CN1307251C - 聚烯烃树脂组合物 - Google Patents
聚烯烃树脂组合物 Download PDFInfo
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- CN1307251C CN1307251C CNB038163721A CN03816372A CN1307251C CN 1307251 C CN1307251 C CN 1307251C CN B038163721 A CNB038163721 A CN B038163721A CN 03816372 A CN03816372 A CN 03816372A CN 1307251 C CN1307251 C CN 1307251C
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- Prior art keywords
- polyolefin resin
- modified
- resin composition
- polyolefine
- infrared absorption
- Prior art date
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Organic Insulating Materials (AREA)
Abstract
Description
改性层状硅酸盐 | h | 添加量 | 改性聚烯烃树脂 | 添加量 | Pc1 | PcH | 聚烯烃树脂 | 添加量 | HRR | 热变形温度 | |
实施例1 | Nanomer 1.30P | >65 | 4 | HW2203A | 16 | 0.058 | 0.88 | S360 | 80 | 650 | ○ |
实施例2 | Nanomer 1.30P | >65 | 4 | HW1105A | 16 | 0.095 | 0.92 | S360 | 80 | 650 | ○ |
实施例3 | ME100C18 | >65 | 4 | HW2203A | 16 | 0.058 | 0.88 | S360 | 80 | 580 | ○ |
实施例4 | MGC18 | >65 | 4 | HW2203A | 16 | 0.058 | 0.88 | S360 | 80 | 800 | ○ |
实施例5 | MGBrij72 | >65 | 4 | HW2203A | 16 | 0.058 | 0.88 | S360 | 80 | 720 | ○ |
比较例1 | Nanomer 1.30P | 16.5 | 4 | 未改性聚烯烃 | 16 | S360 | 80 | 1250 | × | ||
比较例2 | HW2203A | 16 | 0.058 | 0.88 | S360 | 80 | 1100 | × | |||
比较例3 | Nanomer 1.30P | 24.5 | 4 | Yumex1010 | 16 | 0.296 | 0.25 | S360 | 80 | 850 | × |
比较例4 | Nanomer 1.30P | 28.9 | 4 | Yumex2000 | 16 | 0.101 | 0.49 | S360 | 80 | 800 | × |
比较例5 | Nanomer 1.30P | 27.5 | 4 | Yumex1001 | 16 | 0.181 | 0.65 | S360 | 80 | 800 | × |
Claims (4)
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JP2002210604 | 2002-07-19 | ||
JP210604/2002 | 2002-07-19 |
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CN1668687A CN1668687A (zh) | 2005-09-14 |
CN1307251C true CN1307251C (zh) | 2007-03-28 |
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CNB038163721A Expired - Fee Related CN1307251C (zh) | 2002-07-19 | 2003-07-17 | 聚烯烃树脂组合物 |
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US (1) | US20050239941A1 (zh) |
EP (1) | EP1553136B1 (zh) |
JP (1) | JPWO2004009697A1 (zh) |
KR (1) | KR100619642B1 (zh) |
CN (1) | CN1307251C (zh) |
AT (1) | ATE352582T1 (zh) |
AU (1) | AU2003281617A1 (zh) |
DE (1) | DE60311500T2 (zh) |
WO (1) | WO2004009697A1 (zh) |
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US7648771B2 (en) * | 2003-12-31 | 2010-01-19 | Kimberly-Clark Worldwide, Inc. | Thermal stabilization and processing behavior of block copolymer compositions by blending, applications thereof, and methods of making same |
US20080108742A1 (en) * | 2004-09-16 | 2008-05-08 | Asahi Kasei Life & Living Corporation | Aliphatic Polyester Resin Composition Superior in Heat Resistance |
CN1326931C (zh) * | 2004-12-12 | 2007-07-18 | 青岛大学 | 聚烯烃/层状硅酸盐纳米复合物的制备方法 |
CN100410309C (zh) * | 2005-02-21 | 2008-08-13 | 中国科学院化学研究所 | 聚烯烃/蒙脱土纳米复合材料的制备方法 |
US8377027B2 (en) | 2005-04-29 | 2013-02-19 | Kimberly-Clark Worldwide, Inc. | Waist elastic members for use in absorbent articles |
WO2007049734A1 (ja) * | 2005-10-28 | 2007-05-03 | Asahi Kasei Chemicals Corporation | ポリエチレン系樹脂組成物及びそのフィルム |
JP5232504B2 (ja) * | 2008-03-04 | 2013-07-10 | 日本ポリエチレン株式会社 | ポリエチレン系容器蓋 |
US8751169B1 (en) * | 2010-09-29 | 2014-06-10 | The United States of America, as represented by the Secretary of the Department of the Interior | Spectral method for determining the source of expanded vermiculite insulation in attics and walls |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09302170A (ja) * | 1996-05-14 | 1997-11-25 | Mitsui Petrochem Ind Ltd | 変性ポリエチレン樹脂組成物、易リサイクル性樹脂組成物、多層積層体および容器 |
JPH10130434A (ja) * | 1996-11-01 | 1998-05-19 | Du Pont Kk | 低密度ポリエチレン−層状珪酸塩複合材料およびその製造方法 |
WO2000061676A1 (fr) * | 1999-04-12 | 2000-10-19 | Sekisui Chemical Co., Ltd. | Composite de resine polyolefinique, composite de resine thermoplastique et procede de production du composite de resine thermoplastique |
