DE2760481C2 - - Google Patents

Info

Publication number
DE2760481C2
DE2760481C2 DE2760481A DE2760481A DE2760481C2 DE 2760481 C2 DE2760481 C2 DE 2760481C2 DE 2760481 A DE2760481 A DE 2760481A DE 2760481 A DE2760481 A DE 2760481A DE 2760481 C2 DE2760481 C2 DE 2760481C2
Authority
DE
Germany
Prior art keywords
zeolite
catalyst
catalyst according
xylene
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE2760481A
Other languages
German (de)
English (en)
Inventor
Chin-Chiun Chu
Werner Otto Haag
David Harold Olson
Paul Gerhard Rodewald
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/672,194 external-priority patent/US4060568A/en
Priority claimed from US05/680,998 external-priority patent/US4011276A/en
Priority claimed from US05/726,091 external-priority patent/US4090981A/en
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Application granted granted Critical
Publication of DE2760481C2 publication Critical patent/DE2760481C2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66Catalytic processes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41Catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/12After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/26After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/32Reaction with silicon compounds, e.g. TEOS, siliconfluoride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/34Reaction with organic or organometallic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/36Steaming
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/42Addition of matrix or binder particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE2760481A 1976-03-31 1977-03-30 Expired - Lifetime DE2760481C2 (US07534539-20090519-C00280.png)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US05/672,194 US4060568A (en) 1976-03-31 1976-03-31 Silica-modified zeolite catalyst and conversion therewith
US05/680,998 US4011276A (en) 1976-04-28 1976-04-28 Disproportionation of toluene
US68586976A 1976-05-12 1976-05-12
US68587276A 1976-05-12 1976-05-12
US05/726,091 US4090981A (en) 1976-09-23 1976-09-23 Catalyst for selective production of para dialkyl substituted benzenes

Publications (1)

Publication Number Publication Date
DE2760481C2 true DE2760481C2 (US07534539-20090519-C00280.png) 1993-07-15

Family

ID=27542059

Family Applications (3)

Application Number Title Priority Date Filing Date
DE19772714239 Granted DE2714239A1 (de) 1976-03-31 1977-03-30 Verfahren zur selektiven herstellung von p-dialkylbenzolen und katalysator zu dessen durchfuehrung
DE2760481A Expired - Lifetime DE2760481C2 (US07534539-20090519-C00280.png) 1976-03-31 1977-03-30
DE2760479A Expired - Lifetime DE2760479C2 (US07534539-20090519-C00280.png) 1976-03-31 1977-03-30

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE19772714239 Granted DE2714239A1 (de) 1976-03-31 1977-03-30 Verfahren zur selektiven herstellung von p-dialkylbenzolen und katalysator zu dessen durchfuehrung

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE2760479A Expired - Lifetime DE2760479C2 (US07534539-20090519-C00280.png) 1976-03-31 1977-03-30

Country Status (12)

