DE2217570A1 - Verfahren zum bleichfixieren von farbfotografischem material - Google Patents
Verfahren zum bleichfixieren von farbfotografischem materialInfo
- Publication number
- DE2217570A1 DE2217570A1 DE2217570A DE2217570A DE2217570A1 DE 2217570 A1 DE2217570 A1 DE 2217570A1 DE 2217570 A DE2217570 A DE 2217570A DE 2217570 A DE2217570 A DE 2217570A DE 2217570 A1 DE2217570 A1 DE 2217570A1
- Authority
- DE
- Germany
- Prior art keywords
- bleach
- silver
- fix
- bath
- fixing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims description 34
- 238000000034 method Methods 0.000 title claims description 24
- 229910052709 silver Inorganic materials 0.000 claims description 43
- 239000004332 silver Substances 0.000 claims description 43
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 38
- 230000001590 oxidative effect Effects 0.000 claims description 13
- 239000003638 chemical reducing agent Substances 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 9
- 239000007844 bleaching agent Substances 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 230000009467 reduction Effects 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 150000004696 coordination complex Chemical class 0.000 claims description 2
- 229910001385 heavy metal Inorganic materials 0.000 claims description 2
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 230000000536 complexating effect Effects 0.000 claims 1
- 238000012545 processing Methods 0.000 description 9
- 239000002351 wastewater Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 238000004061 bleaching Methods 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 230000008929 regeneration Effects 0.000 description 3
- 238000011069 regeneration method Methods 0.000 description 3
- -1 silver ions Chemical class 0.000 description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- 229940075397 calomel Drugs 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical compound Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000834 fixative Substances 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- JAWGVVJVYSANRY-UHFFFAOYSA-N cobalt(3+) Chemical compound [Co+3] JAWGVVJVYSANRY-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 229940017705 formaldehyde sulfoxylate Drugs 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 239000001046 green dye Substances 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- SBGKURINHGJRFN-UHFFFAOYSA-N hydroxymethanesulfinic acid Chemical compound OCS(O)=O SBGKURINHGJRFN-UHFFFAOYSA-N 0.000 description 1
- 239000000797 iron chelating agent Substances 0.000 description 1
- QTWZICCBKBYHDM-UHFFFAOYSA-N leucomethylene blue Chemical compound C1=C(N(C)C)C=C2SC3=CC(N(C)C)=CC=C3NC2=C1 QTWZICCBKBYHDM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000003716 rejuvenation Effects 0.000 description 1
- 238000010405 reoxidation reaction Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000003567 thiocyanates Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/42—Bleach-fixing or agents therefor ; Desilvering processes
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/26—Processes using silver-salt-containing photosensitive materials or agents therefor
- G03C5/395—Regeneration of photographic processing agents other than developers; Replenishers therefor
- G03C5/3958—Replenishment processes or compositions, i.e. addition of useful photographic processing agents
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03D—APPARATUS FOR PROCESSING EXPOSED PHOTOGRAPHIC MATERIALS; ACCESSORIES THEREFOR
- G03D3/00—Liquid processing apparatus involving immersion; Washing apparatus involving immersion
- G03D3/02—Details of liquid circulation
- G03D3/06—Liquid supply; Liquid circulation outside tanks
- G03D3/065—Liquid supply; Liquid circulation outside tanks replenishment or recovery apparatus
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Photographic Processing Devices Using Wet Methods (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2217570A DE2217570A1 (de) | 1972-04-12 | 1972-04-12 | Verfahren zum bleichfixieren von farbfotografischem material |
| BE1004950A BE797844A (nl) | 1972-04-12 | 1973-04-06 | Werkwijze voor het bleekfixeren van fotografisch kleurenmateriaal |
| US349229A US3879203A (en) | 1972-04-12 | 1973-04-09 | Process for bleach-fixing color photographic silver halide material |
| GB1760373A GB1427386A (en) | 1972-04-12 | 1973-04-12 | Process for bleach-fixing colour photographic silver halide material |
| JP48040924A JPS4911131A (US20080293856A1-20081127-C00139.png) | 1972-04-12 | 1973-04-12 | |
| FR7313323A FR2180052B3 (US20080293856A1-20081127-C00139.png) | 1972-04-12 | 1973-04-12 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2217570A DE2217570A1 (de) | 1972-04-12 | 1972-04-12 | Verfahren zum bleichfixieren von farbfotografischem material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2217570A1 true DE2217570A1 (de) | 1973-10-18 |
