CN1197476A - 合成柴油及其生产方法 - Google Patents

合成柴油及其生产方法 Download PDF

Info

Publication number
CN1197476A
CN1197476A CN96197172A CN96197172A CN1197476A CN 1197476 A CN1197476 A CN 1197476A CN 96197172 A CN96197172 A CN 96197172A CN 96197172 A CN96197172 A CN 96197172A CN 1197476 A CN1197476 A CN 1197476A
Authority
CN
China
Prior art keywords
cut
diesel oil
weight
product
oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN96197172A
Other languages
English (en)
Other versions
CN1082541C (zh
Inventor
R·J·维藤布林克
R·F·鲍曼
P·J·伯洛维茨
B·R·库克
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
ExxonMobil Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=24171786&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN1197476(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by ExxonMobil Research and Engineering Co filed Critical ExxonMobil Research and Engineering Co
Publication of CN1197476A publication Critical patent/CN1197476A/zh
Application granted granted Critical
Publication of CN1082541C publication Critical patent/CN1082541C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C10L1/08—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for compression ignition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Fats And Perfumes (AREA)

Abstract

把费—托合成产物分离成为例如小于约700°F和大于约700°F的较轻的和较重的馏分,把700°F+的馏分进行加氢处理,并且把加氢处理的产物的700°F－部分与未加氢处理的较轻的馏分混合,由非变换的费—托法生产具有优异的润滑性、氧化稳定性和高的十六烷值的柴油或调合料。

Description

合成柴油及其生产方法
发明领域
本发明涉及一种馏分物料，该馏分物料具有高十六烷值并且可以作为柴油或者作为其调合料，并涉及该馏分物料的制备方法。更具体地说，本发明涉及由费-托合成蜡生产馏分物料的方法。
发明背景
不含有即没有硫、氮或芳烃的洁净馏分作为柴油或调合柴油现在是或者将来也可能是非常需要的。具有比较高的十六烷值的洁净馏分是特别有价值的。一般的石油衍生的馏分是不洁净的，一般的它们含有显著量的硫、氮和芳烃，并且它们的十六烷值比较低。通过高费用的苛刻的加氢处理可以从石油基馏分生产洁净馏分。这样的苛刻的加氢处理对十六烷值的改善很小，对燃料的润滑性能也是不利的。可以通过使用比较贵的添加剂整套配方来改善燃料输送系统的有效操作所需要的燃料润滑性能。在公开的文献中已经讨论了由费-托合成蜡生产洁净的高十六烷值的馏分的方法，但是所公开的生产这样的馏分的方法也使得该馏分缺少一种或多种重要的性能，例如润滑性能。因此，所公开的费-托合成馏分需要与其它的不合乎要求的原料调合或者使用很贵的添加剂。这些较早的方案公开了加氢处理全部的费-托合成产物，包括完全的700°F-馏分。该加氢处理使得从该馏分中脱除了氧化物质。
根据本发明，保留了少量的氧化物质，所得到的产物具有很高的十六烷值和很高的润滑性能。因此该产物本身就可以作为柴油，或者作为由其它的较低级的物料制备柴油的调合料。
发明概述
根据本发明，优选的可以由费-托合成蜡，优选的由钴或钌费-托合成催化剂所得到的费-托合成蜡，通过把该含蜡的产物分离成为较重的馏分和较轻的馏分来生产洁净的馏分，该馏分可以用作比汽油重的燃料，例如用作柴油或者作为柴油的调合料，该洁净的馏分的十六烷值至少约60，优选至少约70，更优选至少约74。该标称的分离在约700°F进行，该较重的馏分主要含有700°F+的馏分，该较轻的馏分主要含有700°F-的馏分。
把该较重的馏分在加氢异构化催化剂存在下，在通常的加氢异构化条件下进行加氢异构化，该加氢异构化催化剂含有一种或多种贵金属或非贵金属，在此当中，至少一部分700°F+的物料转化成为700°F-的馏分。至少一部分，优选所有的较轻的馏分，优选在分离C5-(虽然某些C3和C4可能溶解在C5+中)之后，仍然未被处理，即不被物理分离，并且与至少一部分且优选全部的加氢异构化的700°F-的产物调合。由该混合的产物可以回收沸点范围为250°F-700°F的柴油或柴油调合料，该柴油或柴油调合料具有下面所述的性质。
附图的说明
图1是本发明的方法的流程图。
图2表示两种燃料的IR吸收度谱图：I柴油B，和II具有0.0005mmol/gm棕榈酸(palnitic acid)(按氧计，其相当于15wppm氧)的柴油B；纵坐标为吸收度，横坐标为波长。
优选实施方案的描述
参考附图来更详细地描述本发明。在管线1中所含有的合成气、氢气和一氧化碳按照合适的比例加入到费-托合成反应器2中，优选的是浆液反应器，从管线3和4分别回收700°F+和700°F-的产物。较轻的馏分通过热分离器6，在管线8中回收500-700°F的馏分，而在管线7中回收500°F-的馏分。该500°F-的馏分通过冷却分离器9，由其在管线10中回收C4气体。在管线11中回收C5-700°F的馏分，并且与管线8中的500-700°F的馏分混合。至少一部分，优选几乎全部，更优选基本上所有的该C5-700°F的馏分与管线12中的加氢异构化的产物调合。
把在管线3中的较重的，例如700°F+的馏分送到加氢异构化装置5中。下面的表中列出了加氢异构化过程装置的一般较宽的和优选的条件。
        条件        宽范围      优选范围
温度°F             300-800     550-750
总压力，psig        0-2500      300-1200
氢处理速率，SCF/B   500-5000    2000-4000
氢耗速率，SCF/B     50-500      100-300
虽然实际上用于加氢异构化或选择性的加氢裂化的任何的催化剂都可以满足该步骤，但是某些催化剂比其它催化剂好并且是优选的。例如，含有担载VIII族贵金属例如铂或钯的催化剂是有用的，含有一种或多种VIII族贱金属例如镍、钴的含量约为0.5-20％(重)的催化剂也是有用的，其可以或也可以不包括量约为1-20％(重)的VI族金属例如钼。这些金属的载体可以是任何的耐熔的氧化物或沸石或其混合物。优选的载体包括氧化硅、氧化铝、氧化硅-氧化铝、氧化硅-氧化铝磷酸盐、氧化钛、氧化锆、氧化钒和其它III族、IV族、VA族和VI族氧化物，以及Y型分子筛例如超稳Y分子筛。优选的载体包括氧化铝和氧化硅-氧化铝，其中主体载体中的氧化硅的浓度少于约50％(重)，优选少于35％(重)。
优选的催化剂的表面积是约180-400m2/gm，优选230-350m2/gm，孔体积为0.3-1.0ml/gm，优选0.35-0.75ml/gm，堆积密度约为0.5-1.0g/ml，侧向抗碎强度约为0.8-3.5kg/mm。
优选的催化剂含有VIII族非贵金属例如铁、镍，连同IB族金属例如铜，担载在酸性载体上。该载体优选是无定型氧化硅-氧化铝，其中氧化铝的存在量小于约30％(重)，优选5-30％(重)，更优选10-20％(重)。另外，该载体可以含有少量的例如20-30％(重)的粘合剂，例如氧化铝、氧化硅、IVA族金属氧化物和各种类型的粘土，氧化镁等，优选氧化铝。通过把金属从溶液中共沉淀到载体上，在100-150℃干燥，并在200-550℃空气中焙烧来制备该催化剂。
在Ryland，Lloyd B.，Yamele，M.W.，and Wilson，J.N.，Cracking Catalysts，Catalysis：VolumeVII，Ed.Paul H.Emmertt，Reinhold Publishing Corporation，New York，1960，pp.5-9中介绍了用作载体的无定型氧化硅-氧化铝微球的制备方法。
VIII族金属的存在量约为15％(重)或更少，优选1-12％(重)，而IB族金属通常的存在量比较少，例如其与VIII族金属的比为1∶2-约1∶20。典型的催化剂表示如下：
            Ni，％(重)        2.5-3.5
            Cu，％(重)        0.25-0.35
            Al2O3-SiO2     65-75
            Al2O3(粘合剂)   25-30
             表面积             290-355m2/gm
             孔体积(Hg)         0.35-0.45ml/gm
             堆积密度           0.58-0.68g/ml
在加氢异构化装置中700°F+的物料转化为700°F-的物料约为20-80％，优选20-50％，更优选约30-50％。在加氢异构化的过程中基本上所有的烯烃和含氧的物质都被加氢。
在管线12中回收的加氢异构化的产物，管线8和11中的C5-700°F的物流在管线12中进行调合。在塔13中分馏该调合的物流，由其，在管线14中的700°F+的馏分任意地循回到管线3中，在管线16中回收C5-的馏分，在管线15中回收沸点范围为250-700°F的洁净馏分油。该馏分油有极好的性能，可以用作柴油或者用作柴油的调合组分。可以在管线16中回收轻的气体，并且在管线17中与由冷分离器9分离出的轻的气体混合，用作燃料或化学品的加工过程。
从分馏塔13回收的柴油馏分有下面所示的性质：
烷烃           95％(重)，优选至少96％(重)，更优选至少
               97％(重)，仍然更优选至少98％(重)，最优选
               至少99％(重)；
异构/正构比    约0.3-3.0，优选0.7-2.0；
硫                   ≤50ppm(重)，优选没有；
氮                   ≤50ppm(重)，优选≤20ppm(重)，更优选没有；
不饱和物             ≤2％(重)；
(烯烃和芳烃)
氧化物质             约0.001到少于0.3％(重)的氧(无水基)
异构烷烃优选是单甲基支链的，因为该方法使用费-托蜡，所以该产物不含有环状烷烃，例如没有环己烷。
在较轻的馏分例如700°F-的馏分中，该氧化产品基本上含有例如≥95％的氧化产物。另外，较轻馏分中的烯烃的浓度足够的低，以使得没有必要回收烯烃，并且进一步的避免处理该馏分中的烯烃。
优选的费-托合成方法是这样一种方法：使用非变换(即没有水气转换能力)催化剂，例如钴或钌或其混合物，优选钴，并且优选的是助催化的钴，该助催化剂是锆或铼，优选铼。这样的催化剂是公知的，优选的催化剂在U.S.P4,568,663和EP 0 266 898中作了介绍。在该方法中，H2∶CO比是至少约1.7，优选至少约1.75，更优选1.75-2.5。
费-托合成方法的产物主要是烷烃。钌主要生产馏分油沸点范围例如C10-C20的烷烃；而钴催化剂一般地生产更多的较重的烃例如C20+，钴是优选的费-托合成催化金属。
柴油一般的具有如下性质：高的十六烷值，通常50或更高，优选至少约60，更优选至少约65；润滑性；氧化稳定性；和与柴油管道规格相容的物理性能。
本发明的产品本身就可以用作柴油，或用来与其它的不合乎要求的含有大约相同的沸点范围的原料的石油或烃调合。当用作调合料时，可以使用比较少量的本发明的产品，例如10％或多点，就可以明显的改善最终调合柴油产品。虽然本发明的产品会改善几乎任何的柴油产品，但是特别希望把该产品与低质量的炼厂柴油物料调合。一般的物料是粗的或加氢催化的或热裂化的馏分油和瓦斯油。
通过使用费-托合成方法，回收的馏分油没有硫和氮。这些杂原子化合物对费-托合成催化剂是有毒的，它们要从含甲烷的天然气中除去，天然气是费-托合成方法的便宜的原料。(在任何情况下，在天然气中，含硫和氮的化合物都是非常低浓度的)另外，该方法不产生芳烃，或者在通常的操作条件下实际上不产生芳烃。因为所提供的生产烷烃的通道通过烯烃中间产物，所以产生一定量的烯烃。不过，烯烃的浓度通常非常的低。
含氧化合物包括在费-托合成过程中产生的醇和某些酸，但是在至少一种公知的方法中，含氧化合物和不饱和化合物通过加氢处理都完全从产物中消除了。例如见The Shell Middle Distillate Process，Eiler，J.；Posthuma，S.A.；Sie，S.T.，Catalysis Letter，1990，7，253-270。
但是，我们已经发现，在700°F-的馏分中，优选在500-700°F的馏分中，更优选在600-700°F的馏分中的通常以浓缩形式的少量的氧化合物，优选醇，对柴油提供所希望的润滑性。例如，按所具体说明的那样将表明，含有少量的氧化合物的高含量烷烃的柴油，由BOCLE试验(球在汽缸润滑性能评价装置上)所表示的那样，具有优异的润滑性能。但是，当例如通过萃取、分子筛吸附、加氢等除去氧化合物，使得在试验的馏分中氧的含量小于10ppm％(重)(无水基)时，润滑性能就非常差。
根据于本发明所公开的加工方法，较轻的700°F-的馏分不进行任何的加氢处理。在较轻的的馏分不进行加氢处理的情况下，在该馏分中的少量的氧化合物，主要是直链醇被保存，而在加氢异构化步骤中在较重的馏分中的氧化合物被除去。加氢异构化也为了增加馏分燃料中的异构烷烃的量，使得该燃料满足倾点和浊点的规格，为了这些目的虽然可以使用添加剂。
被认为是提高润滑性能的氧化合物可以描述为其具有的氢键合能大于烃的键合能(各种化合物的能量测定可从标准参考书中获得)；该差别越大，润滑效果越好。氧化合物也具有亲油端和亲水端，以使燃料润湿。
优选的氧化合物，主要是醇，具有比较长的链，即C12+，更优选C12-C24伯直链醇。
虽然酸是含氧化合物，但酸是腐蚀性的，在费-托合成的过程中，在非变换的条件下，会产生很少量的酸。与由直链醇所表示的优选的一氧化合物相对比，这些酸也是二氧化合物。因此，二或多氧化合物通常用红外测量是不可检测的，例如按氧计是小于约15wppm氧。
本领域的技术人员都熟知非变换费-托合成反应，其特征是其条件使得形成的CO2副产物减少到最少。通过各种各样的方法，包括一种或多种下面的方法可以达到这些条件：在低的CO分压下操作，即在氢与CO的比至少约1.7/1，优选约1.7/1-2.5/1，更优选至少约1.9/1，并且在1.9/1-2.5/1的范围内操作，所有的α值至少约0.88，优选至少约0.91；温度约175-225℃，优选180-210℃；使用含有钴或铼作为主要费-托合成催化剂的催化剂。
以无水基的氧计，要达到所要求的润滑性能，存在的氧化合物的量是较少的，即至少约0.001％(重)的氧(无水基)，优选0.001-0.3％(重)的氧(无水基)，更优选0.0025-0.3％(重)的氧(无水基)。
下面的实施例将用来说明本发明，但不是限制本发明。
在浆液费-托合成反应器中，氢和一氧化碳合成气(H2∶CO 2.11-2.16)转化成重的烷烃。费-托合成反应所用的催化剂是在前面的USP4,568,663中所描述的氧化钛载钴/铼催化剂。反应条件是422-428°F，287-289psig，线速度是12-17.5厘米/秒。费-托合成步骤的α值是0.92。然后，以三种不同标称沸点的物流分离烷烃费-托合成产物，使用粗略的闪蒸来分离。这三种沸点接近的馏分是：1)C5-500°F的馏分，指定低于F-T冷分离器液体；2)500-700°F的馏分，指定低于F-T热分离器液体；和3)700+°F的馏分，指定低于F-T反应器蜡。实施例1
把70％(重)的加氢异构化的F-T反应器蜡、16.8％(重)的加氢处理的F-T冷分离器液体和13.2％(重)的加氢处理的F-T热分离器液体混合在一起，并很好的混合。柴油A是通过蒸馏分离出的该调合物的260-700°F的馏分，其按如下制备：按USP5,292,989和USP5,378,348所述，使用含有钴和钼促进的无定型氧化硅-氧化铝催化剂的固定床装置，一次通过，来制备该加氢异构化的F-T反应器蜡。加氢异构化的条件是708°F，750psig H2，2500SCF/B H2，液时空速(LHSV)是0.7-0.8。使用循环的未处理的700°F+的反应器蜡进行加氢异构化。混合的进料比(新鲜进料+循环进料)/新鲜进料等于1.5。使用一次通过的固定床反应器和市场上买到的镍催化剂，制备加氢处理的F-T冷分离器液体和F-T热分离器液体。加氢处理的条件是450°F，430psig H2，1000SCF/B H2和3.0LHSV。燃料A是一般的完全加氢处理的钴衍生的费-托柴油的代表，其是本领域公知的。实施例2
把78％(重)的加氢异构化的F-T反应器蜡、12％(重)的未加氢处理的F-T冷分离器液体和10％(重)的F-T热分离器液体混合在一起，并很好的混合。柴油B是通过蒸馏分离出的该调合物的250-700°F的馏分，其按如下制备：按USP5,292,989和USP5,378,348所述，使用含有钴和钼促进的无定型氧化硅-氧化铝催化剂的固定床装置，一次通过，来制备该加氢异构化的F-T反应器蜡。加氢异构化的条件是690°F，725psigH2，2500SCF/B H2，液时空速(LHSV)是0.6-0.7。燃料B是本发明的代表性实施例。实施例3
通过蒸馏燃料B成为两个馏分来制备柴油C和D。柴油C代表柴油B的250-500°F的馏分，柴油D代表柴油B的500-700°F的馏分。实施例4
100.81克柴油B与33.11克Grace硅铝酸盐沸石：13X，等级544，8-12目颗粒接触，柴油E是由该处理得到的滤液。该处理有效地从燃料中除去了醇和氧化合物。实施例5
柴油F是加氢处理的由大约40％的催化馏分和60％直馏馏分组成的石油物流。其后，其在工业加氢处理装置进行加氢处理。该石油馏分的沸点范围是250-800°F，含有663ppm硫(x-光)和40％FIA芳烃。柴油F代表本发明的石油的基本情况。实施例6
混合等量的柴油B和柴油F来制备柴油G。柴油G应该含有600ppm总氧(中子活化法)，80ppm 500+°F沸点的伯醇(GC/MS)，伯醇的信号表明320ppm作为伯醇的总氧(1H NMR；250-700°F)。柴油G代表本发明的另一个例子，其中HCS和石油馏分都用于包括柴油。实施例7
使用质子核磁共振(1H NMR)、红外光谱(IR)和气相色谱/质谱(GC/MS)来测定柴油A、B和E的氧化合物、二氧化合物和醇组成。使用BruckerMSL-500谱仪进行1H NMR试验。使用频率500.13Mhz，脉冲宽度2.9μs(45度斜角)，延迟60s，和64扫描，在常温下测定溶解在CDCl3中的样品，得到定量数据。在每一种情况下，都使用四甲基硅烷作为内参，二噁烷作为内标。通过与内标比较分别在3.6(2H)、3.4(1H)、4.1(2H)和2.4(2H)的整体峰，来直接估算伯醇、仲醇、酯和酸的量ppm。使用Nicolet 800光谱仪进行IR光谱分析。把样品放在Kbr固定的光程长度盒(额定1.0mm)来制备样品，并且加4096扫描0.3cm-1分辨来进行测量。分别用在1720和1738cm-1的吸光度来测定二氧化合物例如羧酸和酯的量。使用Hewlett-Packard 5980/Hewlett-Packard 5970B Mass Selective DetecterCombination(MSD)或者Kratos Modle MS-890 GC/MS来进行GC/MS。使用选择的离子检测m/z 31(CH3O+)来定量伯醇。把称量的C2-C14、C16和C18伯醇加入到C8-C16正构烷烃的混合物中来制备内标。按ASTM D 2710所述，用溴指数来确定烯烃。这些分析的结果列于表1。含有未加氢处理的热和冷分离器液体的柴油B含有明显量的氧化合物例如直链伯醇。这些主要的馏分是重要的C12-C18伯醇。提供柴油的优异的润滑性能的是这些醇。在除去基本上所有量的氧化合物和烯烃方面加氢处理(柴油A)是极为有效的。在除去醇污染物方面，不使用过程氢的分子筛处理(柴油E)也是有效的。这些燃料中没有含有明显量的二氧化合物例如羧酸或酯的。图2表示柴油B的样品的IR谱图。
        表1
所有的加氢处理的柴油(柴油A)、部分加氢处理的柴油(柴油B)和分子筛处理的部分加氢处理的柴油(柴油E)的氧化合物和二氧化合物(羧酸，酯)组成。
                                     柴油A      柴油B      柴油E二氧化合物(羧酸，酯)中的wppm氧-(IR)      未检测     未检测     未检测C5-C18伯醇中的wppm氧-(1H NMR)         未检测     640ppm     未检测C5-C18伯醇中的wppm氧-(GC/MS)           5.3        824        未检测C12-C18伯醇中的wppm氧-(GC/MS)          3.3        195ppm     未检测总烯烃-摩尔/克(溴指数，ASTM D 2710)      0.004      0.78       -实施例8
也按Lacey，P.I.“The U.S.Army Scuffing Load Wear Test”，1994年1月1日所述，使用标准的球关于汽缸润滑性能评价(BOCLE)对柴油A-G都进行试验。该试验是基于ASTM D 5001。结果列于表2，，其是作为在Lacey中所述的参照燃料2的百分比。
                     表2燃料A-G的BOCLE结果，结果是在Lacey中所述的参照燃料2的百分比。
        柴油              ％参照燃料2
          A                  42.1
          B                  88.9
          C                  44.7
          D                  94.7
          E                  30.6
          F                  80.0
          G                  84.4完全加氢处理的柴油A呈现出非常低的完全是烷烃柴油的一般的润滑性能。柴油B含有大量的氧化合物如直链C5-C24伯醇，柴油B呈现出非常优异的润滑性能。柴油E是通过13X分子筛脱附从柴油B分离氧化合物制备的。柴油E呈现出非常差的润滑性能，表明直链C5-C24伯醇使柴油B具有高润滑性能。柴油C和D分别表示柴油B的250-500°F和500-700°F沸点的馏分。柴油C含有沸点低于500°F的直链C5-C11伯醇，柴油D含有沸点为500-700°F的直链C12-C24伯醇。与柴油C比较，柴油D呈现出非常优异的润滑性能，实际上，柴油D性能优于柴油B，由柴油B得到柴油D。这就清楚的表明，要生产高润滑性能的饱和柴油，沸点为500-700°F的直链C12-C24伯醇是很重要的。柴油F是由石油得到的低硫柴油的代表，虽然其呈现出相当高的润滑性能，但是没有高链烷烃柴油B的那么高。柴油G是柴油B和柴油F的1∶1的调合物，与柴油F比较，其呈现出改善的润滑性能。这表明高链烷柴油B不仅是很好的洁净的燃料组合物，而且也是能够改善由石油得到的低硫柴油的性能的很好的柴油调合组分。

