DE2523991C2 - - Google Patents
Info
- Publication number
- DE2523991C2 DE2523991C2 DE2523991A DE2523991A DE2523991C2 DE 2523991 C2 DE2523991 C2 DE 2523991C2 DE 2523991 A DE2523991 A DE 2523991A DE 2523991 A DE2523991 A DE 2523991A DE 2523991 C2 DE2523991 C2 DE 2523991C2
- Authority
- DE
- Germany
- Prior art keywords
- molecular weight
- catalyst
- average molecular
- branched
- polyamide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 92
- 239000003054 catalyst Substances 0.000 claims description 57
- 239000004952 Polyamide Substances 0.000 claims description 54
- 229920002647 polyamide Polymers 0.000 claims description 54
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 43
- 238000000034 method Methods 0.000 claims description 28
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 23
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims description 18
- 229920000642 polymer Polymers 0.000 claims description 14
- 239000011541 reaction mixture Substances 0.000 claims description 14
- 125000001931 aliphatic group Chemical group 0.000 claims description 11
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 6
- 229920001400 block copolymer Polymers 0.000 claims description 5
- 238000001125 extrusion Methods 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 2
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 claims description 2
- 238000007493 shaping process Methods 0.000 claims 2
- 239000000047 product Substances 0.000 description 54
- -1 aliphatic dicarboxylic acids Chemical class 0.000 description 35
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 30
- 238000006243 chemical reaction Methods 0.000 description 24
- 238000002474 experimental method Methods 0.000 description 24
- 238000006068 polycondensation reaction Methods 0.000 description 19
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 16
- 239000001361 adipic acid Substances 0.000 description 15
- 235000011037 adipic acid Nutrition 0.000 description 15
- 238000004519 manufacturing process Methods 0.000 description 15
- 238000002844 melting Methods 0.000 description 14
- 230000008018 melting Effects 0.000 description 14
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 10
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 10
- YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 229920000570 polyether Polymers 0.000 description 8
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 8
- GUOSQNAUYHMCRU-UHFFFAOYSA-N 11-Aminoundecanoic acid Chemical compound NCCCCCCCCCCC(O)=O GUOSQNAUYHMCRU-UHFFFAOYSA-N 0.000 description 7
- 239000004721 Polyphenylene oxide Substances 0.000 description 7
- 150000002009 diols Chemical class 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 239000000654 additive Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 229920001451 polypropylene glycol Polymers 0.000 description 6
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000011261 inert gas Substances 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 150000005690 diesters Chemical class 0.000 description 4
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 4
- 229920006146 polyetheresteramide block copolymer Polymers 0.000 description 4
- SYXYWTXQFUUWLP-UHFFFAOYSA-N sodium;butan-1-olate Chemical compound [Na+].CCCC[O-] SYXYWTXQFUUWLP-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000002430 hydrocarbons Chemical group 0.000 description 3
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 3
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 3
- 238000005809 transesterification reaction Methods 0.000 description 3
- PBLZLIFKVPJDCO-UHFFFAOYSA-N 12-aminododecanoic acid Chemical compound NCCCCCCCCCCCC(O)=O PBLZLIFKVPJDCO-UHFFFAOYSA-N 0.000 description 2
- GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000002841 Lewis acid Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 2
