DE2660683C2 - - Google Patents
Info
- Publication number
- DE2660683C2 DE2660683C2 DE2660683A DE2660683A DE2660683C2 DE 2660683 C2 DE2660683 C2 DE 2660683C2 DE 2660683 A DE2660683 A DE 2660683A DE 2660683 A DE2660683 A DE 2660683A DE 2660683 C2 DE2660683 C2 DE 2660683C2
- Authority
- DE
- Germany
- Prior art keywords
- alkali
- detergent
- weight
- fine particles
- inorganic fine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003599 detergent Substances 0.000 claims description 96
- 238000005406 washing Methods 0.000 claims description 49
- 239000003513 alkali Substances 0.000 claims description 43
- 239000000203 mixture Substances 0.000 claims description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 29
- 239000000872 buffer Substances 0.000 claims description 23
- 239000000725 suspension Substances 0.000 claims description 21
- 239000007787 solid Substances 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 18
- 239000010419 fine particle Substances 0.000 claims description 17
- 238000002425 crystallisation Methods 0.000 claims description 16
- 230000008025 crystallization Effects 0.000 claims description 16
- 238000002441 X-ray diffraction Methods 0.000 claims description 15
- 239000011164 primary particle Substances 0.000 claims description 15
- 239000002245 particle Substances 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 12
- 239000012459 cleaning agent Substances 0.000 claims description 11
- 239000000377 silicon dioxide Substances 0.000 claims description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- 229910052906 cristobalite Inorganic materials 0.000 claims description 10
- 235000012239 silicon dioxide Nutrition 0.000 claims description 10
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 229910001424 calcium ion Inorganic materials 0.000 claims description 9
- 229910052681 coesite Inorganic materials 0.000 claims description 9
- 239000011163 secondary particle Substances 0.000 claims description 9
- 229910052682 stishovite Inorganic materials 0.000 claims description 9
- 229910052905 tridymite Inorganic materials 0.000 claims description 9
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 8
- 229960000907 methylthioninium chloride Drugs 0.000 claims description 8
- 239000000047 product Substances 0.000 claims description 8
- 238000010521 absorption reaction Methods 0.000 claims description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
- 239000002734 clay mineral Substances 0.000 claims description 7
- 229910052593 corundum Inorganic materials 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 7
- 238000009826 distribution Methods 0.000 claims description 7
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 7
- 239000003945 anionic surfactant Substances 0.000 claims description 6
- 239000002736 nonionic surfactant Substances 0.000 claims description 6
- 239000004094 surface-active agent Substances 0.000 claims description 6
- 230000003139 buffering effect Effects 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 238000004062 sedimentation Methods 0.000 claims description 5
- 229910021647 smectite Inorganic materials 0.000 claims description 5
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 239000000429 sodium aluminium silicate Substances 0.000 claims description 3
- 235000012217 sodium aluminium silicate Nutrition 0.000 claims description 3
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- 239000006228 supernatant Substances 0.000 claims description 2
- 230000004580 weight loss Effects 0.000 claims description 2
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 claims 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims 1
- 239000002280 amphoteric surfactant Substances 0.000 claims 1
- 125000000129 anionic group Chemical group 0.000 claims 1
- 239000007900 aqueous suspension Substances 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- 238000001493 electron microscopy Methods 0.000 claims 1
- 238000000605 extraction Methods 0.000 claims 1
- 239000010954 inorganic particle Substances 0.000 claims 1
- 238000005259 measurement Methods 0.000 claims 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 1
- 239000010457 zeolite Substances 0.000 description 50