Claims (12)

1.一种可用作比汽油重的燃料或用作馏分燃料的调合组分的物料，其包括由非变换费-托催化方法所得到的250-700°F的馏分，并且含有至少95％(重)的异构与正构比约0.3-3.0的链烷烃、≤50ppm(重)的硫和氮、少于约2％(重)的不饱和烃和约0.001-少于0.3％(重)的氧。
2.权利要求1的物料，其中氧主要是作为直链醇存在。
3.权利要求2的物料，其中直链醇是C12+醇。
4.权利要求3的物料，其特征在于十六烷值至少70。
5.一种生产比汽油重的馏分燃料的方法，其包括：
(a)把费-托方法的产物分离成为较重的馏分和较轻的馏分；
(b)在加氢异构化的条件下加氢异构化该较重的馏分，并且由其回收700°F-的馏分；
(c)把至少一部分步骤(b)回收的馏分与至少一部分较轻的馏分调合。
6.权利要求5的方法，其中从步骤(c)的调合产物回收沸点范围250-700°F的产物。
7.权利要求6的方法，其中从步骤(c)回收的产物含有0.001-0.3％(重)的氧，无水基。
8.权利要求7的产物。
9.权利要求6的方法，其中较轻的馏分的特征是未加氢处理。
10.权利要求6的方法，其中较轻的馏分含有C12+伯醇。
11.权利要求10的方法，其中较轻的馏分含有基本上全是C12-C24的伯醇。
12.权利要求6的方法，其中费-托方法的特征是非变换条件。
CN96197172A 1995-10-17 1996-10-08 合成柴油及其生产方法 Expired - Lifetime CN1082541C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/544,343 US6296757B1 (en) 1995-10-17 1995-10-17 Synthetic diesel fuel and process for its production
US08/544,343 1995-10-17

Publications (2)

Publication Number Publication Date
CN1197476A true CN1197476A (zh) 1998-10-28
CN1082541C CN1082541C (zh) 2002-04-10

Family

ID=24171786

Family Applications (1)

Application Number Title Priority Date Filing Date
CN96197172A Expired - Lifetime CN1082541C (zh) 1995-10-17 1996-10-08 合成柴油及其生产方法

Country Status (22)

Country Link
US (3) US6296757B1 (zh)
EP (2) EP1323813B1 (zh)
JP (1) JP3459651B2 (zh)
KR (1) KR100450812B1 (zh)
CN (1) CN1082541C (zh)
AR (1) AR004020A1 (zh)
AT (1) ATE258217T1 (zh)
AU (1) AU711556B2 (zh)
BR (1) BR9611080A (zh)
CA (1) CA2229433C (zh)
DE (1) DE69631383T2 (zh)
DK (1) DK0885275T3 (zh)
ES (1) ES2214549T3 (zh)
HK (1) HK1017009A1 (zh)
MX (1) MX9801989A (zh)
MY (2) MY114802A (zh)
NO (1) NO328941B1 (zh)
PT (1) PT885275E (zh)
RU (1) RU2160763C2 (zh)
TW (1) TW364010B (zh)
WO (1) WO1997014769A1 (zh)
ZA (1) ZA968338B (zh)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1659258B (zh) * 2002-06-07 2011-10-12 萨索尔技术(控股)有限公司 减少颗粒物排放的合成燃料及使用所述燃料和氧化催化剂操作压燃式发动机的方法
CN1692152B (zh) * 2001-03-05 2012-03-07 国际壳牌研究有限公司 中间馏分油的制备方法
CN101050392B (zh) * 2002-06-07 2012-07-11 萨索尔技术(控股)有限公司 减少颗粒物排放的合成燃料及使用所述燃料和氧化催化剂操作压燃式发动机的方法
CN106255739A (zh) * 2014-05-19 2016-12-21 国际壳牌研究有限公司 制备高纯度费‑托气油馏分的方法
CN106255740A (zh) * 2014-05-19 2016-12-21 国际壳牌研究有限公司 制备高纯度费‑托气油馏分的方法
CN106459785A (zh) * 2014-05-19 2017-02-22 国际壳牌研究有限公司 制备高纯度费托气油馏分的方法
CN108102703A (zh) * 2016-11-24 2018-06-01 中国石油化工股份有限公司 一种催化柴油的加工处理方法
CN113316629A (zh) * 2018-09-11 2021-08-27 巴西石油公司 通过集成到精炼厂中的费-托方法制备液体烃的方法

