CN1123527A - 制备不饱和羧酸酯用催化剂和使用该催化剂制备所述酯的方法 - Google Patents

制备不饱和羧酸酯用催化剂和使用该催化剂制备所述酯的方法 Download PDF

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Publication number
CN1123527A
CN1123527A CN94192124A CN94192124A CN1123527A CN 1123527 A CN1123527 A CN 1123527A CN 94192124 A CN94192124 A CN 94192124A CN 94192124 A CN94192124 A CN 94192124A CN 1123527 A CN1123527 A CN 1123527A
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CN
China
Prior art keywords
gram
catalyst
alkali metal
support
palladium
Prior art date
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Pending
Application number
CN94192124A
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English (en)
Chinese (zh)
Inventor
J·F·怀特
B·斯劳斯基
G·怀特
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BASF Catalysts LLC
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Engelhard Corp
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Publication of CN1123527A publication Critical patent/CN1123527A/zh
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926—Copper and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN94192124A 1993-05-25 1994-05-11 制备不饱和羧酸酯用催化剂和使用该催化剂制备所述酯的方法 Pending CN1123527A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/067,445 US5347046A (en) 1993-05-25 1993-05-25 Catalyst and process for using same for the preparation of unsaturated carboxylic acid esters
US08/067,445 1993-05-25

Publications (1)

Publication Number Publication Date
CN1123527A true CN1123527A (zh) 1996-05-29

Family

ID=22076033

Family Applications (1)

Application Number Title Priority Date Filing Date
CN94192124A Pending CN1123527A (zh) 1993-05-25 1994-05-11 制备不饱和羧酸酯用催化剂和使用该催化剂制备所述酯的方法

Country Status (10)

Country Link
US (1) US5347046A (enExample)
EP (1) EP0708684A1 (enExample)
JP (1) JP3698322B2 (enExample)
KR (1) KR960702348A (enExample)
CN (1) CN1123527A (enExample)
AU (1) AU6912994A (enExample)
BR (1) BR9406696A (enExample)
CA (1) CA2161952A1 (enExample)
TW (1) TW254934B (enExample)
WO (1) WO1994027720A1 (enExample)

Cited By (12)

* Cited by examiner, † Cited by third party
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CN1107538C (zh) * 1997-06-03 2003-05-07 国际人造丝公司 包含沉积在含铜载体上的钯和金的乙酸乙烯酯催化剂
CN1129481C (zh) * 1998-06-02 2003-12-03 国际人造丝公司 包含金属钯、铜和金的乙酸乙烯酯催化剂及其制备
TWI396588B (zh) * 2007-08-13 2013-05-21 Asahi Kasei Chemicals Corp Catalysts for the production of carboxylic acid esters, methods for their manufacture and methods for producing carboxylic acids
US8450235B2 (en) 2007-10-26 2013-05-28 Asahi Kasei Chemicals Corporation Supported composite particle material, production process of same and process for producing compounds using supported composite particle material as catalyst for chemical synthesis
CN101098754B (zh) * 2004-11-17 2013-07-17 三菱丽阳株式会社 含钯的载体催化剂的制造方法
CN104428062A (zh) * 2012-06-19 2015-03-18 庄信万丰股份有限公司 催化剂组合物
CN106582871A (zh) * 2015-10-19 2017-04-26 中国石油化工股份有限公司 醋酸烯丙酯生产所用的催化剂
CN110773163A (zh) * 2019-12-02 2020-02-11 上海华谊（集团）公司 甲基丙烯醛选择加氢制甲基烯丙醇的催化剂及其制备方法
CN112823882A (zh) * 2019-11-20 2021-05-21 Sk新技术株式会社 成型的脱氢催化剂和使用其将链烷烃转化为相应烯烃的方法
CN112996596A (zh) * 2018-10-31 2021-06-18 Sk新技术株式会社 钴基单原子脱氢催化剂及利用该催化剂由链烷烃制备相应的烯烃的方法
US20210402379A1 (en) 2020-06-25 2021-12-30 Sk Innovation Co., Ltd. Cobalt-Based Single-Atom Dehydrogenation Catalysts Having Improved Thermal Stability and Method for Producing Olefins From Corresponding Paraffins by Using the Same
US12064750B2 (en) 2020-09-17 2024-08-20 Sk Innovation Co., Ltd. Cobalt-based single-atom dehydrogenation catalysts having high selectivity and regenerability and method for producing corresponding olefins from paraffins using the same

