CN1838990A - 改性氧化铝载体和用于制造烯化氧的银基催化剂 - Google Patents

改性氧化铝载体和用于制造烯化氧的银基催化剂 Download PDF

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Publication number
CN1838990A
CN1838990A CNA2004800241445A CN200480024144A CN1838990A CN 1838990 A CN1838990 A CN 1838990A CN A2004800241445 A CNA2004800241445 A CN A2004800241445A CN 200480024144 A CN200480024144 A CN 200480024144A CN 1838990 A CN1838990 A CN 1838990A
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China
Prior art keywords
support
alumina
catalyst
silver
impregnated
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Pending
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CNA2004800241445A
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English (en)
Chinese (zh)
Inventor
E·M·索尔斯坦森
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Dow Technology Investments LLC
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Union Carbide Chemicals and Plastics Technology LLC
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Publication of CN1838990A publication Critical patent/CN1838990A/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
CNA2004800241445A 2003-08-22 2004-06-02 改性氧化铝载体和用于制造烯化氧的银基催化剂 Pending CN1838990A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US49743203P 2003-08-22 2003-08-22
US60/497,432 2003-08-22

Publications (1)

Publication Number Publication Date
CN1838990A true CN1838990A (zh) 2006-09-27

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CNA2004800241445A Pending CN1838990A (zh) 2003-08-22 2004-06-02 改性氧化铝载体和用于制造烯化氧的银基催化剂

Country Status (9)

Country Link
US (1) US20060293180A1 (https=)
EP (1) EP1658135A1 (https=)
JP (1) JP2007503304A (https=)
CN (1) CN1838990A (https=)
CA (1) CA2538989A1 (https=)
IN (1) IN2006CH00631A (https=)
RU (1) RU2340607C2 (https=)
TW (1) TW200507934A (https=)
WO (1) WO2005023417A1 (https=)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104437665A (zh) * 2013-09-16 2015-03-25 中国石油化工股份有限公司 一种银催化剂的α-氧化铝载体的制备方法
CN109499558A (zh) * 2017-09-15 2019-03-22 中国石油化工股份有限公司 一种α-氧化铝载体、银催化剂及烯烃环氧化方法

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040225138A1 (en) 2003-05-07 2004-11-11 Mcallister Paul Michael Reactor system and process for the manufacture of ethylene oxide
AU2004238820B2 (en) 2003-05-07 2008-01-31 Shell Internationale Research Maatschappij B.V. Silver-containing catalysts, the manufacture of such silver containing catalysts, and the use thereof
EP2277622B1 (en) 2003-10-16 2013-01-09 Dow Technology Investments LLC Method for the preparation of catalysts having enhanced stability, efficiency and/or activity for alkylene oxide production
TW200600190A (en) 2004-04-01 2006-01-01 Shell Int Research Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation
JP2008514405A (ja) 2004-09-24 2008-05-08 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 成形粒子を選択するプロセス、システムを取り付けるプロセス、このようなシステム内で気体原料を反応させるプロセス、コンピュータプログラム製品、およびコンピュータシステム