JP2002030181A (ja) * | 2000-07-14 | 2002-01-31 | Jsp Corp | 発泡用ポリオレフィン系樹脂組成物 |
JP2002037940A (ja) * | 2000-07-21 | 2002-02-06 | Grand Polymer Co Ltd | ポリプロピレン樹脂組成物および製造方法 |
JP2002060555A (ja) * | 2000-08-11 | 2002-02-26 | Sekisui Chem Co Ltd | ポリオレフィン系複合材料及びその製造方法 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5869025A (ja) * | 1981-10-21 | 1983-04-25 | Toyo Ink Mfg Co Ltd | 塗装可能な未変性ポリオレフイン系樹脂成型物の製造方法 |
US5973053A (en) * | 1995-06-05 | 1999-10-26 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Composite clay material and method for producing the same, blend material and composite clay rubber using the same and production method thereof |
JP2000355640A (ja) * | 1999-04-12 | 2000-12-26 | Sekisui Chem Co Ltd | ポリオレフィン系複合材料 |
JP2001064454A (ja) * | 1999-08-30 | 2001-03-13 | Sekisui Chem Co Ltd | ポリオレフィン系樹脂複合材料 |
JP2001026724A (ja) * | 1999-07-16 | 2001-01-30 | Sekisui Chem Co Ltd | 熱可塑性樹脂複合材料及びその製造方法 |
JP2001181513A (ja) * | 1999-12-24 | 2001-07-03 | Konica Corp | 複合材料の製造方法、複合材料及び成形品 |
US6632868B2 (en) * | 2000-03-01 | 2003-10-14 | Amcol International Corporation | Intercalates formed with polypropylene/maleic anhydride-modified polypropylene intercalants |
JP4356212B2 (ja) * | 2000-08-09 | 2009-11-04 | コニカミノルタビジネステクノロジーズ株式会社 | 静電荷像現像用トナー |
JP2002192663A (ja) * | 2000-12-22 | 2002-07-10 | Polyplastics Co | 熱溶着用シート、それを用いた複合成形品並びにその製造法 |
JP2003003027A (ja) * | 2001-06-19 | 2003-01-08 | Idemitsu Petrochem Co Ltd | ポリプロピレン系複合樹脂組成物 |
US6841226B2 (en) * | 2001-11-13 | 2005-01-11 | Eastman Kodak Company | Ethoxylated alcohol intercalated smectite materials and method |
US6844389B2 (en) * | 2001-12-20 | 2005-01-18 | Equistar Chemicals, Lp | Ethylene polymer compositions having improved melt strength |
-
2003
- 2003-07-17 AU AU2003281617A patent/AU2003281617A1/en not_active Abandoned
- 2003-07-17 DE DE60311500T patent/DE60311500T2/de not_active Expired - Lifetime
- 2003-07-17 WO PCT/JP2003/009071 patent/WO2004009697A1/ja active IP Right Grant
- 2003-07-17 KR KR1020047020832A patent/KR100619642B1/ko not_active IP Right Cessation
- 2003-07-17 CN CNB038163721A patent/CN1307251C/zh not_active Expired - Fee Related
- 2003-07-17 EP EP03741446A patent/EP1553136B1/en not_active Expired - Lifetime
- 2003-07-17 JP JP2004522743A patent/JPWO2004009697A1/ja active Pending
- 2003-07-17 AT AT03741446T patent/ATE352582T1/de not_active IP Right Cessation
- 2003-07-17 US US10/517,828 patent/US20050239941A1/en not_active Abandoned
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09302170A (ja) * | 1996-05-14 | 1997-11-25 | Mitsui Petrochem Ind Ltd | 変性ポリエチレン樹脂組成物、易リサイクル性樹脂組成物、多層積層体および容器 |
JPH10130434A (ja) * | 1996-11-01 | 1998-05-19 | Du Pont Kk | 低密度ポリエチレン−層状珪酸塩複合材料およびその製造方法 |
WO2000061676A1 (fr) * | 1999-04-12 | 2000-10-19 | Sekisui Chemical Co., Ltd. | Composite de resine polyolefinique, composite de resine thermoplastique et procede de production du composite de resine thermoplastique |
JP2002030181A (ja) * | 2000-07-14 | 2002-01-31 | Jsp Corp | 発泡用ポリオレフィン系樹脂組成物 |
JP2002037940A (ja) * | 2000-07-21 | 2002-02-06 | Grand Polymer Co Ltd | ポリプロピレン樹脂組成物および製造方法 |
JP2002060555A (ja) * | 2000-08-11 | 2002-02-26 | Sekisui Chem Co Ltd | ポリオレフィン系複合材料及びその製造方法 |
Also Published As
Publication number | Publication date |
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ATE352582T1 (de) | 2007-02-15 |
CN1668687A (zh) | 2005-09-14 |
US20050239941A1 (en) | 2005-10-27 |
EP1553136A4 (en) | 2006-03-15 |
EP1553136A1 (en) | 2005-07-13 |
JPWO2004009697A1 (ja) | 2005-11-17 |
WO2004009697A1 (ja) | 2004-01-29 |
DE60311500T2 (de) | 2007-11-08 |
EP1553136B1 (en) | 2007-01-24 |
DE60311500D1 (de) | 2007-03-15 |
KR100619642B1 (ko) | 2006-09-08 |
KR20050010962A (ko) | 2005-01-28 |
AU2003281617A1 (en) | 2004-02-09 |
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