CN1302164C - 弹性聚氨酯纤维的制备方法及由此制得的弹性聚氨酯纤维 - Google Patents
弹性聚氨酯纤维的制备方法及由此制得的弹性聚氨酯纤维 Download PDFInfo
- Publication number
- CN1302164C CN1302164C CNB2003101163173A CN200310116317A CN1302164C CN 1302164 C CN1302164 C CN 1302164C CN B2003101163173 A CNB2003101163173 A CN B2003101163173A CN 200310116317 A CN200310116317 A CN 200310116317A CN 1302164 C CN1302164 C CN 1302164C
- Authority
- CN
- China
- Prior art keywords
- elastic polyurethane
- polyurethane fiber
- polystyrene
- fiber
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920006306 polyurethane fiber Polymers 0.000 title claims abstract description 55
- 238000000034 method Methods 0.000 title claims abstract description 42
- 238000004519 manufacturing process Methods 0.000 title abstract description 3
- 239000004793 Polystyrene Substances 0.000 claims abstract description 52
- 229920002223 polystyrene Polymers 0.000 claims abstract description 52
- 229920002635 polyurethane Polymers 0.000 claims abstract description 28
- 239000004814 polyurethane Substances 0.000 claims abstract description 28
- 229920000642 polymer Polymers 0.000 claims abstract description 24
- 238000002360 preparation method Methods 0.000 claims abstract description 12
- 238000009987 spinning Methods 0.000 claims description 18
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 5
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 5
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 5
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 4
- 239000002174 Styrene-butadiene Substances 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 2
- 239000011115 styrene butadiene Substances 0.000 claims description 2
- 210000004177 elastic tissue Anatomy 0.000 abstract description 2
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 229920002959 polymer blend Polymers 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 17
- 239000000835 fiber Substances 0.000 description 12
- 238000000578 dry spinning Methods 0.000 description 7
- 238000007796 conventional method Methods 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000012948 isocyanate Substances 0.000 description 4
- 150000002513 isocyanates Chemical class 0.000 description 4
- 238000002074 melt spinning Methods 0.000 description 4
- 229920005862 polyol Polymers 0.000 description 4
- 150000003077 polyols Chemical class 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 150000002009 diols Chemical class 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000002166 wet spinning Methods 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000005442 diisocyanate group Chemical group 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- -1 diisocyanate compound Chemical class 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000009998 heat setting Methods 0.000 description 1
- WFKAJVHLWXSISD-UHFFFAOYSA-N isobutyramide Chemical compound CC(C)C(N)=O WFKAJVHLWXSISD-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/70—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/94—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of other polycondensation products
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Artificial Filaments (AREA)
- Multicomponent Fibers (AREA)
Abstract
Description
聚苯乙烯聚合物/共聚物 | 聚合物/共聚物的数均分子量 | 混合时重量比(w/w) | |
实施例1 | 聚苯乙烯 | 100,000 | 10/90 |
对比例1 | 10,000 | ||
对比例2 | 700,000 | ||
对比例3 | 100,000 | 40/60 | |
实施例2 | 对甲基聚苯乙烯 | 150,000 | 10/90 |
实施例3 | SAN | ||
实施例4 | SBS | ||
实施例5 | ABS |
热固性(%) | 200%模量 | 拉伸 | |||
测量值(g/d) | 改变(%) | 测量值(g/d) | 改变(%) | ||
实施例1 | 70.7 | 0.15 | -4 | 670 | 8 |
对比例1 | 40 | 0.11 | -29 | 630 | 2 |
对比例2 | 84 | 0.07 | -50 | 850 | 37 |
对比例3 | 85 | 0.06 | -61 | 900 | 45 |
