CN1203209C - 金属底材的防腐蚀方法和组合物 - Google Patents
金属底材的防腐蚀方法和组合物 Download PDFInfo
- Publication number
- CN1203209C CN1203209C CN98809232.8A CN98809232A CN1203209C CN 1203209 C CN1203209 C CN 1203209C CN 98809232 A CN98809232 A CN 98809232A CN 1203209 C CN1203209 C CN 1203209C
- Authority
- CN
- China
- Prior art keywords
- metal substrate
- treatment soln
- aminosilane
- composition
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 90
- 239000002184 metal Substances 0.000 title claims abstract description 90
- 238000000034 method Methods 0.000 title claims abstract description 74
- 239000000758 substrate Substances 0.000 title claims abstract description 72
- 239000000203 mixture Substances 0.000 title claims abstract description 33
- 238000005260 corrosion Methods 0.000 title abstract description 18
- 230000007797 corrosion Effects 0.000 title abstract description 15
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229910000838 Al alloy Inorganic materials 0.000 claims abstract description 10
- 239000011737 fluorine Substances 0.000 claims abstract description 10
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 10
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 8
- 239000011248 coating agent Substances 0.000 claims description 35
- 238000000576 coating method Methods 0.000 claims description 35
- 239000002253 acid Substances 0.000 claims description 29
- 150000002222 fluorine compounds Chemical class 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- 239000003973 paint Substances 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 13
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 12
- 229910000077 silane Inorganic materials 0.000 claims description 12
- 238000007739 conversion coating Methods 0.000 claims description 11
- 150000003839 salts Chemical class 0.000 claims description 11
- 230000007062 hydrolysis Effects 0.000 claims description 10
- 238000006460 hydrolysis reaction Methods 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 8
- KPAXGXGDUKHAIF-UHFFFAOYSA-N [Hf].[F] Chemical compound [Hf].[F] KPAXGXGDUKHAIF-UHFFFAOYSA-N 0.000 claims description 7
- 239000005060 rubber Substances 0.000 claims description 7
- 238000004140 cleaning Methods 0.000 claims description 6
- UTEBVBBGZIBAGZ-UHFFFAOYSA-N 3-[3-aminopropyl(dimethoxy)silyl]oxypentane-1,5-diamine Chemical compound NCCC[Si](OC)(OC)OC(CCN)CCN UTEBVBBGZIBAGZ-UHFFFAOYSA-N 0.000 claims description 5
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 claims description 5
- 239000004411 aluminium Substances 0.000 claims description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 239000011707 mineral Substances 0.000 claims description 5
- INJVFBCDVXYHGQ-UHFFFAOYSA-N n'-(3-triethoxysilylpropyl)ethane-1,2-diamine Chemical compound CCO[Si](OCC)(OCC)CCCNCCN INJVFBCDVXYHGQ-UHFFFAOYSA-N 0.000 claims description 5
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- XROWMBWRMNHXMF-UHFFFAOYSA-J titanium tetrafluoride Chemical compound [F-].[F-].[F-].[F-].[Ti+4] XROWMBWRMNHXMF-UHFFFAOYSA-J 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- 150000002484 inorganic compounds Chemical class 0.000 abstract 1
- 229910010272 inorganic material Inorganic materials 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 18
- 230000003628 erosive effect Effects 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- 125000004103 aminoalkyl group Chemical group 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 238000005554 pickling Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 239000010953 base metal Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- SJTNICJEANXTBY-UHFFFAOYSA-N [SiH4].CC Chemical compound [SiH4].CC SJTNICJEANXTBY-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 2