- 125000005521 carbonamide group Chemical group 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 150000003951 lactams Chemical class 0.000 description 2
- 150000007517 lewis acids Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- 229910015900 BF3 Inorganic materials 0.000 description 1
- 101100296543 Caenorhabditis elegans pbo-4 gene Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001408 amides Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- CJYXCQLOZNIMFP-UHFFFAOYSA-N azocan-2-one Chemical compound O=C1CCCCCCN1 CJYXCQLOZNIMFP-UHFFFAOYSA-N 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000007799 cork Substances 0.000 description 1
- IKKDOVDKPZJAGM-UHFFFAOYSA-N decanedioate;dihexylazanium Chemical compound CCCCCC[NH2+]CCCCCC.CCCCCC[NH2+]CCCCCC.[O-]C(=O)CCCCCCCCC([O-])=O IKKDOVDKPZJAGM-UHFFFAOYSA-N 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000003827 glycol group Chemical group 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 229940100630 metacresol Drugs 0.000 description 1
- PXSXRABJBXYMFT-UHFFFAOYSA-N n-hexylhexan-1-amine Chemical compound CCCCCCNCCCCCC PXSXRABJBXYMFT-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- SXJVFQLYZSNZBT-UHFFFAOYSA-N nonane-1,9-diamine Chemical compound NCCCCCCCCCN SXJVFQLYZSNZBT-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 229920006301 statistical copolymer Polymers 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/44—Polyester-amides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
- Polyesters Or Polycarbonates (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Artificial Filaments (AREA)
- Polyethers (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2560680A DE2560680C2 (de) | 1974-05-31 | 1975-05-30 | Verform- oder extrudierbare Polyether-Ester-Amid-Blockmischpolymere |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7418913A FR2273021B1 (en, 2012) | 1974-05-31 | 1974-05-31 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2523991A1 DE2523991A1 (de) | 1975-12-18 |
| DE2523991C2 true DE2523991C2 (en, 2012) | 1988-07-07 |
Family
ID=9139505
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19752523991 Granted DE2523991A1 (de) | 1974-05-31 | 1975-05-30 | Verfahren zur herstellung von polyaether-ester-amid-blockmischpolymerisaten als verformbare oder extrudierbare produkte |
Country Status (16)
| Country | Link |
|---|---|
| US (2) | US4230838A (en, 2012) |
| JP (1) | JPS5645419B2 (en, 2012) |
| AR (1) | AR214388A1 (en, 2012) |
| BE (1) | BE829700A (en, 2012) |
| BR (1) | BR7503436A (en, 2012) |
| CH (1) | CH606194A5 (en, 2012) |
| CS (1) | CS192544B2 (en, 2012) |
| DD (1) | DD120036A5 (en, 2012) |
| DE (1) | DE2523991A1 (en, 2012) |
| FR (1) | FR2273021B1 (en, 2012) |
| GB (1) | GB1473972A (en, 2012) |
| IT (1) | IT1038574B (en, 2012) |
| LU (1) | LU72615A1 (en, 2012) |
| MX (1) | MX3162E (en, 2012) |
| NL (1) | NL173654C (en, 2012) |
| SE (1) | SE422805B (en, 2012) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023099349A1 (de) | 2021-11-30 | 2023-06-08 | Covestro Deutschland Ag | Besondere kunststofffolie für die herstellung von sicherheitsdokumenten |
Families Citing this family (246)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2273021B1 (en, 2012) * | 1974-05-31 | 1977-03-11 | Ato Chimie | |
| US4195015A (en) | 1976-07-30 | 1980-03-25 | Ato Chimie | Heat and aging stable copolyetheresteramides and method of manufacturing same |
| FR2378058A1 (fr) | 1977-01-24 | 1978-08-18 | Ato Chimie | Copolyetheresteramides stables a l'hydrolyse |
| DE2712987C2 (de) | 1977-03-24 | 1981-09-24 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur Herstellung von thermoplastischen Polyetheresteramiden mit statistisch in der Polymerkette verteilten Einheiten der Ausgangskomponenten |
| DE2716004C3 (de) * | 1977-04-09 | 1987-01-22 | Hüls AG, 4370 Marl | Thermoplastische Formmassen auf der Basis von Polylaurinlactam und deren Verwendung zur Herstellung von Rohren |
| FR2401947A1 (fr) | 1977-09-02 | 1979-03-30 | Ato Chimie | Procede de preparation de polyether-ester-amides sequences utilisables, entre autres, comme produits a mouler, a extruder ou a filer |
| FR2413417A1 (fr) * | 1977-12-30 | 1979-07-27 | Ato Chimie | Procede de synthese en continu de copolycondensats sequences poly(ether-ester-amide) |
| FR2418250A1 (fr) * | 1978-02-24 | 1979-09-21 | Ato Chimie | Enveloppe en matiere polymere thermoplastique pour balles de golf et balles de golf comportant une telle enveloppe |
| JPS5577234U (en, 2012) * | 1978-11-22 | 1980-05-28 | ||
| FR2447941A2 (fr) * | 1979-02-01 | 1980-08-29 | Ato Chimie | Procede de synthese en continu de copolycondensats sequences poly (ether-ester-amide) |
| DE2930343A1 (de) * | 1979-07-26 | 1981-02-19 | Huels Chemische Werke Ag | Formmasse aus einem hochmolekularen linearen polyester |
| DE2932234C2 (de) | 1979-08-09 | 1982-01-28 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur Herstellung von Polyether(ester)amiden |
| DE2936976C2 (de) * | 1979-09-13 | 1986-09-18 | Hüls AG, 4370 Marl | Verfahren zur Herstellung von Polyether(ester)amiden |
| DE2936977C2 (de) | 1979-09-13 | 1986-06-12 | Hüls AG, 4370 Marl | Verfahren zur Herstellung von Polyether(ester)amiden |
| FR2466478B2 (fr) * | 1979-10-02 | 1986-03-14 | Ato Chimie | Procede de preparation de copolyetheresteramides aliphatiques elastomeres |
| DE2949064C2 (de) * | 1979-12-06 | 1985-10-31 | Chemische Werke Hüls AG, 4370 Marl | Verwendung von Copolyetheresteramiden als Schmelzkleber zum Heißsiegeln von Textilien |
| US4346024A (en) * | 1979-12-10 | 1982-08-24 | Rhone-Poulenc Industries | Heat-stable polyphase polyamide/polyesteramide compositions |
| US4288647A (en) * | 1980-03-10 | 1981-09-08 | Mobil Oil Corporation | Shape selective reactions with alkaline earth-modified zeolite catalysts |
| JPS5790017A (en) * | 1980-11-25 | 1982-06-04 | Toray Ind Inc | Production of polyether-ester-amide |
| FR2497518A1 (fr) * | 1981-01-05 | 1982-07-09 | Ato Chimie | Compositions adhesives thermofusibles a base de copolyetheramides sequences |
| JPS58117537A (ja) * | 1982-01-06 | 1983-07-13 | Toray Ind Inc | 感光性樹脂組成物 |
| FR2533577B1 (fr) * | 1982-09-27 | 1986-02-28 | Norton Sa | Compositions thermoplastiques adhesives |
| EP0108491B1 (en) * | 1982-10-01 | 1987-08-12 | Raychem Limited | Electric wire with flame retarded cladding |
| JPS59202220A (ja) * | 1983-05-02 | 1984-11-16 | Mitsui Petrochem Ind Ltd | 共重合ポリアミドの製法 |
| JPS59207930A (ja) * | 1983-05-13 | 1984-11-26 | Toray Ind Inc | ポリアミドエラストマの製造方法 |
| US4617235A (en) * | 1983-05-23 | 1986-10-14 | Unitika Ltd. | Antistatic synthetic fibers |
| JPS608322A (ja) * | 1983-06-29 | 1985-01-17 | Toray Ind Inc | 親水性のポリアミドエラストマ |
| CH658062A5 (de) * | 1983-08-04 | 1986-10-15 | Inventa Ag | Verfahren zur herstellung von blockpolyetheresteramiden. |
| CH658063A5 (de) * | 1983-08-05 | 1986-10-15 | Inventa Ag | Verfahren zur herstellung von hydrolysestabilen blockpolyetheresteramiden. |
| JPS60110724A (ja) * | 1983-11-18 | 1985-06-17 | Daicel Chem Ind Ltd | ポリエ−テルエステルアミドの製造方法 |
| US4556705A (en) * | 1984-10-26 | 1985-12-03 | General Electric Company | Thermoplastic polyetherimide ester elastomers |
| US4556688A (en) * | 1984-10-26 | 1985-12-03 | General Electric Company | Thermoplastic polyetherimide ester elastomers |
| US4544734A (en) * | 1984-10-26 | 1985-10-01 | General Electric Company | Modified thermoplastic copolyetherimide ester elastomers |
| US4594377A (en) * | 1984-10-26 | 1986-06-10 | General Electric Company | Modified thermoplastic copolyetherimide ester elastomers |
| US4873292A (en) * | 1984-12-28 | 1989-10-10 | Research Development Corporation Of Japan | Antithrombogenic synthetic polymer and process for its preparation |
| JPS61155426A (ja) * | 1984-12-28 | 1986-07-15 | Res Dev Corp Of Japan | 抗血栓性を有する医療用材 |
| US4598117A (en) * | 1985-01-11 | 1986-07-01 | General Electric Company | Elastomeric compositions comprising a combination of (a) an aromatic thermoplastic polyester and (b) clay/syenite |
| CH662356A5 (fr) * | 1985-04-04 | 1987-09-30 | Firmenich & Cie | Article pour la diffusion de vapeurs assaississantes a base de resine polyamide et polyether. |
| JPH0672181B2 (ja) | 1985-09-25 | 1994-09-14 | 旭化成工業株式会社 | 透明なポリアミドエラストマ− |
| JPH0672182B2 (ja) | 1985-10-30 | 1994-09-14 | 旭化成工業株式会社 | ポリアミドエラストマ− |
| EP0221188B1 (en) * | 1985-04-26 | 1992-04-01 | Asahi Kasei Kogyo Kabushiki Kaisha | Transparent polyamide elastomer |
| US4698242A (en) * | 1985-08-12 | 1987-10-06 | National Starch And Chemical Corporation | Thermoplastic elastic adhesive containing polyether block amides |
| US4970274A (en) * | 1988-09-30 | 1990-11-13 | Allied-Signal Inc. | Nylon compositions with superior film properties and impact strength |
| US4899521A (en) * | 1986-10-14 | 1990-02-13 | W. R. Grace & Co. - Conn. | Antistatic thermoplastic/polyamide-polyether compositions and antistatic polymeric films made therefrom |
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| US2925405A (en) * | 1955-04-26 | 1960-02-16 | Eastman Kodak Co | Linear polyesters containing an alkylene diamine group and manufacture thereof |
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| FR2273021B1 (en, 2012) * | 1974-05-31 | 1977-03-11 | Ato Chimie | |
| GB1588526A (en) * | 1976-07-21 | 1981-04-23 | Anic Spa | Elastomeric copolyesteramides |
-
1974
- 1974-05-31 FR FR7418913A patent/FR2273021B1/fr not_active Expired
-
1975
- 1975-05-23 GB GB2272575A patent/GB1473972A/en not_active Expired
- 1975-05-29 JP JP6479075A patent/JPS5645419B2/ja not_active Expired
- 1975-05-30 CH CH701725A patent/CH606194A5/xx not_active IP Right Cessation
- 1975-05-30 SE SE7506234A patent/SE422805B/xx not_active IP Right Cessation
- 1975-05-30 BE BE156875A patent/BE829700A/xx not_active IP Right Cessation
- 1975-05-30 IT IT23869/75A patent/IT1038574B/it active
- 1975-05-30 DE DE19752523991 patent/DE2523991A1/de active Granted
- 1975-05-30 NL NLAANVRAGE7506488,A patent/NL173654C/xx not_active IP Right Cessation
- 1975-05-30 DD DD186364A patent/DD120036A5/xx unknown
- 1975-05-30 CS CS753812A patent/CS192544B2/cs unknown
- 1975-05-30 BR BR4400/75D patent/BR7503436A/pt unknown
- 1975-05-30 AR AR259017A patent/AR214388A1/es active
- 1975-05-30 LU LU72615A patent/LU72615A1/xx unknown
- 1975-06-02 MX MX100232U patent/MX3162E/es unknown
-
1978
- 1978-10-03 US US05/948,297 patent/US4230838A/en not_active Expired - Lifetime
-
1980
- 1980-05-16 US US06/150,288 patent/US4332920A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023099349A1 (de) | 2021-11-30 | 2023-06-08 | Covestro Deutschland Ag | Besondere kunststofffolie für die herstellung von sicherheitsdokumenten |
Also Published As
| Publication number | Publication date |
|---|---|
| NL173654B (nl) | 1983-09-16 |
| CH606194A5 (en, 2012) | 1978-10-31 |
| DE2523991A1 (de) | 1975-12-18 |
| US4230838A (en) | 1980-10-28 |
| JPS5645419B2 (en, 2012) | 1981-10-26 |
| AR214388A1 (es) | 1979-06-15 |
| BR7503436A (pt) | 1976-05-25 |
| SE7506234L (sv) | 1975-12-01 |
| NL7506488A (nl) | 1975-12-02 |
| MX3162E (es) | 1980-05-27 |
| FR2273021A1 (en, 2012) | 1975-12-26 |
| GB1473972A (en) | 1977-05-18 |
| IT1038574B (it) | 1979-11-30 |
| CS192544B2 (en) | 1979-08-31 |
| BE829700A (fr) | 1975-09-15 |
| NL173654C (nl) | 1984-02-16 |
| FR2273021B1 (en, 2012) | 1977-03-11 |
| LU72615A1 (en, 2012) | 1975-10-08 |
| DD120036A5 (en, 2012) | 1976-05-20 |
| US4332920A (en) | 1982-06-01 |
| JPS50159586A (en, 2012) | 1975-12-24 |
| SE422805B (sv) | 1982-03-29 |
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