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 41
- 229910021536 Zeolite Inorganic materials 0.000 description 33
- 238000012360 testing method Methods 0.000 description 23
- 239000011734 sodium Substances 0.000 description 22
- 235000015424 sodium Nutrition 0.000 description 22
- 229910052708 sodium Inorganic materials 0.000 description 22
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 21
- 239000000843 powder Substances 0.000 description 21
- 239000004744 fabric Substances 0.000 description 17
- -1 sodium alkylsulfonates Chemical class 0.000 description 16
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 13
- 239000000344 soap Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 10
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 8
- 239000001768 carboxy methyl cellulose Substances 0.000 description 8
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 8
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 8
- 239000004927 clay Substances 0.000 description 8
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 8
- 239000000194 fatty acid Substances 0.000 description 8
- 229930195729 fatty acid Natural products 0.000 description 8
- 229910021645 metal ion Inorganic materials 0.000 description 8
- 239000002002 slurry Substances 0.000 description 8
- 239000004115 Sodium Silicate Substances 0.000 description 7
- 239000013078 crystal Substances 0.000 description 7
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 7
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 7
- 229910052911 sodium silicate Inorganic materials 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 description 6
- 235000017550 sodium carbonate Nutrition 0.000 description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 description 6
- 235000011152 sodium sulphate Nutrition 0.000 description 6
- 238000001179 sorption measurement Methods 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000002537 cosmetic Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000004570 mortar (masonry) Substances 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- 235000019832 sodium triphosphate Nutrition 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 150000004645 aluminates Chemical class 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 230000000536 complexating effect Effects 0.000 description 4
- 238000011109 contamination Methods 0.000 description 4
- 239000003623 enhancer Substances 0.000 description 4
- 238000005342 ion exchange Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 150000004996 alkyl benzenes Chemical class 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000010668 complexation reaction Methods 0.000 description 3
- JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 235000002639 sodium chloride Nutrition 0.000 description 3
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910001491 alkali aluminosilicate Inorganic materials 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 229940077388 benzenesulfonate Drugs 0.000 description 2
- 229910021538 borax Inorganic materials 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 229910052665 sodalite Inorganic materials 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000000271 synthetic detergent Substances 0.000 description 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 1
- 206010010774 Constipation Diseases 0.000 description 1
- 229910017488 Cu K Inorganic materials 0.000 description 1
- 229910017541 Cu-K Inorganic materials 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 239000003568 Sodium, potassium and calcium salts of fatty acids Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- IFTMCARQCOKBFG-UHFFFAOYSA-H [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]C(=O)c1c(C([O-])=O)c(C([O-])=O)c(C([O-])=O)c(C([O-])=O)c1C([O-])=O Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]C(=O)c1c(C([O-])=O)c(C([O-])=O)c(C([O-])=O)c(C([O-])=O)c1C([O-])=O IFTMCARQCOKBFG-UHFFFAOYSA-H 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical group [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910052676 chabazite Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910001603 clinoptilolite Inorganic materials 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- IILQHMMTOSAJAR-UHFFFAOYSA-L disodium;2-(carboxylatomethoxy)acetate Chemical compound [Na+].[Na+].[O-]C(=O)COCC([O-])=O IILQHMMTOSAJAR-UHFFFAOYSA-L 0.000 description 1
- BNVZBQVIMPLFNA-UHFFFAOYSA-L disodium;2-(carboxymethoxy)butanedioate Chemical compound [Na+].[Na+].OC(=O)COC(C([O-])=O)CC([O-])=O BNVZBQVIMPLFNA-UHFFFAOYSA-L 0.000 description 1
- NPCCEUVRYRJOLM-UHFFFAOYSA-L disodium;2-(carboxymethoxy)propanedioate Chemical compound [Na+].[Na+].OC(=O)COC(C([O-])=O)C([O-])=O NPCCEUVRYRJOLM-UHFFFAOYSA-L 0.000 description 1
- 238000005108 dry cleaning Methods 0.000 description 1
- 229910052675 erionite Inorganic materials 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002193 fatty amides Chemical class 0.000 description 1
- 239000012013 faujasite Substances 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- TVHALOSDPLTTSR-UHFFFAOYSA-H hexasodium;[oxido-[oxido(phosphonatooxy)phosphoryl]oxyphosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O TVHALOSDPLTTSR-UHFFFAOYSA-H 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000009938 salting Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- 235000011083 sodium citrates Nutrition 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 239000000176 sodium gluconate Substances 0.000 description 1
- 235000012207 sodium gluconate Nutrition 0.000 description 1
- 229940005574 sodium gluconate Drugs 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical class [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000013875 sodium salts of fatty acid Nutrition 0.000 description 1
- 229910000031 sodium sesquicarbonate Inorganic materials 0.000 description 1
- 235000018341 sodium sesquicarbonate Nutrition 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical class [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
- C01B33/2815—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of type A (UNION CARBIDE trade name; corresponds to GRACE's types Z-12 or Z-12L)
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/24—LTA, e.g. A, alpha, ZK-4, ZK-21, ZK-22
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Detergent Compositions (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13781475A JPS5262315A (en) | 1975-11-18 | 1975-11-18 | Detergent composition |
| JP50141141A JPS5851992B2 (ja) | 1975-11-27 | 1975-11-27 | センザイビルダ− オヨビ ソノセイホウ |
| JP12179576A JPS5347408A (en) | 1976-10-13 | 1976-10-13 | Detergent builder and preparation thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2660683C2 true DE2660683C2 (OSRAM) | 1988-05-26 |
Family
ID=27314324
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2652409A Expired DE2652409C2 (de) | 1975-11-18 | 1976-11-17 | Verfahren zur Herstellung von Waschmittelverstärkern |
| DE2660683A Expired DE2660683C2 (OSRAM) | 1975-11-18 | 1976-11-17 | |
| DE2660682A Expired DE2660682C2 (OSRAM) | 1975-11-18 | 1976-11-17 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2652409A Expired DE2652409C2 (de) | 1975-11-18 | 1976-11-17 | Verfahren zur Herstellung von Waschmittelverstärkern |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2660682A Expired DE2660682C2 (OSRAM) | 1975-11-18 | 1976-11-17 |
Country Status (6)
| Country | Link |
|---|---|
| US (3) | US4102977A (OSRAM) |
| CA (1) | CA1087152A (OSRAM) |
| DE (3) | DE2652409C2 (OSRAM) |
| FR (1) | FR2332321B1 (OSRAM) |
| GB (1) | GB1571003A (OSRAM) |
| NL (1) | NL174713C (OSRAM) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2727053C2 (de) * | 1977-06-15 | 1982-11-25 | Süd-Chemie AG, 8000 München | Adsorptiv wirkendes silikatisches Mittel zur Bindung von Erdalkali-Ionen |
| DE2734296A1 (de) * | 1977-07-29 | 1979-02-08 | Degussa | Verfahren zur herstellung von feinteiligen, zum kationenaustausch befaehigten wasserunloeslichen silikaten |
| DE2738085A1 (de) * | 1977-08-24 | 1979-03-08 | Kali Chemie Ag | Verfahren zur verbesserung der eigenschaften von natriumaluminiumsilikatteigen und -pulvern |
| DE2751354A1 (de) * | 1977-11-17 | 1979-05-23 | Hoechst Ag | Verfahren zur herstellung von gemischen aus kristallinem zeolith und natriumtriphosphat |
| US4415489A (en) * | 1979-04-06 | 1983-11-15 | Colgate Palmolive Company | Process for making high solids content zeolite A-alkylbenzene sulfonate compositions suitable for use in making spray dried detergent compositions |