- 238000006392 deoxygenation reaction Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000007746 phosphate conversion coating Methods 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
- 229910001094 6061 aluminium alloy Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- -1 aminopropyl Chemical group 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004532 chromating Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002221 fluorine Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052909 inorganic silicate Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
- C23C2222/20—Use of solutions containing silanes
Landscapes
- Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Laminated Bodies (AREA)
- Chemically Coating (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US5919797P | 1997-09-17 | 1997-09-17 | |
| US60/059,197 | 1997-09-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1270641A CN1270641A (zh) | 2000-10-18 |
| CN1203209C true CN1203209C (zh) | 2005-05-25 |
Family
ID=22021427
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN98809232.8A Expired - Lifetime CN1203209C (zh) | 1997-09-17 | 1998-09-16 | 金属底材的防腐蚀方法和组合物 |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US6203854B1 (enExample) |
| EP (1) | EP1017880B1 (enExample) |
| JP (4) | JP2001516810A (enExample) |
| KR (1) | KR20010024006A (enExample) |
| CN (1) | CN1203209C (enExample) |
| AT (1) | ATE217363T1 (enExample) |
| BR (1) | BR9812235A (enExample) |
| CA (1) | CA2304240C (enExample) |
| DK (1) | DK1017880T3 (enExample) |
| EA (1) | EA200000323A1 (enExample) |
| ES (1) | ES2175778T3 (enExample) |
| HU (1) | HUP0003824A2 (enExample) |
| IL (1) | IL134925A0 (enExample) |
| NZ (1) | NZ503269A (enExample) |
| PL (1) | PL339409A1 (enExample) |
| TR (1) | TR200000687T2 (enExample) |
| WO (1) | WO1999014399A1 (enExample) |
Families Citing this family (60)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4165943B2 (ja) * | 1998-11-18 | 2008-10-15 | 日本ペイント株式会社 | 亜鉛被覆鋼および無被覆鋼の防錆コーティング剤 |
| US6132808A (en) * | 1999-02-05 | 2000-10-17 | Brent International Plc | Method of treating metals using amino silanes and multi-silyl-functional silanes in admixture |
| US7344607B2 (en) * | 1999-07-08 | 2008-03-18 | Ge Betz, Inc. | Non-chromate conversion coating treatment for metals |
| US6827981B2 (en) * | 1999-07-19 | 2004-12-07 | The University Of Cincinnati | Silane coatings for metal |
| WO2001007679A1 (en) * | 1999-07-26 | 2001-02-01 | Chemetall Plc | Metal surface treatment |
| US6270884B1 (en) * | 1999-08-02 | 2001-08-07 | Metal Coatings International Inc. | Water-reducible coating composition for providing corrosion protection |
| DE19961411A1 (de) * | 1999-12-17 | 2001-06-21 | Chemetall Gmbh | Verfahren zur Herstellung von beschichteten Metalloberflächen und deren Verwendung |
| JP2001342578A (ja) * | 2000-05-31 | 2001-12-14 | Honda Motor Co Ltd | 金属表面処理剤 |
| EP1191074A1 (en) | 2000-09-25 | 2002-03-27 | Sigma Coatings B.V. | Water-based two component protective coating compositions |
| JP2002264253A (ja) * | 2001-03-12 | 2002-09-18 | Nisshin Steel Co Ltd | ガスケット用表面処理ステンレス鋼板およびガスケット |
| JP4096595B2 (ja) * | 2002-03-29 | 2008-06-04 | 住友金属工業株式会社 | 表面処理ステンレス鋼板とその製造方法 |
| KR100475849B1 (ko) * | 2002-04-17 | 2005-03-10 | 한국전자통신연구원 | 습식 공정에 의하여 형성된 엔캡슐레이션 박막을 갖춘유기 전기발광 소자 및 그 제조 방법 |
| US20040094235A1 (en) * | 2002-11-18 | 2004-05-20 | Ge Betz, Inc. | Chrome free treatment for aluminum |
| US20040187967A1 (en) * | 2002-12-24 | 2004-09-30 | Nippon Paint Co., Ltd. | Chemical conversion coating agent and surface-treated metal |
| JP4526807B2 (ja) * | 2002-12-24 | 2010-08-18 | 日本ペイント株式会社 | 塗装前処理方法 |
| ES2316706T3 (es) * | 2002-12-24 | 2009-04-16 | Chemetall Gmbh | Metodo de pre-tratamiento para revestir. |