US7759284B2 (en) * 2005-05-09 2010-07-20 Scientific Design Company, Inc. Calcination in an inert gas in the presence of a small concentration of an oxidizing component
WO2006137539A1 (ja) * 2005-06-24 2006-12-28 Nippon Sheet Glass Company, Limited 多孔質シリカセラミックスの製造方法
US8318627B2 (en) * 2005-08-10 2012-11-27 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Process for preparation of a catalyst carrier
EP2274093A1 (en) 2008-04-30 2011-01-19 Dow Technology Investments LLC Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same
CN102015095B (zh) * 2008-04-30 2013-05-08 陶氏技术投资有限公司 多孔体前体，成形多孔体，它们的制备方法和基于它们的终端产品
US20110059843A1 (en) * 2008-04-30 2011-03-10 Howard Kevin E Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same
US8349765B2 (en) * 2008-07-18 2013-01-08 Scientific Design Company, Inc. Mullite-containing carrier for ethylene oxide catalysts
JP5328452B2 (ja) * 2009-03-31 2013-10-30 株式会社日本触媒 酸化エチレン製造用触媒の担体、酸化エチレン製造用触媒および酸化エチレンの製造方法
CA2759560C (en) 2009-04-21 2017-05-30 Dow Technology Investments Llc Rhenium-promoted epoxidation catalysts and methods of making and using them
US8586769B2 (en) * 2010-06-04 2013-11-19 Scientific Design Company, Inc. Carrier for ethylene oxide catalysts
RU2477174C2 (ru) * 2011-02-08 2013-03-10 Государственное образовательное учреждение высшего профессионального образования "Российский химико-технологический университет им. Д.И. Менделеева" (РХТУ им. Д.И. Менделеева) Способ получения катализатора для изотопного обмена протия-дейтерия и орто-пара конверсии протия
CN103582524B (zh) 2011-06-06 2017-06-23 陶氏技术投资有限责任公司 生产环氧化催化剂的方法和利用它们的环氧化方法
RU2490061C2 (ru) * 2011-07-14 2013-08-20 Государственное образовательное учреждение высшего профессионального образования "Российский химико-технологический университет им. Д.И. Менделеева (РХТУ им. Д.И. Менделеева) Способ получения катализатора для изотопного обмена протия-дейтерия
RU2477175C1 (ru) * 2011-07-14 2013-03-10 Государственное образовательное учреждение высшего профессионального образования "Российский химико-технологический университет им. Д.И. Менделеева (РХТУ им. Д.И. Менделеева) Способ получения катализатора для изотопного обмена протия-дейтерия
CA2867506C (en) 2012-03-27 2020-08-18 Dow Technology Investments Llc Method of making a manganese containing supported silver catalyst intermediate
TW201442779A (zh) * 2013-02-07 2014-11-16 Scient Design Co 用於銀基環氧乙烷觸媒之經改質載體
CN109722280B (zh) * 2017-10-27 2020-06-09 中国石油化工股份有限公司 一种用于加氢处理的载体、催化剂及其制备方法和应用
CN113244931B (zh) * 2020-02-11 2022-05-03 中国石油化工股份有限公司 催化剂以及含不饱和烃气体的催化氧化脱氧方法
EP4370246A1 (en) 2021-07-15 2024-05-22 Dow Global Technologies LLC Alkylene oxide catalyst that can be manufactured rapidly in one step
CN117942963A (zh) * 2022-10-25 2024-04-30 中国石油化工股份有限公司 一种双重孔分布氧化铝载体的制备方法
CN116351407B (zh) * 2023-03-23 2024-08-30 天津科技大学 一种花瓣状α-Al2O3载体、载银催化剂的制备方法及其应用
CN118831617B (zh) * 2023-04-19 2026-02-06 中国石油化工股份有限公司 一种加氢处理催化剂及其制备方法
CN118874400B (zh) * 2023-04-26 2026-02-06 中国石油化工股份有限公司 一种多形态氧化铝载体及其制备方法

