MX2009002359A - Catalizador soportado en carbon para la desmetalizacion de crudos pesados y residuos. - Google Patents

Catalizador soportado en carbon para la desmetalizacion de crudos pesados y residuos.

Info

Publication number
MX2009002359A
MX2009002359A MX2009002359A MX2009002359A MX2009002359A MX 2009002359 A MX2009002359 A MX 2009002359A MX 2009002359 A MX2009002359 A MX 2009002359A MX 2009002359 A MX2009002359 A MX 2009002359A MX 2009002359 A MX2009002359 A MX 2009002359A
Authority
MX
Mexico
Prior art keywords
residue
crude oil
heavy crude
catalyst
demetallation
Prior art date
Application number
MX2009002359A
Other languages
English (en)
Inventor
Satoshi Terai
Jorge Ancheyta Juarez
Dres Samir Kumar Maity
M En C Fernando Alonso Martinez
Dres Hidetsugu Fukuyama
Masayuki Uchida
Original Assignee
Mexicano Inst Petrol
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mexicano Inst Petrol filed Critical Mexicano Inst Petrol
Priority to MX2009002359A priority Critical patent/MX2009002359A/es
Priority to US12/716,776 priority patent/US8431018B2/en
Publication of MX2009002359A publication Critical patent/MX2009002359A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)

Abstract

En la presente invención se empleó un soporte de carbón que contiene alta área superficial específica alta, volumen de poro grande y (i) un metal de transición del Grupo VIB, (ii) un metal no noble del Grupo VIII, (iii) fósforo, para la hidrodesmetalización e hidrodesulfuración de crudos pesados y residuos. Asimismo, el catalizador es preparado mediante el uso de un agente quelante y posee una actividad hacia la hidrodesulfuración más alta, asumiendo que están presentes metales activos más dispersados sobre este catalizador. Los estudios de la actividad en una corrida de larga duración mostraron que el catalizador que posee solamente molibdeno soportado en carbón activado posee buena estabilidad conforme avanza el tiempo de corrida y una capacidad de retención de metales alta.
MX2009002359A 2009-03-03 2009-03-03 Catalizador soportado en carbon para la desmetalizacion de crudos pesados y residuos. MX2009002359A (es)

Priority Applications (2)

Application Number Priority Date Filing Date Title
MX2009002359A MX2009002359A (es) 2009-03-03 2009-03-03 Catalizador soportado en carbon para la desmetalizacion de crudos pesados y residuos.
US12/716,776 US8431018B2 (en) 2009-03-03 2010-03-03 Carbon supported catalyst for demetallation of heavy crude oil and residue

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
MX2009002359A MX2009002359A (es) 2009-03-03 2009-03-03 Catalizador soportado en carbon para la desmetalizacion de crudos pesados y residuos.

Publications (1)

Publication Number Publication Date
MX2009002359A true MX2009002359A (es) 2010-10-01

Family

ID=42677275

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2009002359A MX2009002359A (es) 2009-03-03 2009-03-03 Catalizador soportado en carbon para la desmetalizacion de crudos pesados y residuos.

Country Status (2)

