CN108884185A - 用于生产环氧化的聚合物的方法 - Google Patents
用于生产环氧化的聚合物的方法 Download PDFInfo
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- CN108884185A CN108884185A CN201780022017.9A CN201780022017A CN108884185A CN 108884185 A CN108884185 A CN 108884185A CN 201780022017 A CN201780022017 A CN 201780022017A CN 108884185 A CN108884185 A CN 108884185A
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- polymer
- solvent
- epoxidation
- anhydride
- epoxidized
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- DMEGYFMYUHOHGS-UHFFFAOYSA-N cycloheptane Chemical compound C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 238000007306 functionalization reaction Methods 0.000 description 2
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- SHFJWMWCIHQNCP-UHFFFAOYSA-M hydron;tetrabutylazanium;sulfate Chemical compound OS([O-])(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC SHFJWMWCIHQNCP-UHFFFAOYSA-M 0.000 description 2
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- MWSPFHZPVVWJCO-UHFFFAOYSA-M hydron;methyl(trioctyl)azanium;sulfate Chemical compound OS([O-])(=O)=O.CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC MWSPFHZPVVWJCO-UHFFFAOYSA-M 0.000 description 1
- RULHPTADXJPDSN-UHFFFAOYSA-M hydron;tetrahexylazanium;sulfate Chemical compound OS([O-])(=O)=O.CCCCCC[N+](CCCCCC)(CCCCCC)CCCCCC RULHPTADXJPDSN-UHFFFAOYSA-M 0.000 description 1
- YAJHSQKPLBOAEV-UHFFFAOYSA-M hydron;tetrahexylphosphanium;sulfate Chemical compound OS([O-])(=O)=O.CCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC YAJHSQKPLBOAEV-UHFFFAOYSA-M 0.000 description 1
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- LSACYLWPPQLVSM-UHFFFAOYSA-N isobutyric acid anhydride Chemical compound CC(C)C(=O)OC(=O)C(C)C LSACYLWPPQLVSM-UHFFFAOYSA-N 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
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- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
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- DCUFMVPCXCSVNP-UHFFFAOYSA-N methacrylic anhydride Chemical compound CC(=C)C(=O)OC(=O)C(C)=C DCUFMVPCXCSVNP-UHFFFAOYSA-N 0.000 description 1
- QLPMKRZYJPNIRP-UHFFFAOYSA-M methyl(trioctyl)azanium;bromide Chemical compound [Br-].CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC QLPMKRZYJPNIRP-UHFFFAOYSA-M 0.000 description 1
- AMUCTDNDAXEAOW-UHFFFAOYSA-M methyl(trioctyl)azanium;iodide Chemical compound [I-].CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC AMUCTDNDAXEAOW-UHFFFAOYSA-M 0.000 description 1
- UEPYVEILIFKOAA-UHFFFAOYSA-N methyl(trioctyl)azanium;nitrate Chemical compound [O-][N+]([O-])=O.CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC UEPYVEILIFKOAA-UHFFFAOYSA-N 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- XKBGEWXEAPTVCK-UHFFFAOYSA-M methyltrioctylammonium chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC XKBGEWXEAPTVCK-UHFFFAOYSA-M 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 235000010460 mustard Nutrition 0.000 description 1
- XRSFQLOANYRGRT-UHFFFAOYSA-N n,n-dimethyldocosan-1-amine;hydrochloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[NH+](C)C XRSFQLOANYRGRT-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 229920006173 natural rubber latex Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- DUCKXCGALKOSJF-UHFFFAOYSA-N pentanoyl pentanoate Chemical compound CCCCC(=O)OC(=O)CCCC DUCKXCGALKOSJF-UHFFFAOYSA-N 0.000 description 1
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- REJGOFYVRVIODZ-UHFFFAOYSA-N phosphanium;chloride Chemical compound P.Cl REJGOFYVRVIODZ-UHFFFAOYSA-N 0.000 description 1
- 150000004714 phosphonium salts Chemical group 0.000 description 1
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- 238000006116 polymerization reaction Methods 0.000 description 1