Families Citing this family (128)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6296757B1 (en) * 1995-10-17 2001-10-02 Exxon Research And Engineering Company Synthetic diesel fuel and process for its production
US5689031A (en) † 1995-10-17 1997-11-18 Exxon Research & Engineering Company Synthetic diesel fuel and process for its production
US5807413A (en) * 1996-08-02 1998-09-15 Exxon Research And Engineering Company Synthetic diesel fuel with reduced particulate matter emissions
ZA98619B (en) * 1997-02-07 1998-07-28 Exxon Research Engineering Co Alcohol as lubricity additives for distillate fuels
US5814109A (en) * 1997-02-07 1998-09-29 Exxon Research And Engineering Company Diesel additive for improving cetane, lubricity, and stability
US5766274A (en) 1997-02-07 1998-06-16 Exxon Research And Engineering Company Synthetic jet fuel and process for its production
US6162956A (en) † 1998-08-18 2000-12-19 Exxon Research And Engineering Co Stability Fischer-Tropsch diesel fuel and a process for its production
US6180842B1 (en) * 1998-08-21 2001-01-30 Exxon Research And Engineering Company Stability fischer-tropsch diesel fuel and a process for its production
US6475960B1 (en) * 1998-09-04 2002-11-05 Exxonmobil Research And Engineering Co. Premium synthetic lubricants
US6165949A (en) * 1998-09-04 2000-12-26 Exxon Research And Engineering Company Premium wear resistant lubricant
AU765274B2 (en) * 1998-10-05 2003-09-11 Sasol Technology (Pty) Ltd. Process for producing middle distillates and middle distillates produced by that process
EP1835011A1 (en) * 1998-10-05 2007-09-19 Sasol Technology (Pty) Ltd Biodegradable middle distillates and production thereof
US7217852B1 (en) 1998-10-05 2007-05-15 Sasol Technology (Pty) Ltd. Process for producing middle distillates and middle distillates produced by that process
EP2316874A1 (en) 1999-01-20 2011-05-04 Cabot Corporation Aggregates having attached polymer groups and polymer foams
AU2003252879B2 (en) * 1999-04-06 2005-04-21 Sasol Technology (Pty) Ltd Process for producing synthetic naphtha fuel and synthetic naphtha fuel produced by that process
EA002794B1 (ru) * 1999-04-06 2002-10-31 Сэсол Текнолоджи (Пти) Лтд. Способ получения синтетического бензинового топлива и бензиновое топливо, полученное таким способом
GB2357298A (en) * 1999-12-16 2001-06-20 Exxon Research Engineering Co Diesel fuel composition with enhanced lubricity
JP3662165B2 (ja) 2000-03-27 2005-06-22 トヨタ自動車株式会社 含酸素燃料の製造方法
US6695965B1 (en) * 2000-04-04 2004-02-24 Exxonmobil Research And Engineering Company Process for adjusting the hardness of Fischer-Tropsch wax by blending
US6663767B1 (en) * 2000-05-02 2003-12-16 Exxonmobil Research And Engineering Company Low sulfur, low emission blends of fischer-tropsch and conventional diesel fuels
EP1307529B1 (en) * 2000-05-02 2006-06-14 ExxonMobil Research and Engineering Company Use of fischer-tropsch fuel/cracked stock blends to achieve low emissions
US6787022B1 (en) * 2000-05-02 2004-09-07 Exxonmobil Research And Engineering Company Winter diesel fuel production from a fischer-tropsch wax
DE10038428A1 (de) * 2000-08-07 2002-02-21 Volkswagen Ag Dieselkraftstoff
US6908543B1 (en) * 2000-10-23 2005-06-21 Chevron U.S.A. Inc. Method for retarding fouling of feed heaters in refinery processing
US6872231B2 (en) * 2001-02-08 2005-03-29 Bp Corporation North America Inc. Transportation fuels
US6589415B2 (en) 2001-04-04 2003-07-08 Chevron U.S.A., Inc. Liquid or two-phase quenching fluid for multi-bed hydroprocessing reactor
US6583186B2 (en) 2001-04-04 2003-06-24 Chevron U.S.A. Inc. Method for upgrading Fischer-Tropsch wax using split-feed hydrocracking/hydrotreating
US6656342B2 (en) 2001-04-04 2003-12-02 Chevron U.S.A. Inc. Graded catalyst bed for split-feed hydrocracking/hydrotreating
US6833484B2 (en) * 2001-06-15 2004-12-21 Chevron U.S.A. Inc. Inhibiting oxidation of a Fischer-Tropsch product using petroleum-derived products
US6709569B2 (en) * 2001-12-21 2004-03-23 Chevron U.S.A. Inc. Methods for pre-conditioning fischer-tropsch light products preceding upgrading
US6759438B2 (en) * 2002-01-15 2004-07-06 Chevron U.S.A. Inc. Use of oxygen analysis by GC-AED for control of fischer-tropsch process and product blending
US6765025B2 (en) * 2002-01-17 2004-07-20 Dalian Institute Of Chemical Physics, Chinese Academy Of Science Process for direct synthesis of diesel distillates with high quality from synthesis gas through Fischer-Tropsch synthesis
US7208078B2 (en) * 2002-03-22 2007-04-24 Exxonmobil Research And Engineering Company Diesel fuel formulation for reduced emissions
AR043292A1 (es) * 2002-04-25 2005-07-27 Shell Int Research Uso de gasoil derivado de fischer-tropsch y una composicion combustible que lo contiene
ITMI20021131A1 (it) * 2002-05-24 2003-11-24 Agip Petroli Composizioni essenzialmente idrocarburiche utilizzabili come carburanti con migliorate proprieta' lubrificante
US20050154240A1 (en) * 2002-06-07 2005-07-14 Myburgh Ian S. Synthetic fuel with reduced particulate matter emissions and a method of operating a compression ignition engine using said fuel in conjunction with oxidation catalysts
JP3735594B2 (ja) * 2002-06-28 2006-01-18 株式会社東芝 光ディスク装置と光ディスク装置の待機方法
US7199088B2 (en) 2002-07-01 2007-04-03 Shell Oil Company Lubricating oil for a diesel powered engine and method of operating a diesel powered engine
CA2493879A1 (en) * 2002-07-19 2004-01-29 Shell Internationale Research Maatschappij B.V. Use of a fischer-tropsch derived fuel in a condensing boiler
US7354462B2 (en) * 2002-10-04 2008-04-08 Chevron U.S.A. Inc. Systems and methods of improving diesel fuel performance in cold climates
US6949180B2 (en) * 2002-10-09 2005-09-27 Chevron U.S.A. Inc. Low toxicity Fischer-Tropsch derived fuel and process for making same
US6824574B2 (en) 2002-10-09 2004-11-30 Chevron U.S.A. Inc. Process for improving production of Fischer-Tropsch distillate fuels
MY140297A (en) 2002-10-18 2009-12-31 Shell Int Research A fuel composition comprising a base fuel, a fischer-tropsch derived gas oil and an oxygenate
AR041930A1 (es) 2002-11-13 2005-06-01 Shell Int Research Composiciones de combustible diesel
JP5021168B2 (ja) * 2002-12-03 2012-09-05 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 予混合圧縮着火（ｈｃｃｉ）エンジンの性能を制御する方法及び装置
AU2004200235B2 (en) * 2003-01-31 2009-12-03 Chevron U.S.A. Inc. Stable olefinic, low sulfur diesel fuels
US7150821B2 (en) * 2003-01-31 2006-12-19 Chevron U.S.A. Inc. High purity olefinic naphthas for the production of ethylene and propylene
US6933323B2 (en) * 2003-01-31 2005-08-23 Chevron U.S.A. Inc. Production of stable olefinic fischer tropsch fuels with minimum hydrogen consumption
US7179311B2 (en) * 2003-01-31 2007-02-20 Chevron U.S.A. Inc. Stable olefinic, low sulfur diesel fuels
US6872752B2 (en) * 2003-01-31 2005-03-29 Chevron U.S.A. Inc. High purity olefinic naphthas for the production of ethylene and propylene
US7479168B2 (en) * 2003-01-31 2009-01-20 Chevron U.S.A. Inc. Stable low-sulfur diesel blend of an olefinic blend component, a low-sulfur blend component, and a sulfur-free antioxidant
US7431821B2 (en) * 2003-01-31 2008-10-07 Chevron U.S.A. Inc. High purity olefinic naphthas for the production of ethylene and propylene
BRPI0400580A (pt) * 2003-02-24 2005-01-04 Syntroleum Corp Fluidos base, e de perfuração, processo para a produção de um fluido de perfuração, e, método de perfuração de um furo de sondagem em uma formação subterrânea
US20040173501A1 (en) * 2003-03-05 2004-09-09 Conocophillips Company Methods for treating organic compounds and treated organic compounds
US20050165261A1 (en) * 2003-03-14 2005-07-28 Syntroleum Corporation Synthetic transportation fuel and method for its production
NL1026215C2 (nl) * 2003-05-19 2005-07-08 Sasol Tech Pty Ltd Koolwaterstofsamenstelling voor gebruik in CI motoren.
JP4580152B2 (ja) * 2003-06-12 2010-11-10 出光興産株式会社 ディーゼルエンジン用燃料油
US20050016899A1 (en) * 2003-07-21 2005-01-27 Syntroleum Corporation Synthetic lubricant basestock and an integrated fischer-tropsch process for its production
CA2534083A1 (en) * 2003-08-01 2005-03-03 The Procter & Gamble Company Fuel for jet, gas turbine, rocket, and diesel engines
BRPI0413191A (pt) * 2003-08-01 2006-10-03 Procter & Gamble combustìvel para motores a jato, de turbina a gás, de foguete e a diesel
EP1664248B1 (en) * 2003-09-03 2011-12-21 Shell Internationale Research Maatschappij B.V. Fuel compositions
AU2004269169B2 (en) * 2003-09-03 2008-11-13 Shell Internationale Research Maatschappij B.V. Fuel compositions comprising Fischer-Tropsch derived fuel
EP1678275A1 (en) * 2003-10-29 2006-07-12 Shell Internationale Researchmaatschappij B.V. Process to transport a methanol or hydrocarbon product
FR2864532B1 (fr) * 2003-12-31 2007-04-13 Total France Procede de transformation d'un gaz de synthese en hydrocarbures en presence de sic beta et effluent de ce procede
FR2864528B1 (fr) * 2003-12-31 2006-12-15 Total France Procede de traitement des melanges methane/dioxyde de carbone
US7354507B2 (en) * 2004-03-17 2008-04-08 Conocophillips Company Hydroprocessing methods and apparatus for use in the preparation of liquid hydrocarbons
JP4955541B2 (ja) * 2004-05-26 2012-06-20 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ フィッシャー・トロプシュ生成物の接触分解によるガス油の製造方法
US7345210B2 (en) * 2004-06-29 2008-03-18 Conocophillips Company Blending for density specifications using Fischer-Tropsch diesel fuel
US7404888B2 (en) * 2004-07-07 2008-07-29 Chevron U.S.A. Inc. Reducing metal corrosion of hydrocarbons using acidic fischer-tropsch products
US20060016722A1 (en) * 2004-07-08 2006-01-26 Conocophillips Company Synthetic hydrocarbon products
US7345211B2 (en) * 2004-07-08 2008-03-18 Conocophillips Company Synthetic hydrocarbon products
US7951287B2 (en) * 2004-12-23 2011-05-31 Chevron U.S.A. Inc. Production of low sulfur, moderately aromatic distillate fuels by hydrocracking of combined Fischer-Tropsch and petroleum streams
US7374657B2 (en) * 2004-12-23 2008-05-20 Chevron Usa Inc. Production of low sulfur, moderately aromatic distillate fuels by hydrocracking of combined Fischer-Tropsch and petroleum streams
US20060222828A1 (en) * 2005-04-01 2006-10-05 John Boyle & Company, Inc. Recyclable display media
JP5339897B2 (ja) * 2005-04-11 2013-11-13 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 船舶上で鉱物誘導生成物とフィッシャー−トロプシュ誘導生成物とをブレンドする方法
CN100389181C (zh) * 2005-04-29 2008-05-21 中国石油化工股份有限公司 一种从费托合成油多产中间馏分油的方法
CN100395315C (zh) * 2005-04-29 2008-06-18 中国石油化工股份有限公司 一种费托合成物加氢提质组合工艺方法
US7447597B2 (en) * 2005-05-06 2008-11-04 Exxonmobil Research And Engineering Company Data processing/visualization method for two (multi) dimensional separation gas chromatography xmass spectrometry (GCxMS) technique with a two (multiply) dimensional separation concept as an example
US20060278565A1 (en) * 2005-06-10 2006-12-14 Chevron U.S.A. Inc. Low foaming distillate fuel blend
BRPI0615192A2 (pt) 2005-08-22 2011-05-10 Shell Int Research combustÍvel diesel, e, mÉtodos para operar um motor a diesel e para reduzir a emissço de àxidos de nitrogÊnio
WO2007039460A1 (en) * 2005-09-21 2007-04-12 Shell Internationale Research Maatschappij B.V. Process to blend a mineral derived hydrocarbon product and a fisher-tropsch derived hydrocarbon product
WO2007055935A2 (en) * 2005-11-03 2007-05-18 Chevron U.S.A. Inc. Fischer-tropsch derived turbine fuel and process for making same
AR059751A1 (es) 2006-03-10 2008-04-23 Shell Int Research Composiciones de combustible diesel
MY148376A (en) * 2006-03-30 2013-04-15 Nippon Oil Corp Method for treatment of synthetic oil, process for production of hydrocarbon oil, hydrocarbon oil for hydrogen production, hydrocarbon oil for the smoke point improver for kerosene, and hydrocarbon oil for diesel fuel base
US8080068B2 (en) * 2006-03-31 2011-12-20 Jx Nippon Oil & Energy Corporation Light oil compositions
US20070259973A1 (en) * 2006-05-03 2007-11-08 Syntroleum Corporation Optimized hydrocarbon synthesis process
US8766022B2 (en) * 2006-06-28 2014-07-01 Shell Oil Company Method for synergistically increasing the cetane number of a fuel composition and a fuel composition comprising a synergistically increased cetane number
WO2008012320A1 (en) 2006-07-27 2008-01-31 Shell Internationale Research Maatschappij B.V. Fuel compositions
WO2008046901A1 (en) 2006-10-20 2008-04-24 Shell Internationale Research Maatschappij B.V. Fuel compositions
US20080155889A1 (en) * 2006-12-04 2008-07-03 Chevron U.S.A. Inc. Fischer-tropsch derived diesel fuel and process for making same
US20080260631A1 (en) 2007-04-18 2008-10-23 H2Gen Innovations, Inc. Hydrogen production process
EP2158306A1 (en) 2007-05-11 2010-03-03 Shell Internationale Research Maatschappij B.V. Fuel composition
CA2617614C (en) 2007-08-10 2012-03-27 Indian Oil Corporation Limited Novel synthetic fuel and method of preparation thereof
CA2702860A1 (en) 2007-10-19 2009-04-23 Mark Lawrence Brewer Functional fluids for internal combustion engines
EP2078744A1 (en) 2008-01-10 2009-07-15 Shell Internationale Researchmaatschappij B.V. Fuel compositions
US7955495B2 (en) * 2008-07-31 2011-06-07 Chevron U.S.A. Inc. Composition of middle distillate
EP2370553B1 (en) 2008-12-29 2013-07-24 Shell Internationale Research Maatschappij B.V. FUEL COMPOSITIONS containing tetrahydroquinoline
WO2010076303A1 (en) 2008-12-29 2010-07-08 Shell Internationale Research Maatschappij B.V. Fuel compositions
JP2013515802A (ja) 2009-12-24 2013-05-09 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 液体燃料組成物
RU2012132488A (ru) 2009-12-29 2014-02-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Композиции жидких топлив
WO2011110551A1 (en) 2010-03-10 2011-09-15 Shell Internationale Research Maatschappij B.V. Method of reducing the toxicity of used lubricating compositions
EP2371931B1 (en) 2010-03-23 2013-12-11 Shell Internationale Research Maatschappij B.V. Fuel compositions containing biodiesel and Fischer-Tropsch derived diesel
SE534969C2 (sv) * 2010-05-25 2012-03-06 Ec1 Invent Ab Värmeväxlingsmedium innefattande en syntetisk diesel
RU2484457C2 (ru) * 2011-02-21 2013-06-10 Муниципальное унитарное предприятие по эксплуатации водопроводно-канализационного хозяйства "Уфаводоканал" Способ определения загрязненности воды дизельным топливом
US20120304531A1 (en) 2011-05-30 2012-12-06 Shell Oil Company Liquid fuel compositions
EP2748290A1 (en) 2011-09-06 2014-07-02 Shell Internationale Research Maatschappij B.V. Liquid fuel compositions
EP2738240A1 (en) 2012-11-30 2014-06-04 Schepers Handels- en domeinnamen B.V. Use of a Gas-to-Liquids gas oil in a lamp oil composition or fire lighter
TR201908686T4 (tr) 2012-12-21 2019-07-22 Shell Int Research Bir dizel yakıt bileşiminde bir organik güneş koruyucu bileşiklerin kullanımı.
US9447356B2 (en) 2013-02-20 2016-09-20 Shell Oil Company Diesel fuel with improved ignition characteristics
FI126330B (en) * 2013-04-02 2016-10-14 Upm Kymmene Corp Renewable hydrocarbon composition
FI126331B (en) 2013-04-02 2016-10-14 Upm Kymmene Corp Renewable hydrocarbon composition
CN105658774B (zh) 2013-10-24 2018-04-06 国际壳牌研究有限公司 液体燃料组合物
CN105814176B (zh) 2013-12-16 2017-08-15 国际壳牌研究有限公司 液体燃料组合物
EP2889361A1 (en) 2013-12-31 2015-07-01 Shell Internationale Research Maatschappij B.V. Diesel fuel formulation and use thereof
DK3129449T3 (en) 2014-04-08 2018-06-14 Shell Int Research DIESEL FUEL WITH IMPROVED IGNITION FEATURES
US20180036709A1 (en) * 2014-05-27 2018-02-08 Portable GTL Systems, LLC Portable fuel synthesizer
EP2949732B1 (en) 2014-05-28 2018-06-20 Shell International Research Maatschappij B.V. Use of an oxanilide compound in a diesel fuel composition for the purpose of modifying the ignition delay and/or the burn period
WO2016075166A1 (en) 2014-11-12 2016-05-19 Shell Internationale Research Maatschappij B.V. Fuel composition
EP3353270B1 (en) 2015-09-22 2022-08-10 Shell Internationale Research Maatschappij B.V. Fuel compositions
MY188997A (en) 2015-11-11 2022-01-17 Shell Int Research Process for preparing a diesel fuel composition
BR112018010277B1 (pt) 2015-11-30 2021-09-21 Shell Internationale Research Maatschappij B.V. Composição de combustível líquido para um motor de combustão interna de ignição por centelha
EP3184612A1 (en) 2015-12-21 2017-06-28 Shell Internationale Research Maatschappij B.V. Process for preparing a diesel fuel composition
WO2018077976A1 (en) 2016-10-27 2018-05-03 Shell Internationale Research Maatschappij B.V. Process for preparing an automotive gasoil
WO2018206729A1 (en) 2017-05-11 2018-11-15 Shell Internationale Research Maatschappij B.V. Process for preparing an automotive gas oil fraction
MX2020010890A (es) 2018-04-20 2020-11-09 Shell Int Research Combustible diesel con caracteristicas de ignicion mejoradas.
MX2020013813A (es) 2018-07-02 2021-03-09 Shell Int Research Composiciones de combustible liquido.
MX2023012349A (es) 2021-04-26 2023-10-30 Shell Int Research Composiciones de combustible.
JP2024515768A (ja) 2021-04-26 2024-04-10 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 燃料組成物

Family Cites Families (250)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3123573A (en) 1964-03-03 Isomerization catalyst and process
CA539698A (en) 1957-04-16 M. Good George Isomerization of paraffin waxes
CA700237A (en) 1964-12-22 L. Miller Elmer Fluorinated palladium on silica-alumina catalyst for isomerizing normal paraffin hydrocarbons
FR732964A (fr) 1931-03-20 1932-09-28 Deutsche Hydrierwerke Ag Procédé d'amélioration des combustibles ou carburants pour moteurs
US2243760A (en) 1936-03-04 1941-05-27 Ruhrchemie Ag Process for producing diesel oils
FR859686A (fr) 1938-08-31 1940-12-24 Synthetic Oils Ltd Procédé pour améliorer les produits de la synthèse d'hydrocarbures à partir d'oxyde de carbone et d'hydrogène
US2562980A (en) 1948-06-05 1951-08-07 Texas Co Process for upgrading diesel fuel
US2668866A (en) 1951-08-14 1954-02-09 Shell Dev Isomerization of paraffin wax
GB728543A (en) 1952-03-05 1955-04-20 Koppers Gmbh Heinrich Process for the synthesis of hydrocarbons
NL94402C (zh) 1952-05-13
US2668790A (en) 1953-01-12 1954-02-09 Shell Dev Isomerization of paraffin wax
US2914464A (en) 1953-05-01 1959-11-24 Kellogg M W Co Hydrocarbon conversion process with platinum or palladium containing composite catalyst
US2817693A (en) 1954-03-29 1957-12-24 Shell Dev Production of oils from waxes
US2838444A (en) 1955-02-21 1958-06-10 Engelhard Ind Inc Platinum-alumina catalyst manufacture
US2779713A (en) 1955-10-10 1957-01-29 Texas Co Process for improving lubricating oils by hydro-refining in a first stage and then hydrofinishing under milder conditions
US2906688A (en) 1956-03-28 1959-09-29 Exxon Research Engineering Co Method for producing very low pour oils from waxy oils having boiling ranges of 680 deg.-750 deg. f. by distilling off fractions and solvents dewaxing each fraction
NL223552A (zh) 1956-12-24
US2888501A (en) 1956-12-31 1959-05-26 Pure Oil Co Process and catalyst for isomerizing hydrocarbons
US2892003A (en) 1957-01-09 1959-06-23 Socony Mobil Oil Co Inc Isomerization of paraffin hydrocarbons
US2982802A (en) 1957-10-31 1961-05-02 Pure Oil Co Isomerization of normal paraffins
US3002827A (en) 1957-11-29 1961-10-03 Exxon Research Engineering Co Fuel composition for diesel engines
US2993938A (en) 1958-06-18 1961-07-25 Universal Oil Prod Co Hydroisomerization process
GB848198A (en) 1958-07-07 1960-09-14 Universal Oil Prod Co Process for hydroisomerization of hydrocarbons
US3078323A (en) 1959-12-31 1963-02-19 Gulf Research Development Co Hydroisomerization process
US3052622A (en) 1960-05-17 1962-09-04 Sun Oil Co Hydrorefining of waxy petroleum residues
GB953189A (en) 1960-09-07 1964-03-25 British Petroleum Co Improvements relating to the isomerisation of paraffin hydrocarbons
US3206525A (en) 1960-10-26 1965-09-14 Sinclair Refining Co Process for isomerizing paraffinic hydrocarbons
NL270707A (zh) 1960-10-28
BE615233A (zh) 1960-12-01 1900-01-01
US3121696A (en) 1960-12-06 1964-02-18 Universal Oil Prod Co Method for preparation of a hydrocarbon conversion catalyst
GB968891A (en) 1961-07-04 1964-09-02 British Petroleum Co Improvements relating to the conversion of hydrocarbons
US3188286A (en) 1961-10-03 1965-06-08 Cities Service Res & Dev Co Hydrocracking heavy hydrocarbon oil
GB951997A (en) 1962-01-26 1964-03-11 British Petroleum Co Improvements relating to the preparation of lubricating oils
BE627517A (zh) 1962-01-26
BE628572A (zh) 1962-02-20
US3147210A (en) 1962-03-19 1964-09-01 Union Oil Co Two stage hydrogenation process
US3268436A (en) 1964-02-25 1966-08-23 Exxon Research Engineering Co Paraffinic jet fuel by hydrocracking wax
US3308052A (en) 1964-03-04 1967-03-07 Mobil Oil Corp High quality lube oil and/or jet fuel from waxy petroleum fractions
US3340180A (en) 1964-08-25 1967-09-05 Gulf Research Development Co Hydrofining-hydrocracking process employing special alumina base catalysts
US3362378A (en) * 1964-10-28 1968-01-09 Navy Usa Light extending product and process
GB1065205A (en) 1964-12-08 1967-04-12 Shell Int Research Process for the production of lubricating oils or lubricating oil components
DE1233369B (de) 1965-03-10 1967-02-02 Philips Nv Verfahren zur Herstellung von Aluminiumnitrid
US3404086A (en) 1966-03-30 1968-10-01 Mobil Oil Corp Hydrothermally stable catalysts of high activity and methods for their preparation
US3365390A (en) 1966-08-23 1968-01-23 Chevron Res Lubricating oil production
US3471399A (en) 1967-06-09 1969-10-07 Universal Oil Prod Co Hydrodesulfurization catalyst and process for treating residual fuel oils
US3629096A (en) 1967-06-21 1971-12-21 Atlantic Richfield Co Production of technical white mineral oil
US3770618A (en) 1967-06-26 1973-11-06 Exxon Research Engineering Co Hydrodesulfurization of residua
US3507776A (en) 1967-12-29 1970-04-21 Phillips Petroleum Co Isomerization of high freeze point normal paraffins
US3486993A (en) 1968-01-24 1969-12-30 Chevron Res Catalytic production of low pour point lubricating oils
US3487005A (en) 1968-02-12 1969-12-30 Chevron Res Production of low pour point lubricating oils by catalytic dewaxing
GB1242889A (en) 1968-11-07 1971-08-18 British Petroleum Co Improvements relating to the hydrocatalytic treatment of hydrocarbons
US3668112A (en) 1968-12-06 1972-06-06 Texaco Inc Hydrodesulfurization process
US3594307A (en) 1969-02-14 1971-07-20 Sun Oil Co Production of high quality jet fuels by two-stage hydrogenation
US3660058A (en) 1969-03-17 1972-05-02 Exxon Research Engineering Co Increasing low temperature flowability of middle distillate fuel
US3607729A (en) 1969-04-07 1971-09-21 Shell Oil Co Production of kerosene jet fuels
US3620960A (en) 1969-05-07 1971-11-16 Chevron Res Catalytic dewaxing
US3861005A (en) 1969-05-28 1975-01-21 Sun Oil Co Pennsylvania Catalytic isomerization of lube streams and waxes
US3658689A (en) 1969-05-28 1972-04-25 Sun Oil Co Isomerization of waxy lube streams and waxes
US3725302A (en) 1969-06-17 1973-04-03 Texaco Inc Silanized crystalline alumino-silicate
US3530061A (en) 1969-07-16 1970-09-22 Mobil Oil Corp Stable hydrocarbon lubricating oils and process for forming same
GB1314828A (en) 1969-08-13 1973-04-26 Ici Ltd Transition metal compositions and polymerisation process catalysed thereby
US3630885A (en) 1969-09-09 1971-12-28 Chevron Res Process for producing high yields of low freeze point jet fuel
US3619408A (en) 1969-09-19 1971-11-09 Phillips Petroleum Co Hydroisomerization of motor fuel stocks
FR2091872B1 (zh) 1970-03-09 1973-04-06 Shell Berre Raffinage
DE2113987A1 (de) 1970-04-01 1972-03-09 Rafinaria Ploiesti Verfahren zur Raffination von Erdoelfraktionen
US3674681A (en) 1970-05-25 1972-07-04 Exxon Research Engineering Co Process for isomerizing hydrocarbons by use of high pressures
FR2194767B1 (zh) 1972-08-04 1975-03-07 Shell France
US3843746A (en) 1970-06-16 1974-10-22 Texaco Inc Isomerization of c10-c14 hydrocarbons with fluorided metal-alumina catalyst
US3717586A (en) 1970-06-25 1973-02-20 Texaco Inc Fluorided composite alumina catalysts
US3692696A (en) 1970-06-25 1972-09-19 Texaco Inc Catalyst for hydrocarbon conversion
US3840614A (en) 1970-06-25 1974-10-08 Texaco Inc Isomerization of c10-c14 hydrocarbons with fluorided metal-alumina catalyst
US3681232A (en) 1970-11-27 1972-08-01 Chevron Res Combined hydrocracking and catalytic dewaxing process
US3711399A (en) 1970-12-24 1973-01-16 Texaco Inc Selective hydrocracking and isomerization of paraffin hydrocarbons
GB1342500A (en) 1970-12-28 1974-01-03 Shell Int Research Process for the preparation of a catalyst suitable for the production of lubricating oil
US3709817A (en) 1971-05-18 1973-01-09 Texaco Inc Selective hydrocracking and isomerization of paraffin hydrocarbons
US3767562A (en) 1971-09-02 1973-10-23 Lummus Co Production of jet fuel
US3775291A (en) 1971-09-02 1973-11-27 Lummus Co Production of jet fuel
US3870622A (en) 1971-09-09 1975-03-11 Texaco Inc Hydrogenation of a hydrocracked lubricating oil
US3761388A (en) 1971-10-20 1973-09-25 Gulf Research Development Co Lube oil hydrotreating process
JPS5141641B2 (zh) 1972-01-06 1976-11-11
GB1429291A (en) 1972-03-07 1976-03-24 Shell Int Research Process for the preparation of lubricating oil
US3848018A (en) 1972-03-09 1974-11-12 Exxon Research Engineering Co Hydroisomerization of normal paraffinic hydrocarbons with a catalyst composite of chrysotile and hydrogenation metal
GB1381004A (en) 1972-03-10 1975-01-22 Exxon Research Engineering Co Preparation of high viscosity index lubricating oils
US3830728A (en) 1972-03-24 1974-08-20 Cities Service Res & Dev Co Hydrocracking and hydrodesulfurization process
CA1003778A (en) 1972-04-06 1977-01-18 Peter Ladeur Hydrocarbon conversion process
US3814682A (en) 1972-06-14 1974-06-04 Gulf Research Development Co Residue hydrodesulfurization process with catalysts whose pores have a large orifice size
US3876522A (en) 1972-06-15 1975-04-08 Ian D Campbell Process for the preparation of lubricating oils
FR2209827B1 (zh) 1972-12-08 1976-01-30 Inst Francais Du Petrole Fr
US3852207A (en) 1973-03-26 1974-12-03 Chevron Res Production of stable lubricating oils by sequential hydrocracking and hydrogenation
US3852186A (en) 1973-03-29 1974-12-03 Gulf Research Development Co Combination hydrodesulfurization and fcc process
US3976560A (en) 1973-04-19 1976-08-24 Atlantic Richfield Company Hydrocarbon conversion process
US3963601A (en) 1973-08-20 1976-06-15 Universal Oil Products Company Hydrocracking of hydrocarbons with a catalyst comprising an alumina-silica support, a group VIII metallic component, a group VI-B metallic component and a fluoride
US3864425A (en) 1973-09-17 1975-02-04 Phillips Petroleum Co Ruthenium-promoted fluorided alumina as a support for SBF{HD 5{B -HF in paraffin isomerization
NL177696C (nl) 1973-12-18 1985-11-01 Shell Int Research Werkwijze voor het bereiden van smeerolien met een hoge viscositeitsindex door hydrokraken van zware koolwaterstoffen.
US4014821A (en) 1974-02-07 1977-03-29 Exxon Research And Engineering Company Heavy crude conversion catalyst
US3977961A (en) 1974-02-07 1976-08-31 Exxon Research And Engineering Company Heavy crude conversion
US3977962A (en) 1974-02-07 1976-08-31 Exxon Research And Engineering Company Heavy crude conversion
US3887455A (en) 1974-03-25 1975-06-03 Exxon Research Engineering Co Ebullating bed process for hydrotreatment of heavy crudes and residua
CA1069452A (en) 1974-04-11 1980-01-08 Atlantic Richfield Company Production of white oils by two stages of hydrogenation
US4067797A (en) 1974-06-05 1978-01-10 Mobil Oil Corporation Hydrodewaxing
US3979279A (en) 1974-06-17 1976-09-07 Mobil Oil Corporation Treatment of lube stock for improvement of oxidative stability
GB1460476A (en) 1974-08-08 1977-01-06 Carl Mfg Co Hole punches
US4032304A (en) 1974-09-03 1977-06-28 The Lubrizol Corporation Fuel compositions containing esters and nitrogen-containing dispersants
NL180636C (nl) 1975-04-18 1987-04-01 Shell Int Research Werkwijze voor het fluoreren van een katalysator.
US4041095A (en) 1975-09-18 1977-08-09 Mobil Oil Corporation Method for upgrading C3 plus product of Fischer-Tropsch Synthesis
US4079025A (en) 1976-04-27 1978-03-14 A. E. Staley Manufacturing Company Copolymerized starch composition
US4073718A (en) 1976-05-12 1978-02-14 Exxon Research & Engineering Co. Process for the hydroconversion and hydrodesulfurization of heavy feeds and residua
US4051021A (en) 1976-05-12 1977-09-27 Exxon Research & Engineering Co. Hydrodesulfurization of hydrocarbon feed utilizing a silica stabilized alumina composite catalyst
US4059648A (en) 1976-07-09 1977-11-22 Mobil Oil Corporation Method for upgrading synthetic oils boiling above gasoline boiling material
FR2362208A1 (fr) 1976-08-17 1978-03-17 Inst Francais Du Petrole Procede de valorisation d'effluents obtenus dans des syntheses de type fischer-tropsch
JPS5335705A (en) 1976-09-14 1978-04-03 Toa Nenryo Kogyo Kk Hydrogenation and purification of petroleum wax
US4304871A (en) 1976-10-15 1981-12-08 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbon mixtures utilizing a dual catalyst bed
US4087349A (en) 1977-06-27 1978-05-02 Exxon Research & Engineering Co. Hydroconversion and desulfurization process
US4186078A (en) 1977-09-12 1980-01-29 Toa Nenryo Kogyo Kabushiki Kaisha Catalyst and process for hydrofining petroleum wax
US4212771A (en) 1978-08-08 1980-07-15 Exxon Research & Engineering Co. Method of preparing an alumina catalyst support and catalyst comprising the support
US4162962A (en) 1978-09-25 1979-07-31 Chevron Research Company Sequential hydrocracking and hydrogenating process for lube oil production
US4487688A (en) 1979-12-19 1984-12-11 Mobil Oil Corporation Selective sorption of lubricants of high viscosity index
US4263127A (en) 1980-01-07 1981-04-21 Atlantic Richfield Company White oil process
DE3030998A1 (de) 1980-08-16 1982-04-01 Metallgesellschaft Ag, 6000 Frankfurt Verfahren zur herstellung von kraftstoffen mit einem ueberwiegenden anteil an dieseloel
US4539014A (en) 1980-09-02 1985-09-03 Texaco Inc. Low flash point diesel fuel of increased conductivity containing amyl alcohol
US4342641A (en) 1980-11-18 1982-08-03 Sun Tech, Inc. Maximizing jet fuel from shale oil
US4392940A (en) 1981-04-09 1983-07-12 International Coal Refining Company Coal-oil slurry preparation
US4394251A (en) 1981-04-28 1983-07-19 Chevron Research Company Hydrocarbon conversion with crystalline silicate particle having an aluminum-containing outer shell
US4390414A (en) 1981-12-16 1983-06-28 Exxon Research And Engineering Co. Selective dewaxing of hydrocarbon oil using surface-modified zeolites
US4378973A (en) 1982-01-07 1983-04-05 Texaco Inc. Diesel fuel containing cyclohexane, and oxygenated compounds
US4427790A (en) 1982-03-08 1984-01-24 Mobil Oil Corporation Activation of zeolites
US4444895A (en) 1982-05-05 1984-04-24 Exxon Research And Engineering Co. Reactivation process for iridium-containing catalysts using low halogen flow rates
US4855530A (en) 1982-05-18 1989-08-08 Mobil Oil Corporation Isomerization process
US4962269A (en) 1982-05-18 1990-10-09 Mobil Oil Corporation Isomerization process
US4427534A (en) 1982-06-04 1984-01-24 Gulf Research & Development Company Production of jet and diesel fuels from highly aromatic oils
US4428819A (en) 1982-07-22 1984-01-31 Mobil Oil Corporation Hydroisomerization of catalytically dewaxed lubricating oils
US4477586A (en) 1982-08-27 1984-10-16 Phillips Petroleum Company Polymerization of olefins
US4518395A (en) 1982-09-21 1985-05-21 Nuodex Inc. Process for the stabilization of metal-containing hydrocarbon fuel compositions
JPS59122597A (ja) 1982-11-30 1984-07-16 Honda Motor Co Ltd 潤滑油組成物
US4472529A (en) 1983-01-17 1984-09-18 Uop Inc. Hydrocarbon conversion catalyst and use thereof
NZ208911A (en) * 1983-07-15 1988-04-29 Broken Hill Pty Co Ltd Liquid fuels containing cycloalkanes
US4427791A (en) 1983-08-15 1984-01-24 Mobil Oil Corporation Activation of inorganic oxides