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US5688993A (en) * 1995-12-22 1997-11-18 E. I. Du Pont De Nemours And Company Method for modifying catalyst performance during the gas phase synthesis of vinyl acetate
DE19623226A1 (de) * 1996-06-11 1997-12-18 Basf Ag Katalysatorsysteme vom Typ der Ziegler-Natta-Katalysatoren
US5693586A (en) * 1996-06-28 1997-12-02 Hoechst Celanese Corporation Palladium-gold catalyst for vinyl acetate production
US5731457A (en) * 1997-06-03 1998-03-24 Hoechst Celanese Corporation Vinyl acetate process utilizing a palladium-gold-copper catalyst
DE19734975A1 (de) * 1997-08-13 1999-03-11 Hoechst Ag Schalenkatalysator, Verfahren zu dessen Herstellung sowie Verwendung, insbesondere zur Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat
US5948724A (en) 1997-10-28 1999-09-07 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium and gold and cupric acetate
US6072078A (en) * 1997-12-12 2000-06-06 Celanese International Corporation Vinyl acetate production using a catalyst comprising palladium, gold, copper and any of certain fourth metals
GB9810928D0 (en) * 1998-05-22 1998-07-22 Bp Chem Int Ltd Catalyst and process
US6015769A (en) * 1998-06-02 2000-01-18 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium, gold and copper supported on a carrier and prepared with potassium aurate
JP2000070718A (ja) * 1998-06-17 2000-03-07 Nippon Shokubai Co Ltd ベンジルエステルの製造方法
US6303537B1 (en) 1999-11-17 2001-10-16 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication
CN1090997C (zh) * 2000-04-30 2002-09-18 中国石油化工集团公司 一种选择加氢除炔多金属催化剂
US20040242918A1 (en) * 2000-06-27 2004-12-02 Showa Denko K.K Support and catalyst for use in producing lower aliphatic carboxylic acid ester, process for producing the catalyst and process for producing lower aliphatic carboxylic acid ester using the catalyst
US6534438B1 (en) * 2000-07-26 2003-03-18 Bp Chemicals Limited Catalyst composition
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US6576665B2 (en) 2001-04-03 2003-06-10 Braintree Laboratories, Inc. Encapsulated calcium acetate caplet and a method for inhibiting gastrointestinal phosphorous absorption
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US6620965B1 (en) * 2002-03-08 2003-09-16 Catalytic Distillation Technologies Process for vinyl acetate
US8563032B2 (en) 2005-12-05 2013-10-22 Roxane Laboratories, Inc. Formulation and manufacturing process for calcium acetate capsules
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US7825204B2 (en) * 2006-12-19 2010-11-02 Lyondell Chemical Technology, L.P. Inorganic oxide extrudates
JP2008173629A (ja) * 2006-12-20 2008-07-31 Showa Denko Kk アシルオキシ化反応用触媒およびその製造方法
JP2009220099A (ja) * 2008-02-20 2009-10-01 Showa Denko Kk 低級脂肪族カルボン酸製造用触媒の製造方法
US8173830B2 (en) * 2009-05-07 2012-05-08 Celanese International Corporation Vinyl ester production from acetylene and carboxylic acid utilizing homogeneous catalyst
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GB201110850D0 (en) 2011-03-04 2011-08-10 Johnson Matthey Plc Catalyst and mehtod of preparation
DE102012008715A1 (de) * 2012-05-03 2013-11-07 Clariant Produkte (Deutschland) Gmbh Herstellung von Schalenkatalysatoren in einer Beschichtungsvorrichtung
DE102012008714A1 (de) * 2012-05-03 2013-11-07 Clariant Produkte (Deutschland) Gmbh Vorimprägnierung von Schalenkatalysatoren mit einem Acetat
TWI510293B (zh) * 2012-09-19 2015-12-01 Clariant Int Ltd 用於製造烯基羧酸酯之銅促進殼催化劑，及用於製造該銅促進殼催化劑之方法。
US10596552B2 (en) * 2017-06-21 2020-03-24 China Petroleum & Chemical Corporation Catalyst for preparing cumene and use thereof
WO2018235705A1 (ja) * 2017-06-23 2018-12-27 エヌ・イーケムキャット株式会社 酢酸ビニル合成用パラジウム－金担持触媒の製造方法
US20210300848A1 (en) * 2018-09-17 2021-09-30 Sabic Global Technologies B.V. Catalysts for producing alcohols and ethers from synthesis gas
CN112642480B (zh) * 2019-10-10 2022-12-09 中国石油化工股份有限公司 乙烯法醋酸乙烯催化剂
EP4252905A4 (en) * 2020-11-27 2024-10-23 Resonac Corporation PROCESS FOR MANUFACTURING CATALYST FOR MANUFACTURING VINYL ACETATE AND PROCESS FOR MANUFACTURING VINYL ACETATE

