CN113227311A - 板状化学蓄热体 - Google Patents

板状化学蓄热体 Download PDF

Info

Publication number
CN113227311A
CN113227311A CN201980084905.2A CN201980084905A CN113227311A CN 113227311 A CN113227311 A CN 113227311A CN 201980084905 A CN201980084905 A CN 201980084905A CN 113227311 A CN113227311 A CN 113227311A
Authority
CN
China
Prior art keywords
heat storage
chemical heat
plate
oxide
material composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201980084905.2A
Other languages
English (en)
Inventor
甲斐启一郎
清泽正志
横山公一
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Power Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Power Ltd filed Critical Mitsubishi Power Ltd
Publication of CN113227311A publication Critical patent/CN113227311A/zh
Pending legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/16—Materials undergoing chemical reactions when used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00—Layered products having a non-planar shape
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/266—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by an apertured layer, the apertures going through the whole thickness of the layer, e.g. expanded metal, perforated layer, slit layer regular cells B32B3/12
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/28—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer comprising a deformed thin sheet, i.e. the layer having its entire thickness deformed out of the plane, e.g. corrugated, crumpled
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/16—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer formed of particles, e.g. chips, powder or granules
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/003—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using thermochemical reactions
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F3/00—Plate-like or laminated elements; Assemblies of plate-like or laminated elements
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F3/00—Plate-like or laminated elements; Assemblies of plate-like or laminated elements
    • F28F3/02—Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations
    • F28F3/025—Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations the means being corrugated, plate-like elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/06—Coating on the layer surface on metal layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/20—Inorganic coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/24—Organic non-macromolecular coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04—Impregnation, embedding, or binder material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04—Impregnation, embedding, or binder material
    • B32B2260/046—Synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/101—Glass fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10—Inorganic particles
    • B32B2264/102—Oxide or hydroxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10—Inorganic particles
    • B32B2264/104—Oxysalt, e.g. carbonate, sulfate, phosphate or nitrate particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/38—Meshes, lattices or nets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/302—Conductive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/30—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14—Thermal energy storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12361—All metal or with adjacent metals having aperture or cut
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12361—All metal or with adjacent metals having aperture or cut
    • Y10T428/12368—Struck-out portion type
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
    • Y10T428/24281—Struck out portion type
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
    • Y10T428/24322—Composite web or sheet
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
    • Y10T428/24322—Composite web or sheet
    • Y10T428/24331—Composite web or sheet including nonapertured component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
    • Y10T428/24322—Composite web or sheet
    • Y10T428/24331—Composite web or sheet including nonapertured component
    • Y10T428/24339—Keyed
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
    • Y10T428/24322—Composite web or sheet
    • Y10T428/24331—Composite web or sheet including nonapertured component
    • Y10T428/24339—Keyed
    • Y10T428/24347—From both sides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24628—Nonplanar uniform thickness material
    • Y10T428/24661—Forming, or cooperating to form cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24628—Nonplanar uniform thickness material
    • Y10T428/24669—Aligned or parallel nonplanarities
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24628—Nonplanar uniform thickness material
    • Y10T428/24669—Aligned or parallel nonplanarities
    • Y10T428/24694—Parallel corrugations
    • Y10T428/24711—Plural corrugated components
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24628—Nonplanar uniform thickness material
    • Y10T428/24669—Aligned or parallel nonplanarities
    • Y10T428/24694—Parallel corrugations
    • Y10T428/24711—Plural corrugated components
    • Y10T428/24727—Plural corrugated components with planar component

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Laminated Bodies (AREA)

Abstract

一种板状化学蓄热体，其具有由金属制的网构成的基板和担载于该基板的蓄热材料组合物，该蓄热材料组合物包含选自镁的氢氧化物或氧化物、锶的氢氧化物或氧化物、钡的氢氧化物或氧化物、钙的氢氧化物或氧化物、及硫酸钙中的至少一种、以及根据需要的选自二氧化钛、二氧化硅、硅酸铝纤维、E玻璃纤维和纤维素中的至少一种。

