DE1122251B - Verfahren zum Haerten ungesaettigter Polyesterharzmassen - Google Patents
Verfahren zum Haerten ungesaettigter PolyesterharzmassenInfo
- Publication number
- DE1122251B DE1122251B DEE18971A DEE0018971A DE1122251B DE 1122251 B DE1122251 B DE 1122251B DE E18971 A DEE18971 A DE E18971A DE E0018971 A DEE0018971 A DE E0018971A DE 1122251 B DE1122251 B DE 1122251B
- Authority
- DE
- Germany
- Prior art keywords
- minutes
- polyester resin
- unsaturated polyester
- resin compositions
- peroctoate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims description 36
- 229920006337 unsaturated polyester resin Polymers 0.000 title claims description 20
- 238000000034 method Methods 0.000 title claims description 7
- 239000003054 catalyst Substances 0.000 claims description 13
- 239000004014 plasticizer Substances 0.000 claims description 8
- 150000002978 peroxides Chemical class 0.000 claims description 5
- 150000002989 phenols Chemical class 0.000 claims description 5
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 claims description 4
- 150000003682 vanadium compounds Chemical class 0.000 claims description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 22
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 22
- 235000019400 benzoyl peroxide Nutrition 0.000 description 22
- 229920001225 polyester resin Polymers 0.000 description 13
- 239000004645 polyester resin Substances 0.000 description 13
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 12
- 238000001723 curing Methods 0.000 description 11
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 5
- 238000013007 heat curing Methods 0.000 description 5
- MMEDJBFVJUFIDD-UHFFFAOYSA-N 2-[2-(carboxymethyl)phenyl]acetic acid Chemical compound OC(=O)CC1=CC=CC=C1CC(O)=O MMEDJBFVJUFIDD-UHFFFAOYSA-N 0.000 description 4
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 4
- 229910052720 vanadium Inorganic materials 0.000 description 4
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 4
- 238000004383 yellowing Methods 0.000 description 4
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- WUAIVKFIBCXSJI-UHFFFAOYSA-N butane-1,3-diol;butane-1,4-diol Chemical compound CC(O)CCO.OCCCCO WUAIVKFIBCXSJI-UHFFFAOYSA-N 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 150000001869 cobalt compounds Chemical class 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- BANVYIJYBXWPOY-UHFFFAOYSA-N C1(=CC=CC=C1)O.C(C)(C)(C)C1=C(C(=CC=C1C)O)C(C)(C)C Chemical class C1(=CC=CC=C1)O.C(C)(C)(C)C1=C(C(=CC=C1C)O)C(C)(C)C BANVYIJYBXWPOY-UHFFFAOYSA-N 0.000 description 1
- DRSHXJFUUPIBHX-UHFFFAOYSA-N COc1ccc(cc1)N1N=CC2C=NC(Nc3cc(OC)c(OC)c(OCCCN4CCN(C)CC4)c3)=NC12 Chemical compound COc1ccc(cc1)N1N=CC2C=NC(Nc3cc(OC)c(OC)c(OCCCN4CCN(C)CC4)c3)=NC12 DRSHXJFUUPIBHX-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003681 vanadium Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/38—Peroxy compounds the —O—O— group being bound between a >C=O group and a carbon atom, not further substituted by oxygen atoms, i.e. esters of peroxy acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polyesters Or Polycarbonates (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL123460D NL123460C (enrdf_load_stackoverflow) | 1960-03-01 | ||
| NL294650D NL139325C (nl) | 1960-03-01 | Werkwijze voor de polymerisatie van etheen of een monomere alkenylverbinding. | |
| NL261851D NL261851A (enrdf_load_stackoverflow) | 1960-03-01 | ||
| DEE18971A DE1122251B (de) | 1960-03-01 | 1960-03-01 | Verfahren zum Haerten ungesaettigter Polyesterharzmassen |