| JPS5919597B2 (ja) * | 1980-04-23 | 1984-05-07 | ライオン株式会社 | ゼオライト含有無燐粒状洗剤組成物 |
| US4622166A (en) * | 1982-03-17 | 1986-11-11 | Mizusawa Kagaku Kogyo Kabushiki Kaisha | Process for preparation of zeolite slurry excellent in static stability and dynamic stability |
| US4528111A (en) * | 1983-12-22 | 1985-07-09 | Colgate-Palmolive Company | Shaving cream gel containing interpolymer reaction product of selected cationic polymers and anionic polymers |
| US4668484A (en) * | 1984-02-13 | 1987-05-26 | Elliott David J | Transport containers for semiconductor wafers |
| FR2568790B1 (fr) * | 1984-08-10 | 1990-01-12 | Rhone Poulenc Chim Base | Procede d'obtention d'une suspension aqueuse stable et pompable de zeolite et suspension ainsi obtenue |
| DE3612701A1 (de) * | 1986-04-15 | 1987-10-22 | Degussa | Waschmittel in stueckiger form |
| GB8725802D0 (en) * | 1987-11-04 | 1987-12-09 | Unilever Plc | Liquid detergent compositions |
| US5443812A (en) * | 1989-04-24 | 1995-08-22 | Kanebo Ltd. | Stabilized synthetic zeolite and a process for the preparation thereof |
| GB9216386D0 (en) * | 1992-07-31 | 1992-09-16 | Unilever Plc | Use of aluminosilicates of the zeolite p type as low temperature calcium binders |
| DE4309656A1 (de) * | 1993-03-25 | 1994-09-29 | Henkel Kgaa | Verfahren zur Herstellung von feinstteiligen zeolithischen Alkalimetallaluminiumsilicaten |
| WO1995028354A1 (en) * | 1994-04-13 | 1995-10-26 | Romano Dominic A | Apparatus for and method of treatment of media containing unwanted substances |
| US6140301A (en) * | 1995-04-27 | 2000-10-31 | The Procter & Gamble Company | Process for producing granular detergent components or compositions |
| GB9605534D0 (en) * | 1996-03-15 | 1996-05-15 | Unilever Plc | Detergent compositions |
| SG74639A1 (en) | 1997-07-10 | 2000-08-22 | Toray Industries | A catalyst composition and a method for isomerizing halogenated aromatics |
| HU218835B (hu) * | 1997-10-28 | 2000-12-28 | Péter Siklósi | Eljárás zeolitok előállítására alkáli-alumínium-hidroszilikát-tartalmú nyersanyagokból |
| CA2362475A1 (en) * | 1999-03-09 | 2000-09-14 | The Procter & Gamble Company | Detergent compositions |
| BR9917202A (pt) * | 1999-03-09 | 2001-12-26 | Procter & Gamble | Composições detergentes |
| CN1321889C (zh) * | 1999-11-09 | 2007-06-20 | 花王株式会社 | 制备细沸石颗粒的方法 |
| BR0109300A (pt) * | 2000-03-17 | 2002-12-24 | Pq Holding Inc | Processo para a fabricação de um produto de zeólito, produto de zeólito, e, composição detergente |
| US6475246B1 (en) | 2000-05-22 | 2002-11-05 | Pariser Industries | Dry cleaning additive, bath, and method |
| CN1307099C (zh) * | 2000-12-28 | 2007-03-28 | 花王株式会社 | 微细沸石颗粒 |
| DE10105801B4 (de) * | 2001-02-07 | 2004-07-08 | Henkel Kgaa | Wasch- und Reinigungsmittel umfassend feine Mikropartikel mit Reinigungsmittelbestandteilen |
| US7435426B2 (en) * | 2001-03-22 | 2008-10-14 | Church & Dwight Co., Inc. | Micron sized bicarbonate particles and slurrys containing the same |
| US8288169B2 (en) * | 2005-01-21 | 2012-10-16 | Argylla Technologies | Surface mediated self-assembly of nanoparticles |
| US7964380B2 (en) * | 2005-01-21 | 2011-06-21 | Argylia Technologies | Nanoparticles for manipulation of biopolymers and methods of thereof |
| US20090208919A1 (en) * | 2005-01-21 | 2009-08-20 | Argylla Technologies, Llp | Particle matrix for storage of biomolecules |
| WO2016057057A1 (en) * | 2014-10-09 | 2016-04-14 | Metron Nutraceuticals, Llc | Production of water-soluble hydrolyzed clinoptilolite fragments for use in nutraceutical products |
| US10206948B2 (en) | 2014-10-09 | 2019-02-19 | Nikolaos Tsirikos-Karapanos | Production of water-soluble clinoptilolite fragments |
| US10828324B2 (en) | 2014-10-09 | 2020-11-10 | Nikolaos Tsirikos-Karapanos | Production of water-soluble hydrolyzed clinoptilolite fragments |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2412837A1 (de) * | 1973-04-13 | 1974-10-31 | Henkel & Cie Gmbh | Verfahren zum waschen und reinigen der oberflaechen von festen werkstoffen, insbesondere von textilien, sowie mittel zur durchfuehrung des verfahrens |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1038017B (de) * | 1953-12-24 | 1958-09-04 | Union Carbide Corp | Verfahren zur Herstellung kristalliner zeolithischer Molekularsiebe |