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- ARJOQCYCJMAIFR-UHFFFAOYSA-N prop-2-enoyl prop-2-enoate Chemical compound C=CC(=O)OC(=O)C=C ARJOQCYCJMAIFR-UHFFFAOYSA-N 0.000 description 1
- CZPZWMPYEINMCF-UHFFFAOYSA-N propaneperoxoic acid Chemical compound CCC(=O)OO CZPZWMPYEINMCF-UHFFFAOYSA-N 0.000 description 1
- WYVAMUWZEOHJOQ-UHFFFAOYSA-N propionic anhydride Chemical compound CCC(=O)OC(=O)CC WYVAMUWZEOHJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 125000005207 tetraalkylammonium group Chemical group 0.000 description 1
- 150000005622 tetraalkylammonium hydroxides Chemical class 0.000 description 1
- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 description 1
- RKHXQBLJXBGEKF-UHFFFAOYSA-M tetrabutylphosphanium;bromide Chemical compound [Br-].CCCC[P+](CCCC)(CCCC)CCCC RKHXQBLJXBGEKF-UHFFFAOYSA-M 0.000 description 1
- IBWGNZVCJVLSHB-UHFFFAOYSA-M tetrabutylphosphanium;chloride Chemical compound [Cl-].CCCC[P+](CCCC)(CCCC)CCCC IBWGNZVCJVLSHB-UHFFFAOYSA-M 0.000 description 1
- CCIYPTIBRAUPLQ-UHFFFAOYSA-M tetrabutylphosphanium;iodide Chemical compound [I-].CCCC[P+](CCCC)(CCCC)CCCC CCIYPTIBRAUPLQ-UHFFFAOYSA-M 0.000 description 1
- KUBXSUKJFAQDPV-UHFFFAOYSA-N tetrabutylphosphanium;nitrate Chemical compound [O-][N+]([O-])=O.CCCC[P+](CCCC)(CCCC)CCCC KUBXSUKJFAQDPV-UHFFFAOYSA-N 0.000 description 1
- SYZCZDCAEVUSPM-UHFFFAOYSA-M tetrahexylazanium;bromide Chemical compound [Br-].CCCCCC[N+](CCCCCC)(CCCCCC)CCCCCC SYZCZDCAEVUSPM-UHFFFAOYSA-M 0.000 description 1
- ODTSDWCGLRVBHJ-UHFFFAOYSA-M tetrahexylazanium;chloride Chemical compound [Cl-].CCCCCC[N+](CCCCCC)(CCCCCC)CCCCCC ODTSDWCGLRVBHJ-UHFFFAOYSA-M 0.000 description 1
- VRKHAMWCGMJAMI-UHFFFAOYSA-M tetrahexylazanium;iodide Chemical compound [I-].CCCCCC[N+](CCCCCC)(CCCCCC)CCCCCC VRKHAMWCGMJAMI-UHFFFAOYSA-M 0.000 description 1
- LHIGLAVLYYKORA-UHFFFAOYSA-N tetrahexylazanium;nitrate Chemical compound [O-][N+]([O-])=O.CCCCCC[N+](CCCCCC)(CCCCCC)CCCCCC LHIGLAVLYYKORA-UHFFFAOYSA-N 0.000 description 1
- ZDPBCYYDJHTNKC-UHFFFAOYSA-M tetrahexylphosphanium;bromide Chemical compound [Br-].CCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC ZDPBCYYDJHTNKC-UHFFFAOYSA-M 0.000 description 1
- PJSMIDZMHMDOSX-UHFFFAOYSA-M tetrahexylphosphanium;chloride Chemical compound [Cl-].CCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC PJSMIDZMHMDOSX-UHFFFAOYSA-M 0.000 description 1
- CKNDHLPGNJKRLC-UHFFFAOYSA-N tetrahexylphosphanium;nitrate Chemical compound [O-][N+]([O-])=O.CCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC CKNDHLPGNJKRLC-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- 238000005829 trimerization reaction Methods 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/08—Epoxidation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/04—Oxidation
- C08C19/06—Epoxidation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/08—Isoprene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L15/00—Compositions of rubber derivatives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Tires In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
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| US201662318387P | 2016-04-05 | 2016-04-05 | |
| US62/318,387 | 2016-04-05 | ||
| PCT/US2017/025857 WO2017176686A1 (en) | 2016-04-05 | 2017-04-04 | Process for producing epoxidized polymers |
Publications (1)
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| CN108884185A true CN108884185A (zh) | 2018-11-23 |
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| CN201780022017.9A Pending CN108884185A (zh) | 2016-04-05 | 2017-04-04 | 用于生产环氧化的聚合物的方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US10836841B2 (https=) |
| EP (1) | EP3440116A4 (https=) |
| JP (2) | JP2019513866A (https=) |
| KR (1) | KR20180123585A (https=) |
| CN (1) | CN108884185A (https=) |