实施例2 | 68 | 0.14 | -11 | 690 | 11 |
实施例3 | 69 | 0.14 | -11 | 630 | 2 |
实施例4 | 65 | 0.16 | 2 | 600 | -3 |
实施例5 | 65 | 0.17 | 9 | 580 | -6 |
Claims (3)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR0075228/02 | 2002-11-29 | ||
KR10-2002-0075228A KR100461760B1 (ko) | 2002-11-29 | 2002-11-29 | 폴리우레탄 탄성사의 제조 방법 |
KR0075228/2002 | 2002-11-29 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1504593A CN1504593A (zh) | 2004-06-16 |
CN1302164C true CN1302164C (zh) | 2007-02-28 |
Family
ID=32322357
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2003101163173A Expired - Lifetime CN1302164C (zh) | 2002-11-29 | 2003-11-19 | 弹性聚氨酯纤维的制备方法及由此制得的弹性聚氨酯纤维 |
Country Status (5)
Country | Link |
---|---|
US (1) | US7255820B2 (zh) |
KR (1) | KR100461760B1 (zh) |
CN (1) | CN1302164C (zh) |
DE (1) | DE10355665B4 (zh) |
IT (1) | ITMI20032269A1 (zh) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100807041B1 (ko) * | 2004-12-31 | 2008-02-25 | 주식회사 효성 | 세트성이 우수한 탄성사 및 그 제조 방법 |
DE102005008926A1 (de) | 2005-02-24 | 2006-11-16 | Philipps-Universität Marburg | Verfahren zur Herstellung von Nano- und Mesofasern durch Elektrospinning von kolloidalen Dispersionen |
KR101003282B1 (ko) * | 2005-12-30 | 2010-12-21 | 주식회사 효성 | 폴리우레탄 탄성사와 폴리에스테르 섬유로부터 제조되는신축성 편, 직물 |
KR100730447B1 (ko) * | 2005-12-30 | 2007-06-19 | 주식회사 효성 | 신축성 직· 편물 |
EP2057307A2 (de) * | 2006-08-21 | 2009-05-13 | Basf Se | Verfahren zur herstellung von nano- und mesofasern durch elektrospinnen von kolloidalen dispersionen |
DE102006049666A1 (de) | 2006-10-18 | 2008-04-30 | Carl Freudenberg Kg | Verwendung eines Verfahrens zur Herstellung von Reinigungsprodukten, Hygieneprodukten oder medizinischen Produkten |
EP2222902A2 (de) * | 2007-12-11 | 2010-09-01 | Basf Se | Verfahren zur herstellung von nano- und mesofasern durch elektrospinnen von kolloidalen dispersionen, enthaltend mindestens ein im wesentlichen wasserunlösliches polymer |
CN102176904B (zh) | 2008-08-08 | 2014-06-25 | 巴斯夫欧洲公司 | 基于生物聚合物的包含活性物质的连续纤维层、其用途和产生方法 |
US20110129510A1 (en) * | 2008-08-08 | 2011-06-02 | Basf Se | Fibrous surface structure containing active ingredients with controlled release of active ingredients, use thereof and method for the production thereof |
KR101086744B1 (ko) | 2008-12-18 | 2011-11-24 | 주식회사 효성 | 초저온에서의 열세트성이 우수한 폴리우레탄우레아 탄성사의 제조방법 |
WO2010072665A1 (de) | 2008-12-23 | 2010-07-01 | Basf Se | Modifizierung von nano- oder mesofasern oder textilen flächengebilden hergestellt mittels elektrospinnen mit amphiphilen proteinen |
CN103290521B (zh) * | 2013-05-24 | 2015-07-15 | 宁波三邦超细纤维有限公司 | 高弹性涤锦复合超细纤维及生产方法 |
CN103290524B (zh) * | 2013-05-24 | 2015-01-07 | 宁波三邦日用品有限公司 | 远红外涤锦复合超细纤维及生产方法 |
CN103290513B (zh) * | 2013-05-24 | 2015-07-15 | 宁波三邦超细纤维有限公司 | 高弹性丙锦复合超细纤维及生产方法 |
CN103290520B (zh) * | 2013-05-24 | 2015-07-15 | 宁波三邦超细纤维有限公司 | 高收缩涤锦复合超细纤维及生产方法 |
CN103290517B (zh) * | 2013-05-24 | 2015-07-15 | 宁波三邦超细纤维有限公司 | 高收缩丙锦复合超细纤维及生产方法 |
KR101506799B1 (ko) * | 2013-08-13 | 2015-03-27 | 주식회사 효성 | 핫멜트 접착제와의 접착 특성이 향상된 스판덱스 섬유 및 그의 제조방법 |
KR20210118954A (ko) * | 2013-09-13 | 2021-10-01 | 더 라이크라 컴퍼니 유케이 리미티드 | 향상된 결합을 위한 스판덱스 섬유 |
DE102014013354A1 (de) | 2014-09-08 | 2016-03-10 | Rainer Busch | Die Erfindung betrifft eine Vorrichtung und Verfahren zur Herstellung von mikroverkapselten Paraffinpartikel durch ein elektrostatisches Rotationsdüsen-Absprühverfahren sowie die Verwendung dieses Verfahren. Die so verkapselten Paraffinpartikel können für |
WO2017122879A1 (ko) * | 2016-01-15 | 2017-07-20 | (주)효성 | 해사성 개선 및 핫멜트 접착제와의 접착특성이 향상된 스판덱스 및 이의 제조방법 |
WO2017122982A1 (ko) * | 2016-01-15 | 2017-07-20 | 주식회사 효성 | 해사성 개선 및 핫멜트 접착제와의 접착특성이 향상된 스판덱스 및 이의 제조방법 |
KR101913418B1 (ko) * | 2017-01-26 | 2018-10-30 | 효성티앤씨 주식회사 | 해사 특성, 마찰 특성 및 핫멜트 접착제와의 접착특성이 향상된 스판덱스, 및 이의 제조방법 |
US11097261B1 (en) * | 2018-04-17 | 2021-08-24 | The United States Of America As Represented By The Secretary Of The Army | Single threaded composite fibers and yarns for the degradation of and protection against toxic chemicals and biological agents |
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JPS60126322A (ja) * | 1983-12-06 | 1985-07-05 | Kuraray Co Ltd | ポリウレタン系混合繊維の製造法 |
JPH04185716A (ja) * | 1990-11-09 | 1992-07-02 | Kuraray Co Ltd | 複合弾性繊維 |
US5834542A (en) * | 1994-12-01 | 1998-11-10 | Basf Aktiengesellschaft | Impact-resistant thermoplastic molding materials |
WO2002050349A1 (en) * | 2000-12-20 | 2002-06-27 | Dupont-Toray Company, Ltd | Elastomeric polyurethane fiber with high heat-set efficiency |
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US4831096A (en) * | 1984-12-14 | 1989-05-16 | Pennwalt Corporation | Process of bulk polymerization of styrene using azoalkane mixtures containing unsymmetrical azoalkanes |
JPS6353287A (ja) | 1986-08-21 | 1988-03-07 | Furukawa Electric Co Ltd:The | Ag被覆導体 |
JPS6353288A (ja) | 1986-08-22 | 1988-03-07 | Nippon Steel Corp | 溶接性に優れた低コスト表面処理鋼板 |
JPH0830288B2 (ja) * | 1987-08-20 | 1996-03-27 | 株式会社クラレ | 着色ポリウレタン系多成分繊維の製造法 |
DD301044A7 (de) * | 1988-09-27 | 1992-10-01 | Basf Schwarzheide Gmbh | Verfahren zur herstellung von nicht blockenden polyurethan-elastomeren |
JP2786514B2 (ja) * | 1990-04-27 | 1998-08-13 | 鐘紡株式会社 | 複合糸及びストッキング |
JPH04316609A (ja) * | 1991-04-12 | 1992-11-09 | Kanebo Ltd | ポリオレフィン系複合弾性糸 |
EP0611077A3 (en) * | 1993-02-08 | 1994-12-28 | Rohm & Haas | Polyurethane elastomer blends. |
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US6500911B1 (en) * | 1999-05-20 | 2002-12-31 | Daicel Chemical Industries, Ltd. | Polyester diol and derived polyurethane and acrylic copolymer |
US6537661B1 (en) * | 1999-07-02 | 2003-03-25 | Kraton Polymers U.S. Llc | Melt processable, bleach resistant, durable fibers having high elastic recovery and low stress relaxation from polyurethane elastomers |
KR100587903B1 (ko) | 1999-08-04 | 2006-06-08 | 주식회사 코오롱 | 폴리우레탄 탄성섬유 및 그의 제조방법 |
US6994913B1 (en) * | 1999-09-30 | 2006-02-07 | Sekisui Chemical Co., Ltd. | Thermoplastic elastomer, use thereof, and process for producing the same |
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KR100548915B1 (ko) * | 2002-03-29 | 2006-02-02 | 주식회사 효성 | 우수한 내염소성을 갖는 폴리우레탄 탄성섬유 |
-
2002
- 2002-11-29 KR KR10-2002-0075228A patent/KR100461760B1/ko active IP Right Review Request
-
2003
- 2003-11-19 CN CNB2003101163173A patent/CN1302164C/zh not_active Expired - Lifetime
- 2003-11-21 US US10/719,758 patent/US7255820B2/en active Active
- 2003-11-21 IT IT002269A patent/ITMI20032269A1/it unknown
- 2003-11-28 DE DE10355665A patent/DE10355665B4/de not_active Expired - Lifetime
Patent Citations (4)
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JPS60126322A (ja) * | 1983-12-06 | 1985-07-05 | Kuraray Co Ltd | ポリウレタン系混合繊維の製造法 |
JPH04185716A (ja) * | 1990-11-09 | 1992-07-02 | Kuraray Co Ltd | 複合弾性繊維 |
US5834542A (en) * | 1994-12-01 | 1998-11-10 | Basf Aktiengesellschaft | Impact-resistant thermoplastic molding materials |
WO2002050349A1 (en) * | 2000-12-20 | 2002-06-27 | Dupont-Toray Company, Ltd | Elastomeric polyurethane fiber with high heat-set efficiency |
Also Published As
Publication number | Publication date |
---|---|
KR20040047129A (ko) | 2004-06-05 |
US7255820B2 (en) | 2007-08-14 |
US20040106733A1 (en) | 2004-06-03 |
DE10355665B4 (de) | 2005-12-15 |
CN1504593A (zh) | 2004-06-16 |
DE10355665A1 (de) | 2004-06-17 |
ITMI20032269A1 (it) | 2004-05-30 |
KR100461760B1 (ko) | 2004-12-14 |
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