Family Cites Families (78)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2294383A (en) * 1942-09-01 Process for the preparation of
US2040782A (en) * 1936-05-12 Manufacture of olefine oxides
USRE20370E (en) * 1937-05-18 Process for the production of
US2238474A (en) * 1941-04-15 Process for making olefin oxides
US2209908A (en) * 1938-07-14 1940-07-30 Calorider Corp Contact mass for use in the catalytic vapor phase oxidation of organic compounds
US2177361A (en) * 1939-06-22 1939-10-24 Us Ind Alcohol Co Production of olefin oxides
US3119660A (en) * 1960-09-26 1964-01-28 Union Carbide Corp Process for producing molecular sieve bodies
NL290291A (https=) * 1962-03-21 1900-01-01
US3172893A (en) * 1964-08-27 1965-03-09 Ethylene oxtoationximproved s silver catalyst
US3423328A (en) * 1965-11-22 1969-01-21 Engelhard Ind Inc Silver-barium catalyst
GB1170663A (en) * 1967-03-22 1969-11-12 Shell Int Research Process for preparing Silver Catalysts
NL7015145A (https=) * 1969-10-29 1971-05-04
US3726811A (en) * 1971-05-07 1973-04-10 Shell Oil Co Production of catalyst or catalyst support
US3962136A (en) * 1972-01-07 1976-06-08 Shell Oil Company Catalyst for production of ethylene oxide
US3898094A (en) * 1973-08-20 1975-08-05 Ppg Industries Inc High temperature adhesive-sealant composition
US3950507A (en) * 1974-03-19 1976-04-13 Boreskov Georgy Konstantinovic Method for producing granulated porous corundum
US3972829A (en) * 1974-11-07 1976-08-03 Universal Oil Products Company Method of depositing a catalytically active metallic component on a carrier material
CH638767A5 (fr) * 1978-03-31 1983-10-14 Comp Generale Electricite Procede de preparation de pieces en alumine beta-alcaline.
US4318896A (en) * 1980-04-14 1982-03-09 Uop Inc. Manufacture of alumina particles
US4379134A (en) * 1981-02-13 1983-04-05 Union Carbide Corporation Process of preparing high purity alumina bodies
HU185474B (en) * 1981-11-10 1985-02-28 Almasfuezitoei Timfoeldgyar Process for preparing alpha-aluminium oxyde poor in alkali for ceramic purposes
US4428863A (en) * 1982-07-06 1984-01-31 The Dow Chemical Company Alumina compositions of improved strength useful as catalyst supports
JPS59190983A (ja) * 1983-04-12 1984-10-29 Mitsubishi Petrochem Co Ltd エチレンオキシド製造用反応器に使用する充填材
US4616875A (en) * 1983-10-17 1986-10-14 Ferro Manufacturing Corporation Adjustable seat construction
US4845296A (en) * 1983-12-13 1989-07-04 Union Carbide Corporation Process for preparing alkanolamines
JPS60216844A (ja) * 1984-04-13 1985-10-30 Nippon Shokubai Kagaku Kogyo Co Ltd エチレンオキシド製造用銀触媒
GB8423044D0 (en) * 1984-09-12 1984-10-17 Ici Plc Production of ethylene oxide
EP0207542B1 (en) * 1985-06-28 1989-05-24 Shell Internationale Researchmaatschappij B.V. Process for the preparation of a silver-containing catalyst
NL8501862A (nl) * 1985-06-28 1987-01-16 Shell Int Research Werkwijze ter bereiding van een zilver-houdende katalysator.
US4994587A (en) * 1985-08-12 1991-02-19 Union Carbide Chemicals And Plastics Company, Inc. Catalytic system for epoxidation of alkenes employing low sodium catalyst supports
US4994589A (en) * 1985-08-13 1991-02-19 Union Carbide Chemicals And Plastics Company Inc. Catalytic system for epoxidation of alkenes
US4994588A (en) * 1985-08-13 1991-02-19 Union Carbide Chemicals And Plastics Company Inc. Fluorine-containing catalytic system for expoxidation of alkenes
AU586048B2 (en) * 1985-11-12 1989-06-29 Nippon Shokubai Kagaku Kogyo Co. Ltd. Silver catalyst for production of ethylene oxide and method for manufacture thereof
GB8610441D0 (en) * 1986-04-29 1986-06-04 Shell Int Research Preparation of silver-containing catalyst
GB8611121D0 (en) * 1986-05-07 1986-06-11 Shell Int Research Silver catalyst
GB2190855A (en) * 1986-05-28 1987-12-02 Shell Int Research Process for the preparation of a silver-containing catalyst
GB8618325D0 (en) * 1986-07-28 1986-09-03 Shell Int Research Catalyst
US4766105A (en) * 1986-10-31 1988-08-23 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4761394A (en) * 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
GB8626687D0 (en) * 1986-11-07 1986-12-10 Shell Int Research Preparing silver catalyst
US5057481A (en) * 1987-02-20 1991-10-15 Union Carbide Chemicals And Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US4908343A (en) * 1987-02-20 1990-03-13 Union Carbide Chemicals And Plastics Company Inc. Catalyst composition for oxidation of ethylene to ethylene oxide
GB8716653D0 (en) * 1987-07-15 1987-08-19 Shell Int Research Silver-containing catalyst
CN1009437B (zh) * 1988-02-03 1990-09-05 中国石油化工总公司 乙烯氧化制环氧乙烷高效银催化剂
CA1337722C (en) * 1989-04-18 1995-12-12 Madan Mohan Bhasin Alkylene oxide catalysts having enhanced activity and/or stability