Country Link
JP (3) JPS52120292A (US07534539-20090519-C00280.png)
BE (1) BE852865A (US07534539-20090519-C00280.png)
CS (1) CS218565B2 (US07534539-20090519-C00280.png)
DE (3) DE2714239A1 (US07534539-20090519-C00280.png)
FR (1) FR2357303A1 (US07534539-20090519-C00280.png)
GB (1) GB1574523A (US07534539-20090519-C00280.png)
IT (1) IT1075368B (US07534539-20090519-C00280.png)
NL (1) NL187424C (US07534539-20090519-C00280.png)
NO (1) NO149492C (US07534539-20090519-C00280.png)
NZ (1) NZ183608A (US07534539-20090519-C00280.png)
PL (1) PL115528B1 (US07534539-20090519-C00280.png)
SE (1) SE438606B (US07534539-20090519-C00280.png)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ183608A (en) * 1976-03-31 1978-12-18 Mobil Oil Corp Aluminosilicate zeolite catalyst for selectine production of para-diakyl substituted benzenes
PL199748A1 (pl) * 1976-07-19 1978-04-24 Mobil Oil Corp Sposob selektywnego wytwarzania p-dwualkilobenzenow
US4104319A (en) * 1977-06-23 1978-08-01 Mobil Oil Corporation Ethylation of mono alkyl benzene
US4117024A (en) * 1977-07-29 1978-09-26 Mobil Oil Corporation Ethylation of aromatic compounds
FR2417540A1 (fr) * 1978-02-20 1979-09-14 Shell France Procede de craquage catalytique d'hydrocarbures et catalyseur pour la mise en oeuvre du procede
FR2442881A2 (fr) * 1978-11-29 1980-06-27 Shell France Procede de craquage catalytique d'hydrocarbures, et catalyseur pour la mise en oeuvre du procede
AU538578B2 (en) * 1979-01-31 1984-08-23 Mobil Oil Corp. Zeolite catalyst containing gp za or gp8 metal and its use to convert hydrocarbons
US4274982A (en) * 1979-10-12 1981-06-23 Mobil Oil Corporation Method for maintaining para-selectivity of modified zeolite catalyst
US4288647A (en) * 1980-03-10 1981-09-08 Mobil Oil Corporation Shape selective reactions with alkaline earth-modified zeolite catalysts
US4357264A (en) 1980-03-10 1982-11-02 Mobil Oil Corporation Alkaline earth metal modified zeolite catalysts
US4278827A (en) * 1980-04-07 1981-07-14 Mobil Oil Corporation Shape selective reactions with zeolite catalyst modified with group IVB metal
EP0040463B1 (en) * 1980-05-19 1984-09-05 Mobil Oil Corporation Shape selective reactions with zeolite catalyst modified with iron and/or cobalt
JPS57108023A (en) * 1980-12-26 1982-07-05 Toa Nenryo Kogyo Kk Oligomerization catalyst for isobutene
US4431527A (en) * 1981-11-13 1984-02-14 Standard Oil Company (Indiana) Process for hydrogen treating high nitrogen content hydrocarbon feeds
JPS5931718A (ja) * 1982-08-17 1984-02-20 Toray Ind Inc パラジアルキルベンゼンの選択的製造法
JPS59107921A (ja) * 1982-12-10 1984-06-22 Idemitsu Kosan Co Ltd p―キシレンの製造方法
ZA845190B (en) * 1983-08-19 1986-02-26 Mobil Oil Corp A process for preparing a coked zeolite catalyst and a process for the selective disproportionation of toluene using said catalyst
EP0134076B1 (en) * 1983-08-19 1988-10-26 Mobil Oil Corporation A process for preparing a coked zeolite catalyst and a process for the selective disproportionation of toluene using said catalyst
US4613717A (en) * 1984-06-25 1986-09-23 Research Association For Utilization Of Light Oil Process for producing a 1,4-dialkylbenzene
JPS61221137A (ja) * 1985-03-28 1986-10-01 Teijin Yuka Kk P−キシレンの製造法
JPS6263528A (ja) * 1985-09-17 1987-03-20 Teijin Yuka Kk P−キシレンの製造法
JPS62115088A (ja) * 1985-11-13 1987-05-26 Res Assoc Util Of Light Oil 芳香族炭化水素の製造方法
US4902841A (en) * 1987-03-11 1990-02-20 Nippon Petrochemicals Company, Ltd. Method for producing electrical insulating oil composition
US4849386A (en) * 1987-04-08 1989-07-18 Taiwan Styrene Monomer Corporation Novel silicon-modified catalyst Si/HZSM-5 preparation
US4851604A (en) * 1987-09-02 1989-07-25 Mobil Oil Corp. Toluene disproportionation
JPH0788319B2 (ja) * 1987-09-09 1995-09-27 日本石油化学株式会社 m−ベンジルトルエンの製造方法
JPH0810566B2 (ja) * 1988-03-09 1996-01-31 日本石油化学株式会社 改良された留分からなる電気絶縁油
EP0424539B1 (en) * 1989-03-22 1996-07-31 Matsushita Refrigeration Company Expanded heat-insulating material
WO1991008998A1 (en) * 1989-12-13 1991-06-27 Mobil Oil Corporation A process for the catalytic conversion of a c9+ aromatics feed
US5448005A (en) * 1994-04-04 1995-09-05 Mobil Oil Corporation Crystallization of paraxlene from high purity paraxylene feeds
JP3427507B2 (ja) * 1994-09-12 2003-07-22 東レ株式会社 パラジアルキルベンゼンの製造用触媒及びその製造法及びパラキシレンを製造する方法
DE19538799A1 (de) * 1995-10-18 1997-04-24 Sued Chemie Ag Wabenförmiger Katalysatorträger
US6316683B1 (en) * 1999-06-07 2001-11-13 Exxonmobil Chemical Patents Inc. Protecting catalytic activity of a SAPO molecular sieve
US6709570B1 (en) * 1999-09-27 2004-03-23 Shell Oil Company Method for preparing a catalyst
US7049260B2 (en) 2003-06-03 2006-05-23 Chevron Phillips Chemical Company Lp Selective para-xylene production via methylation of toluene with methanol in the presence of modified HZSM-5 catalyst
JP4843501B2 (ja) * 2003-12-31 2011-12-21 エクソンモービル・ケミカル・パテンツ・インク 芳香族のアルキル化プロセス
JP5294928B2 (ja) * 2009-03-06 2013-09-18 三井化学株式会社 芳香族炭化水素の製造方法およびその製造方法に使用される触媒