| CA (1) | CA3018778A1 (https=) |
| MX (1) | MX2018012259A (https=) |
| WO (1) | WO2017176686A1 (https=) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113072652A (zh) * | 2021-04-25 | 2021-07-06 | 岭南师范学院 | 一种定量环氧化天然橡胶及其制备方法 |
| CN116135887A (zh) * | 2021-11-17 | 2023-05-19 | 北京化工大学 | 一种环氧化橡胶的制备方法、环氧化橡胶及应用 |
| CN116162296A (zh) * | 2021-11-25 | 2023-05-26 | 北京化工大学 | 一种高性能绿色轮胎的胎面材料及其制备方法和应用 |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020132236A1 (en) | 2018-12-21 | 2020-06-25 | Bridgestone Corporation | Processes for increasing the molecular weight of guayule natural rubber |
| KR102394623B1 (ko) * | 2020-09-01 | 2022-05-06 | 김진국 | 에폭시화 고무의 제조방법 |
| US20230382007A1 (en) * | 2020-10-16 | 2023-11-30 | Arizona Board Of Regents On Behalf Of The University Of Arizona | Particleboards including modified guayule resins/soy protein resin blends and associated methods for forming same |
| CN116162205B (zh) * | 2021-11-25 | 2025-09-16 | 北京化工大学 | 一种环氧化溶聚丁苯橡胶及其制备方法和应用 |
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| US5034470A (en) * | 1990-09-04 | 1991-07-23 | The Goodyear Tire & Rubber Company | Process for the preparation of epoxidized synthetic cis-1,4-polyisoprene |
| CN1292388A (zh) * | 2000-10-29 | 2001-04-25 | 青岛化工学院 | 环氧化反式－1,4－聚异戊二烯的合成方法 |
| US20020077427A1 (en) * | 1995-12-14 | 2002-06-20 | Takai Hideyuki | Process for producing epoxidized organic polymer, thermoplastic resin composition, primer composition, unvulcanized rubber composition, rubber moldings, and process for producing the moldings |
| US20080300367A1 (en) * | 2007-06-01 | 2008-12-04 | Abhimanyu Onkar Patil | Impact modification and functionalization of copolymers of olefins and dienes |
| CN103130990A (zh) * | 2012-10-03 | 2013-06-05 | 大连理工大学 | 星形梳状聚乳酸及其制备方法 |
| CN103570848A (zh) * | 2013-10-24 | 2014-02-12 | 沈阳化工大学 | 环氧化天然杜仲胶的合成方法 |
| CN103910816A (zh) * | 2014-04-12 | 2014-07-09 | 青岛科技大学 | 一种改进的环氧化反式异戊橡胶制备方法 |
| CN104768938A (zh) * | 2012-10-26 | 2015-07-08 | 陶氏环球技术有限公司 | 新颖环氧化合物:1,3-二环氧乙烷基环戊烷衍生物 |
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|---|---|---|---|---|
| US3305515A (en) | 1964-05-06 | 1967-02-21 | Exxon Research Engineering Co | Solvent for polybutadiene rubber |
| US4219627A (en) | 1977-03-09 | 1980-08-26 | The Firestone Tire & Rubber Company | Process for the preparation of block copolymers |
| US5747598A (en) | 1990-01-16 | 1998-05-05 | Mobil Oil Corporation | Epoxidized solid elastomeric copolymers |
| US5399626A (en) | 1991-04-29 | 1995-03-21 | Shell Oil Company | Viscous conjugated diene block copolymers |
| US5310819A (en) | 1992-01-23 | 1994-05-10 | The United States Of America As Represented By The Secretary Of The Navy | Surface epoxidation of elastomers |
| DE69404740T2 (de) | 1993-05-13 | 1998-01-22 | Kao Corp | Verfahren zur Herstellung von Rohkautschuk |
| JP3722238B2 (ja) * | 1995-12-14 | 2005-11-30 | ダイセル化学工業株式会社 | エポキシ化有機系重合体の製造方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113072652A (zh) * | 2021-04-25 | 2021-07-06 | 岭南师范学院 | 一种定量环氧化天然橡胶及其制备方法 |
| CN113072652B (zh) * | 2021-04-25 | 2022-06-28 | 岭南师范学院 | 一种定量环氧化天然橡胶及其制备方法 |
| CN116135887A (zh) * | 2021-11-17 | 2023-05-19 | 北京化工大学 | 一种环氧化橡胶的制备方法、环氧化橡胶及应用 |
| CN116162296A (zh) * | 2021-11-25 | 2023-05-26 | 北京化工大学 | 一种高性能绿色轮胎的胎面材料及其制备方法和应用 |
Also Published As
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|---|---|
| US20190127495A1 (en) | 2019-05-02 |
| JP2019513866A (ja) | 2019-05-30 |
| MX2018012259A (es) | 2019-02-07 |
| JP2022068188A (ja) | 2022-05-09 |
| EP3440116A1 (en) | 2019-02-13 |
| KR20180123585A (ko) | 2018-11-16 |
| WO2017176686A1 (en) | 2017-10-12 |
| EP3440116A4 (en) | 2019-12-18 |
| US10836841B2 (en) | 2020-11-17 |
| CA3018778A1 (en) | 2017-10-12 |
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