US5015614A (en) * 1989-07-03 1991-05-14 Exxon Research And Engineering Company Novel alumina support materials
US5051395A (en) * 1989-09-25 1991-09-24 Union Carbide Chemicals And Plastics Technology Corporation Alkylene oxide catalysts having enhanced activity and/or efficiency
US5187140A (en) * 1989-10-18 1993-02-16 Union Carbide Chemicals & Plastics Technology Corporation Alkylene oxide catalysts containing high silver content
US5248557A (en) * 1990-12-07 1993-09-28 E. I. Du Pont De Nemours And Company Coated refractory composition and method for making the same
AU639326B2 (en) * 1990-05-23 1993-07-22 Atochem Ceramic preforms comprising monocrystalline hexagonal platelets of alpha-alumina, their production and applications thereof
US5102848A (en) * 1990-09-28 1992-04-07 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
JPH04329279A (ja) * 1991-04-30 1992-11-18 Yamaichi Electron Co Ltd 電気部品用ソケット
US5288371A (en) * 1992-01-21 1994-02-22 The United States Of America As Represented By The Secretary Of The Navy Oxidation of organic materials by electrified microheterogeneous catalysis
JP3744010B2 (ja) * 1993-06-30 2006-02-08 住友化学株式会社 α−アルミナ粉末の製造方法
US5380697A (en) * 1993-09-08 1995-01-10 Shell Oil Company Ethylene oxide catalyst and process
US5566755A (en) * 1993-11-03 1996-10-22 Amoco Corporation Method for recovering methane from a solid carbonaceous subterranean formation
US5739075A (en) * 1995-10-06 1998-04-14 Shell Oil Company Process for preparing ethylene oxide catalysts
US5733842A (en) * 1996-04-30 1998-03-31 Norton Checmical Process Products Corporation Method of making porous catalyst carrier without the addition of pore forming agents
WO1997046317A1 (en) * 1996-06-05 1997-12-11 Shell Internationale Research Maatschappij B.V. Epoxidation catalyst and process
US5780656A (en) * 1997-04-14 1998-07-14 Scientific Design Company, Inc. Ethylene oxide catalyst and process
DE69919425T2 (de) * 1998-02-20 2005-09-08 Nippon Shokubai Co. Ltd. Silberkatalysator zur Herstellung von Ethylenoxid , Verfahren zu seiner Herstellung und Verfahren zur Herstellung von Ethylenoxid
RU2232049C2 (ru) * 1998-09-14 2004-07-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ удаления ионизируемых частиц с поверхности катализатора для улучшения каталитических свойств
CA2343836C (en) * 1998-09-14 2007-12-04 Shell Internationale Research Maatschappij B.V. Epoxidation catalyst carrier, preparation and use thereof
JP4354060B2 (ja) * 1998-11-17 2009-10-28 株式会社日本触媒 酸化エチレン製造用触媒の担体、酸化エチレン製造用触媒および酸化エチレンの製造方法
IN193645B (https=) * 1998-11-17 2004-07-31 Nippon Catalytic Chem Ind
US6203773B1 (en) * 1999-07-12 2001-03-20 Alcoa Inc. Low temperature mineralization of alumina
US6417136B2 (en) * 1999-09-17 2002-07-09 Phillips Petroleum Company Hydrocarbon hydrogenation catalyst and process
EP1086743B1 (en) * 1999-09-21 2006-08-16 Nippon Shokubai Co., Ltd. Catalyst for production of epoxides and methods for production thereof and epoxides
JP3739265B2 (ja) * 1999-09-21 2006-01-25 株式会社日本触媒 エポキシド製造用触媒及びその調製方法並びにエポキシドの製造方法
JP4050041B2 (ja) * 2001-11-06 2008-02-20 株式会社日本触媒 酸化エチレン製造用触媒、その製造方法および当該触媒による酸化エチレンの製造方法
CN100408168C (zh) * 2002-02-25 2008-08-06 国际壳牌研究有限公司 负载的银催化剂和使用该催化剂的环氧化方法
US6667270B2 (en) * 2002-05-22 2003-12-23 Shell Oil Company Bismuth-and phosphorus-containing catalyst support, reforming catalysts made from same, method of making and naphtha reforming process
CN1838991A (zh) * 2003-08-22 2006-09-27 联合碳化化学及塑料技术公司 改进的氧化铝载体和用于制造烯化氧的银基催化剂
EP2277622B1 (en) * 2003-10-16 2013-01-09 Dow Technology Investments LLC Method for the preparation of catalysts having enhanced stability, efficiency and/or activity for alkylene oxide production
EP1765800B1 (en) * 2004-06-18 2012-04-18 Shell Internationale Research Maatschappij B.V. A process for the production of an olefin oxide, a 1,2-diol, a 1.2-diol ether, or an alkanolamine
EP1765799A1 (en) * 2004-06-18 2007-03-28 Shell Oil Company A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine
KR20070058576A (ko) * 2004-09-01 2007-06-08 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 올레핀 에폭시화 방법, 이 방법에 사용되는 촉매, 이촉매의 제조에 사용되는 담체, 및 이 담체의 제조방법
KR20070106772A (ko) * 2005-02-21 2007-11-05 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 올레핀의 에폭시화 방법, 그 방법에 사용하기 위한 촉매,그 촉매를 제조하는데 이용하기 위한 담체, 및 그 담체의제조방법

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104437665A (zh) * 2013-09-16 2015-03-25 中国石油化工股份有限公司 一种银催化剂的α-氧化铝载体的制备方法
CN104437665B (zh) * 2013-09-16 2017-01-18 中国石油化工股份有限公司 一种银催化剂的α‑氧化铝载体的制备方法
CN109499558A (zh) * 2017-09-15 2019-03-22 中国石油化工股份有限公司 一种α-氧化铝载体、银催化剂及烯烃环氧化方法

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WO2005023417A1 (en) 2005-03-17
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