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3682996A (en) * 1970-02-24 1972-08-08 Mobil Oil Corp Zeolite esters
US3698157A (en) * 1971-06-01 1972-10-17 Mobil Oil Corp Separation of mixtures with modified zeolites

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2722504A (en) * 1950-12-04 1955-11-01 Union Oil Co Silicone coated catalyst and use thereof
US3417157A (en) * 1967-12-28 1968-12-17 Universal Oil Prod Co Transalkylation of toluene and catalyst therefor
US3525775A (en) * 1968-03-29 1970-08-25 Union Carbide Corp Catalytic xylene isomerization process and catalyst therefor
US3651162A (en) * 1969-02-27 1972-03-21 Standard Oil Co Isomerization and disproportionation of alkyl aromatics
US3658696A (en) * 1969-06-17 1972-04-25 Texaco Inc Selected adsorption with a silanized crystalline alumino-silicate
US3790471A (en) * 1969-10-10 1974-02-05 Mobil Oil Corp Conversion with zsm-5 family of crystalline aluminosilicate zeolites
US3702886A (en) * 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3832449A (en) * 1971-03-18 1974-08-27 Mobil Oil Corp Crystalline zeolite zsm{14 12
GB1403329A (en) * 1972-04-28 1975-08-28 Mobil Oil Corp Vapour-phase alkylation in presence of crystalline alumino silicate catalyst
US3751504A (en) * 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation
US3808284A (en) * 1972-09-11 1974-04-30 Texaco Inc Process for disproportionating hydrocarbons
US3894104A (en) * 1973-08-09 1975-07-08 Mobil Oil Corp Aromatization of hetero-atom substituted hydrocarbons
US3890218A (en) * 1974-03-29 1975-06-17 Mobil Oil Corp Upgrading aliphatic naphthas to higher octane gasoline
CA1062285A (en) * 1974-04-24 1979-09-11 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbon mixtures
US3980586A (en) * 1974-08-28 1976-09-14 Mobil Oil Corporation Modified solid catalyst materials
NZ178543A (en) * 1974-09-23 1978-04-03 Mobil Oil Corp Conversion catalyst, crystalline alumin osilicate zeolite containing phosphorus
US4016218A (en) * 1975-05-29 1977-04-05 Mobil Oil Corporation Alkylation in presence of thermally modified crystalline aluminosilicate catalyst
NZ183608A (en) * 1976-03-31 1978-12-18 Mobil Oil Corp Aluminosilicate zeolite catalyst for selectine production of para-diakyl substituted benzenes
US4086262A (en) * 1976-09-20 1978-04-25 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbon mixtures

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3682996A (en) * 1970-02-24 1972-08-08 Mobil Oil Corp Zeolite esters
US3698157A (en) * 1971-06-01 1972-10-17 Mobil Oil Corp Separation of mixtures with modified zeolites

Also Published As

Publication number Publication date
SE438606B (sv) 1985-04-29
NO149492B (no) 1984-01-23
DE2714239A1 (de) 1977-10-20
SE7703593L (sv) 1977-10-01
NL187424B (nl) 1991-05-01
DE2714239C2 (US07534539-20090519-C00280.png) 1993-07-22
NL7703484A (nl) 1977-10-04
JPS52120292A (en) 1977-10-08
DE2760479C2 (US07534539-20090519-C00280.png) 1993-08-12
FR2357303B1 (US07534539-20090519-C00280.png) 1984-06-01
NO149492C (no) 1984-05-09
JPH01199920A (ja) 1989-08-11
BE852865A (fr) 1977-09-26
IT1075368B (it) 1985-04-22
JPS6247854B2 (US07534539-20090519-C00280.png) 1987-10-09
NZ183608A (en) 1978-12-18
GB1574523A (en) 1980-09-10
PL115528B1 (en) 1981-04-30
FR2357303A1 (fr) 1978-02-03
NO771085L (no) 1977-10-03
NL187424C (nl) 1991-10-01
CS218565B2 (en) 1983-02-25
JPH0567613B1 (US07534539-20090519-C00280.png) 1993-09-27

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