| JP2008184690A (ja) * | 2002-12-24 | 2008-08-14 | Nippon Paint Co Ltd | 塗装前処理方法 |
| JP4989842B2 (ja) * | 2002-12-24 | 2012-08-01 | 日本ペイント株式会社 | 塗装前処理方法 |
| CA2517057C (en) * | 2003-02-25 | 2013-11-12 | Chemetall Gmbh | Process for coating metallic surfaces with a silane-rich composition |
| EP1582571A1 (de) * | 2004-03-23 | 2005-10-05 | Sika Technology AG | Zweikomponentige Haftvermittlerzusammensetzung und Verwendung einer Verpackung mit zwei Kammern |
| CA2575885A1 (en) * | 2004-08-03 | 2006-02-16 | Chemetall Gmbh | Method for protecting a metal surface by means of a corrosion-inhibiting coating |
| US20060042726A1 (en) * | 2004-09-02 | 2006-03-02 | General Electric Company | Non-chrome passivation of steel |
| US7491274B2 (en) * | 2004-10-29 | 2009-02-17 | Chemetall Corp. | Non-chrome metal treatment composition |
| US20060099332A1 (en) | 2004-11-10 | 2006-05-11 | Mats Eriksson | Process for producing a repair coating on a coated metallic surface |
| DE102005015573B4 (de) * | 2005-04-04 | 2014-01-23 | Chemetall Gmbh | Verfahren zur Beschichtung von metallischen Oberflächen mit einer wässerigen Silan/Silanol/Siloxan/Polysiloxan enthaltenden Zusammensetzung, diese wässerige Zusammensetzung und Verwendung der nach dem Verfahren beschichteten Substrate |
| DE102005015575B4 (de) * | 2005-04-04 | 2014-01-23 | Chemetall Gmbh | Verfahren zur Beschichtung von metallischen Oberflächen mit einer Silan, Silanol, Siloxan oder/und Polysiloxan enthaltenden Zusammensetzung, diese Zusammensetzung und Verwendung der nach dem Verfahren beschichteten Substrate |
| US8101014B2 (en) * | 2004-11-10 | 2012-01-24 | Chemetall Gmbh | Process for coating metallic surfaces with a multicomponent aqueous composition |
| EP1812621B1 (de) | 2004-11-10 | 2019-03-06 | Chemetall GmbH | Verfahren zur beschichtung von metallischen oberflächen mit einer wässerigen silan/ silanol/ siloxan/ polysiloxan enthaltenden zusammensetzung |
| JP2006161110A (ja) | 2004-12-08 | 2006-06-22 | Nippon Paint Co Ltd | 車両のシャシ用金属表面の塗装前処理方法及び粉体塗料の塗装方法 |
| US20060151070A1 (en) | 2005-01-12 | 2006-07-13 | General Electric Company | Rinsable metal pretreatment methods and compositions |
| US20080138615A1 (en) * | 2005-04-04 | 2008-06-12 | Thomas Kolberg | Method for Coating Metallic Surfaces with an Aqueous Composition and Said Composition |
| US10041176B2 (en) | 2005-04-07 | 2018-08-07 | Momentive Performance Materials Inc. | No-rinse pretreatment methods and compositions |
| US20060257555A1 (en) * | 2005-05-12 | 2006-11-16 | Brady Brian K | Sub-layer for adhesion promotion of fuel cell bipolar plate coatings |
| JP4473185B2 (ja) * | 2005-07-01 | 2010-06-02 | 本田技研工業株式会社 | 化成処理方法、化成処理剤、及び化成処理部材 |
| US8133591B2 (en) * | 2006-06-27 | 2012-03-13 | GM Global Technology Operations LLC | Adhesion of polymeric coatings to bipolar plate surfaces using silane coupling agents |
| KR101512844B1 (ko) * | 2008-02-01 | 2015-04-21 | 삼성전자주식회사 | 항산화막용 조성물, 이를 이용한 항산화막 형성방법 및이로부터 제조된 전자부품용 기재 |
| US8398838B2 (en) * | 2008-10-10 | 2013-03-19 | Wealtec Bioscience Co., Ltd. | Technical measure for gel electrophoresis shaping |
| JP5034059B2 (ja) * | 2009-03-19 | 2012-09-26 | メック株式会社 | 積層体の形成方法 |
| JP2010236000A (ja) * | 2009-03-31 | 2010-10-21 | Nippon Zeon Co Ltd | 金属表面の腐食防止方法及び光学部材 |
| JP5669293B2 (ja) * | 2009-09-24 | 2015-02-12 | 関西ペイント株式会社 | 金属表面処理用組成物及び金属表面処理方法 |
| JP2011186401A (ja) * | 2010-03-11 | 2011-09-22 | Nagoya City | アルミニウム反射鏡及びアルミニウム反射鏡の製造方法 |
| US8597482B2 (en) * | 2010-09-14 | 2013-12-03 | Ecosil Technologies Llc | Process for depositing rinsable silsesquioxane films on metals |
| US9073083B2 (en) * | 2010-12-15 | 2015-07-07 | Bulk Chemicals, Inc. | Process and seal coat for improving paint adhesion |
| DE102011106293B3 (de) * | 2011-05-18 | 2012-05-24 | Harting Kgaa | Steckverbindergehäuse |
| KR101613335B1 (ko) | 2012-02-07 | 2016-04-18 | 삼성에스디아이 주식회사 | 리튬이차전지 및 그 제조방법 |
| CN102677039B (zh) * | 2012-05-21 | 2014-12-03 | 合肥工业大学 | 一种铝及铝合金表面硅烷稀土复合保护膜及其制备方法 |
| DE102013215441A1 (de) | 2013-08-06 | 2015-02-12 | Henkel Ag & Co. Kgaa | Metallvorbehandlungszusammensetzungen umfassend Silane und Organophosphonsäuren |
| DE102013215440A1 (de) * | 2013-08-06 | 2015-02-12 | Henkel Ag & Co. Kgaa | Metallvorbehandlung mit sauren wasserhaltigen Zusammensetzungen umfassend Silane |
| CN103602971A (zh) * | 2013-09-27 | 2014-02-26 | 宁波英科特精工机械股份有限公司 | 一种金属表面处理剂 |
| CN103773234B (zh) * | 2014-01-10 | 2016-04-06 | 湖南金裕化工有限公司 | 硅烷表面处理剂及其制备方法 |
| CN104846359B (zh) * | 2014-02-17 | 2017-12-29 | 广州中国科学院工业技术研究院 | 用于金属表面预处理的复合处理剂及其制备方法和应用 |
| US10259832B2 (en) | 2015-05-28 | 2019-04-16 | Evonik Degussa Gmbh | Method for producing aqueous hydrolysates from aminoalkyltrialkoxysilanes |
| KR102347596B1 (ko) * | 2015-06-26 | 2022-01-06 | 동우 화인켐 주식회사 | 잔류물 제거를 위한 수성 세정제 조성물 |
| JP6660116B2 (ja) * | 2015-08-03 | 2020-03-04 | 東京応化工業株式会社 | シランカップリング剤水溶液、単分子膜製造方法及びめっき造形方法 |
| CN105131001A (zh) * | 2015-08-25 | 2015-12-09 | 辽宁大学 | 一种无取代锌酞菁的合成方法 |
| KR20180058001A (ko) * | 2016-11-23 | 2018-05-31 | 강남제비스코 주식회사 | 논크롬형 클리어 도료가 코팅된 스테인리스 강판 |
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-
1998
- 1998-09-16 EA EA200000323A patent/EA200000323A1/ru unknown
- 1998-09-16 NZ NZ503269A patent/NZ503269A/xx unknown
- 1998-09-16 IL IL13492598A patent/IL134925A0/xx unknown
- 1998-09-16 JP JP2000511932A patent/JP2001516810A/ja not_active Withdrawn
- 1998-09-16 CN CN98809232.8A patent/CN1203209C/zh not_active Expired - Lifetime
- 1998-09-16 AT AT98946071T patent/ATE217363T1/de active
- 1998-09-16 PL PL98339409A patent/PL339409A1/xx unknown
- 1998-09-16 WO PCT/US1998/019257 patent/WO1999014399A1/en not_active Ceased
- 1998-09-16 ES ES98946071T patent/ES2175778T3/es not_active Expired - Lifetime
- 1998-09-16 TR TR2000/00687T patent/TR200000687T2/xx unknown
- 1998-09-16 HU HU0003824A patent/HUP0003824A2/hu unknown
- 1998-09-16 CA CA002304240A patent/CA2304240C/en not_active Expired - Lifetime
- 1998-09-16 EP EP98946071A patent/EP1017880B1/en not_active Expired - Lifetime
- 1998-09-16 DK DK98946071T patent/DK1017880T3/da active
- 1998-09-16 BR BR9812235-5A patent/BR9812235A/pt not_active Application Discontinuation
- 1998-09-16 US US09/154,251 patent/US6203854B1/en not_active Expired - Lifetime
- 1998-09-16 KR KR1020007002735A patent/KR20010024006A/ko not_active Withdrawn
-
2006
- 2006-03-09 JP JP2006064787A patent/JP4227999B2/ja not_active Expired - Lifetime
-
2007
- 2007-05-14 JP JP2007127937A patent/JP4865632B2/ja not_active Expired - Lifetime
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2010
- 2010-03-01 JP JP2010044335A patent/JP2010156055A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| HUP0003824A2 (en) | 2001-03-28 |
| ES2175778T3 (es) | 2002-11-16 |
| EA200000323A1 (ru) | 2000-10-30 |
| ATE217363T1 (de) | 2002-05-15 |
| JP4865632B2 (ja) | 2012-02-01 |
| TR200000687T2 (tr) | 2000-11-21 |
| WO1999014399A1 (en) | 1999-03-25 |
| CA2304240C (en) | 2007-05-22 |
| BR9812235A (pt) | 2000-07-18 |
| JP4227999B2 (ja) | 2009-02-18 |
| CN1270641A (zh) | 2000-10-18 |
| EP1017880B1 (en) | 2002-05-08 |
| EP1017880A1 (en) | 2000-07-12 |
| KR20010024006A (ko) | 2001-03-26 |
| PL339409A1 (en) | 2000-12-18 |
| AU9316798A (en) | 1999-04-05 |
| AU724978B2 (en) | 2000-10-05 |
| CA2304240A1 (en) | 1999-03-25 |
| JP2007291526A (ja) | 2007-11-08 |
| JP2006233335A (ja) | 2006-09-07 |
| DK1017880T3 (da) | 2002-08-26 |
| JP2001516810A (ja) | 2001-10-02 |
| US6203854B1 (en) | 2001-03-20 |
| IL134925A0 (en) | 2001-05-20 |
| NZ503269A (en) | 2001-03-30 |
| JP2010156055A (ja) | 2010-07-15 |
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