Country Link
US (1) US8431018B2 (es)
MX (1) MX2009002359A (es)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102091651A (zh) * 2010-12-10 2011-06-15 中国石油天然气股份有限公司 一种选择性加氢脱硫催化剂的制备方法
CN102091652B (zh) * 2010-12-10 2013-04-24 中国石油天然气股份有限公司 一种选择性加氢脱硫催化剂和应用
BR112013033111B1 (pt) * 2011-06-22 2020-02-11 Shell Internationale Research Maatschappij B.V. Método para preparar uma composição de catalisador útil no hidroprocessamento de matérias-primas de hidrocarboneto
CN102861589A (zh) * 2011-07-07 2013-01-09 中国石油化工股份有限公司 一种高活性加氢脱金属催化剂及其制备方法
CN102861590A (zh) * 2011-07-07 2013-01-09 中国石油化工股份有限公司 一种加氢脱金属催化剂及其制备方法
RU2495717C1 (ru) * 2012-09-24 2013-10-20 Федеральное государственное бюджетное учреждение науки Институт проблем переработки углеводородов Сибирского отделения Российской академии наук (ИППУ СО РАН) Способ получения нанесенного катализатора гидропереработки тяжелых нефтяных фракций
BR112015027028A2 (pt) * 2013-04-24 2017-07-25 Shell Int Research ativação de um catalisador de hidroprocessamento com vapor
CN105273746B (zh) * 2014-07-18 2017-05-24 中国石油化工股份有限公司 一种加氢脱氧方法
CN106268848A (zh) * 2016-07-22 2017-01-04 西安向阳航天材料股份有限公司 一种焦炉煤气加氢脱硫催化剂及其制备方法
CN107961795B (zh) * 2016-10-20 2020-12-04 中国石油化工股份有限公司 一种加氢脱硫催化剂及其制备方法和硫化态加氢脱硫催化剂的制备方法
CN107961773B (zh) * 2016-10-20 2020-12-04 中国石油化工股份有限公司 一种加氢脱硫催化剂及其制备方法和硫化态加氢脱硫催化剂的制备方法
US9861972B1 (en) 2017-04-04 2018-01-09 Kuwait Institute For Scientific Research Hydrodemetallization catalysts
CN111195525A (zh) * 2018-11-19 2020-05-26 中国石油天然气股份有限公司 一种渣油加氢脱硫催化剂及其制备方法
CN111375436B (zh) * 2018-12-29 2022-06-07 中国石油化工股份有限公司 重油加氢处理催化剂及其制法
CN111375422B (zh) * 2018-12-29 2022-10-11 中国石油化工股份有限公司 一种用于催化氧化甲醛的催化剂及其制备方法
CN111375406B (zh) * 2018-12-29 2022-06-07 中国石油化工股份有限公司 一种臭氧催化氧化催化剂及其制备方法
CN111375430B (zh) * 2018-12-29 2022-04-08 中国石油化工股份有限公司 一种硫化型加氢催化剂及其制备方法
CN111375415B (zh) * 2018-12-29 2022-10-11 中国石油化工股份有限公司 一种低碳烷烃脱氢制烯烃催化剂及其制备方法
US11325107B2 (en) * 2019-02-13 2022-05-10 King Fahd University Of Petroleum And Minerals Method for producing activated carbon supported Ni/Mo catalyst for hydrodesulfurization
CN116060033B (zh) * 2021-10-29 2024-05-10 中国石油化工股份有限公司 一种石蜡加氢精制催化剂及其制备方法和应用
CN114029046B (zh) * 2021-12-20 2022-08-19 黑龙江大学 一种以生物质制备的片层碳为载体的复合加氢脱硫催化剂的制备方法

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3770617A (en) 1970-12-28 1973-11-06 Exxon Research Engineering Co Hydrodesulfurization with a specified pore size distribution in silica-stabilized alumina
US3864416A (en) 1974-03-18 1975-02-04 Universal Oil Prod Co Separation of tetra-alkyl substituted aromatic hydrocarbon isomers
US4082695A (en) 1975-01-20 1978-04-04 Mobil Oil Corporation Catalyst for residua demetalation and desulfurization
US4016106A (en) 1976-01-05 1977-04-05 Exxon Research And Engineering Company Preparation of catalysts of predetermined pore size distribution and pore volume
JPS601056B2 (ja) 1980-02-19 1985-01-11 千代田化工建設株式会社 アスファルテンを含む重質炭化水素油の水素化処理
US4456701A (en) 1980-06-09 1984-06-26 Chevron Research Company Hydroprocessing catalyst having bimodal pore distribution and process for preparing the catalyst
US4332782A (en) 1980-07-28 1982-06-01 Filtrol Corporation Method of producing pseudoboehmite
US4328127A (en) 1980-09-16 1982-05-04 Mobil Oil Corporation Residua demetalation/desulfurization catalyst
NL8200087A (nl) 1981-01-19 1982-08-16 Mitsubishi Chem Ind Werkwijze voor het bereiden van een poreus vuurvast anorganisch oxyde.
US4520128A (en) 1983-12-19 1985-05-28 Intevep, S.A. Catalyst having high metal retention capacity and good stability for use in the demetallization of heavy crudes and method of preparation of same
US4572778A (en) 1984-01-19 1986-02-25 Union Oil Company Of California Hydroprocessing with a large pore catalyst
US4613427A (en) 1984-10-03 1986-09-23 Intevep, S.A. Process for the demetallization and hydroconversion of heavy crudes and residues using a natural clay catalyst
US4870044A (en) 1987-03-12 1989-09-26 Phillips Petroleum Company Treated alumina material for fixed hydrofining beds
US5037791A (en) * 1988-07-28 1991-08-06 Hri, Inc. Porous metal oxide supported carbon-coated catalysts and method for producing same
US5210061A (en) 1991-09-24 1993-05-11 Union Oil Company Of California Resid hydroprocessing catalyst
CA2131796C (en) 1992-03-12 2004-01-27 Lewis Bernard Decker Jr. Preparation of alumina having increased porosity
US5435907A (en) * 1992-04-20 1995-07-25 Texaco Inc. Hydrodearomatization of middle distillate hydrocarbons
US6162351A (en) 1993-02-25 2000-12-19 Texaco Inc. Hydrodenitrogenation of hydrocarbons utilizing a carbon-supported catalyst
US5928499A (en) * 1993-10-01 1999-07-27 Texaco Inc Hydroconversion process employing catalyst with specified pore size distribution, median pore diameter by surface area, and pore mode by volume
US5466363A (en) * 1994-02-10 1995-11-14 Mobil Oil Corporation Integrated process for hydrotreating heavy oil, then manufacturing an alloy or steel using a carbon-based catalyst
US6015485A (en) * 1994-05-13 2000-01-18 Cytec Technology Corporation High activity catalysts having a bimodal mesopore structure
US5472595A (en) 1994-08-09 1995-12-05 Texaco Inc. Process for hydrodearomatization of hydrocarbon oils using carbon supported metal sulfide catalysts promoted by phosphate
US6218333B1 (en) * 1999-02-15 2001-04-17 Shell Oil Company Preparation of a hydrotreating catalyst
JP2004515355A (ja) * 2000-12-11 2004-05-27 ユナイテッド・ステイツ・フィルター・コーポレイション 臭気抑制用活性炭およびその製法