FR2560068B1 (fr) 1984-02-28 1986-08-01 Shell Int Research Procede de fluoration in situ d'un catalyseur
NL8401253A (nl) 1984-04-18 1985-11-18 Shell Int Research Werkwijze voor de bereiding van koolwaterstoffen.
US4579986A (en) 1984-04-18 1986-04-01 Shell Oil Company Process for the preparation of hydrocarbons
US4527995A (en) 1984-05-14 1985-07-09 Kabushiki Kaisha Komatsu Seisakusho Fuel blended with alcohol for diesel engine
US4568663A (en) 1984-06-29 1986-02-04 Exxon Research And Engineering Co. Cobalt catalysts for the conversion of methanol to hydrocarbons and for Fischer-Tropsch synthesis
US4588701A (en) 1984-10-03 1986-05-13 Union Carbide Corp. Catalytic cracking catalysts
US4673487A (en) 1984-11-13 1987-06-16 Chevron Research Company Hydrogenation of a hydrocrackate using a hydrofinishing catalyst comprising palladium
US4960504A (en) 1984-12-18 1990-10-02 Uop Dewaxing catalysts and processes employing silicoaluminophosphate molecular sieves
US4919788A (en) 1984-12-21 1990-04-24 Mobil Oil Corporation Lubricant production process
US4599162A (en) 1984-12-21 1986-07-08 Mobil Oil Corporation Cascade hydrodewaxing process
US4749467A (en) 1985-04-18 1988-06-07 Mobil Oil Corporation Lube dewaxing method for extension of cycle length
US4618412A (en) 1985-07-31 1986-10-21 Exxon Research And Engineering Co. Hydrocracking process
US4755280A (en) 1985-07-31 1988-07-05 Exxon Research And Engineering Company Process for improving the color and oxidation stability of hydrocarbon streams containing multi-ring aromatic and hydroaromatic hydrocarbons
US4627908A (en) 1985-10-24 1986-12-09 Chevron Research Company Process for stabilizing lube base stocks derived from bright stock
AU603344B2 (en) 1985-11-01 1990-11-15 Mobil Oil Corporation Two stage lubricant dewaxing process
US5037528A (en) 1985-11-01 1991-08-06 Mobil Oil Corporation Lubricant production process with product viscosity control
US4608151A (en) 1985-12-06 1986-08-26 Chevron Research Company Process for producing high quality, high molecular weight microcrystalline wax derived from undewaxed bright stock
EP0227218A1 (en) 1985-12-23 1987-07-01 Exxon Research And Engineering Company Method for improving the fuel economy of an internal combustion engine
US4684756A (en) 1986-05-01 1987-08-04 Mobil Oil Corporation Process for upgrading wax from Fischer-Tropsch synthesis
US5504118A (en) 1986-05-08 1996-04-02 Rentech, Inc. Process for the production of hydrocarbons
US5543437A (en) 1986-05-08 1996-08-06 Rentech, Inc. Process for the production of hydrocarbons
US5324335A (en) 1986-05-08 1994-06-28 Rentech, Inc. Process for the production of hydrocarbons
US4695365A (en) 1986-07-31 1987-09-22 Union Oil Company Of California Hydrocarbon refining process
CA1312066C (en) 1986-10-03 1992-12-29 William C. Behrmann Surface supported particulate metal compound catalysts, their use in hydrocarbon synthesis reactions and their preparation
CA1305467C (en) 1986-12-12 1992-07-21 Nobumitsu Ohtake Additive for the hydroconversion of a heavy hydrocarbon oil
US4764266A (en) 1987-02-26 1988-08-16 Mobil Oil Corporation Integrated hydroprocessing scheme for production of premium quality distillates and lubricants
US4851109A (en) * 1987-02-26 1989-07-25 Mobil Oil Corporation Integrated hydroprocessing scheme for production of premium quality distillates and lubricants
US4812246A (en) 1987-03-12 1989-03-14 Idemitsu Kosan Co., Ltd. Base oil for lubricating oil and lubricating oil composition containing said base oil
US5128377A (en) 1987-05-07 1992-07-07 Exxon Research And Engineering Company Cobalt-titania catalysts, process utilizing these catalysts for the preparation of hydrocarbons from synthesis gas, and process for the preparation of said catalysts (C-2448)
US5545674A (en) 1987-05-07 1996-08-13 Exxon Research And Engineering Company Surface supported cobalt catalysts, process utilizing these catalysts for the preparation of hydrocarbons from synthesis gas and process for the preparation of said catalysts
US4929795A (en) 1987-12-18 1990-05-29 Exxon Research And Engineering Company Method for isomerizing wax to lube base oils using an isomerization catalyst
US4875992A (en) 1987-12-18 1989-10-24 Exxon Research And Engineering Company Process for the production of high density jet fuel from fused multi-ring aromatics and hydroaromatics
US4832819A (en) 1987-12-18 1989-05-23 Exxon Research And Engineering Company Process for the hydroisomerization and hydrocracking of Fisher-Tropsch waxes to produce a syncrude and upgraded hydrocarbon products
US4943672A (en) 1987-12-18 1990-07-24 Exxon Research And Engineering Company Process for the hydroisomerization of Fischer-Tropsch wax to produce lubricating oil (OP-3403)
NO885553L (no) 1987-12-18 1989-06-19 Exxon Research Engineering Co Katalysator for hydroisomerisering og hydrokrakking av voks for aa fremstille flytende hydrokarbon-brennstoff.
US5158671A (en) 1987-12-18 1992-10-27 Exxon Research And Engineering Company Method for stabilizing hydroisomerates
NO885605L (no) 1987-12-18 1989-06-19 Exxon Research Engineering Co Fremgangsmaate for fremstilling av smoereolje.
US4937399A (en) 1987-12-18 1990-06-26 Exxon Research And Engineering Company Method for isomerizing wax to lube base oils using a sized isomerization catalyst
US4923841A (en) 1987-12-18 1990-05-08 Exxon Research And Engineering Company Catalyst for the hydroisomerization and hydrocracking of waxes to produce liquid hydrocarbon fuels and process for preparing the catalyst
US5059299A (en) 1987-12-18 1991-10-22 Exxon Research And Engineering Company Method for isomerizing wax to lube base oils
US4959337A (en) 1987-12-18 1990-09-25 Exxon Research And Engineering Company Wax isomerization catalyst and method for its production
US4900707A (en) 1987-12-18 1990-02-13 Exxon Research And Engineering Company Method for producing a wax isomerization catalyst
US4919786A (en) 1987-12-18 1990-04-24 Exxon Research And Engineering Company Process for the hydroisomerization of was to produce middle distillate products (OP-3403)
US4804802A (en) 1988-01-25 1989-02-14 Shell Oil Company Isomerization process with recycle of mono-methyl-branched paraffins and normal paraffins
US4910227A (en) 1988-10-11 1990-03-20 Air Products And Chemicals, Inc. High volumetric production of methanol in a liquid phase reactor
US4990713A (en) 1988-11-07 1991-02-05 Mobil Oil Corporation Process for the production of high VI lube base stocks
DE3838918A1 (de) 1988-11-17 1990-05-23 Basf Ag Kraftstoffe fuer verbrennungsmaschinen
US4992406A (en) 1988-11-23 1991-02-12 Exxon Research And Engineering Company Titania-supported catalysts and their preparation for use in Fischer-Tropsch synthesis
US4935120A (en) 1988-12-08 1990-06-19 Coastal Eagle Point Oil Company Multi-stage wax hydrocracking
US5075269A (en) 1988-12-15 1991-12-24 Mobil Oil Corp. Production of high viscosity index lubricating oil stock
US4992159A (en) 1988-12-16 1991-02-12 Exxon Research And Engineering Company Upgrading waxy distillates and raffinates by the process of hydrotreating and hydroisomerization
US4906599A (en) 1988-12-30 1990-03-06 Exxon Research & Engineering Co. Surface silylated zeolite catalysts, and processes for the preparation, and use of said catalysts in the production of high octane gasoline
US5015361A (en) 1989-01-23 1991-05-14 Mobil Oil Corp. Catalytic dewaxing process employing surface acidity deactivated zeolite catalysts
US4914786A (en) * 1989-03-08 1990-04-10 Consolidated Hgm Corporation Feeder for cotton gin
US5120425A (en) 1989-07-07 1992-06-09 Chevron Research Company Use of zeolite SSZ-33 in hydrocarbon conversion processes
ES2017030A6 (es) 1989-07-26 1990-12-16 Lascaray Sa Composicion aditiva para gasolinas empleadas en vehiculos automoviles.
JP2602102B2 (ja) 1989-09-20 1997-04-23 日本石油株式会社 内燃機関用潤滑油組成物
US5281347A (en) 1989-09-20 1994-01-25 Nippon Oil Co., Ltd. Lubricating composition for internal combustion engine
US5156114A (en) 1989-11-22 1992-10-20 Gunnerman Rudolf W Aqueous fuel for internal combustion engine and method of combustion
US4982031A (en) 1990-01-19 1991-01-01 Mobil Oil Corporation Alpha olefins from lower alkene oligomers
DE69001295T2 (de) 1990-02-06 1993-07-22 Ethyl Petroleum Additives Ltd In zufuhranlage niederschlaege kontrollierende zusammensetzungen.
US5348982A (en) 1990-04-04 1994-09-20 Exxon Research & Engineering Co. Slurry bubble column (C-2391)
US5242469A (en) 1990-06-07 1993-09-07 Tonen Corporation Gasoline additive composition
US5110445A (en) 1990-06-28 1992-05-05 Mobil Oil Corporation Lubricant production process
US5282958A (en) 1990-07-20 1994-02-01 Chevron Research And Technology Company Use of modified 5-7 a pore molecular sieves for isomerization of hydrocarbons
US5157187A (en) 1991-01-02 1992-10-20 Mobil Oil Corp. Hydroisomerization process for pour point reduction of long chain alkyl aromatic compounds
US5059741A (en) 1991-01-29 1991-10-22 Shell Oil Company C5/C6 isomerization process
WO1992014804A1 (en) * 1991-02-26 1992-09-03 Century Oils Australia Pty Limited Low aromatic diesel fuel
US5183556A (en) 1991-03-13 1993-02-02 Abb Lummus Crest Inc. Production of diesel fuel by hydrogenation of a diesel feed
FR2676749B1 (fr) 1991-05-21 1993-08-20 Inst Francais Du Petrole Procede d'hydroisomerisation de paraffines issues du procede fischer-tropsch a l'aide de catalyseurs a base de zeolithe h-y.
FR2676750B1 (fr) 1991-05-21 1993-08-13 Inst Francais Du Petrole Procede d'hydrocraquage de paraffines issue du procede fischer-tropsch a l'aide de catalyseurs a base de zeolithe h-y.
US5323335A (en) * 1991-07-05 1994-06-21 General Electric Co. Regular and fault-tolerant Kalman filter systolic arrays
GB9119504D0 (en) 1991-09-12 1991-10-23 Shell Int Research Process for the preparation of naphtha
GB9119494D0 (en) 1991-09-12 1991-10-23 Shell Int Research Hydroconversion catalyst
US5187138A (en) 1991-09-16 1993-02-16 Exxon Research And Engineering Company Silica modified hydroisomerization catalyst
US5210347A (en) 1991-09-23 1993-05-11 Mobil Oil Corporation Process for the production of high cetane value clean fuels
MY108159A (en) 1991-11-15 1996-08-30 Exxon Research Engineering Co Hydroisomerization of wax or waxy feeds using a catalyst comprising thin shell of catalytically active material on inert core
US5522983A (en) 1992-02-06 1996-06-04 Chevron Research And Technology Company Hydrocarbon hydroconversion process
CZ280251B6 (cs) 1992-02-07 1995-12-13 Slovnaft A.S. Bratislava Deriváty dikarboxylových kyselín ako prísady do nizkoolovnatých alebo bezoolovnatých automobilových benzínov
US5248644A (en) 1992-04-13 1993-09-28 Exxon Research And Engineering Company Zirconia-pillared clays and micas
AU668151B2 (en) 1992-05-06 1996-04-26 Afton Chemical Corporation Composition for control of induction system deposits
US5385588A (en) 1992-06-02 1995-01-31 Ethyl Petroleum Additives, Inc. Enhanced hydrocarbonaceous additive concentrate
MY107780A (en) 1992-09-08 1996-06-15 Shell Int Research Hydroconversion catalyst
EP0587245A1 (en) 1992-09-08 1994-03-16 Shell Internationale Researchmaatschappij B.V. Hydroconversion catalyst
US5300212A (en) 1992-10-22 1994-04-05 Exxon Research & Engineering Co. Hydroconversion process with slurry hydrotreating
JP3581365B2 (ja) 1992-10-28 2004-10-27 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 潤滑基油の製造方法
US5466362A (en) 1992-11-19 1995-11-14 Texaco Inc. Process and system for catalyst addition to an ebullated bed reactor
US5362378A (en) 1992-12-17 1994-11-08 Mobil Oil Corporation Conversion of Fischer-Tropsch heavy end products with platinum/boron-zeolite beta catalyst having a low alpha value
US5370788A (en) 1992-12-18 1994-12-06 Texaco Inc. Wax conversion process
US5382748A (en) 1992-12-18 1995-01-17 Exxon Research & Engineering Co. Hydrocarbon synthesis reactor employing vertical downcomer with gas disengaging means
US5302279A (en) 1992-12-23 1994-04-12 Mobil Oil Corporation Lubricant production by hydroisomerization of solvent extracted feedstocks
GB9301119D0 (en) * 1993-01-21 1993-03-10 Exxon Chemical Patents Inc Fuel composition
US5292988A (en) 1993-02-03 1994-03-08 Phillips Petroleum Company Preparation and use of isomerization catalysts
EP0621400B1 (de) 1993-04-23 1999-03-31 Daimler-Benz Aktiengesellschaft Luftverdichtende Einspritzbrennkraftmaschine mit einer Abgasnachbehandlungseinrichtung zur Reduzierung von Stickoxiden
US5378249A (en) 1993-06-28 1995-01-03 Pennzoil Products Company Biodegradable lubricant
SG54968A1 (en) 1993-06-28 1998-12-21 Chemadd Ltd Fuel additive
GB2279965A (en) 1993-07-12 1995-01-18 Ethyl Petroleum Additives Ltd Additive compositions for control of deposits, exhaust emissions and/or fuel consumption in internal combustion engines
US5527473A (en) 1993-07-15 1996-06-18 Ackerman; Carl D. Process for performing reactions in a liquid-solid catalyst slurry
US5378348A (en) 1993-07-22 1995-01-03 Exxon Research And Engineering Company Distillate fuel production from Fischer-Tropsch wax
US5308365A (en) 1993-08-31 1994-05-03 Arco Chemical Technology, L.P. Diesel fuel
EP0668342B1 (en) 1994-02-08 1999-08-04 Shell Internationale Researchmaatschappij B.V. Lubricating base oil preparation process
CA2179093A1 (en) 1995-07-14 1997-01-15 Stephen Mark Davis Hydroisomerization of waxy hydrocarbon feeds over a slurried catalyst
US6296757B1 (en) * 1995-10-17 2001-10-02 Exxon Research And Engineering Company Synthetic diesel fuel and process for its production
US5689031A (en) * 1995-10-17 1997-11-18 Exxon Research & Engineering Company Synthetic diesel fuel and process for its production
US5833839A (en) 1995-12-08 1998-11-10 Exxon Research And Engineering Company High purity paraffinic solvent compositions, and process for their manufacture
US5866748A (en) 1996-04-23 1999-02-02 Exxon Research And Engineering Company Hydroisomerization of a predominantly N-paraffin feed to produce high purity solvent compositions
US5807413A (en) * 1996-08-02 1998-09-15 Exxon Research And Engineering Company Synthetic diesel fuel with reduced particulate matter emissions
US5814109A (en) 1997-02-07 1998-09-29 Exxon Research And Engineering Company Diesel additive for improving cetane, lubricity, and stability
US5766274A (en) 1997-02-07 1998-06-16 Exxon Research And Engineering Company Synthetic jet fuel and process for its production
US6168768B1 (en) 1998-01-23 2001-01-02 Exxon Research And Engineering Company Production of low sulfer syngas from natural gas with C4+/C5+ hydrocarbon recovery
US6162956A (en) 1998-08-18 2000-12-19 Exxon Research And Engineering Co Stability Fischer-Tropsch diesel fuel and a process for its production
US6180842B1 (en) 1998-08-21 2001-01-30 Exxon Research And Engineering Company Stability fischer-tropsch diesel fuel and a process for its production
US6080301A (en) 1998-09-04 2000-06-27 Exxonmobil Research And Engineering Company Premium synthetic lubricant base stock having at least 95% non-cyclic isoparaffins

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1692152B (zh) * 2001-03-05 2012-03-07 国际壳牌研究有限公司 中间馏分油的制备方法
CN1659258B (zh) * 2002-06-07 2011-10-12 萨索尔技术(控股)有限公司 减少颗粒物排放的合成燃料及使用所述燃料和氧化催化剂操作压燃式发动机的方法
CN101050392B (zh) * 2002-06-07 2012-07-11 萨索尔技术(控股)有限公司 减少颗粒物排放的合成燃料及使用所述燃料和氧化催化剂操作压燃式发动机的方法
CN106255739A (zh) * 2014-05-19 2016-12-21 国际壳牌研究有限公司 制备高纯度费‑托气油馏分的方法
CN106255740A (zh) * 2014-05-19 2016-12-21 国际壳牌研究有限公司 制备高纯度费‑托气油馏分的方法
CN106459785A (zh) * 2014-05-19 2017-02-22 国际壳牌研究有限公司 制备高纯度费托气油馏分的方法
CN108102703A (zh) * 2016-11-24 2018-06-01 中国石油化工股份有限公司 一种催化柴油的加工处理方法
CN108102703B (zh) * 2016-11-24 2020-06-09 中国石油化工股份有限公司 一种催化柴油的加工处理方法
CN113316629A (zh) * 2018-09-11 2021-08-27 巴西石油公司 通过集成到精炼厂中的费-托方法制备液体烃的方法

Also Published As

Publication number Publication date
BR9611080A (pt) 1999-07-13
JPH11513730A (ja) 1999-11-24
KR100450812B1 (ko) 2004-12-17
US6607568B2 (en) 2003-08-19
EP0885275A1 (en) 1998-12-23
NO981712L (no) 1998-04-16
DE69631383T2 (de) 2004-12-02
JP3459651B2 (ja) 2003-10-20
US20010004971A1 (en) 2001-06-28
CA2229433A1 (en) 1997-04-24
EP1323813B1 (en) 2013-05-15
NO981712D0 (no) 1998-04-16
US6274029B1 (en) 2001-08-14
MX9801989A (es) 1998-08-30
WO1997014769A1 (en) 1997-04-24
HK1017009A1 (en) 1999-11-12
ATE258217T1 (de) 2004-02-15
AR004020A1 (es) 1998-09-30
NO328941B1 (no) 2010-06-21
CN1082541C (zh) 2002-04-10
MY121975A (en) 2006-03-31
EP1323813A3 (en) 2003-11-19
KR19990044420A (ko) 1999-06-25
EP0885275B1 (en) 2004-01-21
TW364010B (en) 1999-07-11
AU711556B2 (en) 1999-10-14
AU7395196A (en) 1997-05-07
DE69631383D1 (de) 2004-02-26
DK0885275T3 (da) 2004-05-24
ES2214549T3 (es) 2004-09-16
PT885275E (pt) 2004-06-30
CA2229433C (en) 2003-12-09
RU2160763C2 (ru) 2000-12-20
EP1323813A2 (en) 2003-07-02
MY114802A (en) 2003-01-31
ZA968338B (en) 1997-05-13
US6296757B1 (en) 2001-10-02

Similar Documents

Publication Publication Date Title
CN1082541C (zh) 合成柴油及其生产方法
CN1081667C (zh) 合成柴油及其生产方法
CN1097083C (zh) 合成喷气燃料和其生产方法
CN1181166C (zh) 可生物降解的高性能烃类基础油
EP1693432B1 (en) Vegetable oil hydroconversion process
EP1284281B1 (en) Synthetic Naphtha Fuel
CN100587043C (zh) 低硫柴油燃料和航空涡轮燃料
CN101067089A (zh) 一种页岩油的加工方法
CN101177623A (zh) 费-托合成油的加氢裂化方法
CN1297635C (zh) 一种用费托合成产物生产乙烯装置专用石脑油原料的方法
AU730173B2 (en) Synthetic diesel fuel and process for its production
AU730128B2 (en) Synthetic diesel fuel and process for its production
RU2141503C1 (ru) Способ получения низкозастывающих нефтепродуктов
CN1670138A (zh) 合成运输用燃料及其制造方法
CN101177622A (zh) 全馏分费-托合成油的氢化加工方法
CN1821362A (zh) 用合成石脑油燃料的方法生产的合成石脑油燃料

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CX01 Expiry of patent term

Granted publication date: 20020410

EXPY Termination of patent right or utility model