Description

板状化学蓄热体
技术领域
本发明涉及板状化学蓄热体。
背景技术
作为蓄热技术之一，已知有利用了物质的相变的潜热蓄热材料。例如，专利文献1公开了一种蓄热体，其将多个潜热蓄热性的粒子载置于片材上，从其上涂布涂料而将上述粒子固定于上述片材。该蓄热体被涂膜覆盖，以使得在由于相变而转化成液体、气体时蓄热材料不会泄漏到外部。
作为其他蓄热技术，已知有化学蓄热材料。在化学蓄热材料中，水等气体工作介质与化学蓄热材料反应，利用此时的吸热或发热。据说化学蓄热材料与潜热蓄热材料、显热蓄热材料等相比，每单位质量的蓄热量高。
作为化学蓄热材料，例如，专利文献2公开了将氧化钙、氧化镁等金属氧化物的粉末成形为板状而成的蓄热构件。
专利文献3公开了一种化学蓄热材料体，其特征在于，具有：通过将粘土矿物和可燃性粒状物混合并烧制而得到的具有大量细孔的笼状结构体、以及担载于该笼状结构体的外表面和细孔内部的化学蓄热材料。
专利文献4公开了一种化学蓄热材料成形体，其特征在于，具有：由具有多个细孔的多孔质的陶瓷形成的骨架结构部；以及担载于该骨架结构部的外表面、或担载于该骨架结构部的外表面和细孔内部的化学蓄热材料。
现有技术文献
专利文献
专利文献1：日本特开平8-29081号公报
专利文献2：日本特开2011-208865号公报
专利文献3：日本特开2009-256517号公报
专利文献4：日本特开2009-221289号公报
发明内容
发明要解决的课题
本发明的课题在于提供耐久性优异的板状化学蓄热体。
用于解决课题的手段
为了解决上述课题而进行了研究，结果完成了包括如下方式的本发明。
〔1〕一种板状化学蓄热体，其具有：
基板，其由金属制的网构成；以及
蓄热材料组合物，其担载于该基板，
该蓄热材料组合物包含选自镁的氢氧化物或氧化物、锶的氢氧化物或氧化物、钡的氢氧化物或氧化物、钙的氢氧化物或氧化物、及硫酸钙中的至少一种。
〔2〕根据〔1〕所述的板状化学蓄热体，其中，蓄热材料组合物还包含选自二氧化钛、二氧化硅、硅酸铝纤维、E玻璃纤维和纤维素中的至少一种。
〔3〕根据〔1〕或〔2〕所述的板状化学蓄热体，其中，网由选自不锈钢、铝、铝合金、铜和铜合金中的至少一种构成。
〔4〕根据〔1〕～〔3〕中任一项所述的板状化学蓄热体，其中，板厚为0.3mm以上且2mm以下。
〔5〕一种化学蓄热结构体，其是将至少一个〔1〕～〔4〕中任一项所述的板状化学蓄热体进行层叠而成的。
〔6〕一种化学蓄热系统，其具备〔1〕～〔4〕中任一项所述的板状化学蓄热体或〔5〕所述的化学蓄热结构体。
发明的效果
本发明的板状化学蓄热体的保形性优异，热响应性快。本发明的板状化学蓄热体由于水蒸气等气体容易侵入至内部的深处，所以吸热反应和发热反应的效率高，每单位重量的蓄热量高。本发明的板状化学蓄热体即使产生伴随着蓄热材料的脱水/水合反应的体积变化，由网构成的基板也会吸收该体积变化，防止破裂、粉化，因此能够长时间维持蓄热/放热的性能高。
附图说明
图1是表示本发明的板状化学蓄热体的一个例子的图。
图2是表示本发明的板状化学蓄热体的一个例子的图。
图3是表示本发明的板状化学蓄热体的一个例子的图。
图4是表示本发明的板状化学蓄热体中使用的基板的一个例子的图。
图5是表示本发明的板状化学蓄热体中使用的基板的一个例子的图。
图6是表示本发明的化学蓄热结构体的一个例子的图。
图7是表示本发明的化学蓄热结构体的一个例子的图。
图8是表示本发明的化学蓄热结构体的一个例子的图。
图9是表示本发明的化学蓄热结构体的一个例子的图。
具体实施方式
本发明的板状化学蓄热体1具有基板3和担载于该基板3的蓄热材料组合物2。
本发明中使用的基板3是金属制的网。网可以是将线材编织而成的网、在板材切出切口并拉伸而成的网(多孔金属网，expand metal)、在板材穿孔而成的网(冲孔金属网，punching metal)等任一种网。
网的材料只要是金属则没有特别限制，优选热导率比蓄热材料组合物高的金属，优选不锈钢、铝、铝合金、铜或铜合金。
网的网眼尺寸没有特别限定，从蓄热材料组合物不易从基板剥离的方面和提高蓄热材料组合物与基板的导热性的方面等出发，优选为10μm以上，更优选为100μm以上，进一步优选为1mm以上且5mm以下。
网可以是主面平坦的平网、在主面具有隆起成瘤状的部分的瘤网、主面呈波状隆起的波形网、具有相对于主面突起的部分的肋网等。蓄热材料组合物进入到网的网眼而发挥锚定效应，因此即使是平网也显示出充分的强度。就瘤网、波网或肋网而言，可以期待瘤、波或肋进一步增强锚定效应。
本发明中使用的蓄热材料组合物包含化学蓄热材料。作为化学蓄热材料，使用选自镁的氢氧化物或氧化物、锶的氢氧化物或氧化物、钡的氢氧化物或氧化物、钙的氢氧化物或氧化物、及硫酸钙中的至少一种。
镁的氢氧化物或氧化物是利用氢氧化镁脱水而转化成氧化镁时的蓄热和氧化镁水合而转化成氢氧化镁时的放热的化学蓄热材料。基于镁的氢氧化物或氧化物的蓄热工作温度为350℃左右。
锶的氢氧化物或氧化物是利用氢氧化锶脱水而转化成氧化锶时的蓄热和氧化锶水合而转化成氢氧化锶时的放热的化学蓄热材料。
钡的氢氧化物或氧化物是利用氢氧化钡脱水而转化成氧化钡时的蓄热和氧化钡水合而转化成氢氧化钡时的放热的化学蓄热材料。
钙的氢氧化物或氧化物是利用氢氧化钙脱水而转化成氧化钙时的蓄热和氧化钙水合而转化成氢氧化钙时的放热的化学蓄热材料。基于钙的氢氧化物或氧化物的蓄热工作温度为500℃左右。
硫酸钙是利用硫酸钙0.5水合物脱水而转化成无水硫酸钙时的蓄热和无水硫酸钙水合而转化成硫酸钙0.5水合物时的放热的化学蓄热材料。基于硫酸钙的蓄热工作温度为90℃左右。
本发明中使用的蓄热材料组合物除了上述化学蓄热材料以外，还可以包含导热性填料、增强纤维、粘结剂等添加剂。
作为导热性填料，可举出熔融二氧化硅、氧化铝、氮化硼、氮化铝、氮化硅、碳酸镁、碳纳米管、氮化硼纳米管、氧化铍等。
作为增强纤维，可举出碳纤维、玻璃纤维、硅酸铝纤维、E玻璃纤维、芳族聚酰胺纤维、聚烯烃纤维、维尼纶纤维、钢纤维等。
作为其他填料，可举出二氧化钛、沸石、活性白土、海泡石、膨润土、坡缕石、水滑石、氧化锌、氧化铁、硫酸钡、碳酸钙、滑石、氢氧化铝、氧化锑、石墨、铁素体等。其中，优选使用担载于基板的蓄热材料组合物成为多孔质的填料。
作为粘结剂，可举出二氧化硅溶胶、硅酸盐、磷酸盐、水泥、硅酮等无机粘结剂；乙酸纤维素、腈纤维素、纤维素、聚偏二氟乙烯、聚乙烯醇、苯乙烯丁二烯橡胶、腈橡胶、聚四氟乙烯、聚丙烯、聚乙烯、丙烯酸类树脂、环氧树脂等有机粘结剂等。
这些添加剂中，可以优选使选自二氧化钛、二氧化硅、硅酸铝纤维、E玻璃纤维和纤维素中的至少一种包含在蓄热材料组合物中。
添加剂的合计量相对于化学蓄热材料的合计量优选为1重量％以上且40重量％以下。
在本发明的板状化学蓄热体中，蓄热材料组合物担载于基板，更详细而言，担载于构成基板的网的外表面和网的网眼中。
就担载而言，可以通过将蓄热材料组合物的浆料或糊涂布于基板并使其干燥来进行，可以通过将蓄热材料组合物的粉末与基板一起进行压粉成形来进行，或者可以通过其他担载方法来进行。
本发明的板状化学蓄热体的板厚t优选为0.3mm以上且2mm以下，更优选为0.5mm以上且1mm以下。
本发明的板状化学蓄热体的表面可以全部被蓄热材料组合物覆盖，也可以在一部分具有基板露出的部分。
本发明的板状化学蓄热体的主面可以为光滑面，也可以为粗糙面。在为粗糙面的情况下，使本发明的板状化学蓄热体层叠时稍微产生间隙，因此作为对于化学蓄热材料的工作介质的水容易进入到深处。从这样的观点出发，主面的表面粗糙度优选为几μm～几百μm。
本发明的板状化学蓄热体可以根据目的进行裁切而制成薄片(chip)状、或弯折而制成筒状、箱状、或进行压花加工等而制成波状(例如图2、图3等所示的形状)。另外，可以将本发明的板状化学蓄热体层叠多张，或者与其他板状物层叠。
本发明的化学蓄热结构体是将至少一个本发明的板状化学蓄热进行层叠而成的。
图6示出了将本发明的板状化学蓄热体1a层叠多张而成的化学蓄热结构体4。在相邻的板状化学蓄热体1a之间具有间隙的情况下，作为工作介质的水蒸气容易通过该间隙。化学蓄热结构体4的每单位体积的化学蓄热材料的填充密度高，能够发挥更高的蓄热/放热性能，并且能够长时间稳定地保持其形状。
图7示出了将本发明的板状化学蓄热体1a与其他板状物3交替地层叠而成的化学蓄热结构体5。其他板状物3没有特别限定，例如可以是由未担载蓄热材料组合物的金属制的网构成的基板3-a等。化学蓄热结构体5中，板状物3发挥隔离物的作用，通向板状化学蓄热体1的流路扩大，因此作为工作介质的水蒸气容易流动，脱水/水合的反应得到促进。
图8示出了将如图3所示的交替地以规定间隔形成了突条部和平坦部的板状化学蓄热体1c层叠而成的结构体。
图9示出了将如图2所示的板状化学蓄热体1b和板状化学蓄热体1a交替层叠而成的波纹蜂窝状的结构体。
此时的层叠高度h没有特别限定，优选设定为2mm以上且4mm以下。
在本发明的结构体中，基板作为骨料发挥功能，因此能够长时间维持高的强度和保形性。需要说明的是，只要是发挥本发明中的作用效果的方式，则不限于上述，也可以形成其他形状。
以下，示出本发明的实施例，更具体地说明本发明。需要说明的是，这些仅是用于说明的例示，本发明不受这些的任何限制。
[实施例1]
一边向氢氧化镁粉末10kg中加入水，一边用捏合机进行混炼。向其中加入二氧化硅/氧化铝系纤维4kg，进一步进行混炼，得到水分约40％的糊状化学蓄热材料组合物。使用一对压延辊，在宽度500mm的SUS430制的多孔金属网基板(金属丝网(metal lath)板，P1＝4.5mm，P2＝3.0mm)上以填埋丝网网孔间的方式涂布糊状化学蓄热材料组合物。接下来，用切割机切割成长度500mm。将其在120℃下干燥2小时。接下来，切割成50×50mm的小片，得到厚度0.7mm的板状化学蓄热体。担载于板状化学蓄热体的蓄热材料组合物的密度为0.95g/cm3。
[实施例2]
将实施例1中使用的SUS430制多孔金属网基板变更为铝制多孔金属网基板(金属丝网板，P1＝4.5mm，P2＝3.0mm)，除此以外，通过与实施例1相同的方法得到板状化学蓄热体。担载于板状化学蓄热体的蓄热材料组合物的密度为0.92g/cm3。
[比较例1]
将氢氧化镁粉末(Kishida化学制)放入到压片成形机中，施加700kg/cm2的压力10秒钟，得到直径13mm、厚度2.4mm的颗粒状蓄热体。颗粒状蓄热体的密度为0.94g/cm3。
[试验]
在表1所示的条件下进行将脱水处理和水合处理作为1次循环的耐久试验。
每1次循环记录蓄热体的形状、脱水率和水合率。将结果示于表2。
需要说明的是，脱水率是将初始的氢氧化镁全部转换为氧化镁时设为100％而算出的。
水合率是将全部氧化镁再转换为初始的氢氧化镁重量时设为100％而算出的。
比较例1的颗粒状蓄热体在第2次循环中发生破裂，在第5次循环中颗粒整面产生裂纹，当用手接触时，为镁的粉末附着于手的状态。
与此相对，实施例1和2的板状化学蓄热体在第5次循环中在蓄热材料组合物的一部分中确认到微少的裂纹，但未观察到从基板的脱落、剥离等，即使用手接触，镁的粉末也没有附着于手。
如表2所示，实施例1和2的板状化学蓄热体与比较例1的颗粒状蓄热体相比，脱水率和水合率高，蓄热性能优异。
根据以上结果可知，本发明的板状化学蓄热体为高强度，并且具有高的脱水/水合反应效率。通过使用本发明的板状化学蓄热体，与使用以往的粉末状、颗粒状的蓄热体的情况相比，能够构成高性能、高耐久的化学蓄热系统。
[表1]
表1
Figure BDA0003123849470000081
[表2]
表2
Figure BDA0003123849470000082
附图标记说明
1a、1b、1：板状化学蓄热体；
2：蓄热材料组合物；
3：基板；
3-a：金属网基板；
3-b：多孔金属网基板；
4：蓄热结构体；
5：蓄热结构体。

Claims (8)

1.一种板状化学蓄热体，其具有：
基板，其由金属制的网构成；以及
蓄热材料组合物，其担载于该基板，
该蓄热材料组合物包含化学蓄热材料。
2.一种板状化学蓄热体，其具有：
基板，其由金属制的网构成；以及
蓄热材料组合物，其担载于该基板，
该蓄热材料组合物包含选自镁的氢氧化物或氧化物、锶的氢氧化物或氧化物、钡的氢氧化物或氧化物、钙的氢氧化物或氧化物、及硫酸钙中的至少一种。
3.根据权利要求1或2所述的板状化学蓄热体，其中，蓄热材料组合物还包含导热性填料、增强纤维或粘结剂。
4.根据权利要求1或2所述的板状化学蓄热体，其中，蓄热材料组合物还包含选自二氧化钛、二氧化硅、硅酸铝纤维、E玻璃纤维和纤维素中的至少一种。
5.根据权利要求1～4中任一项所述的板状化学蓄热体，其中，网由选自不锈钢、铝、铝合金、铜和铜合金中的至少一种构成。
6.根据权利要求1～5中任一项所述的板状化学蓄热体，其中，板厚为0.3mm以上且2mm以下。
7.一种化学蓄热结构体，其是将至少一个权利要求1～6中任一项所述的板状化学蓄热体进行层叠而成的。
8.一种化学蓄热系统，其具备权利要求1～6中任一项所述的板状化学蓄热体或权利要求7所述的化学蓄热结构体。
CN201980084905.2A 2018-12-20 2019-12-19 板状化学蓄热体 Pending CN113227311A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2018-238643 2018-12-20
JP2018238643A JP7296207B2 (ja) 2018-12-20 2018-12-20 板状化学蓄熱体
PCT/JP2019/049770 WO2020130066A1 (ja) 2018-12-20 2019-12-19 板状化学蓄熱体

Publications (1)

Publication Number Publication Date
CN113227311A true CN113227311A (zh) 2021-08-06

Family

ID=71100856

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201980084905.2A Pending CN113227311A (zh) 2018-12-20 2019-12-19 板状化学蓄热体

Country Status (6)

Country Link
US (1) US20220112421A1 (zh)
EP (1) EP3901234A4 (zh)
JP (1) JP7296207B2 (zh)
CN (1) CN113227311A (zh)
TW (1) TWI834785B (zh)
WO (1) WO2020130066A1 (zh)

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100999414A (zh) * 2007-01-05 2007-07-18 华南理工大学 一种超多孔陶瓷基蓄热材料及其制备方法
CN101560377A (zh) * 2009-06-04 2009-10-21 河北科技大学 泡沫金属基高温相变蓄热复合材料及其制备方法
CN102061403A (zh) * 2010-10-28 2011-05-18 华南理工大学 多孔材料基体和复合相变蓄热材料及其制备方法
JP2015098582A (ja) * 2013-10-16 2015-05-28 日本ペイントホールディングス株式会社 化学蓄熱材及び化学蓄熱材形成用組成物
JP2016155895A (ja) * 2015-02-23 2016-09-01 太平洋セメント株式会社 化学蓄熱材成形体、その製造方法および成形体集合体
JP2016190990A (ja) * 2015-03-31 2016-11-10 日本ペイントホールディングス株式会社 化学蓄熱材及び化学蓄熱材形成用組成物
CN107075794A (zh) * 2014-05-19 2017-08-18 智能聚合物有限公司 柔性pcm面料
CN107270755A (zh) * 2016-03-31 2017-10-20 日本碍子株式会社 蓄热部件
CN107266078A (zh) * 2016-03-31 2017-10-20 日本碍子株式会社 蓄热部件
CN108219755A (zh) * 2017-12-29 2018-06-29 北京国能电池科技有限公司 以泡沫铝为基体的复合相变材料及其制备方法与蓄热包
TW201831856A (zh) * 2016-12-05 2018-09-01 日商日產化學工業股份有限公司 蓄熱層形成用組成物

Family Cites Families (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1572680A (en) * 1977-08-11 1980-07-30 United Wire Group Ltd Heat transfer elements
US4361620A (en) * 1979-03-08 1982-11-30 Wing Industries, Inc. Total energy exchange medium and method of making the same
JPS57155098A (en) * 1981-03-20 1982-09-25 Hitachi Ltd Heat accumulating device
JPS58193099A (ja) * 1982-05-07 1983-11-10 Matsushita Electric Ind Co Ltd 熱交換素子
US5451307A (en) * 1985-05-07 1995-09-19 Eltech Systems Corporation Expanded metal mesh and anode structure
JPH0236521B2 (ja) * 1986-03-03 1990-08-17 Sanyo Electric Co Kinzokusuisokabutsuyoki
JP3306482B2 (ja) * 1994-07-19 2002-07-24 株式会社日立製作所 蓄熱体
SE513178C2 (sv) * 1998-11-24 2000-07-24 Suncool Ab Kemisk Värmepump med fast substans
GB9929408D0 (en) * 1999-12-14 2000-02-09 Maxwell Davidson Ltd Composite material
JP2001241871A (ja) 2000-02-29 2001-09-07 Kinki Concrete Industry Co Ltd 氷蓄熱槽およびその製造方法
JP4846210B2 (ja) * 2003-10-09 2011-12-28 エスケー化研株式会社 蓄熱体
KR101219897B1 (ko) * 2005-01-27 2013-01-09 에스케 카켄 가부시키가이샤 축열체 형성용 조성물, 축열체 및 축열체의 제조 방법
WO2006127889A2 (en) * 2005-05-25 2006-11-30 Velocys Inc. Support for use in microchannel processing
JP4938323B2 (ja) * 2006-03-14 2012-05-23 大阪瓦斯株式会社 熱交換型反応器の製造方法
US8048383B2 (en) * 2006-04-20 2011-11-01 Velocys, Inc. Process for treating and/or forming a non-Newtonian fluid using microchannel process technology
JP5086600B2 (ja) * 2006-08-11 2012-11-28 エスケー化研株式会社 蓄熱材組成物、蓄熱体及び蓄熱積層体
JP4911002B2 (ja) * 2007-11-30 2012-04-04 株式会社豊田中央研究所 熱交換型熱利用装置及びその製造方法
JP5231077B2 (ja) * 2007-11-30 2013-07-10 株式会社豊田中央研究所 化学蓄熱材複合体及びその製造方法
JP5303159B2 (ja) * 2008-02-29 2013-10-02 株式会社豊田中央研究所 化学蓄熱材複合体
JP5374683B2 (ja) 2008-03-14 2013-12-25 株式会社豊田中央研究所 化学蓄熱材成形体及びその製造方法
JP5327729B2 (ja) 2008-04-18 2013-10-30 株式会社豊田中央研究所 化学蓄熱材料、及びその製造方法
CN101644548A (zh) * 2009-08-13 2010-02-10 哈尔滨工程大学 高温化学蓄热元件及基于高温化学蓄热元件的蓄热器
US9120959B2 (en) * 2010-03-25 2015-09-01 Kabushiki Kaisha Toyota Chuo Kenkyusho Chemical thermal energy storage material structure, method of producing the same, and chemical heat accumulator
JP5381861B2 (ja) 2010-03-29 2014-01-08 株式会社デンソー 化学蓄熱装置
JP5749050B2 (ja) * 2011-03-18 2015-07-15 株式会社豊田中央研究所 化学蓄熱器及びその製造方法
JP2012211713A (ja) * 2011-03-30 2012-11-01 Toyota Central R&D Labs Inc 化学蓄熱反応器及び化学蓄熱システム
JP5961114B2 (ja) * 2011-12-02 2016-08-02 株式会社Uacj 熱交換器およびその製造方法
JP2013256928A (ja) * 2012-06-14 2013-12-26 Toyota Industries Corp アンモニア貯蔵器
US20140116640A1 (en) * 2012-10-31 2014-05-01 Government Of The United States As Represented By The Secretary Of The Air Force High-thermal conductivity adsorbents for rapid absorption of heat pulses and a pressure-cascade burst desorption system using the same
JP5821834B2 (ja) * 2012-12-26 2015-11-24 株式会社豊田中央研究所 化学蓄熱反応器、化学蓄熱システム
JP6232196B2 (ja) * 2013-03-21 2017-11-15 株式会社豊田中央研究所 箱体、化学蓄熱反応器及び化学蓄熱システム
JP2014224668A (ja) * 2013-04-15 2014-12-04 株式会社リコー 反応材成形体及び蓄放熱ユニット
CN104650821A (zh) * 2013-11-17 2015-05-27 成都奥能普科技有限公司 一种用于化学蓄热的固体粒块
CN104650820A (zh) * 2013-11-17 2015-05-27 成都奥能普科技有限公司 一种用于传热的化学蓄热材料的配方
JP2015160433A (ja) * 2014-02-28 2015-09-07 株式会社リコー 反応材成形体の製造方法
JP6670234B2 (ja) * 2014-05-16 2020-03-18 永大産業株式会社 多孔質基材中に潜熱蓄熱材が含浸された蓄熱体及びその製造方法
JP6256224B2 (ja) * 2014-06-20 2018-01-10 株式会社豊田自動織機 化学蓄熱装置
JP6026469B2 (ja) * 2014-08-01 2016-11-16 古河電気工業株式会社 扁平状蓄熱器、扁平状蓄熱器を備えた蓄熱器ユニット及び蓄熱器ユニットを備えた蓄熱装置
WO2016017782A1 (ja) * 2014-08-01 2016-02-04 三菱化学株式会社 光学素子の製造方法、その方法を用いて得られる光学素子及びその光学素子を備えた画像表示装置
JP6187418B2 (ja) * 2014-09-03 2017-08-30 株式会社豊田自動織機 化学蓄熱装置
JP6422283B2 (ja) * 2014-09-29 2018-11-14 古河電気工業株式会社 蓄熱容器及び蓄熱容器を備えた蓄熱装置
JP6604721B2 (ja) * 2014-12-26 2019-11-13 永大産業株式会社 耐熱性に優れた、潜熱蓄熱材含浸蓄熱体
US20160327315A1 (en) * 2015-05-08 2016-11-10 Ricoh Company, Ltd. Heat exchanger, chemical heat pump, and production method for producing heat exchanger
JP6931821B2 (ja) * 2015-10-16 2021-09-08 国立研究開発法人宇宙航空研究開発機構 蓄熱ユニット
KR101826722B1 (ko) * 2016-04-26 2018-02-12 주식회사 하이낸드 방열테이프 및 이의 제조장치 및 제조방법
KR101828515B1 (ko) * 2016-04-27 2018-02-12 주식회사 영우 방열 필름 및 이를 포함하는 열전도성 복합 시트
FR3052549B1 (fr) * 2016-06-10 2019-10-11 Hutchinson Echangeur stockeur d'energie thermique
DE202016103148U1 (de) * 2016-06-14 2016-08-16 carpion GmbH & Co. KG Verbesserter Wärmetauscher
KR102280229B1 (ko) * 2016-06-22 2021-07-21 디아이씨 가부시끼가이샤 축열성 조성물
EP3299759A1 (en) * 2016-09-21 2018-03-28 Nederlandse Organisatie voor toegepast- natuurwetenschappelijk onderzoek TNO System and method for thermochemical storage of energy
JP2018059682A (ja) 2016-10-06 2018-04-12 株式会社豊田自動織機 化学蓄熱装置
JP2018123217A (ja) * 2017-01-31 2018-08-09 アイシン精機株式会社 化学蓄熱体造粒物

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100999414A (zh) * 2007-01-05 2007-07-18 华南理工大学 一种超多孔陶瓷基蓄热材料及其制备方法
CN101560377A (zh) * 2009-06-04 2009-10-21 河北科技大学 泡沫金属基高温相变蓄热复合材料及其制备方法
CN102061403A (zh) * 2010-10-28 2011-05-18 华南理工大学 多孔材料基体和复合相变蓄热材料及其制备方法
JP2015098582A (ja) * 2013-10-16 2015-05-28 日本ペイントホールディングス株式会社 化学蓄熱材及び化学蓄熱材形成用組成物
CN107075794A (zh) * 2014-05-19 2017-08-18 智能聚合物有限公司 柔性pcm面料
JP2016155895A (ja) * 2015-02-23 2016-09-01 太平洋セメント株式会社 化学蓄熱材成形体、その製造方法および成形体集合体
JP2016190990A (ja) * 2015-03-31 2016-11-10 日本ペイントホールディングス株式会社 化学蓄熱材及び化学蓄熱材形成用組成物
CN107429152A (zh) * 2015-03-31 2017-12-01 日本涂料控股有限公司 化学蓄热材料及化学蓄热材料形成用组合物
CN107270755A (zh) * 2016-03-31 2017-10-20 日本碍子株式会社 蓄热部件
CN107266078A (zh) * 2016-03-31 2017-10-20 日本碍子株式会社 蓄热部件
TW201831856A (zh) * 2016-12-05 2018-09-01 日商日產化學工業股份有限公司 蓄熱層形成用組成物
CN108219755A (zh) * 2017-12-29 2018-06-29 北京国能电池科技有限公司 以泡沫铝为基体的复合相变材料及其制备方法与蓄热包

Also Published As

Publication number Publication date
TWI834785B (zh) 2024-03-11
EP3901234A4 (en) 2022-09-21
TW202031862A (zh) 2020-09-01
JP2020101313A (ja) 2020-07-02
EP3901234A1 (en) 2021-10-27
US20220112421A1 (en) 2022-04-14
JP7296207B2 (ja) 2023-06-22
WO2020130066A1 (ja) 2020-06-25

Similar Documents

Publication Publication Date Title
JP4911002B2 (ja) 熱交換型熱利用装置及びその製造方法
JP5223314B2 (ja) 蓄熱装置
JP5374683B2 (ja) 化学蓄熱材成形体及びその製造方法
JP5277621B2 (ja) 化学蓄熱材成形体及びその製造方法
JP5297669B2 (ja) 化学蓄熱材複合体及びその製造方法
Funayama et al. Calcium hydroxide and porous silicon-impregnated silicon carbide-based composites for thermochemical energy storage
JP2009256517A (ja) 化学蓄熱材料、及びその製造方法
JP5300307B2 (ja) 化学蓄熱材成形体及びその製造方法
CN113227311A (zh) 板状化学蓄热体
JP7202560B2 (ja) 蓄熱反応器
JP2009256520A (ja) 化学蓄熱材複合物及びその製造方法
JP2009256519A (ja) 化学蓄熱材複合物及びその製造方法
JP5231077B2 (ja) 化学蓄熱材複合体及びその製造方法
JP5277138B2 (ja) 蓄熱器及びその製造方法
JP7520548B2 (ja) 蓄熱材組成物
JP5401782B2 (ja) 蓄熱装置及びその製造方法
JP5303159B2 (ja) 化学蓄熱材複合体
JP2022003304A (ja) 化学蓄熱装置
JP5719660B2 (ja) 化学蓄熱器及びその製造方法
JP2002162184A (ja) 蓄熱材料、蓄熱方法ならびに放熱方法
JP5303158B2 (ja) 化学蓄熱材成形体及びその製造方法
TW202210781A (zh) 蓄熱體卡匣以及蓄熱器
JP5719649B2 (ja) 化学蓄熱器及びその製造方法
Kato et al. A. 2 High-Temperature Thermochemical Energy Storage using Calcium Hydroxide and Porous Ceramic Composite
JP2019199993A (ja) 蓄熱装置

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right
TA01 Transfer of patent application right

Effective date of registration: 20220413

Address after: Tokyo

Applicant after: MITSUBISHI HEAVY INDUSTRIES, Ltd.

Address before: Kanagawa County, Japan

Applicant before: Mitsubishi Power Co.,Ltd.