DE2436180C2 - - Google Patents
Info
- Publication number
- DE2436180C2 DE2436180C2 DE2436180A DE2436180A DE2436180C2 DE 2436180 C2 DE2436180 C2 DE 2436180C2 DE 2436180 A DE2436180 A DE 2436180A DE 2436180 A DE2436180 A DE 2436180A DE 2436180 C2 DE2436180 C2 DE 2436180C2
- Authority
- DE
- Germany
- Prior art keywords
- silver halide
- chloride
- silver
- iodide
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052709 silver Inorganic materials 0.000 claims description 57
- 239000004332 silver Substances 0.000 claims description 57
- -1 silver halide Chemical class 0.000 claims description 54
- 239000000839 emulsion Substances 0.000 claims description 53
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 13
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 10
- PKCHODKZKBAVIJ-UHFFFAOYSA-L chloro(iodo)silver Chemical compound Cl[Ag]I PKCHODKZKBAVIJ-UHFFFAOYSA-L 0.000 claims description 6
- IEIREBQISNYNTN-UHFFFAOYSA-K [Ag](I)(Br)Cl Chemical class [Ag](I)(Br)Cl IEIREBQISNYNTN-UHFFFAOYSA-K 0.000 claims description 5
- 238000009792 diffusion process Methods 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 238000006467 substitution reaction Methods 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims 1
- 239000000243 solution Substances 0.000 description 55
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 24
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 21
- 108010010803 Gelatin Proteins 0.000 description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 239000008273 gelatin Substances 0.000 description 18
- 229920000159 gelatin Polymers 0.000 description 18
- 235000019322 gelatine Nutrition 0.000 description 18
- 235000011852 gelatine desserts Nutrition 0.000 description 18
- 238000009826 distribution Methods 0.000 description 13
- 239000000203 mixture Substances 0.000 description 12
- 239000001103 potassium chloride Substances 0.000 description 12
- 235000011164 potassium chloride Nutrition 0.000 description 12
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 12
- 239000012153 distilled water Substances 0.000 description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 8
- 230000035945 sensitivity Effects 0.000 description 8
- 229910021607 Silver chloride Inorganic materials 0.000 description 7
- 239000006185 dispersion Substances 0.000 description 7
- 150000004820 halides Chemical class 0.000 description 7
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 7
- 210000000988 bone and bone Anatomy 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 229910001961 silver nitrate Inorganic materials 0.000 description 6
- 230000003595 spectral effect Effects 0.000 description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 4
- 230000029087 digestion Effects 0.000 description 4
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 4
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 3
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 3
- 206010070834 Sensitisation Diseases 0.000 description 3
- 229910021612 Silver iodide Inorganic materials 0.000 description 3
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical group CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 230000008313 sensitization Effects 0.000 description 3
- 229940045105 silver iodide Drugs 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000006228 supernatant Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IWNXTHHGHAJPDT-UHFFFAOYSA-K N.[Au+3].[S-]C#N.[S-]C#N.[S-]C#N Chemical compound N.[Au+3].[S-]C#N.[S-]C#N.[S-]C#N IWNXTHHGHAJPDT-UHFFFAOYSA-K 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- SOIFLUNRINLCBN-UHFFFAOYSA-N ammonium thiocyanate Chemical compound [NH4+].[S-]C#N SOIFLUNRINLCBN-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- OIPQUBBCOVJSNS-UHFFFAOYSA-L bromo(iodo)silver Chemical compound Br[Ag]I OIPQUBBCOVJSNS-UHFFFAOYSA-L 0.000 description 2
- FDWREHZXQUYJFJ-UHFFFAOYSA-M gold monochloride Chemical compound [Cl-].[Au+] FDWREHZXQUYJFJ-UHFFFAOYSA-M 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 230000001235 sensitizing effect Effects 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-LZFNBGRKSA-N Potassium-45 Chemical compound [45K] ZLMJMSJWJFRBEC-LZFNBGRKSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001649 bromium compounds Chemical group 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 238000000635 electron micrograph Methods 0.000 description 1
- 229940082150 encore Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/02—Photosensitive materials characterised by the image-forming section
- G03C8/04—Photosensitive materials characterised by the image-forming section the substances transferred by diffusion consisting of inorganic or organo-metallic compounds derived from photosensitive noble metals
- G03C8/06—Silver salt diffusion transfer
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/015—Apparatus or processes for the preparation of emulsions
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/035—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein characterised by the crystal form or composition, e.g. mixed grain
- G03C2001/03523—Converted grains
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/035—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein characterised by the crystal form or composition, e.g. mixed grain
- G03C2001/03594—Size of the grains
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/383,177 US4165986A (en) | 1973-07-27 | 1973-07-27 | Substituted-halide silver halide emulsions and products containing same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2436180A1 DE2436180A1 (de) | 1975-02-13 |
| DE2436180C2 true DE2436180C2 (en, 2012) | 1988-02-25 |
Family
ID=23512037
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2436180A Granted DE2436180A1 (de) | 1973-07-27 | 1974-07-26 | Silberhalogenidemulsionen mit substituiertem halogenid und produkte, die diese emulsionen enthalten |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4165986A (en, 2012) |
| JP (1) | JPS5857730B2 (en, 2012) |
| BE (1) | BE818180A (en, 2012) |
| CA (1) | CA1033977A (en, 2012) |
| DE (1) | DE2436180A1 (en, 2012) |
| FR (1) | FR2238949B1 (en, 2012) |
| GB (1) | GB1477901A (en, 2012) |
| IT (1) | IT1016958B (en, 2012) |
| NL (1) | NL181462C (en, 2012) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2534011A1 (de) * | 1975-07-30 | 1977-02-17 | Agfa Gevaert Ag | Verfahren zur herstellung von silberhalogenidemulsionen |
| DE2828112A1 (de) * | 1978-06-27 | 1980-01-10 | Agfa Gevaert Ag | Lichtempfindliches photographisches material |
| DE2932650C2 (de) * | 1979-08-11 | 1982-03-11 | Du Pont de Nemours (Deutschland) GmbH, 4000 Düsseldorf | Verfahren zur Herstellung einer monodispersen photographischen Silberhalogenidemulsion |
| US4433048A (en) * | 1981-11-12 | 1984-02-21 | Eastman Kodak Company | Radiation-sensitive silver bromoiodide emulsions, photographic elements, and processes for their use |
| US4565778A (en) * | 1983-03-31 | 1986-01-21 | Konishiroku Photo Industry Co., Ltd. | Silver halide photographic materials |
| DE3562429D1 (en) * | 1985-01-15 | 1988-06-01 | Agfa Gevaert Nv | Method and material for the production of continuous tone silver images by the silver complex diffusion transfer reversal process |
| JPS61152943U (en, 2012) * | 1985-03-14 | 1986-09-22 | ||
| US5326668A (en) * | 1990-11-01 | 1994-07-05 | Fuji Photo Film Co., Ltd. | Method of image formation by silver salt diffusion transfer |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE522766C (de) * | 1929-08-12 | 1931-04-14 | Albert Steigmann Dr | Verfahren zur Herstellung gruen entwickelbarer photographischer Silbersalzemulsionen |
| DE505012C (de) * | 1929-08-12 | 1930-08-12 | Albert Steigmann Dr | Verfahren zur Herstellung gruen entwickelbarer photographischer Jodsilberemulsionen |
| DE616113C (de) * | 1931-12-18 | 1935-07-19 | I G Farbenindustrie Akt Ges | Verfahren zur Verbesserung der Empfindlichkeit von gruen entwickelbaren Jodsilberemulsionen |
| GB635841A (en) * | 1947-05-13 | 1950-04-19 | Kodak Ltd | Improvements in photographic silver halide emulsions |
| BE639114A (en, 2012) * | 1962-10-25 | |||
| GB1150553A (en) * | 1965-04-30 | 1969-04-30 | Agfa Gevaert Nv | A Method of Producing Photographic Images |
| US3615579A (en) * | 1967-06-22 | 1971-10-26 | Du Pont | Process for making light-developable direct-writing silver halide emulsions containing rhodium or iridium |
| US3573055A (en) * | 1968-03-04 | 1971-03-30 | Eastman Kodak Co | Photodevelopable direct print compositions comprising iodocadmates in admixture with silver halides |
| US3622318A (en) * | 1970-03-20 | 1971-11-23 | Eastman Kodak Co | Photographic materials and processes |
| US3704126A (en) * | 1970-12-07 | 1972-11-28 | Polaroid Corp | Silver image stabilization with noble metal compounds |
| US3821000A (en) * | 1971-05-19 | 1974-06-28 | Polaroid Corp | Silver image stabilization with noble metal compounds and enediol developers |
| US3730716A (en) * | 1971-05-19 | 1973-05-01 | Polaroid Corp | Silver image stabilization with noble metal compounds and alpha,beta-enediol developer |
| US3782954A (en) * | 1971-11-01 | 1974-01-01 | Eastman Kodak Co | Method for the uniform preparation of silver halide grains |
-
1973
- 1973-07-27 US US05/383,177 patent/US4165986A/en not_active Expired - Lifetime
-
1974
- 1974-07-23 IT IT52232/74A patent/IT1016958B/it active
- 1974-07-25 JP JP49085588A patent/JPS5857730B2/ja not_active Expired
- 1974-07-25 NL NLAANVRAGE7410046,A patent/NL181462C/xx not_active IP Right Cessation
- 1974-07-25 GB GB3294774A patent/GB1477901A/en not_active Expired
- 1974-07-26 FR FR7426183A patent/FR2238949B1/fr not_active Expired
- 1974-07-26 BE BE7000549A patent/BE818180A/xx not_active IP Right Cessation
- 1974-07-26 DE DE2436180A patent/DE2436180A1/de active Granted
- 1974-07-26 CA CA205,763A patent/CA1033977A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL181462C (nl) | 1987-08-17 |
| NL7410046A (nl) | 1975-01-29 |
| AU7169974A (en) | 1976-01-29 |
| BE818180A (nl) | 1974-11-18 |
| GB1477901A (en) | 1977-06-29 |
| NL181462B (nl) | 1987-03-16 |
| JPS5857730B2 (ja) | 1983-12-21 |
| DE2436180A1 (de) | 1975-02-13 |
| JPS5045624A (en, 2012) | 1975-04-23 |
| FR2238949A1 (en, 2012) | 1975-02-21 |
| FR2238949B1 (en, 2012) | 1981-05-08 |
| IT1016958B (it) | 1977-06-20 |
| US4165986A (en) | 1979-08-28 |
| CA1033977A (en) | 1978-07-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition |