GB728543A - Process for the synthesis of hydrocarbons - Google Patents

Process for the synthesis of hydrocarbons

Info

Publication number
GB728543A
GB728543A GB5933/53A GB593353A GB728543A GB 728543 A GB728543 A GB 728543A GB 5933/53 A GB5933/53 A GB 5933/53A GB 593353 A GB593353 A GB 593353A GB 728543 A GB728543 A GB 728543A
Authority
GB
United Kingdom
Prior art keywords
oil
gas
synthesis gas
contact
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5933/53A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Heinrich Koppers GmbH
Original Assignee
Heinrich Koppers GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Heinrich Koppers GmbH filed Critical Heinrich Koppers GmbH
Publication of GB728543A publication Critical patent/GB728543A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1818—Feeding of the fluidising gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/06—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
    • B01J2208/00132—Tubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • B01J2219/00081—Tubes

Abstract

<PICT:0728543/IV (b)/1> <PICT:0728543/IV (b)/2> In a process for producing hydrocarbons from carbon monoxide and hydrogen in the presence of synthesis catalyst which is disposed in a hydrocarbon oil (contact oil), the synthesis gas being introduced at the bottom of a column of said oil which moves in the same direction as the gas, the oil which is circulated after separation from hydrocarbons and residual gas, and the synthesis gas are introduced into the reaction chamber below cooling means arranged therein. The catalyst may be fixed or suspended in the oil. The cooling means may comprise a number of stages, the mixture of synthesis gas and contact oil flowing successively through stages at increasing temperature. The reaction chamber is preferably a tower with a high ratio of height to diameter, e.g. 10 : 1. Alternatively, individual reactor units, each with at least one internal cooler, may be arranged with circulation of oil in each unit, if desired with different concentrations of catalyst, while synthesis gas flows successively through them. Nozzles for supply of the gas and oil to the base of the reactor may be provided so that the rate of flow of the oil is different from, preferably greater than that of the gas near the inlet so that the gas is distributed as fine bubbles. Synthesis gas may also be introduced into the return pipe for contact oil. Additional contact oil may be introduced at the top of the reactor to wash the walls and remove any deposit of catalyst while the reactor may be enlarged at the upper end to facilitate separation of contact oil from dissolved gases. Reaction temperatures below 280 DEG C. are suitable for pressures of about 14-20 atmospheres. The tower 1, Fig. 1, is fed from nozzles 2 with synthesis gas from pipe 3 and contact oil from pipe 4. Cooling devices 6 . . . 9 each comprise vertical tubes through which cooling medium circulates by pipes 10 . . . 12 in the same direction as the gas and oil. Vapours and residual gas leave at 15 while contact oil is returned via line 16, which may contain a further cooling device, and pump 5. A nozzle 2 is shown in Fig. 2, the inner tube 18 for gas being surrounded by a flared tube 20 for oil which flows at high speed through the gap 22.
GB5933/53A 1952-03-05 1953-03-03 Process for the synthesis of hydrocarbons Expired GB728543A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE728543X 1952-03-05

Publications (1)

Publication Number Publication Date
GB728543A true GB728543A (en) 1955-04-20

Family

ID=6635727

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5933/53A Expired GB728543A (en) 1952-03-05 1953-03-03 Process for the synthesis of hydrocarbons

Country Status (1)

Country Link
GB (1) GB728543A (en)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0753562A1 (en) * 1995-07-13 1997-01-15 Institut Français du Pétrole Liquid phase conversion of synthesis gas
EP0794239A1 (en) * 1996-03-08 1997-09-10 Institut Français du Pétrole Conversion of synthesis gas into hydrocarbons in the presence of a liquid phase
WO1999020583A1 (en) * 1997-10-21 1999-04-29 Exxon Research And Engineering Company Slurry hydrocarbon synthesis with reduced catalyst attrition and deactivation
US6076810A (en) * 1997-10-21 2000-06-20 Exxon Research And Engineering Co. Throat and cone gas injector and gas distribution grid for slurry reactor
WO2001038269A1 (en) * 1999-11-26 2001-05-31 Bp Exploration Operating Company Limited Process for converting synthesis gas into higher hydrocarbons
US6274029B1 (en) 1995-10-17 2001-08-14 Exxon Research And Engineering Company Synthetic diesel fuel and process for its production
US6309432B1 (en) 1997-02-07 2001-10-30 Exxon Research And Engineering Company Synthetic jet fuel and process for its production
WO2002096838A1 (en) * 2001-05-25 2002-12-05 Bp Exploration Operating Company Limited Fischer-tropsch synthesis process carried out on a floatable structure
WO2002096837A2 (en) * 2001-05-25 2002-12-05 Bp Exploration Operating Company Limited Fischer-tropsch process
WO2002096840A1 (en) * 2001-05-25 2002-12-05 Bp Exploration Operating Company Limited Process for separating liquid hydrocarbons from a particulate fischer-tropsch catalyst
WO2002097011A2 (en) * 2001-05-25 2002-12-05 Bp Exploration Operating Company Limited Fischer-tropsch process
WO2002096841A1 (en) * 2001-05-25 2002-12-05 Bp Exploration Operating Company Limited Fischer-tropsch process in the presence of a coolant introduced into the reactor system
WO2002096833A3 (en) * 2001-05-25 2003-05-30 Bp Exploration Operating Fischer-tropsch process
WO2002096834A3 (en) * 2001-05-25 2003-05-30 Bp Exploration Operating Fischer-tropsch process
US6822131B1 (en) 1995-10-17 2004-11-23 Exxonmobil Reasearch And Engineering Company Synthetic diesel fuel and process for its production
WO2006097904A2 (en) * 2005-03-17 2006-09-21 Sasol Technology (Proprietary) Limited Plate-type fluid bed reactor
CN101462927B (en) * 2007-12-20 2012-04-04 财团法人工业技术研究院 Multi-interval reaction device

Cited By (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2736650A1 (en) * 1995-07-13 1997-01-17 Inst Francais Du Petrole PROCESS FOR CONVERTING SYNTHESIS GAS TO LIQUID PHASE
US5786393A (en) * 1995-07-13 1998-07-28 Institut Francais Du Petrole Liquid phase process for converting synthesis gas
EP0753562A1 (en) * 1995-07-13 1997-01-15 Institut Français du Pétrole Liquid phase conversion of synthesis gas
US6274029B1 (en) 1995-10-17 2001-08-14 Exxon Research And Engineering Company Synthetic diesel fuel and process for its production
US6822131B1 (en) 1995-10-17 2004-11-23 Exxonmobil Reasearch And Engineering Company Synthetic diesel fuel and process for its production
US6607568B2 (en) 1995-10-17 2003-08-19 Exxonmobil Research And Engineering Company Synthetic diesel fuel and process for its production (law3 1 1)
US6296757B1 (en) 1995-10-17 2001-10-02 Exxon Research And Engineering Company Synthetic diesel fuel and process for its production
EP0794239A1 (en) * 1996-03-08 1997-09-10 Institut Français du Pétrole Conversion of synthesis gas into hydrocarbons in the presence of a liquid phase
FR2745820A1 (en) * 1996-03-08 1997-09-12 Inst Francais Du Petrole CONVERSION OF SYNTHESIS GAS TO HYDROCARBONS IN THE PRESENCE OF A LIQUID PHASE
US5869541A (en) * 1996-03-08 1999-02-09 Institut Francais Du Petrole Conversion of synthesis gas to hydrocarbons in the presence of a liquid phase
US6669743B2 (en) 1997-02-07 2003-12-30 Exxonmobil Research And Engineering Company Synthetic jet fuel and process for its production (law724)
US6309432B1 (en) 1997-02-07 2001-10-30 Exxon Research And Engineering Company Synthetic jet fuel and process for its production
US6076810A (en) * 1997-10-21 2000-06-20 Exxon Research And Engineering Co. Throat and cone gas injector and gas distribution grid for slurry reactor
US6199835B1 (en) 1997-10-21 2001-03-13 Exxon Research And Engineering Company Throat and cone gas injector and gas distribution grid for slurry reactor (LAW646)
WO1999020583A1 (en) * 1997-10-21 1999-04-29 Exxon Research And Engineering Company Slurry hydrocarbon synthesis with reduced catalyst attrition and deactivation
US6822007B2 (en) 1999-11-26 2004-11-23 Bp Exploration Operating Company Limited Process for converting synthesis gas into higher hydrocarbons
EP1496040A1 (en) * 1999-11-26 2005-01-12 Bp Exploration Operating Company Limited Process for converting synthesis gas into higher hydrocarbons
KR100719823B1 (en) 1999-11-26 2007-05-18 비피 익스플로레이션 오퍼레이팅 컴파니 리미티드 Process for converting synthesis gas into higher hydrocarbons
JP2003514959A (en) * 1999-11-26 2003-04-22 ビーピー エクスプロレーション オペレーティング カンパニー リミテッド Method for converting synthesis gas to higher hydrocarbons
CN1325443C (en) * 1999-11-26 2007-07-11 英国石油勘探运作有限公司 Process for converting synthesis gas into higher hydrocarbons
AU777045B2 (en) * 1999-11-26 2004-09-30 Bp Exploration Operating Company Limited Process for converting synthesis gas into higher hydrocarbons
WO2001038269A1 (en) * 1999-11-26 2001-05-31 Bp Exploration Operating Company Limited Process for converting synthesis gas into higher hydrocarbons
US6689330B2 (en) 1999-11-26 2004-02-10 Bp Exploration Operating Company Limited Apparatus for converting synthesis gas into higher hydrocarbons
JP4647869B2 (en) * 1999-11-26 2011-03-09 ビーピー エクスプロレーション オペレーティング カンパニー リミテッド Method for converting synthesis gas to higher hydrocarbons
US6635682B2 (en) 1999-11-26 2003-10-21 Bp Exploration Operating Company Limited Process for converting synthesis gas into higher hydrocarbons
WO2002096833A3 (en) * 2001-05-25 2003-05-30 Bp Exploration Operating Fischer-tropsch process
US7008968B2 (en) 2001-05-25 2006-03-07 Bp Exploration Operation Company Limited Fischer-tropsch process
WO2002097011A3 (en) * 2001-05-25 2003-05-08 Bp Exploration Operating Fischer-tropsch process
WO2002096837A3 (en) * 2001-05-25 2003-05-08 Bp Exploration Operating Fischer-tropsch process
WO2002096841A1 (en) * 2001-05-25 2002-12-05 Bp Exploration Operating Company Limited Fischer-tropsch process in the presence of a coolant introduced into the reactor system
US6822005B2 (en) 2001-05-25 2004-11-23 Bp Exploration Operating Company Limited Fischer-tropsch process
JP2004536173A (en) * 2001-05-25 2004-12-02 ビーピー　エクスプロレーション　オペレーティング　カンパニー　リミテッド Fischer-Tropsch method
WO2002097011A2 (en) * 2001-05-25 2002-12-05 Bp Exploration Operating Company Limited Fischer-tropsch process
US7005456B2 (en) 2001-05-25 2006-02-28 Bp Exploration Operating Company Limited Fischer-Tropsch process
AU2002307957B2 (en) * 2001-05-25 2007-08-09 Bp Exploration Operating Company Limited Fischer-Tropsch synthesis process carried out on a floatable structure
US7034062B2 (en) 2001-05-25 2006-04-25 BP Exploration Operatiing Company Limited Fischer-tropsch process
US7037947B2 (en) 2001-05-25 2006-05-02 Bp Exploration Operating Company Limited Fischer-Tropsch synthesis process carried out on a floatable structure
US7071238B2 (en) 2001-05-25 2006-07-04 Bp Exploration Operating Company Limited Fischer-tropsch process in the presence of a coolant introduced into the reactor system
WO2002096834A3 (en) * 2001-05-25 2003-05-30 Bp Exploration Operating Fischer-tropsch process
US7112613B2 (en) 2001-05-25 2006-09-26 Bp Exploration Operating Company Limited Process for separating liquid hydrocarbons from a particulate fisher-tropsch catalyst
WO2002096838A1 (en) * 2001-05-25 2002-12-05 Bp Exploration Operating Company Limited Fischer-tropsch synthesis process carried out on a floatable structure
WO2002096840A1 (en) * 2001-05-25 2002-12-05 Bp Exploration Operating Company Limited Process for separating liquid hydrocarbons from a particulate fischer-tropsch catalyst
WO2002096837A2 (en) * 2001-05-25 2002-12-05 Bp Exploration Operating Company Limited Fischer-tropsch process
WO2006097904A2 (en) * 2005-03-17 2006-09-21 Sasol Technology (Proprietary) Limited Plate-type fluid bed reactor
GB2438815A (en) * 2005-03-17 2007-12-05 Sasol Technology Plate-type fluid bed reactor
GB2438815B (en) * 2005-03-17 2009-12-02 Sasol Technology Method of operating a fluid bed reactor
WO2006097904A3 (en) * 2005-03-17 2007-02-15 Sasol Tech Pty Ltd Plate-type fluid bed reactor
US8008359B2 (en) 2005-03-17 2011-08-30 Sasol Technology (Proprietary) Limited Method of operating a fluid bed reactor
CN101155631B (en) * 2005-03-17 2012-08-15 沙索技术有限公司 Panel type fluid bed reactor
US8283386B2 (en) 2005-03-17 2012-10-09 Sasol Technology (Proprietary) Limited Method of operating a fluid bed reactor
CN101462927B (en) * 2007-12-20 2012-04-04 财团法人工业技术研究院 Multi-interval reaction device

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