DE2450251C2 - Verwendung von Substanzen zur Inhibition der Selbstentzündlichkeit bei Phosphorwasserstoff entwickelnden Phosphiden - Google Patents
Verwendung von Substanzen zur Inhibition der Selbstentzündlichkeit bei Phosphorwasserstoff entwickelnden PhosphidenInfo
- Publication number
- DE2450251C2 DE2450251C2 DE2450251A DE2450251A DE2450251C2 DE 2450251 C2 DE2450251 C2 DE 2450251C2 DE 2450251 A DE2450251 A DE 2450251A DE 2450251 A DE2450251 A DE 2450251A DE 2450251 C2 DE2450251 C2 DE 2450251C2
- Authority
- DE
- Germany
- Prior art keywords
- phosphides
- phosphide
- substances
- self
- hydrolysis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000126 substance Substances 0.000 title claims description 20
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 title claims description 14
- 230000007062 hydrolysis Effects 0.000 claims description 18
- 238000006460 hydrolysis reaction Methods 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 229910052698 phosphorus Inorganic materials 0.000 claims description 7
- 239000011574 phosphorus Substances 0.000 claims description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 6
- -1 aromatic carboxylic acids Chemical class 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 239000012876 carrier material Substances 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 150000001735 carboxylic acids Chemical class 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 238000000354 decomposition reaction Methods 0.000 claims description 4
- 230000005764 inhibitory process Effects 0.000 claims description 4
- 241000607479 Yersinia pestis Species 0.000 claims description 3
- 230000000694 effects Effects 0.000 claims description 3
- 230000008020 evaporation Effects 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 3
- 229910000073 phosphorus hydride Inorganic materials 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 206010061218 Inflammation Diseases 0.000 claims description 2
- 239000005953 Magnesium phosphide Substances 0.000 claims description 2
- 230000004054 inflammatory process Effects 0.000 claims description 2
- 239000002808 molecular sieve Substances 0.000 claims description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 230000015572 biosynthetic process Effects 0.000 claims 2
- 239000002360 explosive Substances 0.000 claims 2
- 238000004806 packaging method and process Methods 0.000 claims 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- BVCZEBOGSOYJJT-UHFFFAOYSA-N ammonium carbamate Chemical compound [NH4+].NC([O-])=O BVCZEBOGSOYJJT-UHFFFAOYSA-N 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical class [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 claims 1
- VSFYIPJGGXNVQM-UHFFFAOYSA-M azanium sodium hydrogen carbonate Chemical compound [NH4+].[Na+].OC([O-])=O.OC([O-])=O VSFYIPJGGXNVQM-UHFFFAOYSA-M 0.000 claims 1
- 239000004202 carbamide Substances 0.000 claims 1
- 239000001569 carbon dioxide Substances 0.000 claims 1
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 claims 1
- 230000007423 decrease Effects 0.000 claims 1
- 230000007812 deficiency Effects 0.000 claims 1
- 230000003111 delayed effect Effects 0.000 claims 1
- 230000001419 dependent effect Effects 0.000 claims 1
- 238000010494 dissociation reaction Methods 0.000 claims 1
- 230000005593 dissociations Effects 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 claims 1
- 239000002316 fumigant Substances 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 230000002209 hydrophobic effect Effects 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 230000000361 pesticidal effect Effects 0.000 claims 1
- 150000003018 phosphorus compounds Chemical class 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 238000004080 punching Methods 0.000 claims 1
- 230000036632 reaction speed Effects 0.000 claims 1
- 239000005871 repellent Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 239000005060 rubber Substances 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 229920002545 silicone oil Polymers 0.000 claims 1
- 230000002269 spontaneous effect Effects 0.000 claims 1
- 238000006467 substitution reaction Methods 0.000 claims 1
- 229920003051 synthetic elastomer Polymers 0.000 claims 1
- 229920003002 synthetic resin Polymers 0.000 claims 1