Also Published As

Publication number Publication date
US8431018B2 (en) 2013-04-30
US20100224535A1 (en) 2010-09-09

Similar Documents

Publication Publication Date Title
MX2009002359A (es) Catalizador soportado en carbon para la desmetalizacion de crudos pesados y residuos.
TW200738865A (en) Selective catalysts having silica supports for naphtha hydrodesulfurization
WO2013033293A3 (en) Hydroprocessing of heavy hydrocarbon feeds using small pore catalysts
WO2007084438A3 (en) Selective catalysts for naphtha hydrodesulfurization
WO2010111168A3 (en) A high surface area composition for use in the catalytic hydroconversion of a heavy hydrocarbon feedstock, a method making such composition and its use
GB2449612A (en) Regeneration of ionic liquid catalyst using a metal in the absence of added hydrogen
CU20100097A7 (es) Proceso de hidroconversión para crudos pesados y extra pesados y productos residuales
MY159668A (en) Catalyst including metal phosphide for preparation of hydrotreated biodiesel and method of preparing hydrotreated biodiesel using the same
JP2010149114A5 (es)
EA201270809A1 (ru) Катализаторы и системы, содержащие оксид графена и оксид графита
WO2010088006A3 (en) Catalyst with bimodal pore size distribution and the use thereof
AR069516A1 (es) Eliminacion del mercurio de fluidos por oxidos metalicos soportados
CA2558194A1 (en) Hydrogenation of acetone
IN2012DN00580A (es)
CA2891797C (en) Catalyst compositions comprising a metal oxide/matrix and use thereof in catalytic biomass pyrolysis
MY146921A (en) Hydrogenation process using catalyst comprising ordered intermetallic compound
WO2012106349A3 (en) High activity early transition metal carbide- and nitride-based catalysts
WO2012084800A3 (en) Titania-supported hydrotreating catalysts
WO2011071803A3 (en) Hydroprocessing of high nitrogen feed using bulk catalyst
EA201391410A1 (ru) Катализатор гидроочистки и способ изготовления углеводородного масла
CA2900730C (fr) Procede pour le demarrage d'unites d'hydrotraitement ou d'hydroconversion
MX2016002868A (es) Catalizador de hidrogenacion selectiva y metodos para hacer y usar el mismo.
MX2014015227A (es) Procesamiento de lavado in-situ para recuperar actividad de un catalizador de hidrodesulfuracion desactivado.
SA517390005B1 (ar) حفاز لهدرجة هيدروكربونات أروماتية، وطريقة معالجة بالهدرجة واستخداماتها فيها
Villarroel et al. Synergism in alumina-supported noble metals and molybdenum stacked-bed catalysts via spillover hydrogen in gas–oil hydrodesulphurization

Legal Events

Date Code Title Description
FG Grant or registration