| FR853288A FR1283423A (fr) | 1960-03-01 | 1961-02-20 | Procédé pour polymériser des résines polyester non saturées et résines polyester conformes à celles obtenues |
| GB727361A GB946696A (en) | 1960-03-01 | 1961-02-28 | A novel per-ester and its use in the cross-linking and polymerisation of unsaturated polyester resin masses |
| DEE23153A DE1198067B (de) | 1960-03-01 | 1962-07-05 | Verfahren zur Polymerisation olefinisch ungesaettigter Verbindungen |
| FR940121A FR83968E (fr) | 1960-03-01 | 1963-07-02 | Procédé pour polymériser des résines polyester non saturées et résines polyester conformes à celles obtenues |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEE18971A DE1122251B (de) | 1960-03-01 | 1960-03-01 | Verfahren zum Haerten ungesaettigter Polyesterharzmassen |
| DEE23153A DE1198067B (de) | 1960-03-01 | 1962-07-05 | Verfahren zur Polymerisation olefinisch ungesaettigter Verbindungen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1122251B true DE1122251B (de) | 1962-01-18 |
Family
ID=25972978
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEE18971A Pending DE1122251B (de) | 1960-03-01 | 1960-03-01 | Verfahren zum Haerten ungesaettigter Polyesterharzmassen |
| DEE23153A Pending DE1198067B (de) | 1960-03-01 | 1962-07-05 | Verfahren zur Polymerisation olefinisch ungesaettigter Verbindungen |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEE23153A Pending DE1198067B (de) | 1960-03-01 | 1962-07-05 | Verfahren zur Polymerisation olefinisch ungesaettigter Verbindungen |
Country Status (4)
| Country | Link |
|---|---|
| DE (2) | DE1122251B (enrdf_load_stackoverflow) |
| FR (2) | FR1283423A (enrdf_load_stackoverflow) |
| GB (1) | GB946696A (enrdf_load_stackoverflow) |
| NL (3) | NL261851A (enrdf_load_stackoverflow) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1198067B (de) | 1960-03-01 | 1965-08-05 | Elektrochem Werke Muenchen Ag | Verfahren zur Polymerisation olefinisch ungesaettigter Verbindungen |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3728417A (en) * | 1968-12-05 | 1973-04-17 | Avisun Corp | Perester free radical initiator for graft polymerization |
| DE3700535A1 (de) * | 1987-01-10 | 1988-07-21 | Basf Ag | Verfahren zur herstellung von wasserloeslichen copoylmerisaten der maleinsaeure und deren verwendung als wasserbehandlungsmittel |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL123460C (enrdf_load_stackoverflow) | 1960-03-01 |
-
0
- NL NL123460D patent/NL123460C/xx active
- NL NL294650D patent/NL139325C/xx active
- NL NL261851D patent/NL261851A/xx unknown
-
1960
- 1960-03-01 DE DEE18971A patent/DE1122251B/de active Pending
-
1961
- 1961-02-20 FR FR853288A patent/FR1283423A/fr not_active Expired
- 1961-02-28 GB GB727361A patent/GB946696A/en not_active Expired
-
1962
- 1962-07-05 DE DEE23153A patent/DE1198067B/de active Pending
-
1963
- 1963-07-02 FR FR940121A patent/FR83968E/fr not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1198067B (de) | 1960-03-01 | 1965-08-05 | Elektrochem Werke Muenchen Ag | Verfahren zur Polymerisation olefinisch ungesaettigter Verbindungen |
Also Published As
| Publication number | Publication date |
|---|---|
| FR83968E (fr) | 1964-11-06 |
| FR1283423A (fr) | 1962-02-02 |
| GB946696A (en) | 1964-01-15 |
| NL123460C (enrdf_load_stackoverflow) | |
| NL294650A (enrdf_load_stackoverflow) | |
| NL261851A (enrdf_load_stackoverflow) | |
| NL139325C (nl) | 1973-07-16 |
| DE1198067B (de) | 1965-08-05 |
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