- 239000000057 synthetic resin Substances 0.000 claims 1
- 239000005061 synthetic rubber Substances 0.000 claims 1
- 239000012855 volatile organic compound Substances 0.000 claims 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 8
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 239000005711 Benzoic acid Substances 0.000 description 4
- 235000010233 benzoic acid Nutrition 0.000 description 4
- 230000002401 inhibitory effect Effects 0.000 description 4
- 238000000465 moulding Methods 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- IHGSAQHSAGRWNI-UHFFFAOYSA-N 1-(4-bromophenyl)-2,2,2-trifluoroethanone Chemical compound FC(F)(F)C(=O)C1=CC=C(Br)C=C1 IHGSAQHSAGRWNI-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000009089 cytolysis Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003574 free electron Substances 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 231100000683 possible toxicity Toxicity 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/06—Hydrogen phosphides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/26—Phosphorus; Compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DD174681A DD112744A1 (enrdf_load_stackoverflow) | 1973-11-14 | 1973-11-14 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2450251A1 DE2450251A1 (de) | 1975-05-15 |
| DE2450251C2 true DE2450251C2 (de) | 1985-10-31 |
Family
ID=5493477
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2450251A Expired DE2450251C2 (de) | 1973-11-14 | 1974-10-23 | Verwendung von Substanzen zur Inhibition der Selbstentzündlichkeit bei Phosphorwasserstoff entwickelnden Phosphiden |
Country Status (7)
| Country | Link |
|---|---|
| CA (1) | CA1048770A (enrdf_load_stackoverflow) |
| DD (1) | DD112744A1 (enrdf_load_stackoverflow) |
| DE (1) | DE2450251C2 (enrdf_load_stackoverflow) |
| HU (1) | HU171099B (enrdf_load_stackoverflow) |
| IN (1) | IN143060B (enrdf_load_stackoverflow) |
| MX (1) | MX3309E (enrdf_load_stackoverflow) |
| SU (1) | SU643426A1 (enrdf_load_stackoverflow) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2729887A1 (de) * | 1977-07-01 | 1979-01-18 | Freyberg Chem Fab Werner | Schaedlingsbekaempfungsmittel und verfahren zu dessen herstellung |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL84858C (enrdf_load_stackoverflow) * | 1952-07-02 | |||
| DE923006C (de) * | 1952-07-02 | 1955-01-31 | Degussa | Verfahren zur Unterdrueckung der Selbstentzuendlichkeit von Phosphiden der Alkalien,Erdalkalien oder Erdmetalle und von aus diesen entwickeltem Phosphorwasserstoff |
| DE1023265B (de) * | 1955-11-16 | 1958-01-23 | Freyberg Werner | Verfahren zur Unterdrueckung der Selbstentzuendlichkeit von Phosphiden der Alkalien, Erdalkalien oder Erdmetallen und zur Regulierung der Bildungs-geschwindigkeit der aus diesen entwickelten Phosphorwasserstoffen, insbesondere bei deren Verwendung zur Bekaempfung von Schaedlingen |
| DE1155631B (de) * | 1959-04-01 | 1963-10-10 | Freyberg Werner | Mittel zur Bekaempfung von Insekten und Nagetieren |
| BE596141A (enrdf_load_stackoverflow) * | 1960-03-31 | 1900-01-01 | ||
| DE1567520B2 (de) * | 1966-04-07 | 1973-01-04 | Freyberg, Werner, Dr., 6149 Kirschhausen | Verfahren zur Herstellung von Magnesiumphosphid |
-
1973
- 1973-11-14 DD DD174681A patent/DD112744A1/xx unknown
-
1974
- 1974-10-23 DE DE2450251A patent/DE2450251C2/de not_active Expired
- 1974-11-11 HU HU74DE00000869A patent/HU171099B/hu unknown
- 1974-11-13 SU SU742075401A patent/SU643426A1/ru active
- 1974-11-13 MX MX100220U patent/MX3309E/es unknown
- 1974-11-13 CA CA74213615A patent/CA1048770A/en not_active Expired
-
1975
- 1975-01-02 IN IN16/CAL/75A patent/IN143060B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| MX3309E (es) | 1980-09-09 |
| HU171099B (hu) | 1977-11-28 |
| IN143060B (enrdf_load_stackoverflow) | 1977-09-24 |
| DE2450251A1 (de) | 1975-05-15 |
| DD112744A1 (enrdf_load_stackoverflow) | 1975-05-05 |
| CA1048770A (en) | 1979-02-20 |
| SU643426A1 (ru) | 1979-01-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OD | Request for examination | ||
| 8181 | Inventor (new situation) |
Free format text: WOLF, FRIEDRICH, PROF. DR.DR., DDR 7031 LEIPZIG, DD HERRMANN, ROLF, DIPL.-CHEM. KRETZSCHMAR, KARLHEINZ, DIPL.-BIOL. DR., DDR 7270 DELITZSCH, DD |
|
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |