DE2560036C2 - Monomethylzinn-tris-thioglykolsäure-n-tetradecylester - Google Patents
Monomethylzinn-tris-thioglykolsäure-n-tetradecylesterInfo
- Publication number
- DE2560036C2 DE2560036C2 DE2560036A DE2560036A DE2560036C2 DE 2560036 C2 DE2560036 C2 DE 2560036C2 DE 2560036 A DE2560036 A DE 2560036A DE 2560036 A DE2560036 A DE 2560036A DE 2560036 C2 DE2560036 C2 DE 2560036C2
- Authority
- DE
- Germany
- Prior art keywords
- stabilizers
- stabilizer
- pvc
- tin
- monoalkyltin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003381 stabilizer Substances 0.000 claims description 38
- 229910052718 tin Inorganic materials 0.000 claims description 12
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 11
- 230000000694 effects Effects 0.000 claims description 9
- 239000000314 lubricant Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 238000000465 moulding Methods 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 6
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 3
- 125000004185 ester group Chemical group 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 238000009472 formulation Methods 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- WFNYGAYHAUKZJC-UHFFFAOYSA-K butyltin(3+) 2-dodecyl-2-dodecylsulfanyltetradecanoate Chemical compound C(CCCCCCCCCCC)SC(C(=O)[O-])(CCCCCCCCCCCC)CCCCCCCCCCCC.C(CCC)[Sn+3].C(CCCCCCCCCCC)SC(C(=O)[O-])(CCCCCCCCCCCC)CCCCCCCCCCCC.C(CCCCCCCCCCC)SC(C(=O)[O-])(CCCCCCCCCCCC)CCCCCCCCCCCC WFNYGAYHAUKZJC-UHFFFAOYSA-K 0.000 claims 1
- HDFRDWFLWVCOGP-UHFFFAOYSA-N carbonothioic O,S-acid Chemical class OC(S)=O HDFRDWFLWVCOGP-UHFFFAOYSA-N 0.000 claims 1
- 230000003247 decreasing effect Effects 0.000 claims 1
- 230000001419 dependent effect Effects 0.000 claims 1
- 229910001385 heavy metal Inorganic materials 0.000 claims 1
- 150000002898 organic sulfur compounds Chemical class 0.000 claims 1
- 229920003023 plastic Polymers 0.000 claims 1
- 239000006077 pvc stabilizer Substances 0.000 claims 1
- 230000000087 stabilizing effect Effects 0.000 claims 1
- -1 mercaptocarboxylic acid ester Chemical class 0.000 description 6
- 238000002845 discoloration Methods 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000012170 montan wax Substances 0.000 description 3
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- YFRLQYJXUZRYDN-UHFFFAOYSA-K trichloro(methyl)stannane Chemical class C[Sn](Cl)(Cl)Cl YFRLQYJXUZRYDN-UHFFFAOYSA-K 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- BVTNMUKMZBWMIC-UHFFFAOYSA-K C[Sn+3].CCCCCCCCCCCCCCC(S)C([O-])=O.CCCCCCCCCCCCCCC(S)C([O-])=O.CCCCCCCCCCCCCCC(S)C([O-])=O Chemical compound C[Sn+3].CCCCCCCCCCCCCCC(S)C([O-])=O.CCCCCCCCCCCCCCC(S)C([O-])=O.CCCCCCCCCCCCCCC(S)C([O-])=O BVTNMUKMZBWMIC-UHFFFAOYSA-K 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000004908 Emulsion polymer Substances 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 239000004164 Wax ester Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000370 acceptor Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- CWERGRDVMFNCDR-UHFFFAOYSA-N alpha-mercaptoacetic acid Natural products OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 206010016256 fatigue Diseases 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- JHHJZXAFNAJSCA-UHFFFAOYSA-N methyl(oxo)tin Chemical class C[Sn]=O JHHJZXAFNAJSCA-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- CSHCPECZJIEGJF-UHFFFAOYSA-N methyltin Chemical compound [Sn]C CSHCPECZJIEGJF-UHFFFAOYSA-N 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- LXDHBOICPCPCKD-UHFFFAOYSA-N tetradecyl 2-sulfanylacetate Chemical compound CCCCCCCCCCCCCCOC(=O)CS LXDHBOICPCPCKD-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 235000019386 wax ester Nutrition 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
- C08K5/58—Organo-tin compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/226—Compounds with one or more Sn-S linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH62074A CH588980A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1974-01-17 | 1974-01-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2560036B1 DE2560036B1 (de) | 1979-12-13 |
| DE2560036C2 true DE2560036C2 (de) | 1980-08-21 |
Family
ID=4191244
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2560036A Expired DE2560036C2 (de) | 1974-01-17 | 1975-01-15 | Monomethylzinn-tris-thioglykolsäure-n-tetradecylester |
| DE2559820A Expired DE2559820C3 (de) | 1974-01-17 | 1975-01-15 | Monooctylzinntristhioglycolsäuretetradecylester |
| DE2501331A Ceased DE2501331B2 (de) | 1974-01-17 | 1975-01-15 | Verpackungsmaterial aus Vinylchloridpolymeren oder -copolymeren |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2559820A Expired DE2559820C3 (de) | 1974-01-17 | 1975-01-15 | Monooctylzinntristhioglycolsäuretetradecylester |
| DE2501331A Ceased DE2501331B2 (de) | 1974-01-17 | 1975-01-15 | Verpackungsmaterial aus Vinylchloridpolymeren oder -copolymeren |
Country Status (18)
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5842217B2 (ja) * | 1975-12-25 | 1983-09-17 | サンキヨウユウキゴウセイ カブシキガイシヤ | エンカビニルジユシノアンテイカホウ |
| EP0013537A3 (de) * | 1978-12-08 | 1980-10-15 | Ciba-Geigy Ag | Organozinnverbindungen, ihre Anwendung zur Stabilisierung von chlorhaltigen Polymeren und die sie enthaltenden chlorhaltigen Polymere; Monothioglycerindiester |
| DE3044106A1 (de) * | 1979-11-30 | 1981-09-03 | Yoshitomi Pharmaceutical Industries, Ltd., Osaka | Verfahren zur herstellung von polyurethanen |
| DE3014291C2 (de) * | 1980-04-15 | 1986-05-15 | Dynamit Nobel Ag, 5210 Troisdorf | Dichtungsbahn auf Basis Weich-PVC |
| JPS57205434A (en) * | 1981-06-12 | 1982-12-16 | Adeka Argus Chem Co Ltd | Halogen-containing resin composition |
| US4988750A (en) * | 1981-07-17 | 1991-01-29 | Schering Ag | Non-toxic stabilizer for halogenated polymer |
| US4554368A (en) * | 1982-12-01 | 1985-11-19 | Ciba-Geigy Corporation | Continuous process for the preparation of alkyltin thiocarboxylic acid esters |
| GB2139625B (en) * | 1983-05-03 | 1987-05-13 | Ciba Geigy Ag | Novel organo-tin pvc stabilisers |
| US4726928A (en) * | 1983-11-15 | 1988-02-23 | American Hoechst Corporation | Radiation-resistant vinyl halide resin compositions and a process for their production |
| FR2599373B1 (fr) * | 1986-05-30 | 1989-06-16 | Ciba Geigy Ag | Compositions a base de poly-(chlorure de vinyle) stabilisees par des composes laurylstanniques, application de ces compositions et procede pour stabiliser des matieres a mouler |
| JPH02155941A (ja) * | 1988-12-07 | 1990-06-15 | Kyodo Yakuhin Kk | 塩化ビニル樹脂組成物 |
| JPH07133391A (ja) * | 1993-11-11 | 1995-05-23 | Kyodo Yakuhin Kk | 熱安定性に優れる含ハロゲン樹脂組成物 |
| EP2123659A1 (en) * | 2008-05-15 | 2009-11-25 | Arkema France | High purity monoalkyltin compounds and uses thereof |
| FR2974101B1 (fr) * | 2011-04-18 | 2015-01-16 | Arkema France | Composition de polymere contenant un halogene avec stabilisant a base d'etain et co-stabilisant |
| DE14747246T1 (de) * | 2013-08-08 | 2016-09-29 | Galata Chemicals Llc | Wärmestabilisator für halogenhaltige Polymere |
| EP3145937B1 (en) | 2015-06-05 | 2018-06-06 | Galata Chemicals LLC | Stabilizers containing high purity mono-octyltin and di-methyltin compounds |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2648650A (en) * | 1951-06-21 | 1953-08-11 | Metal & Thermit Corp | Organo tin compounds and compositions containing same |
| US2641588A (en) * | 1952-02-07 | 1953-06-09 | Argus Chemical Lab Inc | Halogen containing resin stabilized with an organo tin compound |
| US3390159A (en) * | 1963-09-19 | 1968-06-25 | Nitto Chemical Industry Co Ltd | Process for preparing dioctyltin oxide |
| DE1924858U (de) | 1965-07-07 | 1965-10-07 | Josef Wagner | Elektrischer wippankerantrieb. |
| US3544510A (en) * | 1968-05-15 | 1970-12-01 | Cincinnati Milacron Chem | Mercaptal stabilized halogen-containing resins |
| US3640947A (en) * | 1970-06-25 | 1972-02-08 | M & T Chemicals Inc | Non-toxic stabilized polyvinyl chloride products and stabilizer compositions |
| GB1346999A (en) | 1970-10-02 | 1974-02-13 | Interstab Ltd | Stabilisers for vinyl chloride resins |
| US3925309A (en) * | 1971-09-02 | 1975-12-09 | Cincinnati Milacron Chem | Dimethyltin esters |
| DE2307360A1 (de) * | 1972-02-16 | 1973-08-30 | Akzo Gmbh | Stabilisatormischung fuer pvc-harze |
| JPS5314097B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1973-07-17 | 1978-05-15 |
-
1974
- 1974-01-17 CH CH62074A patent/CH588980A5/xx not_active IP Right Cessation
- 1974-11-29 SE SE7415001A patent/SE396398C/xx not_active IP Right Cessation
- 1974-12-24 AU AU76819/74A patent/AU7681974A/en not_active Expired
-
1975
- 1975-01-01 AR AR257307A patent/AR207134A1/es active
- 1975-01-15 BR BR265/75A patent/BR7500265A/pt unknown
- 1975-01-15 DE DE2560036A patent/DE2560036C2/de not_active Expired
- 1975-01-15 DE DE2559820A patent/DE2559820C3/de not_active Expired
- 1975-01-15 DE DE2501331A patent/DE2501331B2/de not_active Ceased
- 1975-01-15 GB GB1673/75A patent/GB1494771A/en not_active Expired
- 1975-01-15 DD DD183644A patent/DD117686A5/xx unknown
- 1975-01-16 ZA ZA00750309A patent/ZA75309B/xx unknown
- 1975-01-16 FR FR7501249A patent/FR2273037B1/fr not_active Expired
- 1975-01-16 ES ES433846A patent/ES433846A1/es not_active Expired
- 1975-01-16 BE BE152412A patent/BE824427A/xx not_active IP Right Cessation
- 1975-01-16 NL NLAANVRAGE7500528,A patent/NL189858C/xx not_active IP Right Cessation
- 1975-01-16 AT AT30775*#A patent/AT335745B/de not_active IP Right Cessation
- 1975-01-17 JP JP50007678A patent/JPS5761052B2/ja not_active Expired
-
1978
- 1978-02-27 US US05/881,445 patent/US4193913A/en not_active Expired - Lifetime
-
1980
- 1980-08-21 HK HK447/80A patent/HK44780A/xx unknown
-
1981
- 1981-12-30 MY MY148/81A patent/MY8100148A/xx unknown
Also Published As
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| BHJ | Nonpayment of the annual fee | ||
| BI | Miscellaneous see part 2 | ||
| OD | Request for examination | ||
| 8339 | Ceased/non-payment of the annual fee |