| DE1095795B (de) * | 1958-10-03 | 1960-12-29 | Bayer Ag | Verfahren zur Herstellung von Natrium-Zeolith A |
| US3094383A (en) * | 1960-12-16 | 1963-06-18 | Minerals & Chem Philipp Corp | Method for making synthetic zeolitic material |
| GB1007853A (en) * | 1961-07-19 | 1965-10-22 | Union Carbide Corp | Process for producing synthetic crystalline zeolites |
| US3185544A (en) * | 1962-07-02 | 1965-05-25 | Grace W R & Co | Preparation of crystalline zeolites of uniform and controlled particle size |
| GB1062064A (en) * | 1964-05-13 | 1967-03-15 | British Petroleum Co | Synthetic zeolite production |
| US3390958A (en) * | 1964-10-19 | 1968-07-02 | Union Carbide Corp | Process for preparing crystalline zeolitic molecular sieves |
| FR1460774A (fr) * | 1964-10-19 | 1966-01-07 | Union Carbide Corp | Procédé de préparation de tamis moléculaires zéolitiques cristallins |
| US3393045A (en) * | 1964-12-03 | 1968-07-16 | Grace W R & Co | Process for the preparation of a crystalline zeolite |
| AR208392A1 (es) * | 1973-05-07 | 1976-12-27 | Henkel & Cie Gmbh | Composicion para lavar blanquear o limpiar materiales resistentes especialmente textiles adicional a la patente no 201687 adicional a la no 253286 |
| DE2433485A1 (de) * | 1973-07-16 | 1975-02-06 | Procter & Gamble | Zur verwendung in waschmitteln geeignete aluminosilikat-ionenaustauscher |
| US3985669A (en) * | 1974-06-17 | 1976-10-12 | The Procter & Gamble Company | Detergent compositions |
| AT338948B (de) * | 1974-10-10 | 1977-09-26 | Henkel & Cie Gmbh | Pulverformige wasch- und reinigungsmittel und verfahren zu ihrer herstellung |
| AT335035B (de) * | 1974-10-10 | 1977-02-25 | Henkel & Cie Gmbh | Stabile suspensionen wasserunloslicher, zum binden von calciumionen befahigter silikate und deren verwendung zur herstellung von wasch- und reinigungsmitteln |
| GB1516848A (en) * | 1974-11-13 | 1978-07-05 | Procter & Gamble Ltd | Detergent composition |
| US4066394A (en) * | 1974-12-30 | 1978-01-03 | Colgate-Palmolive | Reusable zeolite water softener for clothes washing |
| US4041135A (en) * | 1975-07-25 | 1977-08-09 | J. M. Huber Corporation | Production of high capacity inorganic crystalline base exchange materials |
| US4096081A (en) * | 1976-02-06 | 1978-06-20 | The Procter & Gamble Company | Detergent compositions containing aluminosilicate agglomerates |
| US4034058A (en) * | 1976-06-29 | 1977-07-05 | Engelhard Minerals & Chemicals Corporation | Method for producing synthetic sodium aluminosilicate ion-exchange material from calcined kaolin clay |
-
1976
- 1976-11-12 US US05/741,365 patent/US4102977A/en not_active Expired - Lifetime
- 1976-11-17 DE DE2652409A patent/DE2652409C2/de not_active Expired
- 1976-11-17 DE DE2660683A patent/DE2660683C2/de not_active Expired
- 1976-11-17 DE DE2660682A patent/DE2660682C2/de not_active Expired
- 1976-11-17 GB GB47950/76A patent/GB1571003A/en not_active Expired
- 1976-11-17 CA CA265,939A patent/CA1087152A/en not_active Expired
- 1976-11-18 FR FR7634715A patent/FR2332321B1/fr not_active Expired
- 1976-11-18 NL NLAANVRAGE7612844,A patent/NL174713C/xx not_active IP Right Cessation
-
1978
- 1978-01-26 US US05/872,587 patent/US4219535A/en not_active Expired - Lifetime
- 1978-04-17 US US05/896,767 patent/US4238346A/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2412837A1 (de) * | 1973-04-13 | 1974-10-31 | Henkel & Cie Gmbh | Verfahren zum waschen und reinigen der oberflaechen von festen werkstoffen, insbesondere von textilien, sowie mittel zur durchfuehrung des verfahrens |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1571003A (en) | 1980-07-09 |
| FR2332321A1 (fr) | 1977-06-17 |
| CA1087152A (en) | 1980-10-07 |
| NL174713C (nl) | 1984-08-01 |
| FR2332321B1 (fr) | 1985-10-25 |
| DE2652409C2 (de) | 1984-06-14 |
| US4219535A (en) | 1980-08-26 |
| US4102977A (en) | 1978-07-25 |
| NL7612844A (nl) | 1977-05-23 |
| DE2660682C2 (OSRAM) | 1988-05-26 |
| DE2652409A1 (de) | 1977-05-26 |
| NL174713B (nl) | 1984-03-01 |
| US4238346A (en) | 1980-12-09 |
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