (en) * 1958-08-11 1963-04-30 Exxon Research Engineering Co Copolymers of maleic anhydride and unsaturated esters as additives in oils
US3001942A (en) * 1958-12-15 1961-09-26 California Research Corp Lubricant composition
BE637124A (en) * 1962-09-07
BE657317A (en) * 1964-12-18 1965-06-18

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3765849A (en) * 1971-07-07 1973-10-16 Exxon Research Engineering Co Flow improvers for hydrocarbon oils and method of preparing same
US7067599B2 (en) 1998-12-02 2006-06-27 Infineum International Ltd. Fuel oil additives and compositions

Also Published As

Publication number Publication date
DE1794416A1 (en) 1976-08-12
NL154550B (en) 1977-09-15
CA980568A (en) 1975-12-30
BE745920Q (en) 1970-07-16
DE1794416B2 (en) 1981-05-14
DE1645738A1 (en) 1970-12-23
US3729296A (en) 1973-04-24
NL6713932A (en) 1968-04-16
CA977549A (en) 1975-11-11
FR1553794A (en) 1969-01-17

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee