DE2553094B2 - Die Verwendung bestimmter Perverbindungen zur Erhöhung der Beständigkeit von Äthylenpolymerisaten gegen ein Verschmoren und Erhöhung der Aushärtungsgeschwindigkeit - Google Patents
Die Verwendung bestimmter Perverbindungen zur Erhöhung der Beständigkeit von Äthylenpolymerisaten gegen ein Verschmoren und Erhöhung der AushärtungsgeschwindigkeitInfo
- Publication number
- DE2553094B2 DE2553094B2 DE2553094A DE2553094A DE2553094B2 DE 2553094 B2 DE2553094 B2 DE 2553094B2 DE 2553094 A DE2553094 A DE 2553094A DE 2553094 A DE2553094 A DE 2553094A DE 2553094 B2 DE2553094 B2 DE 2553094B2
- Authority
- DE
- Germany
- Prior art keywords
- increase
- weight
- masses
- hydroperoxide
- charring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920000573 polyethylene Polymers 0.000 title claims description 23
- 150000001875 compounds Chemical class 0.000 title description 11
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 21
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims description 13
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 11
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 description 36
- 238000012360 testing method Methods 0.000 description 27
- 238000001125 extrusion Methods 0.000 description 19
- 239000003963 antioxidant agent Substances 0.000 description 13
- 150000002978 peroxides Chemical class 0.000 description 11
- -1 organic peroxide compounds Chemical class 0.000 description 10
- 239000005977 Ethylene Substances 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 238000004073 vulcanization Methods 0.000 description 7
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 6
- 230000003078 antioxidant effect Effects 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000009413 insulation Methods 0.000 description 6
- 238000010998 test method Methods 0.000 description 6
- 239000004020 conductor Substances 0.000 description 5
- 150000002432 hydroperoxides Chemical class 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- 238000009795 derivation Methods 0.000 description 3
- 230000002028 premature Effects 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- KSNRDYQOHXQKAB-UHFFFAOYSA-N 2,2,4-trimethyl-3,4-dihydro-1h-quinoline Chemical compound C1=CC=C2C(C)CC(C)(C)NC2=C1 KSNRDYQOHXQKAB-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 239000011872 intimate mixture Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- QYCGBAJADAGLLK-UHFFFAOYSA-N 1-(cyclohepten-1-yl)cycloheptene Chemical compound C1CCCCC=C1C1=CCCCCC1 QYCGBAJADAGLLK-UHFFFAOYSA-N 0.000 description 1
- KAJRUHJCBCZULP-UHFFFAOYSA-N 1-cyclohepta-1,3-dien-1-ylcyclohepta-1,3-diene Chemical compound C1CCC=CC=C1C1=CC=CCCC1 KAJRUHJCBCZULP-UHFFFAOYSA-N 0.000 description 1
- 125000003143 4-hydroxybenzyl group Chemical group [H]C([*])([H])C1=C([H])C([H])=C(O[H])C([H])=C1[H] 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 101100060894 Schizosaccharomyces pombe (strain 972 / ATCC 24843) ctp1 gene Proteins 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010835 comparative analysis Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- OSPDFFCOJRYDNX-UHFFFAOYSA-N cumene;hydrogen peroxide;2-hydroperoxy-2-methylpropane Chemical compound OO.CC(C)(C)OO.CC(C)C1=CC=CC=C1 OSPDFFCOJRYDNX-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 239000006232 furnace black Substances 0.000 description 1
- 239000007863 gel particle Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 101150033934 nip1 gene Proteins 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 238000010606 normalization Methods 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 125000002081 peroxide group Chemical group 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000004297 potassium metabisulphite Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US52785274A | 1974-11-27 | 1974-11-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2553094A1 DE2553094A1 (de) | 1976-08-12 |
| DE2553094B2 true DE2553094B2 (de) | 1979-05-03 |
Family
ID=24103190
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2553094A Withdrawn DE2553094B2 (de) | 1974-11-27 | 1975-11-26 | Die Verwendung bestimmter Perverbindungen zur Erhöhung der Beständigkeit von Äthylenpolymerisaten gegen ein Verschmoren und Erhöhung der Aushärtungsgeschwindigkeit |
Country Status (12)
| Country | Link |
|---|---|
| JP (1) | JPS5177644A (cg-RX-API-DMAC7.html) |
| AU (1) | AU508623B2 (cg-RX-API-DMAC7.html) |
| BE (1) | BE835962A (cg-RX-API-DMAC7.html) |
| BR (1) | BR7507820A (cg-RX-API-DMAC7.html) |
| CA (1) | CA1047696A (cg-RX-API-DMAC7.html) |
| DE (1) | DE2553094B2 (cg-RX-API-DMAC7.html) |
| FR (1) | FR2292735A1 (cg-RX-API-DMAC7.html) |
| GB (1) | GB1535039A (cg-RX-API-DMAC7.html) |
| IN (1) | IN143890B (cg-RX-API-DMAC7.html) |
| IT (1) | IT1054913B (cg-RX-API-DMAC7.html) |
| NL (1) | NL7513803A (cg-RX-API-DMAC7.html) |
| SE (1) | SE408906B (cg-RX-API-DMAC7.html) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2063478A1 (en) * | 1991-03-22 | 1992-09-23 | Michael F. Novits | Scorch extending curing/crosslinking compositions |
| ITMI960029U1 (it) * | 1996-01-18 | 1997-07-18 | Atochem Elf Italia | Composizioni perossidiche con resistenza allo scorch |
| IT1305321B1 (it) * | 1998-04-21 | 2001-05-04 | Atochem Elf Italia | Composizioni perossidiche con migliorata resistenza allo scorch per lareticolazione di elastomeri e poliolefine |
| IT1305320B1 (it) | 1998-04-21 | 2001-05-04 | Atochem Elf Italia | Composizioni perossidiche con migliorata resistenza allo scorch perla reticolazione di elastomeri e poliolefine |
| IT1305324B1 (it) * | 1998-04-21 | 2001-05-04 | Atochem Elf Italia | Composizioni perossidiche con migliorata resistenza allo scorch per lareticolazione di elastomeri e poliolefine. |
| IT1304174B1 (it) | 1998-12-17 | 2001-03-08 | Atochem Elf Italia | Composizioni perossidiche |
| US20040198920A1 (en) | 2003-04-03 | 2004-10-07 | Atofina | Scorch-retardant composition |
| FR2875502B1 (fr) | 2004-09-22 | 2007-01-05 | Arkema Sa | Composition retardant le grillage |
| US20080115825A1 (en) | 2006-09-20 | 2008-05-22 | Patel Rajen M | Electronic Device Module Comprising an Ethylene Multi-Block Copolymer |
| US8581094B2 (en) | 2006-09-20 | 2013-11-12 | Dow Global Technologies, Llc | Electronic device module comprising polyolefin copolymer |
| CA2663058A1 (en) | 2006-09-20 | 2008-03-27 | Dow Global Technologies Inc. | Electronic device module comprising an ethylene multi-block copolymer |
| US7465769B2 (en) | 2006-10-09 | 2008-12-16 | Dow Global Technologies Inc. | Nitroxide compounds for minimizing scorch in crosslinkable compositions |
| JP5407877B2 (ja) * | 2010-01-08 | 2014-02-05 | 日油株式会社 | エチレン−酢酸ビニル共重合体組成物及び架橋物 |
| JP2013528241A (ja) | 2010-05-26 | 2013-07-08 | ダウ グローバル テクノロジーズ エルエルシー | 低不飽和および任意のビニルシランを有するポリオレフィンコポリマーを含む電子素子モジュール |
| WO2011153540A1 (en) | 2010-06-04 | 2011-12-08 | Dow Global Technologies Llc | Electronic device module comprising film of homogeneous polyolefin copolymer and adhesive property enhancing graft polymer |
| BR112012030650A2 (pt) | 2010-06-04 | 2016-08-16 | Dow Global Technologies Llc | módulo de dispositivo eletrônico compreendendo película de copolímero de poliolefina homogêneo e silano enxertado |
| US20130087199A1 (en) | 2010-06-24 | 2013-04-11 | John A. Naumovitz | Electronic Device Module Comprising Long Chain Branched (LCB), Block or Interconnected Copolymers of Ethylene and Optionally Silane |
| JP2013533623A (ja) | 2010-06-24 | 2013-08-22 | ダウ グローバル テクノロジーズ エルエルシー | エチレンの長鎖分岐した（ｌｃｂ）、ブロック、または相互接続されたコポリマー、および場合によってはシランを含む電子素子モジュール |
| JP6170948B2 (ja) | 2012-02-03 | 2017-07-26 | ダウ グローバル テクノロジーズ エルエルシー | フィルムを含むシラン含有エチレンインターポリマー配合物及びそれを含む電子デバイスモジュール |
| US9388296B2 (en) | 2012-06-04 | 2016-07-12 | National Institute Of Clean-And-Low-Carbon Energy | Crosslinked polyethylene composition having improved processability |
| US9617356B2 (en) | 2012-06-13 | 2017-04-11 | National Institute Of Clean-And-Low-Carbon Energy | Crosslinked polyethylene composition |
| EP3048649A1 (en) | 2015-01-23 | 2016-07-27 | Yparex B.V. | Electronic device module |
| JP2022142499A (ja) * | 2021-03-16 | 2022-09-30 | Ｍｃｐｐイノベーション合同会社 | 熱可塑性エラストマー組成物、成形体及びエアバック収納カバー |
| CN116891601B (zh) * | 2023-07-12 | 2025-07-08 | 浙江瑞堂塑料科技有限公司 | 一种滚塑成型哑铃片用聚烯烃复合材料及其应用 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL225045A (cg-RX-API-DMAC7.html) * | 1957-04-29 | |||
| US3661877A (en) * | 1970-05-21 | 1972-05-09 | Reichhold Chemicals Inc | Polymeric compositions and method of preparation |
-
1975
- 1975-10-21 CA CA238,088A patent/CA1047696A/en not_active Expired
- 1975-11-26 BE BE162190A patent/BE835962A/xx not_active IP Right Cessation
- 1975-11-26 IN IN2260/CAL/75A patent/IN143890B/en unknown
- 1975-11-26 NL NL7513803A patent/NL7513803A/xx not_active Application Discontinuation
- 1975-11-26 AU AU86952/75A patent/AU508623B2/en not_active Expired
- 1975-11-26 BR BR7507820*A patent/BR7507820A/pt unknown
- 1975-11-26 GB GB48550/75A patent/GB1535039A/en not_active Expired
- 1975-11-26 JP JP50140867A patent/JPS5177644A/ja active Pending
- 1975-11-26 DE DE2553094A patent/DE2553094B2/de not_active Withdrawn
- 1975-11-26 IT IT29672/75A patent/IT1054913B/it active
- 1975-11-26 FR FR7536196A patent/FR2292735A1/fr active Granted
- 1975-11-26 SE SE7513320A patent/SE408906B/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5177644A (cg-RX-API-DMAC7.html) | 1976-07-06 |
| BR7507820A (pt) | 1976-08-10 |
| GB1535039A (en) | 1978-12-06 |
| FR2292735A1 (fr) | 1976-06-25 |
| NL7513803A (nl) | 1976-05-31 |
| DE2553094A1 (de) | 1976-08-12 |
| CA1047696A (en) | 1979-01-30 |
| SE7513320L (sv) | 1976-05-28 |
| IN143890B (cg-RX-API-DMAC7.html) | 1978-02-18 |
| AU8695275A (en) | 1977-06-02 |
| BE835962A (fr) | 1976-05-26 |
| SE408906B (sv) | 1979-07-16 |
| IT1054913B (it) | 1981-11-30 |
| AU508623B2 (en) | 1980-03-27 |
| FR2292735B1 (cg-RX-API-DMAC7.html) | 1980-02-08 |
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