Family
ID=5841718
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2217570A Pending DE2217570A1 (de) | 1972-04-12 | 1972-04-12 | Verfahren zum bleichfixieren von farbfotografischem material |
Country Status (6)
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4211630A (en) * | 1974-06-26 | 1980-07-08 | Ciba-Geigy Ag | Electrolytic recovery of silver from photographic bleach-fix baths |
| US4065313A (en) * | 1976-06-11 | 1977-12-27 | Eastman Kodak Company | Bleach-fix regeneration monitoring method |
| JPS578543A (en) * | 1980-06-18 | 1982-01-16 | Konishiroku Photo Ind Co Ltd | Processing method for color photographic sensitive silver halide material |
| JPS58105148A (ja) * | 1981-12-17 | 1983-06-22 | Fuji Photo Film Co Ltd | カラ−写真処理方法 |
| JPS6023857A (ja) * | 1983-07-20 | 1985-02-06 | Fuji Photo Film Co Ltd | ハロゲン化銀カラ−感光材料の処理方法 |
| JPS60244950A (ja) * | 1984-05-21 | 1985-12-04 | Fuji Photo Film Co Ltd | カラ−写真感光材料の処理方法 |
| JPS61149949A (ja) * | 1984-12-25 | 1986-07-08 | Konishiroku Photo Ind Co Ltd | ハロゲン化銀写真感光材料用処理液の管理方法 |
| US4719173A (en) * | 1985-10-07 | 1988-01-12 | Eastman Kodak Company | Process for multistage contacting |
| US4769312A (en) * | 1985-10-15 | 1988-09-06 | Fuji Photo Film Co., Ltd. | Method of processing silver halide color photographic material including the use of a two bath desilvering system comprising two baths |
| JPS6291952A (ja) * | 1985-10-18 | 1987-04-27 | Fuji Photo Film Co Ltd | ハロゲン化銀カラ−写真材料の処理方法 |
| JPS642047A (en) * | 1987-06-24 | 1989-01-06 | Konica Corp | Method for processing silver halide color photographic sensitive material |
| JP2654778B2 (ja) * | 1987-06-26 | 1997-09-17 | コニカ株式会社 | ハロゲン化銀カラー写真感光材料の処理方法 |
| JP2654777B2 (ja) * | 1987-06-25 | 1997-09-17 | コニカ株式会社 | ハロゲン化銀カラー写真感光材料の処理方法 |
| DE3883308D1 (de) * | 1987-06-24 | 1993-09-23 | Konishiroku Photo Ind | Verfahren zur behandlung eines lichtempfindlichen farbphotographischen silberhalogenidmaterials. |
| US5221597A (en) * | 1988-02-13 | 1993-06-22 | Fuji Photo Film Co., Ltd. | Method for processing silver halide color photographic materials |
| US5234801A (en) * | 1989-07-24 | 1993-08-10 | Fuji Photo Film Co., Ltd. | Processing of silver halide color photographic material |
| GB9007361D0 (en) * | 1990-04-02 | 1990-05-30 | Kodak Ltd | Improvements in chemical reaction systems |
| JP2820613B2 (ja) * | 1994-03-29 | 1998-11-05 | 新日本製鐵株式会社 | 酸化雰囲気中で接合可能な耐熱材料用液相拡散接合合金箔 |
| DE19648760A1 (de) * | 1996-11-25 | 1998-05-28 | Agfa Gevaert Ag | Verarbeitung farbfotografischer Materialien |
| US6221570B1 (en) * | 2000-01-06 | 2001-04-24 | Trebla Chemical Company | One-part bleach-fix liquid concentrates |
| JP2003529789A (ja) * | 2000-01-06 | 2003-10-07 | トレブラ・ケミカル・カンパニー | 一浴式漂白・定着濃縮液 |
| EP1160622A1 (en) * | 2000-05-27 | 2001-12-05 | Agfa-Gevaert N.V. | A bleach-fixing concentrate |
| US6468722B1 (en) * | 2001-03-30 | 2002-10-22 | Eastman Kodak Company | Photofinishing processing system and a processing solution supply cartridge for the processing system |
| US20050008613A1 (en) * | 2003-05-22 | 2005-01-13 | Coating Systems Laboratories, Inc. | Antimicrobial quaternary ammonium organosilane coatings |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1991251A (en) * | 1934-02-05 | 1935-02-12 | Thomas M Ingman | Apparatus for and process of developing film |
| BE625533A (US20080293856A1-20081127-C00139.png) * | 1961-12-05 | |||
| US3634088A (en) * | 1970-02-02 | 1972-01-11 | Eastman Kodak Co | Regeneration of blix solutions used in photographic processing |
| US3700450A (en) * | 1971-01-07 | 1972-10-24 | Eastman Kodak Co | Regeneration of bleach-fix solutions used in photographic processing |
| US3767401A (en) * | 1971-12-15 | 1973-10-23 | Minnesota Mining & Mfg | Regeneration of photographic bleach/fix baths |
| US3751251A (en) * | 1972-03-01 | 1973-08-07 | Eastman Kodak Co | Method for preparing bleach-fix regenerator concentrate |
-
1972
- 1972-04-12 DE DE2217570A patent/DE2217570A1/de active Pending
-
1973
- 1973-04-06 BE BE1004950A patent/BE797844A/xx unknown
- 1973-04-09 US US349229A patent/US3879203A/en not_active Expired - Lifetime
- 1973-04-12 GB GB1760373A patent/GB1427386A/en not_active Expired
- 1973-04-12 JP JP48040924A patent/JPS4911131A/ja active Pending
- 1973-04-12 FR FR7313323A patent/FR2180052B3/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BE797844A (nl) | 1973-10-08 |
| FR2180052B3 (US20080293856A1-20081127-C00139.png) | 1976-03-26 |
| US3879203A (en) | 1975-04-22 |
| JPS4911131A (US20080293856A1-20081127-C00139.png) | 1974-01-31 |
| FR2180052A1 (US20080293856A1-20081127-C00139.png) | 1973-11-23 |
| GB1427386A (en) | 1976-03-10 |
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