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Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1107538C (zh) * 1997-06-03 2003-05-07 国际人造丝公司 包含沉积在含铜载体上的钯和金的乙酸乙烯酯催化剂
CN1129481C (zh) * 1998-06-02 2003-12-03 国际人造丝公司 包含金属钯、铜和金的乙酸乙烯酯催化剂及其制备
CN101098754B (zh) * 2004-11-17 2013-07-17 三菱丽阳株式会社 含钯的载体催化剂的制造方法
CN105214683B (zh) * 2007-08-13 2018-02-09 旭化成株式会社 羧酸酯制造用催化剂、其制造方法、以及羧酸酯的制造方法
TWI396588B (zh) * 2007-08-13 2013-05-21 Asahi Kasei Chemicals Corp Catalysts for the production of carboxylic acid esters, methods for their manufacture and methods for producing carboxylic acids
US8461373B2 (en) 2007-08-13 2013-06-11 Asahi Kasei Chemicals Corporation Catalyst for producing carboxylic acid esters, process for producing same and process for producing carboxylic acid esters
CN105148921A (zh) * 2007-08-13 2015-12-16 旭化成化学株式会社 羧酸酯制造用催化剂、其制造方法、以及羧酸酯的制造方法
CN105214683A (zh) * 2007-08-13 2016-01-06 旭化成化学株式会社 羧酸酯制造用催化剂、其制造方法、以及羧酸酯的制造方法
US8450235B2 (en) 2007-10-26 2013-05-28 Asahi Kasei Chemicals Corporation Supported composite particle material, production process of same and process for producing compounds using supported composite particle material as catalyst for chemical synthesis
TWI477453B (zh) * 2007-10-26 2015-03-21 Asahi Kasei Chemicals Corp A composite particle support, a method for producing the composite particle support, and a method for producing the compound using the composite particle support as a catalyst for chemical synthesis
CN104428062A (zh) * 2012-06-19 2015-03-18 庄信万丰股份有限公司 催化剂组合物
CN106582871A (zh) * 2015-10-19 2017-04-26 中国石油化工股份有限公司 醋酸烯丙酯生产所用的催化剂
CN112996596A (zh) * 2018-10-31 2021-06-18 Sk新技术株式会社 钴基单原子脱氢催化剂及利用该催化剂由链烷烃制备相应的烯烃的方法
CN112996596B (zh) * 2018-10-31 2023-10-03 Sk新技术株式会社 钴基单原子脱氢催化剂及利用该催化剂由链烷烃制备相应的烯烃的方法
US12161999B2 (en) 2018-10-31 2024-12-10 Sk Innovation Co., Ltd. Cobalt-based single-atom dehydrogenation catalysts and method for producing corresponding olefins from paraffins using the same
CN112823882A (zh) * 2019-11-20 2021-05-21 Sk新技术株式会社 成型的脱氢催化剂和使用其将链烷烃转化为相应烯烃的方法
CN110773163A (zh) * 2019-12-02 2020-02-11 上海华谊（集团）公司 甲基丙烯醛选择加氢制甲基烯丙醇的催化剂及其制备方法
CN110773163B (zh) * 2019-12-02 2023-07-07 上海华谊（集团）公司 甲基丙烯醛选择加氢制甲基烯丙醇的催化剂及其制备方法
US20210402379A1 (en) 2020-06-25 2021-12-30 Sk Innovation Co., Ltd. Cobalt-Based Single-Atom Dehydrogenation Catalysts Having Improved Thermal Stability and Method for Producing Olefins From Corresponding Paraffins by Using the Same
US11766664B2 (en) 2020-06-25 2023-09-26 Sk Innovation Co., Ltd. Cobalt-based single-atom dehydrogenation catalysts having improved thermal stability and method for producing olefins from corresponding paraffins by using the same
US12064750B2 (en) 2020-09-17 2024-08-20 Sk Innovation Co., Ltd. Cobalt-based single-atom dehydrogenation catalysts having high selectivity and regenerability and method for producing corresponding olefins from paraffins using the same

Also Published As

Publication number Publication date
CA2161952A1 (en) 1994-12-08
AU6912994A (en) 1994-12-20
JP3698322B2 (ja) 2005-09-21
EP0708684A1 (en) 1996-05-01
JPH08510685A (ja) 1996-11-12
TW254934B (enExample) 1995-08-21
BR9406696A (pt) 1996-03-19
US5347046A (en) 1994-09-13
KR960702348A (ko) 1996-04-27
WO1994027720A1 (en) 1994-12-08

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